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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Nitro-4-Methylsulfonylbenzoic Acid? supplier in China

Cas:110964-79-9

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Kono Chem Co.,Ltd

Superiority pioneerbiotech is a leading manufacturer and supplier of chemicals in China. We develop ,produce and distribute high quality pharmaceuticals, intermediates, special chemicals and other fine chemicals. We could give you: 1.Best q

High quality 4-Methylsulfonyl-2-nitrobenzoic acid

Cas:110964-79-9

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Other

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

2-Nitro-4-methylsulfonylbenzoic acid

Cas:110964-79-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Benzoic acid, 4-(methylsulfonyl)-2-nitro-

Cas:110964-79-9

Min.Order:1

Negotiable

Type:Other

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

4-Methylsulfonyl-2-Nitrobenzoic Acid

Cas:110964-79-9

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

2-Nitro-4-methylsulfonylbenzoic acid

Cas:110964-79-9

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

2-Nitro-4-methylsulfonylbenzoic acid -- CHemwill

Cas:110964-79-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 110964-79-9 with fast shipping

Cas:110964-79-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by email in t

Benzoicacid, 4-(methylsulfonyl)-2-nitro-

Cas:110964-79-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

2-Nitro-4-methylsulfonylbenzoic acid CAS110964-79-9

Cas:110964-79-9

Min.Order:1 Kilogram

FOB Price: $7.0 / 9.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name 2-Nitro-4-methylsulfonylbenzoic acid Cas number 110964-79-9 Molecular formula C8H7NO6S Molecular weight 245.21 EINECS 601-017-1

4-Methylsulfonyl-2-nitrobenzoic acid

Cas:110964-79-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Leader Biochemical Group

About Product Details

China Biggest factory Manufacturer Supply 2-Nitro-4-methylsulfonylbenzoic Acid CAS 110964-79-9

Cas:110964-79-9

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:powder Storage:Store in sealed containers at cool & dry pla

2-Nitro-4-methylsulfonylbenzoic acid CAS No.:110964-79-9

Cas:110964-79-9

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzoicacid, 4-(methylsulfonyl)-2-nitro- 110964-79-9

Cas:110964-79-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 2-Nitro-4-methylsulfonylbenzoic acid CAS: 110964-79-9 MF: C8H7NO6S MW: 245.21 EINECS: 601-017-1 Mol File: 110964-79-9.mol 2-Nitro-4-methylsulfonylbenzoic acid Structure 2-Nitro-4-methylsulfonylbenzoic acid Chemical P

2-Nitro-4-methylsulfonylbenzoic acid

Cas:110964-79-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Pharmaceutical Intermediate, 2-Nitro-4-methylsulfonylbenzoic acid CAS:110964-79-9

Cas:110964-79-9

Min.Order:1 Kilogram

FOB Price: $16.0 / 18.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material CAS 110964-79-9 ,2-Nitro-4-methylsulfonylbenzoic acid

Cas:110964-79-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Lonwin Chemical Group Limited

4-(methylsulfonyl)-2-nitro- CAS: 110964-79-9 Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard Shelf life 2 years Storage should be stored in

Factory supply 4-(methylsulfonyl)-2-nitro-

Cas:110964-79-9

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzoicacid, 4-(methylsulfonyl)-2-nitro-

Cas:110964-79-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Nitro-4-Methylsulfonylbenzoic Acid

Cas:110964-79-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Nitro-4-methylsulfonylbenzoic acid

Cas:110964-79-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

2-NITRO-4-METHYLSULFONYLBENZOIC ACID

Cas:110964-79-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Nitro-4-methylsulfonylbenzoic acid

Cas:110964-79-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and als

2-Nitro-4-methylsulfonylbenzoic acid

Cas:110964-79-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2-Nitro-4-methylsulfonylbenzoic acid

Cas:110964-79-9

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

2-Nitro-4-methylsulfonylbenzoic acid Basic information Product Name: 2-Nitro-4-methylsulfonylbenzoic acid Synony

110964-79-9 C8H7NO6S 2-Nitro-4-methylsulfonylbenzoic acid

Cas:110964-79-9

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 4-Methylsulfonyl-2-Nitrobenzoic Acid CAS No.:110964-79-9 Molecule Formula:C8H7NO6S Molecule Weight:245.21 Purity: 99.0% Package: 25kg/drum Description:Light yellow crystalline powder Manufacture Standards:Enterprise Stan

Best Quality 4-Methylsulfonyl-2-Nitrobenzoic Acid

Cas:110964-79-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2-Nitro-4-methylsulfonylbenzoic acid

