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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine c

Diphenylamine 122-39-4 /manufacturer/low price/high quality/in stock

Cas:122-39-4

Min.Order:1 Kilogram

FOB Price: $14.0 / 15.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Test Result Appearance White flake White flake Diphenylamine 152.0~156.0℃

High purity Diphenylamine CAS:122-39-4

Cas:122-39-4

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product description: Product name Diphenylamine CAS number 122-39-4 Assay ≥99.6% Appearance White flake Capacity 2000mt/year Application Rubber antioxidant, dye, pharmaceutic

Diphenylamine

Cas:122-39-4

Min.Order:100 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

diphenylamine

Cas:122-39-4

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

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Hefei TNJ chemical industry co.,ltd

ISO 9001 certificate Good quality Competitive price On time delivery 1.high purity 99.7% 2.use for synthesize rubber antiager, dye, medicine intermediate, lubricating oil antioxidant 3.SGS,MSDS Diphenylamine(DPA) CAS NO.

Good quality Diphenylamine

Cas:122-39-4

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Diphenylamine

Cas:122-39-4

Min.Order:1

Negotiable

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

Good quantity Diphenylamine Basic information Product Name: Diphenylamine Synonyms: (phenylamino)-benzen;Aniline, N-phenyl-;anilino-benzen;Benzenamine, N-phenyl-;Benzenamine,N-phenyl-;

TIANFU-CHEM Diphenylamine, pure, 99%

Cas:122-39-4

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Synonyms: (phenylamino)-benzen;Aniline, N-phenyl-;anilino-benzen;Benzenamine, N-phenyl-;Benzenamine,N-phenyl-;Benzene, (phenylamino)-;Benzene, anilino-;Big Dipper CAS: 122-39-4 MF: C12H11N MW: 169.22 EINECS: 204-539-4 Product Categories: Inter

Diphenylamine 122-39-4 Large in promotion

Cas:122-39-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Diphenylamine with CAS:122-39-4

Cas:122-39-4

Min.Order:1 Kilogram

FOB Price: $35.0 / 50.0

Type:Trading Company

inquiry

Changchun Artel lmport and Export trade company

Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,

Diphenylamine CAS NO.122-39-4

Cas:122-39-4

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Diphenylamine

Cas:122-39-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Diphenylamine

Cas:122-39-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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ZHIJIANG ZENVA SINO COMMERCE AND TRADE CO., LTD.

N-phenylaniline C12H11N 122-39-4 99.5% Appearance:White powder Application:Analytical reagent, REDOX indicator and liquid desiccant, synthesis of organic dyes

Diphenylamine 122-39-4

Cas:122-39-4

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

diphenylamine

Cas:122-39-4

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white crystal powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermed

Diphenylamine

Cas:122-39-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity Diphenylamine

Cas:122-39-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...)

Diphenylamine CAS NO.: 122-39-4

Cas:122-39-4

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Lab/Research institutions

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an

Diphenylamine

Cas:122-39-4

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

Diphenylamin

Cas:122-39-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Diphenylamine

Cas:122-39-4

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Diphenylamine

Cas:122-39-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers233.Safe and fa

Diphenylamine

Cas:122-39-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

DIPHENYLAMINE(RG)

Cas:122-39-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Diphenylamine(DPA)

Cas:122-39-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

Diphenylamine

Cas:122-39-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 122-39-4 with competitive price

Cas:122-39-4

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

DiphenylaMine

Cas:122-39-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Diphenylamine

Cas:122-39-4

Min.Order:0

Negotiable

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

Diphenylamine 99.5% 122-39-4 Application:Diphenylamine 99.5% 122-39-4

Diphenylamine 99.5% 122-39-4

Cas:122-39-4

Min.Order:0

Negotiable

Type:Other

inquiry

Luyunjia Chemistry Xiamen Limited

Xiamen Luyunjia Trading Co.,Ltd Package:1kg/bag; 2644kg/drum, or as customer's request. Application:Xiamen Luyunjia Trading Co.,Ltd Transportation:DHL, EMS, FedEx, TNT, AIR, SEA Port:Beijing,Shanghai,Guangzhou ,China main port

