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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

meso-Tetra (p-bromophenyl) porphine CAS:29162-73-0

Cas:29162-73-0

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 29162-73-0 with competitive price

Cas:29162-73-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

meso-Tetra (p-bromophenyl) porphine CAS:29162-73-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high qual

meso-Tetra (p-bromophenyl) porphine CAS:29162-73-0

Cas:29162-73-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Tetra(p-bromophenyl)porphyrin

Cas:29162-73-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Pharmaceutical Grade CAS 29162-73-0 with competitive price CAS NO.29162-73-0

Cas:29162-73-0

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

meso-Tetra (p-bromophenyl) porphine Basic information Product Name: meso-Tetra (p-bromophenyl) porphine Synonyms: meso -Tetra (4-bromophenyl) porphine;meso-Tetra (p-bromophenyl) porphine;21H,23H-Porphine, 5,10,15,20-tetrakis(4-bromophenyl)-;5,

meso-Tetra (p-bromophenyl) porphine

Cas:29162-73-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

meso-Tetra (p-bromophenyl) porphine

Cas:29162-73-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/5,10,15,20-(tetra-4-bromophenyl)porphyrin

Cas:29162-73-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

29162-73-0

Cas:29162-73-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 5,10,15,20-Tetrakis(4-bromophenyl)porphyrin 25g

Cas:29162-73-0

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

Tetra(p-bromophenyl)porphyrin

Cas:29162-73-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Meso-Tetra (p-broMophenyl) porphine

Cas:29162-73-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

5,10,15,20-Tetrakis(4-bromophenyl)porphyrin

Cas:29162-73-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

meso-Tetra (p-bromophenyl) porphine

Cas:29162-73-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

meso-Tetra (p-bromophenyl) porphine

Cas:29162-73-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

NUTROCHEM- MANUFACTURE PLACE

best seller Application:API

meso-Tetra (p-bromophenyl) porphine

Cas:29162-73-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

5,10,15,20-Tetrakis(4-bromophenyl)porphyrin

Cas:29162-73-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Sun-shine Bio-technology Corporation Limited

Wuhan Sun-shine Bio-technology Corporation Limited is specializing in the anticancer, antitumor,heart head blood-vessel,pharmaceutical intermediates,fine Chemicals production and customization..Company has strong ability of research and development

meso-Tetra (p-bromophenyl) porphine

Cas:29162-73-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

Cerametek Materials (CMT) is your industrial and R&D supplier: 1. Semiconductor materials: Compounds of II, III, IV, V, VI groups such as Metal Sulfides, Selenides, Tellurides, Arsenide, Antimonide, Phosphide... 2. Advanced ceramic and crys

Meso-Tetra (p-bromophenyl) porphine

Cas:29162-73-0

Min.Order:0

Negotiable

Type:Other

inquiry

Luminescence Technology Corp.

World-class service, High quality, Low cost and Quick delivery. All made in our plant! Storage:To be stored in cool dry environment Package:1g,5g,10g or Bulk Application:Photonic and Optical Device > Porphyrins

meso-Tetra(4-bromophenyl)porphine

Cas:29162-73-0

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Shanghai Sunway Co. Ltd.

Shanghai Sunway Corporation Ltd., a high-tech enterprise specializing in R&D, synthesis, and sales of MOF/COF Ligands, fine chemicals and pharmaceutical intermediates. We have established long-term and good business relationship with suppliers

5,10,15,20-Tetrakis(4-bromophenyl)porphyrin

Cas:29162-73-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd.

The company is supplying production of designs, syntheses and material ligands. Package:1g;5g;25g Application:Catalytic;adsorption separation;hydrogen storage;drug carrier

5,10,15,20-tetrakis(4-bromophenyl)porphyrin

Cas:29162-73-0

Min.Order:0

Negotiable

Type:Other

inquiry

LEANCARE Limited

Tetra(p-bromophenyl)porphyrin

Cas:29162-73-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

pyrrole
109-97-7

pyrrole

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

Conditions
ConditionsYield
With propionic acid In dichloromethane for 0.333333h; Reagent/catalyst; Sealed tube; Microwave irradiation; Inert atmosphere; Schlenk technique;78%
With acetic acid; propionic acid at 130℃; for 0.75h;64.4%
Stage #1: pyrrole; 4-bromo-benzaldehyde With boron trifluoride diethyl etherate In chloroform for 1h;
Stage #2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone In chloroform for 1h; Further stages.;
58%
2-[(4-bromophenyl)hydroxymethyl]-5-[(2-allyloxy-5-bromophenyl)hydroxymethyl]thiophene