Cas:110964-79-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

4-(Methylsulfonyl)-2-nitrobenzoicacid

Cas:110964-79-9

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-Nitro-4-methylsulfonylbenzoic acid

Cas:110964-79-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Synthetic route

2-nitro-4-methylsulfonyl benzoic acid dicyclohexyl amine salt

2-nitro-4-methylsulfonyl benzoic acid dicyclohexyl amine salt

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With potassium hydroxide In water pH=13; Reagent/catalyst;98.45%
With potassium hydroxide In water pH=3 - 13;44.1 g
1-methyl-4-(methylsulfonyl)-2-nitrobenzene
1671-49-4

1-methyl-4-(methylsulfonyl)-2-nitrobenzene

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With sulfuric acid; oxygen; nitric acid; vanadia at 140℃; for 11h; Temperature;98%
With sulfuric acid; oxygen; nitric acid; vanadia at 138 - 140℃; under 37.5038 Torr; Catalytic behavior; Temperature; Autoclave;96.7%
With oxygen; nitric acid; acetic acid; 2,6-dihydroxypyrrolo[3,4-f]isoindolo-1,3,5,7(2H,6H)tetrone at 150℃; under 37503.8 Torr; for 5h; Catalytic behavior; Reagent/catalyst; Temperature; Pressure; Autoclave;94.9%
Methyl p-tolyl sulfone
3185-99-7

Methyl p-tolyl sulfone

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
Stage #1: Methyl p-tolyl sulfone With nitric acid In dichloromethane at 10℃; Large scale;
Stage #2: With vanadium(V) oxide; sulfuric acid at 140℃; Large scale;
98%
Stage #1: Methyl p-tolyl sulfone With sulfuric acid for 4.5h; Large scale;
Stage #2: With nitric acid; vanadia In water at 142 - 145℃; for 38.5h; Time; Large scale;
90.2%
Stage #1: Methyl p-tolyl sulfone With sulfuric acid; nitric acid In water for 6.1h; Heating; Industrial scale;
Stage #2: With boron nitride; vanadia In water at 142 - 146℃; for 29h; Temperature; Industrial scale;
90.77%
2-nitro-4-methylsulfonyl benzoic acid n-hexylamine salt

2-nitro-4-methylsulfonyl benzoic acid n-hexylamine salt

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With potassium hydroxide In water pH=13; Reagent/catalyst;98%
With potassium hydroxide In water pH=3 - 13;86.2 g
methyl 2-cyano-2-(4-(methylsulfonyl)-2-nitrophenyl)acetate

methyl 2-cyano-2-(4-(methylsulfonyl)-2-nitrophenyl)acetate

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With dihydrogen peroxide; potassium hydroxide In water at 40℃; for 2h;97%
2-nitro-4-methylsulfonyl benzoic acid n-propylamine salt

2-nitro-4-methylsulfonyl benzoic acid n-propylamine salt

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With potassium carbonate96.5%
With potassium carbonate In water Heating; Further stages;84.9 g
4-(methylsulfonyl)-2-nitrobenzonitrile

4-(methylsulfonyl)-2-nitrobenzonitrile

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With sulfuric acid; acetic acid In water at 100℃; for 6h;93%
1-methyl-4-(methylsulfonyl)-2-nitrobenzene
1671-49-4

1-methyl-4-(methylsulfonyl)-2-nitrobenzene

acetic acid
64-19-7

acetic acid

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With 1,1,2,2-tetrabromoethane; cobalt(II) acetate; manganese(III) triacetate dihydrate In water at 210℃; under 22801.5 Torr; for 3h; Reagent/catalyst; Solvent; Temperature; Pressure; Reflux;92%
diethyl 2-nitro-4-methanesulfonylphenylmalonate

diethyl 2-nitro-4-methanesulfonylphenylmalonate

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With dihydrogen peroxide; sodium hydroxide In N,N-dimethyl-formamide at 80℃; for 2h;88%
2-nitro-4-methylsulfonyl benzoic acid triethylamine salt

2-nitro-4-methylsulfonyl benzoic acid triethylamine salt

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With calcium hydroxide In water pH=12 - 13;87.9%
With calcium hydroxide pH=12 - 13;18.7 g
sodium bicarbona+and

sodium bicarbona+and

nitro-4-sulfinylbenzoic acid

nitro-4-sulfinylbenzoic acid

4-chlorosulfonyl-2-nitro-benzoyl chloride
130264-19-6

4-chlorosulfonyl-2-nitro-benzoyl chloride

sodium monochloroacetic acid
3926-62-3

sodium monochloroacetic acid

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With sodium sulfite In water; ethyl acetate87%
4-chlorosulfonyl-2-nitro-benzoic acid
54090-40-3

