Add time:07/16/2019 Source:sciencedirect.com
The 6-nitro- and 8-nitro- groups in the tetrazolo[1,5-a]pyridine molecule exhibit completely different influences on the tetrazole–azide equilibrium. Introduction of the methyl-, nitro-, azido groups or a bromine atom in positions 5, 6, 7 or 8 of the nitrotetrazolopyridine produce changes in the equilibrium constants. Based on the IR spectra taken in the solid state, the tetrazole structure was assigned for almost all the compounds studied. Only one of them, 2,6-diazido-3-nitropyridine, exists in the diazido-form in the solid. The 1H, 13C, 15N, and 17O NMR spectral parameters (coupling constants, chemical shifts) as well as ab initio molecular orbital calculations were used to describe the tetrazole–azide tautomerism in solutions. The differences in the NMR parameters between the neutral compound (6,8-dinitrotetrazolo[1,5-a]pyridine) and its σ-adducts are also included as data for distinguishing between both molecules.
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