Add time:07/19/2019 Source:sciencedirect.com
The paper reports the results of detailed studies of the molecular structure of lithium hydrazinium sulphate single crystal in a wide temperature range with the aim to clarify previously reported anomalies in the molecular dynamics at ∼100 K. The crystal does not undergo any structural phase transition from 8 to 460 K however, the donor-acceptor distance, between the nitrogen atoms involved in the hydrogen bond along the c-orthorhombic axis, starts to increase from the temperature of ∼100 K. This results in an anomaly of the phase memory time observed in electron spin echo studies and anomalies of hydrazinium internal modes observed in Raman scattering. Moreover, the anisotropy of the SO4 tetrahedra is maximal at ∼100 K and decreases at higher temperatures. The possible contribution of fast proton transport, described by the Grotthuss model, to the proton conductivity along the c-axis at the temperature above ∼400 K is discussed.
We also recommend Trading Suppliers and Manufacturers of Lithium hydrazinium sulphate (cas 14973-29-6). Pls Click Website Link as below: cas 14973-29-6 suppliers
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View