4-chlorosulfonyl-2-nitro-benzoic acid

chloroacetic acid
79-11-8

chloroacetic acid

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With sodium hydroxide; sodium hydrogencarbonate; sodium sulfite 1) H2O, 75 deg C, 1 h, 2) 105 deg C, 7 h, 3) reduction temperature 10-15 deg C; Yield given. Multistep reaction;
vanadium(V) oxide
788133-24-4

vanadium(V) oxide

1-methyl-4-(methylsulfonyl)-2-nitrobenzene
1671-49-4

1-methyl-4-(methylsulfonyl)-2-nitrobenzene

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With nitric acid In sulfuric acid
vanadium(V) oxide
788133-24-4

vanadium(V) oxide

Methyl p-tolyl sulfone
3185-99-7

Methyl p-tolyl sulfone

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
In sulfuric acid; water
mesotrione
104206-82-8

mesotrione

A

2-amino-4-(methylsulfonyl)benzoic acid
393085-45-5

2-amino-4-(methylsulfonyl)benzoic acid

B

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With TiO2 Degussa P25; oxygen In water pH=4; Kinetics; Mechanism; Reagent/catalyst; pH-value; Wavelength; UV-irradiation;
mesotrione
104206-82-8

mesotrione

A

2-amino-4-(methylsulfonyl)benzoic acid
393085-45-5

2-amino-4-(methylsulfonyl)benzoic acid

B

xanthene-1,9-dione-3,4-dihydro-6-methylsulfonyl

xanthene-1,9-dione-3,4-dihydro-6-methylsulfonyl

C

2-hydroxy-4-(methylsulfonyl)-2-nitrobenzoic acid
108153-42-0

2-hydroxy-4-(methylsulfonyl)-2-nitrobenzoic acid

D

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With water; copper(l) chloride for 24h; pH=6.5; Kinetics; Irradiation;
1-fluoro-4-methanesulfonyl-2-nitrobenzene
453-72-5

1-fluoro-4-methanesulfonyl-2-nitrobenzene

cyanoacetic acid amide
107-91-5

cyanoacetic acid amide

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
Stage #1: 1-fluoro-4-methanesulfonyl-2-nitrobenzene; cyanoacetic acid amide With sodium hydroxide In dimethyl sulfoxide at 310℃; for 3h;
Stage #2: With dihydrogen peroxide In dimethyl sulfoxide for 3h;
111 g
Cyanoaceton
2469-99-0

Cyanoaceton

1-chloro-4-methanesulfonyl-2-nitrobenzene
97-07-4

1-chloro-4-methanesulfonyl-2-nitrobenzene

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
Stage #1: Cyanoaceton; 1-chloro-4-methanesulfonyl-2-nitrobenzene With sodium hydroxide In dimethyl sulfoxide at 60℃; for 1h;
Stage #2: With dihydrogen peroxide In dimethyl sulfoxide for 2h;
148.6 g
1-methyl-2-nitrobenzene
88-72-2

1-methyl-2-nitrobenzene

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: chlorosulfonic acid / 3.5 h / 110 - 115 °C
1.2: 3 h / 60 - 65 °C
2.1: sodium sulfite; sodium carbonate / water / 3 h / 0 - 25 °C / pH 7.5 - 8
2.2: 14 h / 40 - 100 °C
3.1: vanadia; nitric acid / 135 - 160 °C
View Scheme
4-methyl-3-nitrobenzenesulfonyl chloride
616-83-1

4-methyl-3-nitrobenzenesulfonyl chloride

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: sodium sulfite; sodium carbonate / water / 3 h / 0 - 25 °C / pH 7.5 - 8
1.2: 14 h / 40 - 100 °C
2.1: vanadia; nitric acid / 135 - 160 °C
View Scheme
1-chloro-4-methanesulfonyl-2-nitrobenzene
97-07-4

1-chloro-4-methanesulfonyl-2-nitrobenzene

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium hydroxide / dimethyl sulfoxide / 1 h / 60 °C
2: potassium hydroxide; dihydrogen peroxide / water / 2 h / 40 °C
View Scheme
p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: sodium hydrogencarbonate; sodium sulfite / water / 9 h / 75 °C
1.2: 4.5 h / 45 - 130 °C
2.1: sulfuric acid / 0.5 h / 20 °C
2.2: 10 h / 10 °C
3.1: vanadia; sulfuric acid; nitric acid / 13 h / 145 - 165 °C
View Scheme
4-bromoohenyl methyl sulfone
3466-32-8