2-[(4-bromophenyl)hydroxymethyl]-5-[(2-allyloxy-5-bromophenyl)hydroxymethyl]thiophene

pyrrole
109-97-7

pyrrole

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

A

5-(2-allyloxy-5-bromophenyl)-10,15,20-tri(4-bromophenyl)-21-thiaporphyrin

5-(2-allyloxy-5-bromophenyl)-10,15,20-tri(4-bromophenyl)-21-thiaporphyrin

B

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

Conditions
ConditionsYield
Stage #1: 2-[(4-bromophenyl)hydroxymethyl]-5-[(2-allyloxy-5-bromophenyl)hydroxymethyl]thiophene; pyrrole; 4-bromo-benzaldehyde With boron trifluoride diethyl etherate In dichloromethane for 3h;
Stage #2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane
A 15%
B n/a
pyrrole
109-97-7

pyrrole

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

A

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

B

C44H26Br4N4

C44H26Br4N4

Conditions
ConditionsYield
Stage #1: pyrrole; 4-bromo-benzaldehyde With methanesulfonic acid In dichloromethane for 0.5h;
Stage #2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane for 0.166667h;
A n/a
B 13%
pyrrole
109-97-7

pyrrole

2-(2-nitro-1-(1H-pyrrol-2-yl)ethyl)-5-(phenyl(1H-pyrrol-2-yl)methyl)-1H-pyrrole

2-(2-nitro-1-(1H-pyrrol-2-yl)ethyl)-5-(phenyl(1H-pyrrol-2-yl)methyl)-1H-pyrrole

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

A

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

B

5,10,15-tris(4-bromophenyl)-20-(nitromethyl)porphyrin

5,10,15-tris(4-bromophenyl)-20-(nitromethyl)porphyrin

Conditions
ConditionsYield
Stage #1: 4-bromo-benzaldehyde With copper(II) bis(trifluoromethanesulfonate) In dichloromethane at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: 2-(2-nitro-1-(1H-pyrrol-2-yl)ethyl)-5-(phenyl(1H-pyrrol-2-yl)methyl)-1H-pyrrole In dichloromethane at 20℃; for 0.166667h; Inert atmosphere;
Stage #3: pyrrole Further stages;
A 9%
B 13%
2-[(4-bromophenyl)hydroxymethyl]-5-[(2-methoxy-5-bromophenyl)hydroxymethyl]thiophene

2-[(4-bromophenyl)hydroxymethyl]-5-[(2-methoxy-5-bromophenyl)hydroxymethyl]thiophene

pyrrole
109-97-7

pyrrole

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

A

5-(2-methoxy-5-bromophenyl)-10,15,20-tri(4-bromophenyl)-21-thiaporphyrin

5-(2-methoxy-5-bromophenyl)-10,15,20-tri(4-bromophenyl)-21-thiaporphyrin

B

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

Conditions
ConditionsYield
Stage #1: 2-[(4-bromophenyl)hydroxymethyl]-5-[(2-methoxy-5-bromophenyl)hydroxymethyl]thiophene; pyrrole; 4-bromo-benzaldehyde With boron trifluoride diethyl etherate In dichloromethane
Stage #2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane
A 9%
B n/a
2-[(4-bromophenyl)hydroxymethyl]-5-[(2-methoxyphenyl)hydroxymethyl]thiophene

