Add time:09/25/2019 Source:sciencedirect.com
A convergent, stereocontrolled synthesis of (3S, 4S, 5E, 7E)-3-amino-8-(4-bromophenyl)-4-hydroxy-6-methyl-5,7-octadienoic acid (Aboa, 2), a constituent of theonellamide F from a marine sponge, has been achieved. The key steps include the carboalumination of the enyne 5a, the formation of the ate complex 16, followed by the reaction with the aluminum complex 10 of the homoserinal derivative.
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