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Qingdao Beluga Import and Export Co., LTD

Benzyl Methyl Carbonate CAS:13326-10-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i

Benzyl Methyl Carbonate CAS:13326-10-8

Cas:13326-10-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzyl methyl carbonate

Cas:13326-10-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzyl methyl carbonate

Cas:13326-10-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Benzyl methyl carbonate

Cas:13326-10-8

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

Benzyl methyl carbonate

Cas:13326-10-8

Min.Order:0

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Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Benzyl methyl carbonate

Cas:13326-10-8

Min.Order:0

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Benzyl methyl carbonate

Cas:13326-10-8

Min.Order:0

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Hangzhou Sartort Biopharma Co., Ltd

Best quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

Benzylmethylcarbonate

Cas:13326-10-8

Min.Order:0

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Type:Lab/Research institutions

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Benzyl methyl carbonate

Cas:13326-10-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Benzyl methyl carbonate

Cas:13326-10-8

Min.Order:0

Negotiable

Type:Trading Company

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Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Benzyl methyl carbonate

Cas:13326-10-8

Min.Order:0

Negotiable

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Nanjing Raymon Biotech Co., Ltd.

Benzyl methyl carbonateAppearance:Off white to slight yellow solid Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL

Benzyl methyl carbonate

Cas:13326-10-8

Min.Order:0

Negotiable

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Skyrun Industrial Co.,Ltd

Purity, Strength, Price Application:dye intermediate

CSR160805-10931

Cas:13326-10-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Ruishun Trade Co.,Ltd

Supply top quality products with a reasonable price Application:api

13326-10-8

Cas:13326-10-8

Min.Order:0

Negotiable

Type:Trading Company

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Chemical Co.Ltd

Benzyl methyl carbonateAppearance:Off white to slight yellow solid Storage:Stored in shaded, cool and dry places Package:1L 5L 10L 25L bottle Application:pharma intermediate Transportation:Handle with cares to avoid damaging the packages. Protect the

Benzyl methyl carbonate

Cas:13326-10-8

Min.Order:0

Negotiable

Type:Trading Company

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Synthetic route

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

benzyl alcohol
100-51-6

benzyl alcohol

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Conditions
ConditionsYield
Stage #1: carbonic acid dimethyl ester With lanthanum(III) isopropoxide; 2-(2-methoxyethoxy)ethyl alcohol at 20℃;
Stage #2: benzyl alcohol for 1h; Reflux; chemoselective reaction;
99%
With lanthanum (III) nitrate * water; 1,1,1-trioctyl-1-methylphosphonium methylcarbonate for 1h; Molecular sieve; Reflux;99%
With 3-methyl-1-(trimethoxysilylpropyl)imidazolium chloride at 80℃; for 5h; Inert atmosphere;99%
methyl chloroformate
79-22-1

methyl chloroformate

benzyl alcohol
100-51-6

benzyl alcohol

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Conditions
ConditionsYield
With pyridine In dichloromethane at 0 - 20℃;97%
With tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide In dichloromethane; water at 20℃; Inert atmosphere;91%
With pyridine In dichloromethane at 0 - 20℃; Inert atmosphere;90%
methanol
67-56-1

methanol

C15H18N4O3

C15H18N4O3

A

BrH*C7H11BrN4O

BrH*C7H11BrN4O

B

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Conditions
ConditionsYield
With bromine at 12℃; for 0h; Inert atmosphere; Darkness;A 97%
B 95%
potassium monomethylcarbonate
14660-45-8

potassium monomethylcarbonate

benzyl chloride
100-44-7

benzyl chloride

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Conditions
ConditionsYield
With 18-crown-6 ether In toluene Heating;95%
silver monomethyl carbonate
100477-67-6

silver monomethyl carbonate

benzyl bromide
100-39-0

benzyl bromide

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Conditions
ConditionsYield
In acetonitrile at 25℃; for 10h;91%
benzyl bromide
100-39-0

benzyl bromide

tetra-n-butylammonium methyl carbonate

tetra-n-butylammonium methyl carbonate

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Conditions
ConditionsYield
In acetonitrile at 25℃; for 18h;86%
carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

benzyl alcohol
100-51-6

benzyl alcohol

A

DBC
3459-92-5

DBC

B

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Conditions
ConditionsYield
ytterbium(III) triflate In 1,2-dichloro-ethane for 8h; Heating;A n/a
B 75%
ytterbium(III) triflate In 1,2-dichloro-ethane for 8h; Heating;A 60%
B 11%
With tungsten hexacarbonyl at 180℃; for 1h;A 50%
B n/a
2-methoxycarbonyl-1,3-dimethylimidazolium triflate

