Add time:09/25/2019 Source:sciencedirect.com
Monoacetate 3 is a synthetic equivalent of asymmetrized tris (hydroxymethyl)methane 1, which is a new chiral building block endowed with latent C3v symmetry. Thanks to this property, starling from a single enantiomer 3, it is possible to get not only both (R) and (S) aldehydes 7, but also all the stereoisomers deriving from addition of a C-nucleophile to 7, just relying on a single diastereocontrol (double stereodivergency).
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