2-[(4-bromophenyl)hydroxymethyl]-5-[(2-methoxyphenyl)hydroxymethyl]thiophene

pyrrole
109-97-7

pyrrole

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

A

5-(2-methoxyphenyl)-10,15,20-tri(4-bromophenyl)-21-thiaporphyrin

5-(2-methoxyphenyl)-10,15,20-tri(4-bromophenyl)-21-thiaporphyrin

B

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

Conditions
ConditionsYield
Stage #1: 2-[(4-bromophenyl)hydroxymethyl]-5-[(2-methoxyphenyl)hydroxymethyl]thiophene; pyrrole; 4-bromo-benzaldehyde With boron trifluoride diethyl etherate In dichloromethane for 3h;
Stage #2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane
A 3%
B n/a
pyrrole
109-97-7

pyrrole

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

A

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

B

(5Z,10Z,14Z,19Z)-5,10,15-Tris-(4-bromo-phenyl)-20-(4-methoxy-phenyl)-porphyrin
93487-58-2

(5Z,10Z,14Z,19Z)-5,10,15-Tris-(4-bromo-phenyl)-20-(4-methoxy-phenyl)-porphyrin

C

5,15-di(4-bromophenyl)-10,20-di(4-methoxyphenyl)porphyrin
93487-60-6

5,15-di(4-bromophenyl)-10,20-di(4-methoxyphenyl)porphyrin

D

5-(4-bromophenyl)-10,15,20-tri(4-methoxyphenyl)porphyrin
93487-61-7

5-(4-bromophenyl)-10,15,20-tri(4-methoxyphenyl)porphyrin

Conditions
ConditionsYield
In propionic acid for 2h; Heating; cooling overnight; Further byproducts given. Yields of byproduct given;A n/a
B 75 mg
C n/a
D 20 mg
pyrrole
109-97-7

pyrrole

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

A

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

B

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin
22112-78-3

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin

C

(5Z,10Z,14Z,19Z)-5,10,15-Tris-(4-bromo-phenyl)-20-(4-methoxy-phenyl)-porphyrin
93487-58-2

(5Z,10Z,14Z,19Z)-5,10,15-Tris-(4-bromo-phenyl)-20-(4-methoxy-phenyl)-porphyrin

D

5-(4-bromophenyl)-10,15,20-tri(4-methoxyphenyl)porphyrin
93487-61-7

5-(4-bromophenyl)-10,15,20-tri(4-methoxyphenyl)porphyrin

Conditions
ConditionsYield
In propionic acid for 2h; Heating; cooling overnight; Further byproducts given;A n/a
B n/a
C 75 mg
D 20 mg
pyrrole
109-97-7

pyrrole

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

A

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

B

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin
22112-78-3

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin

C

(5Z,10Z,14Z,19Z)-5,10,15-Tris-(4-bromo-phenyl)-20-(4-methoxy-phenyl)-porphyrin
93487-58-2

(5Z,10Z,14Z,19Z)-5,10,15-Tris-(4-bromo-phenyl)-20-(4-methoxy-phenyl)-porphyrin

D

5-(4-bromophenyl)-10,15,20-tri(4-methoxyphenyl)porphyrin
93487-61-7

5-(4-bromophenyl)-10,15,20-tri(4-methoxyphenyl)porphyrin

Conditions
ConditionsYield
With 4-bromo-benzaldehyde In propionic acid for 2h; Heating; cooling overnight; Yield given. Further byproducts given. Yields of byproduct given;A n/a
B n/a
C 75 mg
D 20 mg
pyrrole
109-97-7

pyrrole

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

A

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

B

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin
22112-78-3

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin

C

(5Z,10Z,14Z,19Z)-5,10,15-Tris-(4-bromo-phenyl)-20-(4-methoxy-phenyl)-porphyrin
93487-58-2

(5Z,10Z,14Z,19Z)-5,10,15-Tris-(4-bromo-phenyl)-20-(4-methoxy-phenyl)-porphyrin

D

5-(4-bromophenyl)-10,15,20-tri(4-methoxyphenyl)porphyrin
93487-61-7

5-(4-bromophenyl)-10,15,20-tri(4-methoxyphenyl)porphyrin

Conditions
ConditionsYield
With 4-methoxy-benzaldehyde In propionic acid for 2h; Heating; cooling overnight; Yield given. Further byproducts given. Yields of byproduct given;A n/a
B n/a
C 75 mg
D 20 mg
tetrakis(4-aminophenyl)porphyrin
22112-84-1