2-methoxycarbonyl-1,3-dimethylimidazolium triflate

benzyl alcohol
100-51-6

benzyl alcohol

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In acetone Ambient temperature;74%
With 1,4-diaza-bicyclo[2.2.2]octane In acetone Product distribution; Mechanism; Ambient temperature; further alkyl imidazolium-2-carboxylates, further nucleophiles;74%
carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

benzyl alcohol
100-51-6

benzyl alcohol

A

DBC
3459-92-5

DBC

B

dibenzyl ether
103-50-4

dibenzyl ether

C

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Conditions
ConditionsYield
at 90℃; for 6h; Reagent/catalyst; Green chemistry;A 70%
B n/a
C n/a
With potassium carbonate under 0.750075 - 759.826 Torr; Heating / reflux;
tetrabutyl phosphonium bromide
3115-68-2

tetrabutyl phosphonium bromide

benzyl chloride
100-44-7

benzyl chloride

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Conditions
ConditionsYield
With hydrogenchloride In diethyl ether; water; N,N-dimethyl-formamide65%
N-benzyloxycarbonyl-2-amino-3-phenylpropionaldehyde
59830-60-3, 63219-70-5, 68474-26-0

N-benzyloxycarbonyl-2-amino-3-phenylpropionaldehyde

trimethyl ethoxyethyloxyphosphonoacetate
116087-58-2

trimethyl ethoxyethyloxyphosphonoacetate

A

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

B

5-Benzyl-3-(1-ethoxy-ethoxy)-1,5-dihydro-pyrrol-2-one

5-Benzyl-3-(1-ethoxy-ethoxy)-1,5-dihydro-pyrrol-2-one

C

(Z)-4-Benzyloxycarbonylamino-2-(1-ethoxy-ethoxy)-5-phenyl-pent-2-enoic acid methyl ester

(Z)-4-Benzyloxycarbonylamino-2-(1-ethoxy-ethoxy)-5-phenyl-pent-2-enoic acid methyl ester

Conditions
ConditionsYield
With lithium diisopropyl amide 1.) THF, -40 deg C 2.) - 40 to 25 deg C, 2 h; Yield given. Multistep reaction. Yields of byproduct given;
With lithium diisopropyl amide 1.) THF, - 40 deg C 2.) - 40 to 25 deg C, 2 h.; Yield given. Multistep reaction. Yields of byproduct given;
dibutyl isocyanato methoxy tin(IV)

dibutyl isocyanato methoxy tin(IV)

benzyl alcohol
100-51-6

benzyl alcohol

A

O-benzyl carbamate
621-84-1

O-benzyl carbamate

B

DBC
3459-92-5

DBC

C

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

D

dibutyl-bis(benzyloxy)tin
34833-30-2

dibutyl-bis(benzyloxy)tin

Conditions
ConditionsYield
at 175℃; for 6h; Product distribution;
Benzyl N-hydroxycarbamate
3426-71-9

Benzyl N-hydroxycarbamate

methanol
67-56-1

methanol

1,4-diphenyl-1,3-butadiene
886-65-7, 82598-07-0

1,4-diphenyl-1,3-butadiene

benzyl 3,6-diphenyl-3,6-dihydro-2H-1,2-oxazine-2-carboxylate

benzyl 3,6-diphenyl-3,6-dihydro-2H-1,2-oxazine-2-carboxylate

B

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Conditions
ConditionsYield
With 2-ethyl-4,5-dihydrooxazole; oxygen; copper dichloride at 20℃; for 18h; Air atmosphere; chemoselective reaction;
C15H17NO5S

