Add time:09/24/2019 Source:sciencedirect.com
Five derivatives of mesoionic 1,2,3,4-thiatriazolo-5-aminide and its salts were synthesized. The structures of the compounds were examined by 1H, 13C, 14N and 15N NMR techniques. The protonation of the compounds occurs on the nitrogen atoms of the exocyclic group; one or two molecules of acid are bonded, depending on the compound structure.The investigated derivatives are supposed to be a chelate type ligand binding metal cation. Some preliminary investigations on compound interaction with metal cation were performed by VIS/UV technique.
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