Add time:09/07/2019 Source:sciencedirect.com
A new amine bis(phenol) ligand (HLPEA), was synthesized and characterized by IR, 1H NMR spectroscopic techniques and elemental analyses. The mononuclear iron(III) complex (FeLPEA) of this ligand has been prepared and characterized by IR and UV–Vis spectroscopic techniques, ESI-MS, elemental analyses and magnetic susceptibility studies. The molecular mass of complex was determined by ESI-MS which is corresponding to a mononuclear iron(III) complex consist of amine bis(phenolate) ligand coordinated to Fe(III) including chlorine atoms and solvent molecule. The variable temperature magnetic susceptibility indicates paramagnetic character of complex. To determine the formation constant of the complex, multivariate hard modeling method was applied on spectral data collected throughout the titration of Fe(III) with ligand.FeLPEA shows good catalytic activity in cleavage oxygenation of 3,5-di-tert-butyl catechol in the presence of dioxygen at room temperature with a nearly complete conversion and particularly extradiol cleavage mechanism.
We also recommend Trading Suppliers and Manufacturers of N-PHENYLETHYLENEDIAMINE (cas 1664-40-0). Pls Click Website Link as below: cas 1664-40-0 suppliers
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View