Add time:09/06/2019 Source:sciencedirect.com
Publisher SummaryThis chapter discusses carbonic acid and its derivatives, a large and diverse group of compounds. Metacarbonic acid and its esters, such as carbon dioxide, esters of carbonic acid, anhydrides of primary esters of carbonic acid, mixed anhydrides of primary carbonates, and mono-carboxylic acids are also profiled with detailed information on general methods of preparation, properties, and typical reactions. Halides of carbonic acid, sulfur analogues of carbonic acid, and their derivatives, such as carbon oxysulfide and carbon disulfide, thiocarbonic acids and their halides, such as thiophosgene, amides, and related derivatives of carbonic acid, and the thiocarbonic acids are illustrated in a systematic manner. Special stress is evident in the discussion on urea and its derivatives, such as halogenoureas, ureides, and so on because of its commercial relevance as a fertilizer. Derivatives of iminodicarboxylic acid, such as biuret and nitrilotricarboxylic acid, sulfur analogues of carbamic acid, and hydrazino, azo, and azido derivatives of thiocarbonic acid are also emphasized in this chapter. Sulfur compounds of cyanogens, such as thiocyanic acid, cyanamide and its derivatives, and derivatives of carbodi-imide and orthocarbonic acid are also covered.
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