Add time:09/10/2019 Source:sciencedirect.com
An efficient heterogeneously palladium catalysed procedure for the vinylation of aryl iodides and bromides is reported. Using common reaction conditions (Pd/C 2 mol %, AcONa·3H2O, NMP or NMP/H2O), good to complete conversions (40–100%) with high selectivities (79–100%) towards the expected vinylaromatic were achieved.
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