Benzyl Methyl Carbonate CAS:13326-10-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i
Cas:13326-10-8
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Cas:13326-10-8
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Cas:13326-10-8
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou
Cas:13326-10-8
Min.Order:0
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inquiry1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.
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inquiryAnsciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
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inquiryBest quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai
factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
Cas:13326-10-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat
Cas:13326-10-8
Min.Order:0
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Type:Lab/Research institutions
inquiryBenzyl methyl carbonateAppearance:Off white to slight yellow solid Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL
Benzyl methyl carbonateAppearance:Off white to slight yellow solid Storage:Stored in shaded, cool and dry places Package:1L 5L 10L 25L bottle Application:pharma intermediate Transportation:Handle with cares to avoid damaging the packages. Protect the
Conditions | Yield |
---|---|
Stage #1: carbonic acid dimethyl ester With lanthanum(III) isopropoxide; 2-(2-methoxyethoxy)ethyl alcohol at 20℃; Stage #2: benzyl alcohol for 1h; Reflux; chemoselective reaction; | 99% |
With lanthanum (III) nitrate * water; 1,1,1-trioctyl-1-methylphosphonium methylcarbonate for 1h; Molecular sieve; Reflux; | 99% |
With 3-methyl-1-(trimethoxysilylpropyl)imidazolium chloride at 80℃; for 5h; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
With pyridine In dichloromethane at 0 - 20℃; | 97% |
With tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide In dichloromethane; water at 20℃; Inert atmosphere; | 91% |
With pyridine In dichloromethane at 0 - 20℃; Inert atmosphere; | 90% |
Conditions | Yield |
---|---|
With bromine at 12℃; for 0h; Inert atmosphere; Darkness; | A 97% B 95% |
potassium monomethylcarbonate
benzyl chloride
benzyl methyl carbonate
Conditions | Yield |
---|---|
With 18-crown-6 ether In toluene Heating; | 95% |
Conditions | Yield |
---|---|
In acetonitrile at 25℃; for 10h; | 91% |
Conditions | Yield |
---|---|
In acetonitrile at 25℃; for 18h; | 86% |
carbonic acid dimethyl ester
benzyl alcohol
A
DBC
B
benzyl methyl carbonate
Conditions | Yield |
---|---|
ytterbium(III) triflate In 1,2-dichloro-ethane for 8h; Heating; | A n/a B 75% |
ytterbium(III) triflate In 1,2-dichloro-ethane for 8h; Heating; | A 60% B 11% |
With tungsten hexacarbonyl at 180℃; for 1h; | A 50% B n/a |
benzyl alcohol
benzyl methyl carbonate
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane In acetone Ambient temperature; | 74% |
With 1,4-diaza-bicyclo[2.2.2]octane In acetone Product distribution; Mechanism; Ambient temperature; further alkyl imidazolium-2-carboxylates, further nucleophiles; | 74% |
carbonic acid dimethyl ester
benzyl alcohol
A
DBC
B
dibenzyl ether
C
benzyl methyl carbonate
Conditions | Yield |
---|---|
at 90℃; for 6h; Reagent/catalyst; Green chemistry; | A 70% B n/a C n/a |
With potassium carbonate under 0.750075 - 759.826 Torr; Heating / reflux; |
tetrabutyl phosphonium bromide
benzyl chloride
carbonic acid dimethyl ester
benzyl methyl carbonate
Conditions | Yield |
---|---|
With hydrogenchloride In diethyl ether; water; N,N-dimethyl-formamide | 65% |
N-benzyloxycarbonyl-2-amino-3-phenylpropionaldehyde
trimethyl ethoxyethyloxyphosphonoacetate
A
benzyl methyl carbonate
Conditions | Yield |
---|---|
With lithium diisopropyl amide 1.) THF, -40 deg C 2.) - 40 to 25 deg C, 2 h; Yield given. Multistep reaction. Yields of byproduct given; | |
With lithium diisopropyl amide 1.) THF, - 40 deg C 2.) - 40 to 25 deg C, 2 h.; Yield given. Multistep reaction. Yields of byproduct given; |
benzyl alcohol
A
O-benzyl carbamate
B
DBC
C
benzyl methyl carbonate
D
dibutyl-bis(benzyloxy)tin
Conditions | Yield |
---|---|
at 175℃; for 6h; Product distribution; |
Benzyl N-hydroxycarbamate
methanol
1,4-diphenyl-1,3-butadiene
B
benzyl methyl carbonate
Conditions | Yield |
---|---|
