Add time:07/16/2019         Source:sciencedirect.com

Two novel C-2 position modified 8-hydroxyquinoline ligands, (E)-2-[(4-tert-butylphenyl)ethenyl]-8-hydroxyquinoline (L1) and (E)-2-[(2-chloro-3,4-dimethoxyphenyl)ethenyl]-8-hydroxyquinoline (L2) as well as their zinc(II) and cadmium(II) complexes, namely Zn2(L1)4, Cd3(L1)6, Zn3(L2)6 and Cd3(L2)6 were designed and synthesized. Thanks to the introduction of aromatic tert-butyl and methoxy, ligands L1 and L2 are highly soluble and complexes are having good solubility in dimethyl sulfoxide (DMSO) and chloroform. X-ray structural analysis indicate four complexes were in P21/c, P2/c, P1¯, C2/c space group, respectively, and exhibit a monoclinic crystal system except Zn3(L2)6, which hold a triclinic crystal system. Structural formulea and coordinating behavior of these complexes were also investigated by NMR, UV–Vis and fluorescence spectroscopic titrations in solution, revealing four complexes were well coordinated. Solid state photoluminescence studies reveal they emit strong yellow-orange luminescence at 568–612 nm with 5.47–11.79 ns lifetime. Thermogravimetric and theoretical electronic structure analysis indicate that four complexes appear to be promising candidates for the application as yellow luminescent materials.

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