Diphenylamine

Cas:122-39-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

bromobenzene
108-86-1

bromobenzene

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate; Pd{dba(OMe)}2 In toluene at 25℃; for 0.166667h; Buchwald-Hartwig cross coupling reaction;100%
With potassium ethoxide In 1,4-dioxane at 200℃; Catalytic behavior; Buchwald-Hartwig Coupling;100%
With C31H26N4PPdS(1+)*Cl(1-); sodium t-butanolate In toluene at 95℃; for 14h; Catalytic behavior;100%
N-cyclohexylidenebenzenamine
1132-38-3

N-cyclohexylidenebenzenamine

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
palladium-carbon In diethylene glycol dimethyl ether; water; nitrobenzene; benzene100%
palladium-carbon In water; nitrobenzene; benzene100%
palladium-carbon In diethylene glycol dimethyl ether; water; nitrobenzene; benzene100%
diphenylformamide
607-00-1

diphenylformamide

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydroxide In tetrahydrofuran; water for 0.166667h; Ambient temperature;100%
With potassium phosphate; C29H55FeNOP2; hydrogen In tetrahydrofuran at 110℃; under 15001.5 Torr; for 3h; Catalytic behavior;99%
With C18H37ClMoNO2P2; hydrogen; sodium triethylborohydride In tetrahydrofuran; toluene at 100℃; under 37503.8 Torr; for 24h; Autoclave; Glovebox;86%
With [bis({2‐[bis(propan‐2‐yl)phosphanyl]ethyl})amide](carbonyl)(hydride)iron(II); hydrogen In tetrahydrofuran at 100℃; under 22801.5 Torr; for 4h; Catalytic behavior;
iodobenzene
591-50-4

iodobenzene

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
[1,3-{bis-N-(N-methylimidazolylidene)methyl}-5-methylbenzenecopper dibromide]; caesium carbonate at 170℃; for 12h; Conversion of starting material;100%
[(N,N-dipyridyl-imidazolylidene)copper dibromide]; caesium carbonate at 170℃; for 12h; Conversion of starting material;100%
With C31H26N4PPdS(1+)*Cl(1-); sodium t-butanolate In toluene at 95℃; for 10h; Catalytic behavior;100%
aniline
62-53-3

aniline

phenylboronic acid
98-80-6

phenylboronic acid

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With 2,6-dimethylpyridine; fac-tris(2-phenylpyridinato-N,C2')iridium(III); copper diacetate; n-tetradecanoic acid In toluene; acetonitrile at 35℃; for 20h; Chan-Lam Coupling; Irradiation;100%
With copper diacetate; potassium carbonate; benzoic acid In ethyl acetate at 80℃; for 4h; air;98%
With potassium carbonate In water at 20℃; Reagent/catalyst; Solvent;95%
diphenyl-carbamic acid allyl ester

diphenyl-carbamic acid allyl ester

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With aminomethyl resin-supported N-propylbarbituric acid; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃; for 1h;100%
1N-NaOH

1N-NaOH

N-cyclohexylidenebenzenamine
1132-38-3

N-cyclohexylidenebenzenamine

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
palladium-carbon In diethylene glycol dimethyl ether; water; nitrobenzene; benzene100%
palladium-carbon In diethylene glycol dimethyl ether; water; nitrobenzene; benzene100%
palladium-carbon In water; nitrobenzene; benzene99.4%
palladium-carbon In water; nitrobenzene; benzene99.4%
1-tert-butyl-1,1-dimethyl-N,N-diphenylsilanamine
1321455-60-0