tetrakis(4-aminophenyl)porphyrin

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

Conditions
ConditionsYield
With hydrogen bromide; sodium nitrite 1)5 deg C, 2)100 deg. C; Yield given. Multistep reaction;
Stage #1: tetrakis(4-aminophenyl)porphyrin With hydrogenchloride; sodium nitrite In water for 0.166667h; Cooling with ice;
Stage #2: With potassium bromide In water at 20℃; for 2.83333h; Cooling with ice;
pyrrole
109-97-7

pyrrole

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

A

5,10,15,20-tetra-(4-bromophenyl)-17,18-dihydroporphyrin

5,10,15,20-tetra-(4-bromophenyl)-17,18-dihydroporphyrin

B

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

C

5-(4-bromophenyl)-10,15,20-triphenylporphyrin
123444-60-0

5-(4-bromophenyl)-10,15,20-triphenylporphyrin

D

5,10-di-(4-bromophenyl)-15,20-diphenylporphyrin

5,10-di-(4-bromophenyl)-15,20-diphenylporphyrin

Conditions
ConditionsYield
With benzaldehyde; propionic acid for 0.5h; Heating; Further byproducts given. Title compound not separated from byproducts;
5,10,15,20-tetrakis-(4-bromo-phenyl)-porphyrinogene

5,10,15,20-tetrakis-(4-bromo-phenyl)-porphyrinogene

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane; toluene Oxidation;
With air In dichloromethane at 39℃; for 4h;
With air In dichloromethane at 39℃;
5-(4-bromophenyl)dipyrromethane
159152-11-1

5-(4-bromophenyl)dipyrromethane

A

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

B

C48H29Br4N5

C48H29Br4N5

C

C52H32Br4N6

C52H32Br4N6

Conditions
ConditionsYield
With chloranil; trifluoroacetic acid 1.) CH2Cl2, 1 h 2.) CH2Cl2, 1 h, reflux; Yield given; Multistep reaction. Yields of byproduct given;
4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: CF3SO2Cl / CH2Cl2 / 1 h / 20 °C
2: air / CH2Cl2 / 3 h / 39 °C
View Scheme
Multi-step reaction with 2 steps
1: SiO2/SOCl2 / CH2Cl2 / 2 h / 20 °C
2: air / CH2Cl2 / 39 °C
View Scheme
Multi-step reaction with 2 steps
1: PCl5 / CH2Cl2 / 1 h / 20 °C
2: air / CH2Cl2 / 4 h / 39 °C
View Scheme
Multi-step reaction with 2 steps
1: / dichloromethane / 2 h / 20 °C / Green chemistry
2: ammonium cerium (IV) nitrate / dichloromethane / 0.33 h / 20 °C / Green chemistry
View Scheme
Multi-step reaction with 2 steps
1: iodine / dichloromethane / 20 °C / Inert atmosphere
2: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 0.08 h / Inert atmosphere
View Scheme
4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

decyl magnesium halide

decyl magnesium halide

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: BF3*OEt2; NaCl / CH2Cl2 / 0.25 h / 25 °C
2: DDQ / CH2Cl2; toluene
View Scheme
C44H30Br4N4

C44H30Br4N4

A

5,10,15,20-tetra-(4-bromophenyl)-17,18-dihydroporphyrin

5,10,15,20-tetra-(4-bromophenyl)-17,18-dihydroporphyrin

B

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

Conditions
ConditionsYield
With manganese(IV) oxide In 1,4-dioxane at 90℃; for 0.05h; Microwave irradiation; Sealed vessel;
pyrrole
109-97-7

pyrrole

5-nitro-2-thiophenecarboxaldehyde
4521-33-9

5-nitro-2-thiophenecarboxaldehyde

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

A

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

B

C38H20BrN7O6S3

C38H20BrN7O6S3

C

C40H22Br2N6O4S2

C40H22Br2N6O4S2

D

C40H22Br2N6O4S2

C40H22Br2N6O4S2

E

C42H24Br3N5O2S

C42H24Br3N5O2S

Conditions
ConditionsYield
Stage #1: pyrrole; 5-nitro-2-thiophenecarboxaldehyde; 4-bromo-benzaldehyde With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 1h; Inert atmosphere;
Stage #2: With chloranil In dichloromethane for 0.5h; Inert atmosphere;
Stage #3: With triethylamine In dichloromethane Inert atmosphere;
bis(acetylacetonate)nickel(II)

bis(acetylacetonate)nickel(II)

