Add time:09/24/2019 Source:sciencedirect.com
Poly(l-cysteine) bearing imidazolium salts, namely poly(S-(2-(3-(N-butylimidazolium tetrafluoroborate)propoxycarbonyl)ethyl)-l-cysteine) (P(ImBF4)LC) was synthesized by ring-opening polymerization of S-(2-(3-chloropropoxycarbonyl)ethyl)-l-cysteine based N-carboxyanhydride (CPLC-NCA), nucleophilic substitution of poly(S-(2-(3-chloropropoxycarbonyl)ethyl)-l-cysteine) (PCPLC), and subsequent ion-exchange reaction. FTIR and CD analysis revealed the presence of β-sheet conformation of P(ImBF4)LC in the solid-state and aqueous solution, respectively. P(ImBF4)LC with short degree of polymerization (DP = 10) were able to show a distinct upper critical solution temperature (UCST)-type phase behavior at a low critical concentration (1.6 mg mL−1) in water. Variable-temperature UV–vis spectroscopy results revealed that the UCST-type solution phase transition temperature (Tpt) of P(ImBF4)LC in aqueous solutions increased with increasing of polymer concentration or NaBF4 concentration, whereas it decreased by addition of NaI or NaCl.
We also recommend Trading Suppliers and Manufacturers of L-Cysteine methyl ester hydrochloride (cas 18598-63-5). Pls Click Website Link as below: cas 18598-63-5 suppliers
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View