1-tert-butyl-1,1-dimethyl-N,N-diphenylsilanamine

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With silica gel In ethanol; water at 20℃; for 2h;100%
aniline
62-53-3

aniline

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

A

biphenyl
92-52-4

biphenyl

B

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
Stage #1: aniline With n-butyllithium; dichloro(N,N,N’,N‘-tetramethylethylenediamine)zinc In tetrahydrofuran; hexane at 0 - 20℃; for 0.5h; Inert atmosphere; Schlenk technique;
Stage #2: phenylmagnesium bromide With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; bis(acetylacetonate)nickel(II); 1,2-dichloro-2-methylpropane In tetrahydrofuran; hexane at 0 - 20℃; for 3h; Inert atmosphere; Schlenk technique;
A n/a
B 100%
aniline
62-53-3

aniline

chlorobenzene
108-90-7

chlorobenzene

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With sodium t-butanolate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride; Ni(PPh3)2(1-(p-acetylnaphthyl))Cl In 1,4-dioxane at 100℃;99%
With bis(η3-allyl-μ-chloropalladium(II)); potassium tert-butylate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In 1,4-dioxane at 100℃; for 1.5h; Inert atmosphere;99%
With sodium t-butanolate In toluene at 110℃; Inert atmosphere; Glovebox; chemoselective reaction;99%
triphenylbismuth bis(trifluoroacetate)
28719-46-2

triphenylbismuth bis(trifluoroacetate)

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
copper In dichloromethane for 0.5h; Ambient temperature;99%
toluene-4-sulfonic acid phenyl ester
640-60-8

toluene-4-sulfonic acid phenyl ester

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With (1,3-bis(2,6-diisopropylphenyl)imidazolidene)Ni(styrene)2; lithium tert-butoxide In 1,4-dioxane for 10h; Inert atmosphere; Heating; Schlenk technique;99%
With potassium hydroxide; [(N,N-dimethylbenzylamine)(trifluoroacetato)palladium(II)]2; XPhos In water at 80℃; for 16h;91%
With di-tert-butyl{2′-isopropoxy-[1,1′-binaphthalen]-2-yl}phosphane; potassium phosphate; palladium diacetate; phenylboronic acid In butan-1-ol at 110℃; for 2h; Inert atmosphere;99 %Chromat.
N,N-diphenylbenzamide
4051-56-3

N,N-diphenylbenzamide

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With potassium phosphate; C29H55FeNOP2; hydrogen In tetrahydrofuran at 130℃; under 37503.8 Torr; for 3h; Catalytic behavior;99%
With triethyl borane; sodium hydroxide In tert-butyl methyl ether at 80℃; for 6h; Inert atmosphere; Sealed tube;78%
Stage #1: N,N-diphenylbenzamide With Triethoxysilane; sodium triethylborohydride In tert-butyl methyl ether at 80℃; for 6h;
Stage #2: With hydrogenchloride In tert-butyl methyl ether; water at 20℃; for 1h; chemoselective reaction;
73%
Multi-step reaction with 2 steps
1: potassium hydroxide; triethyl borane / tetrahydrofuran / 24 h / 100 °C / Inert atmosphere; Schlenk technique; Sealed tube
2: sodium hydroxide; water / tetrahydrofuran / 1 h / 25 °C / Inert atmosphere; Schlenk technique; Sealed tube
View Scheme
10H-phenothiazine
92-84-2

10H-phenothiazine

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With 3-Hydroxy-1-methylpiperidine; nickel diacetate; sodium hydride In tetrahydrofuran at 65℃; for 4h;98%
With sodium tetrahydroborate; nickel dichloride In tetrahydrofuran; methanol for 1h; Mechanism; Ambient temperature; kinetic isotope effect; desulfurization of other benzo- and dibenzothiophenes;68%
bei der Zinkstaub-Destillation;
4-[(diphenylamino)-methyl]-benzonitrile

4-[(diphenylamino)-methyl]-benzonitrile

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With Triethylgermyl-natrium In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide at 60℃; for 68h;98%
Phenyl triflate
17763-67-6

