Add time:09/28/2019         Source:infona.pl

The reaction of PTCDA (Perylene (cas 198-53-0)‐3,4,9,10‐tetracarboxylic dianhydride) with an alcohol, a bromoalkane, and an alkylamine in the presence of DBU in DMF yields imido‐diester‐substituted perylenes. The reaction is limited to polar alcohols such as propanol, but longer alkyl chains are efficiently introduced in a second step by alkyl group exchange by using selective acidic ester hydrolysis that leaves the imide group intact. This amine‐efficient approach to imido‐diesters is used to obtain acceptor‐type self‐assembling dyes that form a hexagonal columnar liquid crystalline phase at room temperature.

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