With 2-ethyl-4,5-dihydrooxazole; oxygen; copper dichloride at 20℃; for 18h; Air atmosphere; chemoselective reaction; |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: lithium azide; water / N,N-dimethyl-formamide / 2.5 h / 130 °C / Inert atmosphere 2: bromine / 0 h / 12 °C / Inert atmosphere; Darkness View Scheme |
carbonic acid dimethyl ester
benzyl alcohol
cyclohexanol
A
benzyl methyl carbonate
B
methyl cyclohexyl carbonate
Conditions | Yield |
---|---|
With methyl trioctylphosphonium acetate at 90℃; for 4h; |
carbon dioxide
benzyl alcohol
methyl iodide
benzyl methyl carbonate
Conditions | Yield |
---|---|
Stage #1: benzyl alcohol With 1-butyl-2,3-methylimidazolium tetrafluoroborate Inert atmosphere; Electrochemical reaction; Stage #2: carbon dioxide at 40℃; under 760.051 Torr; for 2h; Stage #3: methyl iodide With potassium carbonate at 60℃; for 5h; |
Benzyl acetate
benzyl methyl carbonate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: methanol / 2 h / 84 °C / Inert atmosphere; Schlenk technique 2: heterogeneous zinc/imidazole catalyst / 0.5 h / 100 °C / Inert atmosphere; Schlenk technique View Scheme |
methanol
carbon monoxide
carbonic acid dimethyl ester
benzyl alcohol
A
benzyl methyl carbonate
B
benzeneacetic acid methyl ester
Conditions | Yield |
---|---|
With palladium(II) trifluoroacetate; 1,3-bis-(diphenylphosphino)propane; caesium carbonate at 120℃; under 30003 Torr; for 24h; Reagent/catalyst; | A n/a B 47 %Chromat. |
2-Methyl-4-phenyl-3-butyn-2-ol
benzyl methyl carbonate
1,3-diphenyl-1-propyne
Conditions | Yield |
---|---|
With palladium diacetate; potassium carbonate; 1,4-di(diphenylphosphino)-butane In 1,4-dioxane at 120℃; for 12h; Catalytic behavior; Reagent/catalyst; | 99% |
benzyl methyl carbonate
2-methyl-4-(2-methylphenyl)-3-butyn-2-ol
Conditions | Yield |
---|---|
With palladium diacetate; potassium carbonate; 1,4-di(diphenylphosphino)-butane In 1,4-dioxane at 120℃; for 12h; | 99% |
3-methyl-1-(4'-butylphenyl)-1-butyne-3-ol
benzyl methyl carbonate
Conditions | Yield |
---|---|
With palladium diacetate; potassium carbonate; 1,4-di(diphenylphosphino)-butane In 1,4-dioxane at 120℃; for 12h; | 99% |
benzyl methyl carbonate
diethyl 2-phenylmalonate
diethyl 2-benzyl-2-phenylmalonate
Conditions | Yield |
---|---|
With 1,1'-bis(diisopropylphosphino)ferrocene; {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; caesium carbonate In N,N-dimethyl-formamide at 30℃; for 48h; Inert atmosphere; | 98% |
With 1,1'-bis-(diphenylphosphino)ferrocene; N,O-bis-(trimethylsilyl)-acetamide; {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; potassium acetate In tetrahydrofuran at 80℃; for 24h; | 95% |
With 1,1'-bis-(diphenylphosphino)ferrocene; 1,5-cis,cis-cyclooctadiene; [PdCp(η3-C3H5)] In tetrahydrofuran at 80℃; | 84% |
benzyl methyl carbonate
quinolin-3-ylboronic acid
3-benzylquinoline
Conditions | Yield |
---|---|
With potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)); 1,5-bis-(diphenylphosphino)pentane In N,N-dimethyl-formamide at 80℃; for 45h; Suzuki coupling; | 96% |
Conditions | Yield |
---|---|
With allyl(cyclopentadiene)palladium(II); bis[2-(diphenylphosphino)phenyl] ether In toluene at 60℃; for 20.0833h; Inert atmosphere; | 96% |
benzyl methyl carbonate
methyl 4-hydroxylbenzoate
4-benzyloxy-benzoic acid methyl ester
Conditions | Yield |
---|---|
With allyl(cyclopentadiene)palladium(II); bis[2-(diphenylphosphino)phenyl] ether In toluene at 60℃; for 22.0833h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
With allyl(cyclopentadiene)palladium(II); bis[2-(diphenylphosphino)phenyl] ether In toluene at 60℃; for 24.0833h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
With bis[2-(diphenylphosphino)phenyl] ether; bis(η3-allyl-μ-chloropalladium(II)) In dimethyl sulfoxide at 80℃; for 1h; | 95% |
Conditions | Yield |
---|---|
With allyl(cyclopentadiene)palladium(II); bis[2-(diphenylphosphino)phenyl] ether In toluene at 60℃; for 24.0833h; Inert atmosphere; | 94% |
Conditions | Yield |
---|---|
Stage #1: indole With {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; bis[2-(diphenylphosphino)phenyl] ether In toluene at 20℃; for 0.0833333h; Inert atmosphere; Stage #2: benzyl methyl carbonate With N,O-bis-(trimethylsilyl)-acetamide; triethyl borane In hexane; toluene at 50℃; for 18h; Inert atmosphere; | 94% |
Conditions | Yield |
---|---|
With potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)); 1,5-bis-(diphenylphosphino)pentane In N,N-dimethyl-formamide at 80℃; for 24h; Suzuki coupling; | 93% |