Phenyl triflate

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With C46H27F24FeNiP2(1+)*CF3O3S(1-); triethylamine In 2-methyltetrahydrofuran at 100℃; for 16h; Solvent; Reagent/catalyst; Inert atmosphere; Schlenk technique; Glovebox; Sealed tube;98%
With [(2,6-bis(2,4,6-triisopropylphenyl)phenyl)dicyclohexylphosphine](allyl-η3)palladium(II) chloride; potassium hydrogencarbonate In dodecane; tert-butyl alcohol at 100℃; for 12h; Inert atmosphere; Sealed tube;92%
With caesium carbonate; palladium diacetate In toluene at 100℃; for 10h;
With palladium diacetate; caesium carbonate; XPhos In toluene at 100℃; for 1.5h;
With XPhos; palladium diacetate; caesium carbonate In toluene at 20 - 100℃; Inert atmosphere;
bromobenzene
108-86-1

bromobenzene

Ph5FcP(t-BU)2

Ph5FcP(t-BU)2

Pd(dba)2/Ph5FcP(t-Bu)2

Pd(dba)2/Ph5FcP(t-Bu)2

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With aniline; sodium t-butanolate; Pd(dba)2 In chlorobenzene; toluene98%
phenol
108-95-2

phenol

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With palladium on activated carbon; ammonium formate; lithium hydroxide In m-xylene at 160℃; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Schlenk technique; Inert atmosphere;98%
Multi-step reaction with 2 steps
1: Inert atmosphere
2: bis(1,5-cyclooctadiene)nickel(0); sodium t-butanolate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride / 1,4-dioxane / 3 h / 80 °C / Inert atmosphere
View Scheme
With ammonium formate In 1,3,5-trimethyl-benzene at 140℃; under 760.051 Torr; Reagent/catalyst; Solvent; Temperature; Inert atmosphere;73 %Chromat.
iodobenzene
591-50-4

iodobenzene

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With L-arginine; potassium hydroxide In water at 80℃; under 760.051 Torr; for 2h; Reagent/catalyst; Solvent; Temperature; Green chemistry;98%
With potassium phosphate; copper(l) iodide; lithium amide In N,N-dimethyl-formamide at 130℃; for 24h; Inert atmosphere; chemoselective reaction;90%
Multi-step reaction with 2 steps
1: ammonia / water / 16 h / 75 °C / Ionic liquid
2: Cu2O nanoparticles (Cu2O-NPs) synthesized in n-Bu4POAc from CuCO3 / 16 h / 75 °C / Ionic liquid
View Scheme
N-carbobenzyloxydiphenylamine
102078-86-4

N-carbobenzyloxydiphenylamine

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With N1,N1,N12,N12-tetramethyl-7,8-dihydro-6H-dipyrido[1,2-a:2,1'-c][1,4]diazepine-2,12-diamine In N,N-dimethyl-formamide for 72h; Inert atmosphere; Glovebox; UV-irradiation;98%
phenyl methanesulfonate
16156-59-5

phenyl methanesulfonate

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With potassium phosphate; bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; N-[2-(di(1-adamantyl)phosphino)phenyl]morpholine In 1,4-dioxane; tert-butyl alcohol at 110℃; Buchwald-Hartwig Coupling; Inert atmosphere; Glovebox; chemoselective reaction;98%
phenyl N,N-dimethylsulfamate
66950-63-8

phenyl N,N-dimethylsulfamate

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With sodium t-butanolate In ethylene glycol at 100℃; for 12h;97%
With 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)nickel(0); sodium t-butanolate In toluene at 20 - 105℃; Inert atmosphere;94%
With bis(1,5-cyclooctadiene)nickel(0); sodium t-butanolate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In 1,4-dioxane at 80℃; for 3h; Inert atmosphere;77%
With sodium t-butanolate; bis(1,5-cyclooctadiene)nickel (0); 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In 1,4-dioxane at 80℃; for 3h; Inert atmosphere;77%
With (1,2-dimethoxyethane)dichloronickel(II); 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole; sodium t-butanolate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In 1,4-dioxane at 23 - 80℃; for 4h; Inert atmosphere;63%
triphenyltin chloride
639-58-7

triphenyltin chloride

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With triethylamine at 95℃; Catalytic behavior; Reagent/catalyst; Temperature;97%
With triethylamine at 90℃; for 12h; Reagent/catalyst; Temperature; Stille Cross Coupling;96%
With triethylamine at 20℃; for 15h; Catalytic behavior; Temperature;95%
With copper diacetate; triethylamine at 20℃; for 24h;94%
N,N-diphenylacetamide
519-87-9