C15H17NO5S

A

BrH*C7H11BrN4O

BrH*C7H11BrN4O

B

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: lithium azide; water / N,N-dimethyl-formamide / 2.5 h / 130 °C / Inert atmosphere
2: bromine / 0 h / 12 °C / Inert atmosphere; Darkness
View Scheme
carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

benzyl alcohol
100-51-6

benzyl alcohol

cyclohexanol
108-93-0

cyclohexanol

A

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

B

methyl cyclohexyl carbonate
25066-36-8

methyl cyclohexyl carbonate

Conditions
ConditionsYield
With methyl trioctylphosphonium acetate at 90℃; for 4h;
carbon dioxide
124-38-9

carbon dioxide

benzyl alcohol
100-51-6

benzyl alcohol

methyl iodide
74-88-4

methyl iodide

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Conditions
ConditionsYield
Stage #1: benzyl alcohol With 1-butyl-2,3-methylimidazolium tetrafluoroborate Inert atmosphere; Electrochemical reaction;
Stage #2: carbon dioxide at 40℃; under 760.051 Torr; for 2h;
Stage #3: methyl iodide With potassium carbonate at 60℃; for 5h;
Benzyl acetate
140-11-4

Benzyl acetate

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: methanol / 2 h / 84 °C / Inert atmosphere; Schlenk technique
2: heterogeneous zinc/imidazole catalyst / 0.5 h / 100 °C / Inert atmosphere; Schlenk technique
View Scheme
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

benzyl alcohol
100-51-6

benzyl alcohol

A

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

B

benzeneacetic acid methyl ester
101-41-7

benzeneacetic acid methyl ester

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; 1,3-bis-(diphenylphosphino)propane; caesium carbonate at 120℃; under 30003 Torr; for 24h; Reagent/catalyst;A n/a
B 47 %Chromat.
2-Methyl-4-phenyl-3-butyn-2-ol
1719-19-3

2-Methyl-4-phenyl-3-butyn-2-ol

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

1,3-diphenyl-1-propyne
4980-70-5

1,3-diphenyl-1-propyne

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; 1,4-di(diphenylphosphino)-butane In 1,4-dioxane at 120℃; for 12h; Catalytic behavior; Reagent/catalyst;99%
benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

2-methyl-4-(2-methylphenyl)-3-butyn-2-ol
40888-14-0

2-methyl-4-(2-methylphenyl)-3-butyn-2-ol

1-methyl-2-(3-phenylprop-1-yn-1-yl)benzene

1-methyl-2-(3-phenylprop-1-yn-1-yl)benzene

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; 1,4-di(diphenylphosphino)-butane In 1,4-dioxane at 120℃; for 12h;99%
3-methyl-1-(4'-butylphenyl)-1-butyne-3-ol
155906-12-0

3-methyl-1-(4'-butylphenyl)-1-butyne-3-ol

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

1-butyl-4-(3-phenylprop-1-yn-1-yl)benzene

1-butyl-4-(3-phenylprop-1-yn-1-yl)benzene

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; 1,4-di(diphenylphosphino)-butane In 1,4-dioxane at 120℃; for 12h;99%
benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

diethyl 2-phenylmalonate
83-13-6

diethyl 2-phenylmalonate

diethyl 2-benzyl-2-phenylmalonate
613670-59-0

diethyl 2-benzyl-2-phenylmalonate

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; caesium carbonate In N,N-dimethyl-formamide at 30℃; for 48h; Inert atmosphere;98%
With 1,1'-bis-(diphenylphosphino)ferrocene; N,O-bis-(trimethylsilyl)-acetamide; {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; potassium acetate In tetrahydrofuran at 80℃; for 24h;95%
With 1,1'-bis-(diphenylphosphino)ferrocene; 1,5-cis,cis-cyclooctadiene; [PdCp(η3-C3H5)] In tetrahydrofuran at 80℃;84%
benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

quinolin-3-ylboronic acid
191162-39-7

quinolin-3-ylboronic acid

3-benzylquinoline
37045-16-2

3-benzylquinoline

Conditions
ConditionsYield
With potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)); 1,5-bis-(diphenylphosphino)pentane In N,N-dimethyl-formamide at 80℃; for 45h; Suzuki coupling;96%
benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

