Add time:07/17/2019         Source:sciencedirect.com

A new generation of green solvent, deep eutectic solvents (DESs), are being received increased interest in the fields of organic synthesis, electrochemistry, catalysis and oxidative desulfurization (ODS) process. Despite possessing high ODS activity, little is known for the mechanism of the excellent desulfurization performance of DES. In this study, a class of acidic eutectic mixture was prepared with different molar ratios of acetamide and glutaric acid. It was found that desulfurization process was significantly affected by the composition of prepared DES. Under optimal conditions, the desulfurization efficiencies of acetamide/glutaric acid (molar ratio 1 : 2) DES was capable to reach up to 99% within only 3 h.Density functional theory (DFT) calculation revealed that acetamide/glutaric acid DES possessed intrinsic peroxidase-like property and reduced greatly TS barriers in oxidation process. The synergy cooperation of acetamide and carboxylate likes the active site of enzyme, achieving the catalytic oxidation of dibenzothiophene (DBT). In addition, this DES system was successfully applied for the deep oxidation desulfurization of real fuels, which demonstrated extraordinary catalytic performances.

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