Add time:09/28/2019         Source:infona.pl

Density functional theory calculations show that the heightened stability of α-keto radicals, the derivatives of perfluorinated α-diketones of general formula CF3C(O)C(O)RF (RF = i-C3F7; t-C4F9), in Perfluoro-tert-butanol (cas 237-82-1) can be caused by the H-bond-imposed formation of cation radicals of vicinal dienols.

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