4-methoxy-phenol
150-76-5

4-methoxy-phenol

4-methoxyphenyl benzyl ether
6630-18-8

4-methoxyphenyl benzyl ether

Conditions
ConditionsYield
With allyl(cyclopentadiene)palladium(II); bis[2-(diphenylphosphino)phenyl] ether In toluene at 60℃; for 20.0833h; Inert atmosphere;96%
benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

methyl 4-hydroxylbenzoate
99-76-3

methyl 4-hydroxylbenzoate

4-benzyloxy-benzoic acid methyl ester
32122-11-5

4-benzyloxy-benzoic acid methyl ester

Conditions
ConditionsYield
With allyl(cyclopentadiene)palladium(II); bis[2-(diphenylphosphino)phenyl] ether In toluene at 60℃; for 22.0833h; Inert atmosphere;96%
benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

phenol
108-95-2

phenol

(benzyloxy)benzene
946-80-5

(benzyloxy)benzene

Conditions
ConditionsYield
With allyl(cyclopentadiene)palladium(II); bis[2-(diphenylphosphino)phenyl] ether In toluene at 60℃; for 24.0833h; Inert atmosphere;96%
benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

sodium benzenesulfonate
873-55-2

sodium benzenesulfonate

Benzyl phenyl sulfone
3112-88-7

Benzyl phenyl sulfone

Conditions
ConditionsYield
With bis[2-(diphenylphosphino)phenyl] ether; bis(η3-allyl-μ-chloropalladium(II)) In dimethyl sulfoxide at 80℃; for 1h;95%
O-methylresorcine
150-19-6

O-methylresorcine

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

3-benzyloxyanisole
21144-16-1

3-benzyloxyanisole

Conditions
ConditionsYield
With allyl(cyclopentadiene)palladium(II); bis[2-(diphenylphosphino)phenyl] ether In toluene at 60℃; for 24.0833h; Inert atmosphere;94%
indole
120-72-9

indole

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

3,3-dibenzyl-3H-indole
16886-11-6

3,3-dibenzyl-3H-indole

Conditions
ConditionsYield
Stage #1: indole With {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; bis[2-(diphenylphosphino)phenyl] ether In toluene at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: benzyl methyl carbonate With N,O-bis-(trimethylsilyl)-acetamide; triethyl borane In hexane; toluene at 50℃; for 18h; Inert atmosphere;
94%
benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

3-pyridylboronic acid
1692-25-7

3-pyridylboronic acid

3-benzylpyridine
620-95-1

3-benzylpyridine

Conditions
ConditionsYield
With potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)); 1,5-bis-(diphenylphosphino)pentane In N,N-dimethyl-formamide at 80℃; for 24h; Suzuki coupling;93%
benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

N-tosyl tryptamine
86658-78-8

N-tosyl tryptamine

3a-benzyl-1-tosyl-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole

3a-benzyl-1-tosyl-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole

Conditions
ConditionsYield
Stage #1: N-tosyl tryptamine With {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; bis[2-(diphenylphosphino)phenyl] ether In toluene at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: benzyl methyl carbonate With N,O-bis-(trimethylsilyl)-acetamide; triethyl borane In hexane; toluene at 50℃; for 18h; Inert atmosphere;
92%
benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

2-methyl-4-(4-methylphenyl)-3-butyn-2-ol
79756-91-5

2-methyl-4-(4-methylphenyl)-3-butyn-2-ol

1-methyl-4-(3-phenylprop-1-yn-1-yl)benzene

1-methyl-4-(3-phenylprop-1-yn-1-yl)benzene

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; 1,4-di(diphenylphosphino)-butane In 1,4-dioxane at 120℃; for 12h;92%
fur-2-ylboronic acid
13331-23-2

fur-2-ylboronic acid

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

2-benzylfuran
37542-92-0

2-benzylfuran

Conditions
ConditionsYield
With potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)); 1,5-bis-(diphenylphosphino)pentane In tert-Amyl alcohol at 100℃; for 24h; Suzuki coupling;91%
2,3-dimethyl-5-methoxyindole
828-94-4

2,3-dimethyl-5-methoxyindole

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

3-benzyl-5-methoxy-2,3-dimethyl-3H-indole
1350845-72-5

3-benzyl-5-methoxy-2,3-dimethyl-3H-indole

Conditions
ConditionsYield
Stage #1: 2,3-dimethyl-5-methoxyindole With {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; bis[2-(diphenylphosphino)phenyl] ether In toluene at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: benzyl methyl carbonate With N,O-bis-(trimethylsilyl)-acetamide; triethyl borane In hexane; toluene at 50℃; for 18h; Inert atmosphere;
91%
benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

