Add time:09/10/2019         Source:sciencedirect.com

The mechanism for the direct photolysis of 4-(methylthio)phenylacetic acid (4-MTPA) in acetonitrile was investigated using steady-state and laser flash photolysis. A variety of primary stable photoproducts was found under steady-state, 254 nm irradiation of acetonitrile solutions including carbon dioxide (photodecarboxylation), phenylacetic acid, dimethyl disulfide, methyl p-tolyl sulfide, 4-(methylthio)benzaldehyde, 4-(methylthio)benzyl alcohol and secondary stable photoproducts including toluene, benzyl alcohol, benzaldehyde, 1,2-diphenylethane. These stable photoproducts were identified and characterized using HPLC, GC, GC–MS, and UV–Vis methods. Quantum yields were determined for the formation of the various stable products in steady-state irradiations in the absence and in the presence of oxygen. Following laser flash photolysis (266 nm Nd:YAG laser) a variety of transients (e.g., the 4-MTPA triplet state and the sulfur-centered radical cation, H3CS+C6H4CH2COOH) was found. A detailed mechanism of the primary and secondary processes is proposed and discussed. The photoinduced CC bond cleavages are shown to result from an excited-singlet reaction pathway, and the CS bond cleavages follow a triplet pathway. The validity of this proposed mechanism was supported by an analysis of the quantum yields of stable products and their transient precursors. The results from excited-state quenching by oxygen are also consistent with the proposed mechanism.

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