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The adsorption behavior of zinc(II) dimethyldithiocarbamate (Ziram) was studied on the surface of a poly‐o‐toluidine Zr(IV) phosphate nanocomposite cation exchanger. A spectrophotometric method based on the conversion of Ziram into a copper dimethyldithiocarbamate complex was applied for the study of Ziram at the maximum absorption wavelength of 437 nm. A Ziram‐ sensitive membrane electrode was fabricated with poly‐o‐toluidine Zr(IV) phosphate (an electroactive composite material). The sensitivity of Ziram for the composite cation‐exchange material was monitored with potentiometric methods. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011
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