N,N-diphenylacetamide

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With potassium phosphate; C29H55FeNOP2; hydrogen In tetrahydrofuran at 110℃; under 22502.3 Torr; for 3h; Catalytic behavior;96%
With triethyl borane; sodium hydroxide In tert-butyl methyl ether at 80℃; for 6h; Inert atmosphere; Sealed tube;89%
Stage #1: N,N-diphenylacetamide With Triethoxysilane; sodium triethylborohydride In tert-butyl methyl ether at 80℃; for 6h;
Stage #2: With hydrogenchloride In tert-butyl methyl ether; water at 20℃; for 1h; chemoselective reaction;
83%
triphenylbismuth(V) diacetate
28899-97-0

triphenylbismuth(V) diacetate

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
copper In dichloromethane for 2h; Ambient temperature;96%
With copper(II) dipivaloate In dichloromethane for 0.0833333h; Ambient temperature;100 % Chromat.
N,N-diphenylpyridine-2-sulfonamide
370839-63-7

N,N-diphenylpyridine-2-sulfonamide

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With magnesium In methanol at 0℃; for 1h;96%
iodobenzene
591-50-4

iodobenzene

aniline
62-53-3

aniline

A

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

B

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With [2,2]bipyridinyl; potassium tert-butylate; copper(l) iodide In toluene at 115℃; for 3.5h; Product distribution; Further Variations:; Reagents;A 95%
B 2%
With copper at 180℃; for 12h;A 46%
B 31%
With copper(l) iodide; cesium fluoride In dimethyl sulfoxide at 130℃; for 24h; Ullmann Condensation; Inert atmosphere; Glovebox;A 12%
B 39 %Chromat.
With potassium tert-butylate; copper(l) iodide; tributylphosphine In toluene at 110℃; for 3.5h; Product distribution; Further Variations:; Catalysts; high pressure;
N,N-diphenylacetamide
519-87-9

N,N-diphenylacetamide

A

ethanol
64-17-5

ethanol

B

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With hydrogen In toluene at 160℃; under 45004.5 Torr; for 15h; Catalytic behavior; Autoclave;A 89 %Chromat.
B 95%
With cis-[Ru(CH3CN)2(η3-C3H5)(CO1,5-cyclooctadiene)]BF4; hydrogen; potassium hexamethylsilazane; (2-aminoethyl)diphenylphosphane In tetrahydrofuran at 100℃; under 38002.6 Torr; for 24h; Autoclave;
With {Ru(H)(BH4)(CO)(3-(di-tert-butylphosphino)-N-((1-methyl-1H-imidazol-2-yl)methyl)propylamine)}; hydrogen In isopropyl alcohol at 120℃; under 22502.3 Torr; for 18h; Autoclave;A 96 %Chromat.
B 96 %Chromat.
With C16H25MnN3O3P(1+)*Br(1-); potassium tert-butylate; hydrogen In cyclohexane at 100℃; under 22502.3 Torr; for 16h; Inert atmosphere; Autoclave;A 80 %Chromat.
B 82 %Chromat.
N,N-diphenyloctanamide
1369416-85-2

N,N-diphenyloctanamide

A

octanol
111-87-5

octanol

B

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With hydrogen; sodium methylate; [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II) In methanol at 100℃; under 37503.8 Torr; for 16h; Autoclave;A 77%
B 95%
bromocyane
506-68-3

bromocyane

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With trimethylamine Ambient temperature;100%
With magnesium carbonate In water; acetonitrile for 288h; Heating;54%
diphenylamine
122-39-4

diphenylamine

chloroacetyl chloride
79-04-9

chloroacetyl chloride

2-chloro-N,N-diphenylacetamide
5428-43-3

2-chloro-N,N-diphenylacetamide

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃; for 0.333333h;100%
In toluene at 90℃; for 4h; Inert atmosphere;99%
In N,N-dimethyl-formamide at 80℃; for 2h;97%
diphenylamine
122-39-4

