Add time:09/30/2019 Source:infona.pl
ASARININ (cas 133-04-0), a furo-furan lignan compound with two benzyl-ethereal carbons of opposite stereochemistry, was monooxidised at a selected centre by DMD to a chiral substituted tetrahydrofuran. Use of a dilute solution of DMD was crucial for the success of the process. The stereochemistry of the product was confirmed by a similar oxidation of sesamin, the C-7' isomer of asarinin.
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