Add time:09/25/2019 Source:sciencedirect.com
The microwave spectrum of α-methyl-γ-butyrolactone has been examined in the frequency region 18.0–40.0 GHz. Transitions in the ground and four excited states have been assigned for a ring-twisted-like conformation species in which the methyl group is in the equatorial position. Internal rotation splittings were absent in all observed transitions (up to J = 38), which implies a lower limit for the barrier of ∼3.5 kcal mol−1. The dipole moment components determined from Stark effect measurements are μa = 1.21(2) D, μb = 4.36(5) D, and μc = 0.573(3) D, with μtotal = 4.56(5) D. Despite an intensive effort, no transitions belonging to another species could be identified. A preliminary description of a computer-controlled spectrometer is also given.
We also recommend Trading Suppliers and Manufacturers of ALPHA-METHYL-GAMMA-BUTYROLACTONE (cas 1679-47-6). Pls Click Website Link as below: cas 1679-47-6 suppliers
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View