Solvothermal synthesis and structural characterization of a novel one-dimensional organotin polymer involving high centrosymmetric units containing polyfunctional ligand 4-hydroxy-2-mercapto-6-methylpyrimidine-Science-Chemical Encyclopedia-lookchem

Solvothermal synthesis and structural characterization of a novel one-dimensional organotin polymer involving high centrosymmetric units containing polyfunctional ligand 4-Hydroxy-2-mercapto-6-methylpyrimidine (cas 195-64-2)
Add time:09/29/2019 Source:infona.pl

The self-assembly reaction of 4-hydroxy-2-mercapto-6-methylpyrimidine, KOH and di-n-butyltin dichloride in CH 3 OH and H 2 O (V/V=1:1) under solvothermal conditions (150°C) affords a novel one-dimensional infinite polymeric chain complex 1, which involves high centrosymmetric units containing centrosymmetric hydrolysis ladders and unhydrolyzed Bu 2 Sn(IV) moieties.

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