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

nickel(II) 5,10,15,20-tetrakis-(4’-bromophenyl)porphyrin
112592-50-4

nickel(II) 5,10,15,20-tetrakis-(4’-bromophenyl)porphyrin

Conditions
ConditionsYield
In toluene at 140℃; for 1h;100%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

tetra-4-bromophenylporphyrinzinc

tetra-4-bromophenylporphyrinzinc

Conditions
ConditionsYield
With zinc diacetate In methanol; chloroform for 4h; Reflux;97%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

diethylaluminium chloride
96-10-6

diethylaluminium chloride

C44H26AlBr4ClN4

C44H26AlBr4ClN4

Conditions
ConditionsYield
Stage #1: 5,10,15,20-tetrakis(p-bromophenyl)porphyrin In dichloromethane for 0.0833333h; Inert atmosphere; Cooling with ice;
Stage #2: diethylaluminium chloride In dichloromethane at 20℃; for 1h; Inert atmosphere;
97%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

(5,10,15,20-tetrakis(4-bromophenyl)porphyrinato)zinc(II)
29116-34-5

(5,10,15,20-tetrakis(4-bromophenyl)porphyrinato)zinc(II)

Conditions
ConditionsYield
With zinc diacetate In methanol; dichloromethane at 20℃; for 3h;96%
With zinc(II) acetate dihydrate In N,N-dimethyl-formamide for 5h; Inert atmosphere; Reflux;85%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

zinc diacetate
557-34-6

zinc diacetate

(5,10,15,20-tetrakis(4-bromophenyl)porphyrinato)zinc(II)
29116-34-5

(5,10,15,20-tetrakis(4-bromophenyl)porphyrinato)zinc(II)

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 180℃; for 0.5h; Microwave irradiation;96%
In chloroform; N,N-dimethyl-formamide for 0.133333h; Reflux;80%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

phosphonic acid diethyl ester
762-04-9

phosphonic acid diethyl ester

5,10,15,20-tetrakis(4-phosphonatophenyl)porphyrin octaethyl ester

5,10,15,20-tetrakis(4-phosphonatophenyl)porphyrin octaethyl ester

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); triethylamine In toluene at 80℃; for 24h; Inert atmosphere;95%
With tetrakis(triphenylphosphine) palladium(0); triethylamine In tetrahydrofuran; toluene Reflux;26%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

phenylboronic acid
98-80-6

phenylboronic acid

5,10,15,20-tetrakis((1,1′-biphenyl)-4-yl)porphyrin
81566-83-8

5,10,15,20-tetrakis((1,1′-biphenyl)-4-yl)porphyrin

Conditions
ConditionsYield
With potassium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 100℃; for 24h; Reagent/catalyst; Suzuki-Miyaura Coupling;94%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

diethylaluminium chloride
96-10-6

diethylaluminium chloride

C44H24AlBr4ClN4

C44H24AlBr4ClN4

Conditions
ConditionsYield
In hexane; dichloromethane at 25℃; for 1h; Inert atmosphere;93.5%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

5,10,15,20-tetrakis(4-bromophenyl)porphyrin nickel(II)

5,10,15,20-tetrakis(4-bromophenyl)porphyrin nickel(II)

Conditions
ConditionsYield
With nickel diacetate; acetic acid In chloroform at 120℃; for 1h;93%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

zinc(II) acetate dihydrate
5970-45-6

zinc(II) acetate dihydrate

(5,10,15,20-tetrakis(4-bromophenyl)porphyrinato)zinc(II)
29116-34-5

(5,10,15,20-tetrakis(4-bromophenyl)porphyrinato)zinc(II)

Conditions
ConditionsYield
In methanol; chloroform at 77℃; for 2h; Reflux;92%
With acetic acid In chloroform at 120℃; for 1.5h;90%
In chloroform at 120℃; for 2.5h; Sealed tube; Microwave irradiation;87%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

potassium tris(1-pyrazolyl)borate

potassium tris(1-pyrazolyl)borate

Er[N(SiMe3)2]*x[LiCl(THF)3]

