Add time:09/09/2019 Source:sciencedirect.com
The conformations of various conformers of the molecules methylaminomethanol, 1-methoxymethylamine and 1-methoxy-N,N-dimethylmethylamine, all of which contain an N-C-O unit, were determined by an ab initio method using the 4-21G basis set and complete geometrical optimization. The results were interpreted in terms of anomeric interactions: the most stable conformers of all three molecules have their lone pairs antiperiplanar to their polar bonds.
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