4-bromoohenyl methyl sulfone

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: nitric acid; sulfuric acid / 0.5 h / 0 - 10 °C
2: N,N-dimethyl-formamide / 6 h / 140 °C
3: sulfuric acid; acetic acid / water / 6 h / 100 °C
View Scheme
3-nitrophthalic acid
603-11-2

3-nitrophthalic acid

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: chlorosulfonic acid / dichloromethane / 3 h / 0 - 20 °C
2: sodium carbonate; sodium sulfite / water / 1.5 h / 30 - 105 °C
3: N-benzyl-N,N,N-triethylammonium chloride; sodium hydrogencarbonate / water; N,N-dimethyl-formamide / 10 h / 80 °C
4: copper(I) oxide; triethylamine / 24 h / 50 °C
View Scheme
3-nitro-5-sulfonyl chloride phthalic acid

3-nitro-5-sulfonyl chloride phthalic acid

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: sodium carbonate; sodium sulfite / water / 1.5 h / 30 - 105 °C
2: N-benzyl-N,N,N-triethylammonium chloride; sodium hydrogencarbonate / water; N,N-dimethyl-formamide / 10 h / 80 °C
3: copper(I) oxide; triethylamine / 24 h / 50 °C
View Scheme
3-nitro-5-methylsulfonyl phthalic acid

3-nitro-5-methylsulfonyl phthalic acid

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

Conditions
ConditionsYield
With copper(I) oxide; triethylamine at 50℃; for 24h; Reagent/catalyst;222 g
4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

4-methylsulphonyl-2-nitrobenzoyl chloride
110964-80-2

4-methylsulphonyl-2-nitrobenzoyl chloride

Conditions
ConditionsYield
With thionyl chloride; N,N-dimethyl-formamide In 1,2-dichloro-ethane at 65 - 69℃; for 6.5h; Inert atmosphere;98.2%
4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

1,3-dimethyl-1H-pyrazol-5-ol
5203-77-0

1,3-dimethyl-1H-pyrazol-5-ol

(1,3-dimethyl-5-hydroxypyrazol-4-yl)-(4-methanesulfonyl-2-nitrophenyl)methanone

(1,3-dimethyl-5-hydroxypyrazol-4-yl)-(4-methanesulfonyl-2-nitrophenyl)methanone

Conditions
ConditionsYield
With triethylamine In 1,4-dioxane at 60℃; for 2h;97%
4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

1,3-dimethyl-1H-pyrazol-5-ol
5203-77-0

1,3-dimethyl-1H-pyrazol-5-ol

(1,3-dimethylpyrazole-5-yl methanesulfonate-4-yl)-(4-methanesulfonyl-2-nitrophenyl)methanone

(1,3-dimethylpyrazole-5-yl methanesulfonate-4-yl)-(4-methanesulfonyl-2-nitrophenyl)methanone

Conditions
ConditionsYield
With triethylamine In 1,4-dioxane at 50℃; for 5h;95%
4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

1-methanesulfonyl-3-nitro-benzene
2976-32-1

1-methanesulfonyl-3-nitro-benzene

Conditions
ConditionsYield
With copper(l) iodide; triethylamine In dimethyl sulfoxide at 120℃; under 760.051 Torr; for 20h; Inert atmosphere; Schlenk technique;87%
4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

1,3-cylohexanedione
504-02-9

1,3-cylohexanedione

mesotrione
104206-82-8

mesotrione

Conditions
ConditionsYield
Stage #1: 4-methanesulfonyl-2-nitro-benzoic acid; 1,3-cylohexanedione With dicyclohexyl-carbodiimide In 5,5-dimethyl-1,3-cyclohexadiene at 140 - 150℃;
Stage #2: In 5,5-dimethyl-1,3-cyclohexadiene; acetonitrile Solvent;
80.3%
tert-butyl (2S)-amino(cyclohexyl)ethanoate hydrochloride
213475-52-6

tert-butyl (2S)-amino(cyclohexyl)ethanoate hydrochloride

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

1,1-dimethylethyl (2S)-cyclohexyl-({[4-(methylsulfonyl)-2-nitrophenyl]carbonyl}amino)ethanoate
887243-81-4

1,1-dimethylethyl (2S)-cyclohexyl-({[4-(methylsulfonyl)-2-nitrophenyl]carbonyl}amino)ethanoate

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide at 20℃;74%
4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

benzene
71-43-2

benzene

4-methylsulfonyl-2-nitro-1-phenylbenzene

4-methylsulfonyl-2-nitro-1-phenylbenzene

Conditions
ConditionsYield
With dipotassium peroxodisulfate; silver sulfate In acetonitrile at 120℃; for 24h; Glovebox; Schlenk technique; Sealed tube; Inert atmosphere;70%
1,2,4-Triazole
288-88-0

