Add time:09/29/2019 Source:infona.pl
Copolymerization of meta-phenylenediamine (mPD) and ortho-phenetidine (PHT) was performed by three facile electropolymerization techniques including cyclic voltammetry, constant potential and constant current on platinum electrodes in H 2 SO 4 . The electrochemically functional characteristics, including electroactivity and electrochromism, of the polymers formed are significantly dependent on mPD/PHT ratios and the electropolymerization technique. It is interesting that the black mPD/PHT copolymers obtained by the three electropolymerizations were all soluble in DMSO, i.e., electropolymerized mPD/PHT copolymers exhibit higher solubility than corresponding copolymers produced by chemical oxidation. During the cyclic voltammetry electropolymerization, a significant inhibition effect of mPD monomer on the PHT electropolymerization was observed.
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