Er[N(SiMe3)2]*x[LiCl(THF)3]

C44H24Br4N4(2-)*C9H10BN6(1-)*Er(3+)

C44H24Br4N4(2-)*C9H10BN6(1-)*Er(3+)

Conditions
ConditionsYield
In diethylene glycol dimethyl ether for 12h;91%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

aniline
62-53-3

aniline

5,10,15,20-tetrakis[p-(N-phenylamino)phenyl]porphyrin

5,10,15,20-tetrakis[p-(N-phenylamino)phenyl]porphyrin

Conditions
ConditionsYield
With palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In tetrahydrofuran at 100℃; for 72h;91%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

potassium tris(1-pyrazolyl)borate

potassium tris(1-pyrazolyl)borate

C44H24Br4N4(2-)*C9H10BN6(1-)*Yb(3+)

C44H24Br4N4(2-)*C9H10BN6(1-)*Yb(3+)

Conditions
ConditionsYield
With Yb[N(SiMe3)2]3*x[LiCl(THF)3] In diethylene glycol dimethyl ether for 12h;90%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

zinc(II) acetate dihydrate
5970-45-6

zinc(II) acetate dihydrate

zinc(II) 5,10,15,20-tetrakis-(4'-bromophenyl)porphyrin
29116-34-5

zinc(II) 5,10,15,20-tetrakis-(4'-bromophenyl)porphyrin

Conditions
ConditionsYield
With acetic acid In chloroform at 120℃; for 1.5h;90%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

N-butylamine
109-73-9

N-butylamine

5,10,15,20-tetrakis[p-(n-butylamino)phenyl]porphyrin

5,10,15,20-tetrakis[p-(n-butylamino)phenyl]porphyrin

Conditions
ConditionsYield
With racemic-2-(di-tert-butylphosphino)-1,1′-binaphthyl; palladium diacetate; sodium t-butanolate In tetrahydrofuran at 100℃; for 72h;86%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

[W(≡CSnnBu3)(CO)2(hydrotris(3,5-dimethylpyrazol-1-yl)borate)]

[W(≡CSnnBu3)(CO)2(hydrotris(3,5-dimethylpyrazol-1-yl)borate)]

C116H114B4N28O8W4

C116H114B4N28O8W4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); chloro(dimethylsulfide) gold(I) In toluene for 14h; Inert atmosphere; Schlenk technique; Reflux;86%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

copper(II) acetate monohydrate
6046-93-1

copper(II) acetate monohydrate

copper(II) 5,10,15,20-tetrakis-(4'-bromophenyl)porphyrin
63725-97-3

copper(II) 5,10,15,20-tetrakis-(4'-bromophenyl)porphyrin

Conditions
ConditionsYield
With acetic acid In chloroform at 120℃; for 1.5h;85%
4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triphenylmethyl)-1H-pyrazole
863238-73-7

4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triphenylmethyl)-1H-pyrazole

5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

5,10,15,20-tetrakis(4-(1-trityl-pyrazol-4-yl)phenyl)porphyrin

5,10,15,20-tetrakis(4-(1-trityl-pyrazol-4-yl)phenyl)porphyrin

Conditions
ConditionsYield
With potassium phosphate tribasic trihydrate; palladium diacetate; catacxium A In toluene for 8h; Inert atmosphere; Schlenk technique; Reflux;85%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

phenylacetylene
536-74-3

phenylacetylene

meso-tetrakis(4-phenylethynyl)phenylporphyrin

meso-tetrakis(4-phenylethynyl)phenylporphyrin

Conditions
ConditionsYield
With palladium diacetate; triethylamine; triphenylphosphine In tetrahydrofuran at 91℃; Sonogashira Cross-Coupling; Inert atmosphere;84%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

