Photochemistry of bis(2-methyl-1-propenyl)ether and 2,2,4,4-tetramethyl-6-oxabicyclo [3.1.0] hexan-3-one: on the search for the oxydi-π-methane rearrangement-Science-Chemical Encyclopedia-lookchem

Photochemistry of bis(2-methyl-1-propenyl)ether and 2,2,4,4-tetramethyl-6-oxabicyclo [3.1.0] hexan-3-one: on the search for the oxydi-π-methane rearrangement
Add time:07/19/2019 Source:sciencedirect.com

π,π-Excitation of bis(2-methyl-1-propenyl)ether leads to products derived from a vinyl-vinyloxy radical pair; photochemical decarbonylation (n,π) of the title ketone provides an entry into the diradical manifold of the oxydi-π-methane rearrangement.

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