Add time:09/25/2019         Source:sciencedirect.com

Enthalpies of solution of LiCl and of LiCl · H2O in water at 298.15 K were measured. Results with different procedures of sample handling are discussed, including the use of the equilibrium between LiCl · H2O and its aqueous saturated solution as a hygrostat. The molar enthalpies of solution extrapolated to infinite dilution are ΔsolHm∞(LiCl, 298.15 K) = −(36653 ± 90) J · mol−1 and ΔsolHm∞(LiCl · H2O, 298.15 K) = −(18562 ± 54) J · mol−1. The value for the monohydrate has been calculated by assuming that the excess water in the sample over the theoretical, is present as an aqueous saturated solution.

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