Coordination polymer [Li2Co2(Piv)6(μ-L)2]n (L = 2-amino-5-methylpyridine) as a new molecular precursor for LiCoO2 cathode material-Science-Chemical Encyclopedia-lookchem

Coordination polymer [Li2Co2(Piv)6(μ-L)2]n (L = 2-Amino-5-methylpyridine (cas 1603-41-4)) as a new molecular precursor for LiCoO2 cathode material
Add time:07/18/2019 Source:sciencedirect.com

The solid-state thermolysis (420–450 °С) of the new heterometallic coordination polymer [Li2Co2(Piv)6(μ-L)2]n (1, Piv is the anion of pivalic acid, L is 2-amino-5-methylpyridine) followed by annealing of the decomposition products at 500 °С was shown to afford LiCoO2 in quantitative yield. Compound 1 was characterized by X-ray diffraction and magnetic measurements.

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