diphenylamine

bis(4-bromophenyl)amine
16292-17-4

bis(4-bromophenyl)amine

Conditions
ConditionsYield
With N-Bromosuccinimide Bromination;100%
With N-Bromosuccinimide In N,N-dimethyl-formamide at 0℃; for 6h; Inert atmosphere;100%
With tetra-N-butylammonium tribromide In chloroform for 0.0333333h; Ambient temperature;99%
diphenylamine
122-39-4

diphenylamine

N-nitrosodiphenylamine
382165-80-2

N-nitrosodiphenylamine

Conditions
ConditionsYield
With oxalic acid; sodium nitrite In dichloromethane for 5h; Ambient temperature;100%
With [NO(1+)*18-crown-6*H(NO3)2(1-)] In dichloromethane at 20℃; for 0.0833333h;100%
With sodium azide In water; acetonitrile at 20℃;100%
carbon disulfide
75-15-0

carbon disulfide

diphenylamine
122-39-4

diphenylamine

lithium N,N-diphenyl dithiocarbamate
112492-65-6

lithium N,N-diphenyl dithiocarbamate

Conditions
ConditionsYield
With lithium derivative In water; toluene; benzene for 2h;100%
Stage #1: diphenylamine With Lithium dimsyl In tetrahydrofuran at 0℃; for 0.5h;
Stage #2: carbon disulfide In tetrahydrofuran at 0 - 20℃; for 12h; Reagent/catalyst;
98%
With n-butyllithium 1) hexane, -78 deg C to RT, 2) -78 deg C to RT; Multistep reaction;
Stage #1: diphenylamine With n-butyllithium In tetrahydrofuran at 0 - 20℃; for 0.5h;
Stage #2: carbon disulfide In tetrahydrofuran at 0 - 12℃; for 12h;
Stage #1: diphenylamine With n-butyllithium In tetrahydrofuran at 0℃; for 0.5h;
Stage #2: carbon disulfide In tetrahydrofuran at 0 - 20℃; for 12h;
pentafluorosulfanyl isocyanate
2375-30-6

pentafluorosulfanyl isocyanate

diphenylamine
122-39-4

diphenylamine

N'-(Pentafluorosulfanyl)-N,N-diphenylurea
90598-10-0

N'-(Pentafluorosulfanyl)-N,N-diphenylurea

Conditions
ConditionsYield
In chloroform100%
diphenylamine
122-39-4

diphenylamine

diphenylamine; deprotonated form
61057-05-4

diphenylamine; deprotonated form

Conditions
ConditionsYield
With NaH-cryptand<2.2.1> In tetrahydrofuran for 0.166667h;100%
1-bromo-4-tert-butylbenzene
3972-65-4

1-bromo-4-tert-butylbenzene

diphenylamine
122-39-4

diphenylamine

N,N-diphenyl-N-(4-tert-butylphenyl)amine
36809-23-1

N,N-diphenyl-N-(4-tert-butylphenyl)amine

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); potassium tert-butylate In toluene at 20℃; for 4h;100%
With palladium diacetate; P(i-BuNCH2CH2)3N; sodium t-butanolate In toluene at 80℃;96%
for 3h;96%
diphenylamine
122-39-4

diphenylamine

diphenyl acetylene
501-65-5

diphenyl acetylene

((E)-1,2-Diphenyl-vinyl)-diphenyl-amine
134414-84-9

((E)-1,2-Diphenyl-vinyl)-diphenyl-amine

Conditions
ConditionsYield
phosphazene base-P4-tert-butyl In hexane; dimethyl sulfoxide at 120℃; for 24h;100%
2-chloropyridine
109-09-1

