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The dimethyldioxirane (cas 157-26-6) (DMD) promoted oxidative decomplexation of Fischer carbene complex 1, which contains a conjugated enamino moiety, was investigated. Thus, treatment of 1 with 3 molecular equivalents of DMD afforded a 52% yield of amide 3 as unique isolable organic product. When the reaction was performed with 1 molecular equivalent of DMD the formation of the enol intermediate 15 was evidenced by its capture as the tetrafluoroboric acid salt 16. This salt was unstable and when it was exposed to air gave rise to amide 3 and to low amounts of ethyl benzoate and acetophenone. These results indicate that the presence of an enamino group conjugated to the Fischer carbene moiety inverts the chemoselectivity previously observed in the DMD promoted decomplexation of these compounds. Thus, the major pathway involves the oxidation of the enamino double bond through the formation of an enol intermediate which reacts with oxygen to give products resulting from the breakdown of the molecule.
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