1,2,4-Triazole

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

2-Nitro-4-methanesulphonyl benzoyltriazolamide

2-Nitro-4-methanesulphonyl benzoyltriazolamide

Conditions
ConditionsYield
With thionyl chloride In N-methyl-acetamide; 5,5-dimethyl-1,3-cyclohexadiene; acetonitrile56.8%
3-amino-4-methylfurazan
17647-70-0

3-amino-4-methylfurazan

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

N-(4-methyl-1,2,5-oxadiazol-3-yl)-4-(methylsulfonyl)-2-nitrobenzamide

N-(4-methyl-1,2,5-oxadiazol-3-yl)-4-(methylsulfonyl)-2-nitrobenzamide

Conditions
ConditionsYield
With dmap; 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide; triethylamine In tetrahydrofuran; dichloromethane at 20℃; for 30h;53%
4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

1-iodo-3-(methylsulfonyl)-5-nitrobenzene
62606-16-0

1-iodo-3-(methylsulfonyl)-5-nitrobenzene

Conditions
ConditionsYield
With copper(I) oxide; potassium phosphate; bismuth (III) nitrate pentahydrate; palladium(II) trifluoroacetate; oxygen; sodium iodide In dimethyl sulfoxide at 170℃; for 20h; Schlenk technique;51%
With copper(I) oxide; potassium phosphate; bismuth (III) nitrate pentahydrate; oxygen; palladium diacetate; sodium iodide In dimethyl sulfoxide at 170℃; for 10h; Schlenk technique; Green chemistry; regioselective reaction;24.4 mg
4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

C14H12N2O8S2

C14H12N2O8S2

Conditions
ConditionsYield
With copper(l) iodide In dimethyl sulfoxide at 140℃; for 20h; Inert atmosphere; Molecular sieve;42%
4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

2-amino-4-(methylsulfonyl)benzoic acid
393085-45-5

2-amino-4-(methylsulfonyl)benzoic acid

Conditions
ConditionsYield
With hydrogenchloride; iron
4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

3-methanesulfonyl-benzo[4,5]thiazolo[2,3-b]quinazolin-12-one

3-methanesulfonyl-benzo[4,5]thiazolo[2,3-b]quinazolin-12-one

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: iron-powder; aqueous HCl
View Scheme
3-chloro-2-cyclohexenone
5682-75-7

3-chloro-2-cyclohexenone

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

3-(4'-methylsulfonyl-2'-nitro-benzoyloxy)-2-cyclohexene-1-one
226944-49-6

3-(4'-methylsulfonyl-2'-nitro-benzoyloxy)-2-cyclohexene-1-one

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; zinc(II) chloride In acetonitrile at 45℃; for 58h; Heating / reflux;
With N-ethyl-N,N-diisopropylamine; zinc(II) chloride In acetonitrile at 45℃; for 58h; Heating / reflux;
1-methyl-8-oxa-bicyclo[3.2.1]oct-6-ene-2,4-dione
872030-70-1

1-methyl-8-oxa-bicyclo[3.2.1]oct-6-ene-2,4-dione

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

3-(4-methylsulfonyl-2-nitro-benzoyl)-1-methyl-8-oxa-bicyclo[3.2.1]oct-6-ene-2,4-dione

3-(4-methylsulfonyl-2-nitro-benzoyl)-1-methyl-8-oxa-bicyclo[3.2.1]oct-6-ene-2,4-dione

Conditions
ConditionsYield
Stage #1: 1-methyl-8-oxa-bicyclo[3.2.1]oct-6-ene-2,4-dione; 4-methanesulfonyl-2-nitro-benzoic acid With dicyclohexyl-carbodiimide In dichloromethane; acetonitrile at 20℃; for 2.5h;
Stage #2: With triethylamine; 2-hydroxy-propionitrile In dichloromethane; acetonitrile at 20℃; for 18h;
4-nitro-phenol
100-02-7

4-nitro-phenol

oxalyl dichloride
79-37-8

oxalyl dichloride

4-methanesulfonyl-2-nitro-benzoic acid
110964-79-9

4-methanesulfonyl-2-nitro-benzoic acid

4-nitrophenyl 2-nitro-4-(methylsulfonyl)benzoate
415955-68-9

4-nitrophenyl 2-nitro-4-(methylsulfonyl)benzoate

Conditions
ConditionsYield
With triethylamine In dichloromethane; N,N-dimethyl-formamide
With triethylamine In dichloromethane; N,N-dimethyl-formamide

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