Add time:10/01/2019 Source:sciencedirect.com
Two novel dioxygen heptaoxomolybdates K5[Mo7O22(O2)(OH)]Cl·6H2O (1) and K5[Mo7O22(O2)(O2)]·8H2O (2) were isolated from the solution of peroxo molybdate accidently. The solids were characterized by IR, EPR and X-ray single crystal analysis. Complex 1 contains a superoxo group with a short bond distance 1.27(1) Å, while 2 is a mixed complex with peroxo and superoxo groups [1.43(1), 1.27(1) Å]. All of the dioxygen groups coordinate to molybdenum atoms in side-on (η2) fashion. The two complexes are short-lived and will decompose into peroxo molybdates K5[Mo7O21(O2)2(OH)]·6H2O (3) and K6[Mo7O22(O2)2]·9H2O (4) very quickly.
We also recommend Trading Suppliers and Manufacturers of Iron(II) molybdate(VI) (cas 13718-70-2). Pls Click Website Link as below: cas 13718-70-2 suppliers
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View