benzyl methyl carbonate
N-tosyl tryptamine
Conditions | Yield |
---|---|
Stage #1: N-tosyl tryptamine With {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; bis[2-(diphenylphosphino)phenyl] ether In toluene at 20℃; for 0.0833333h; Inert atmosphere; Stage #2: benzyl methyl carbonate With N,O-bis-(trimethylsilyl)-acetamide; triethyl borane In hexane; toluene at 50℃; for 18h; Inert atmosphere; | 92% |
benzyl methyl carbonate
2-methyl-4-(4-methylphenyl)-3-butyn-2-ol
Conditions | Yield |
---|---|
With palladium diacetate; potassium carbonate; 1,4-di(diphenylphosphino)-butane In 1,4-dioxane at 120℃; for 12h; | 92% |
Conditions | Yield |
---|---|
With potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)); 1,5-bis-(diphenylphosphino)pentane In tert-Amyl alcohol at 100℃; for 24h; Suzuki coupling; | 91% |
2,3-dimethyl-5-methoxyindole
benzyl methyl carbonate
3-benzyl-5-methoxy-2,3-dimethyl-3H-indole
Conditions | Yield |
---|---|
Stage #1: 2,3-dimethyl-5-methoxyindole With {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; bis[2-(diphenylphosphino)phenyl] ether In toluene at 20℃; for 0.0833333h; Inert atmosphere; Stage #2: benzyl methyl carbonate With N,O-bis-(trimethylsilyl)-acetamide; triethyl borane In hexane; toluene at 50℃; for 18h; Inert atmosphere; | 91% |
benzyl methyl carbonate
Diphenylphosphine oxide
benzyldiphenylphosphine oxide
Conditions | Yield |
---|---|
With bis(η3-allyl-μ-chloropalladium(II)); bis[2-(diphenylphosphino)phenyl] ether In N,N-dimethyl-formamide at 100℃; for 48h; Inert atmosphere; Sealed tube; | 91% |
Conditions | Yield |
---|---|
With 1,5-bis-(diphenylphosphino)pentane; potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)) In N,N-dimethyl-formamide at 80℃; for 24h; Suzuki-Miyaura reaction; | 90% |
Conditions | Yield |
---|---|
With allyl(cyclopentadiene)palladium(II); bis[2-(diphenylphosphino)phenyl] ether In toluene at 60℃; for 16.0833h; Inert atmosphere; | 90% |
1,2,3,4-tetrahydrocarbazole
benzyl methyl carbonate
4a-benzyl-2,3,4,4a-tetrahydro-1H-carbazole
Conditions | Yield |
---|---|
Stage #1: 1,2,3,4-tetrahydrocarbazole With {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; bis[2-(diphenylphosphino)phenyl] ether In toluene at 20℃; for 0.0833333h; Inert atmosphere; Stage #2: benzyl methyl carbonate With N,O-bis-(trimethylsilyl)-acetamide; triethyl borane In hexane; toluene at 50℃; for 18h; Inert atmosphere; | 90% |
benzyl methyl carbonate
2-acetylaminomalonic acid diethyl ester
2-(N-acetylamino)-2-benzylpropanedioic diethyl ester
Conditions | Yield |
---|---|
With 1,1'-bis-(diphenylphosphino)ferrocene; N,O-bis-(trimethylsilyl)-acetamide; {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; potassium acetate In tetrahydrofuran at 80℃; for 48h; | 89% |
2.6-dimethylphenol
benzyl methyl carbonate
1,3-Dimethyl-2-(phenylmethoxy)benzene
Conditions | Yield |
---|---|
With allyl(cyclopentadiene)palladium(II); bis[2-(diphenylphosphino)phenyl] ether In toluene at 60℃; for 3.08333h; Inert atmosphere; | 89% |
2-trityl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole
benzyl methyl carbonate
4a-benzyl-2-trityl-2,3,4,4a-tetrahydro-1H-pyrido[3,4-b]indole
Conditions | Yield |
---|---|
Stage #1: 2-trityl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole With {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; bis[2-(diphenylphosphino)phenyl] ether In toluene at 20℃; for 0.0833333h; Inert atmosphere; Stage #2: benzyl methyl carbonate With N,O-bis-(trimethylsilyl)-acetamide; triethyl borane In hexane; toluene at 50℃; for 18h; Inert atmosphere; | 89% |
dimethyl methoxymalonate
benzyl methyl carbonate
dimethyl O-methylbenzyltartronate
Conditions | Yield |
---|---|
With 1,1'-bis-(diphenylphosphino)ferrocene; N,O-bis-(trimethylsilyl)-acetamide; {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; potassium acetate In tetrahydrofuran at 80℃; for 48h; | 88% |
Conditions | Yield |
---|---|
Stage #1: 3-Methylindole With {(η4-1,5-cyclooctadiene)Pd(η3-allyl)}BF4; bis[2-(diphenylphosphino)phenyl] ether In toluene at 20℃; for 0.0833333h; Inert atmosphere; Stage #2: benzyl methyl carbonate With N,O-bis-(trimethylsilyl)-acetamide; triethyl borane In hexane; toluene at 50℃; for 18h; Inert atmosphere; | 88% |
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