N-methylaniline
100-61-8

N-methylaniline

5,10,15,20-tetrakis[p-(N-methyl-N-phenylamino)phenyl]porphyrin

5,10,15,20-tetrakis[p-(N-methyl-N-phenylamino)phenyl]porphyrin

Conditions
ConditionsYield
With palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In tetrahydrofuran at 100℃; for 72h;82%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

cobalt(II) diacetate tetrahydrate
6147-53-1

cobalt(II) diacetate tetrahydrate

cobalt(II) 5,10,15,20-tetrakis-(4'-bromophenyl)porphyrin
178476-63-6

cobalt(II) 5,10,15,20-tetrakis-(4'-bromophenyl)porphyrin

Conditions
ConditionsYield
With acetic acid In chloroform at 120℃; for 1.5h;82%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

diphenylamine
122-39-4

diphenylamine

4,4',4'',4'''-(porphyrin-5,10,15,20-tetrayl)tetrakis(N,N-diphenylaniline)

4,4',4'',4'''-(porphyrin-5,10,15,20-tetrayl)tetrakis(N,N-diphenylaniline)

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; 2-dicyclohexylphosphino-2',6'-dimethylbiphenyl In tetrahydrofuran at 100℃; for 72h;81%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

bis(acetylacetonato)palladium(II)

bis(acetylacetonato)palladium(II)

palladium(II) meso-tetrakis(4-bromophenyl)porphyrin
112592-51-5

palladium(II) meso-tetrakis(4-bromophenyl)porphyrin

Conditions
ConditionsYield
In 1-methyl-pyrrolidin-2-one at 180℃; for 0.25h; Schlenk technique; Microwave irradiation;81%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

methyl vinyl ketone
78-94-4

methyl vinyl ketone

(all-E)-5,10,15,20-tetrakis[4-(3-oxobut-1-enyl)phenyl]porphyrin

(all-E)-5,10,15,20-tetrakis[4-(3-oxobut-1-enyl)phenyl]porphyrin

Conditions
ConditionsYield
With palladium diacetate; sodium acetate; triphenylphosphine In N,N-dimethyl-formamide at 120℃; for 24h; Heck reaction;80%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

tin(II) chloride dihdyrate
10025-69-1

tin(II) chloride dihdyrate

5,10,15,20-tetrakis(4-bromophenyl)porphyrintin chloride

5,10,15,20-tetrakis(4-bromophenyl)porphyrintin chloride

Conditions
ConditionsYield
In pyridine at 120℃; for 4h; Darkness;80%
With pyridine Reflux;
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

A

5,10,15,20-tetrakis(4-formylphenyl)-21H,23H-porphyrin

5,10,15,20-tetrakis(4-formylphenyl)-21H,23H-porphyrin

B

meso-5,10,15-(4-formylphenyl)-20-phenylporphyrin

meso-5,10,15-(4-formylphenyl)-20-phenylporphyrin

Conditions
ConditionsYield
Stage #1: 5,10,15,20-tetrakis(p-bromophenyl)porphyrin In diethyl ether at 20℃; for 0.166667h; Schlenk technique; Inert atmosphere;
Stage #2: N,N-dimethyl-formamide With n-butyllithium In diethyl ether at -50 - 20℃; for 3h; Schlenk technique; Inert atmosphere;
A 80%
B 5%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

5,10,15,20-tetrakis(4’-bromophenyl)porphyrinato cobalt (II)
178476-63-6

5,10,15,20-tetrakis(4’-bromophenyl)porphyrinato cobalt (II)

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 0.00833333h; Reflux;80%
In methanol; chloroform for 1.5h; Reflux;62%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

zinc acetate hydrate

zinc acetate hydrate

(5,10,15,20-tetrakis(4-bromophenyl)porphyrinato)zinc(II)
29116-34-5

(5,10,15,20-tetrakis(4-bromophenyl)porphyrinato)zinc(II)

Conditions
ConditionsYield
In methanol; dichloromethane at 20℃; for 5h;80%
5,10,15,20-tetrakis(p-bromophenyl)porphyrin
29162-73-0

5,10,15,20-tetrakis(p-bromophenyl)porphyrin

cobalt(II) diacetate tetrahydrate
6147-53-1

cobalt(II) diacetate tetrahydrate

5,10,15,20-tetrakis(4’-bromophenyl)porphyrinato cobalt (II)
178476-63-6

5,10,15,20-tetrakis(4’-bromophenyl)porphyrinato cobalt (II)

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 150℃; Inert atmosphere;79%

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