Add time:07/18/2019         Source:sciencedirect.com

Pyrene- and anthracene-appended new crown ether derivatives have been synthesized by Schiff's base reaction, and cation complexation behavior was investigated by fluorescence spectroscopy measurements. Based on photo-induced electron transfer and intramolecular charge transfer mechanism, the host molecules emit stronger fluorescence in the presence of various cations Na+, K+, Rb+, Cs+ and NH4+ since the complexation between guest cations and crown ether compounds inhibit partial electron transfer from the nitrogen atom to the chromophores and subsequently fluorescence is enhanced.The binding constants were estimated from the plots of the fraction of binding sites filled for crown ether compound as a function of free-ion concentration. Results show that 15-crown-5 derivatives exhibit higher binding ability with sodium cations while 18-crown-6 derivatives had higher affinity for potassium cations, which is consistent with the hole-size relationship of the crown ethers. Ammonium ion complexation caused largest fluorescence enhancement. It is understood that ammonium ion cannot only complex with crown ether, but also interact directly with the lone pair electrons of nitrogen atom in CN bond so that electron transfer from the nitrogen atom to chromophores is further inhibited.

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