Add time:09/07/2019 Source:sciencedirect.com
Diiron(II)-(III) complexes [Fe2L(B2](X)2 are prepared, where HL represents 2, 6-bis[bis(2-pyridylmethyl)aminomethyl]-4- methylphenol, HB is carboxylic acid or dicarboxylic acid, and X is ClO4− or BF4−. The valence state of the irons of some complexes is delocalized in the Mössbauer time scale (1 × 10−7 s) at 296 K and localized at 78 K. The valence state of the irons of the other complexes is localized at the temperature range of 78–296 K.
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