Add time:09/09/2019         Source:sciencedirect.com

The formation of positive and negative ions resulting from the electron bombardment of PHOSPHORUS TRIFLUORIDE (cas 13659-65-9) and difluorocyanophosphine has been studied as a function of the electron energy. Appearance potentials have been measured for these ions and various inoisation process suggested to explain their formation; vertical onset behaviour is a feature of the formation of several of the negative ions.From these data bond dissociation energies of several neutral and ionic species have been determined, including D(PF2—CN) ⩽ 3.4±0.5 eV.

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