Diphenylphosphine oxide
4559-70-0

Diphenylphosphine oxide

benzyldiphenylphosphine oxide
2959-74-2

benzyldiphenylphosphine oxide

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); bis[2-(diphenylphosphino)phenyl] ether In N,N-dimethyl-formamide at 100℃; for 48h; Inert atmosphere; Sealed tube;91%
benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

p-benzylanizole
834-14-0

p-benzylanizole

Conditions
ConditionsYield
With 1,5-bis-(diphenylphosphino)pentane; potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)) In N,N-dimethyl-formamide at 80℃; for 24h; Suzuki-Miyaura reaction;90%
benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

4-chloro-phenol
106-48-9

4-chloro-phenol

4-chlorophenyl benzyl ether
7700-27-8

4-chlorophenyl benzyl ether

Conditions
ConditionsYield
With allyl(cyclopentadiene)palladium(II); bis[2-(diphenylphosphino)phenyl] ether In toluene at 60℃; for 16.0833h; Inert atmosphere;90%
1,2,3,4-tetrahydrocarbazole
942-01-8

1,2,3,4-tetrahydrocarbazole

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

4a-benzyl-2,3,4,4a-tetrahydro-1H-carbazole
18781-55-0

4a-benzyl-2,3,4,4a-tetrahydro-1H-carbazole

Conditions
ConditionsYield
Stage #1: 1,2,3,4-tetrahydrocarbazole With {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; bis[2-(diphenylphosphino)phenyl] ether In toluene at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: benzyl methyl carbonate With N,O-bis-(trimethylsilyl)-acetamide; triethyl borane In hexane; toluene at 50℃; for 18h; Inert atmosphere;
90%
benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

2-acetylaminomalonic acid diethyl ester
1068-90-2

2-acetylaminomalonic acid diethyl ester

2-(N-acetylamino)-2-benzylpropanedioic diethyl ester
3235-26-5

2-(N-acetylamino)-2-benzylpropanedioic diethyl ester

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; N,O-bis-(trimethylsilyl)-acetamide; {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; potassium acetate In tetrahydrofuran at 80℃; for 48h;89%
2.6-dimethylphenol
576-26-1

2.6-dimethylphenol

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

1,3-Dimethyl-2-(phenylmethoxy)benzene
19578-74-6

1,3-Dimethyl-2-(phenylmethoxy)benzene

Conditions
ConditionsYield
With allyl(cyclopentadiene)palladium(II); bis[2-(diphenylphosphino)phenyl] ether In toluene at 60℃; for 3.08333h; Inert atmosphere;89%
2-trityl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole
1350845-99-6

2-trityl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

4a-benzyl-2-trityl-2,3,4,4a-tetrahydro-1H-pyrido[3,4-b]indole
1350845-91-8

4a-benzyl-2-trityl-2,3,4,4a-tetrahydro-1H-pyrido[3,4-b]indole

Conditions
ConditionsYield
Stage #1: 2-trityl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole With {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; bis[2-(diphenylphosphino)phenyl] ether In toluene at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: benzyl methyl carbonate With N,O-bis-(trimethylsilyl)-acetamide; triethyl borane In hexane; toluene at 50℃; for 18h; Inert atmosphere;
89%
dimethyl methoxymalonate
5018-30-4

dimethyl methoxymalonate

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

dimethyl O-methylbenzyltartronate
124604-07-5

dimethyl O-methylbenzyltartronate

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; N,O-bis-(trimethylsilyl)-acetamide; {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; potassium acetate In tetrahydrofuran at 80℃; for 48h;88%
3-Methylindole
83-34-1

3-Methylindole

benzyl methyl carbonate
13326-10-8

benzyl methyl carbonate

3-benzyl-3-methyl-3H-indole
19013-48-0

3-benzyl-3-methyl-3H-indole

Conditions
ConditionsYield
Stage #1: 3-Methylindole With {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; bis[2-(diphenylphosphino)phenyl] ether In toluene at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: benzyl methyl carbonate With N,O-bis-(trimethylsilyl)-acetamide; triethyl borane In hexane; toluene at 50℃; for 18h; Inert atmosphere;
88%

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