2-chloropyridine

diphenylamine
122-39-4

diphenylamine

2-N,N-diphenylaminopyridine
50910-08-2

2-N,N-diphenylaminopyridine

Conditions
ConditionsYield
With sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0); P(i-BuNCH2CH2)3N In toluene at 100℃; for 20h; Buchwald-Hartwig amination;100%
With palladium diacetate; sodium t-butanolate; ruphos In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Green chemistry;99%
With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry;99%
bromochlorobenzene
106-39-8

bromochlorobenzene

diphenylamine
122-39-4

diphenylamine

(p-chlorophenyl)diphenylamine
4316-56-7

(p-chlorophenyl)diphenylamine

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; palladium 10% on activated carbon; sodium t-butanolate In 1,3,5-trimethyl-benzene for 24h; Inert atmosphere; Reflux;100%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 80℃;90.7%
With tris-(dibenzylideneacetone)dipalladium(0); johnphos; sodium t-butanolate In toluene at 100℃; for 24h; Buchwald-Hartwig Coupling; Sealed tube; Inert atmosphere;79%
diphenylamine
122-39-4

diphenylamine

allyl bromide
106-95-6

allyl bromide

N-allyldiphenylamine
65178-51-0

N-allyldiphenylamine

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; potassium carbonate In acetonitrile Reflux;100%
With tetra-(n-butyl)ammonium iodide; potassium carbonate In acetonitrile Reflux;100%
With tetra-(n-butyl)ammonium iodide; potassium carbonate In acetonitrile at 110℃; Inert atmosphere;81%
(chloromethyl)methoxydimethylsilane
18143-33-4

(chloromethyl)methoxydimethylsilane

diphenylamine
122-39-4

diphenylamine

N-{[dimethyl(methoxy)silyl]methyl}-N',N'-diphenyl-urea

N-{[dimethyl(methoxy)silyl]methyl}-N',N'-diphenyl-urea

Conditions
ConditionsYield
In toluene at 80℃; for 2h;100%
diphenylamine
122-39-4

diphenylamine

4'-biphenyl chloride
2051-62-9

4'-biphenyl chloride

N,N-bis(phenyl)-4-biphenylamine
4432-94-4

N,N-bis(phenyl)-4-biphenylamine

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; palladium 10% on activated carbon; sodium t-butanolate In 1,3,5-trimethyl-benzene for 24h; Inert atmosphere; Reflux;100%
Stage #1: diphenylamine; 4'-biphenyl chloride With palladium diacetate; sodium sulfate; sodium t-butanolate; XPhos for 1h; Buchwald-Hartwig Coupling; Milling;
Stage #2: In water; ethyl acetate for 0.0333333h; Reagent/catalyst; Buchwald-Hartwig Coupling; Milling;
51%
diphenylamine
122-39-4

diphenylamine

C12H10N(1-)*K(1+)*0.5C4H8O

C12H10N(1-)*K(1+)*0.5C4H8O

Conditions
ConditionsYield
With potassium hydride In tetrahydrofuran at 50℃; for 6h; Schlenk technique; Inert atmosphere;100%
undec-10-enoyl chloride
38460-95-6

undec-10-enoyl chloride

diphenylamine
122-39-4

diphenylamine

N,N-diphenylundec-10-enamide
52007-57-5

N,N-diphenylundec-10-enamide

Conditions
ConditionsYield
In toluene for 3h; Reflux; Inert atmosphere;100%
hydrogen tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
121281-53-6

hydrogen tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

diphenylamine
122-39-4

diphenylamine

C12H11N*H(1+)*C32H12BF24(1-)

C12H11N*H(1+)*C32H12BF24(1-)

Conditions
ConditionsYield
In diethyl ether at 20℃; for 1h; Glovebox; Inert atmosphere;100%
2,2,6-trimethyl-4H-1,3-dioxin-4-one
5394-63-8

2,2,6-trimethyl-4H-1,3-dioxin-4-one

diphenylamine
122-39-4

diphenylamine

N,N-diphenylacetoacetamide
2540-31-0

N,N-diphenylacetoacetamide

Conditions
ConditionsYield
In toluene at 20℃; for 12.25h; Reflux;100%
1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene

1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene

diphenylamine
122-39-4

diphenylamine

C32H42N2

C32H42N2

Conditions
ConditionsYield
In pentane at 20℃; for 0.5h; Inert atmosphere; Glovebox; Schlenk technique;100%
(5R,6S,9R)-2-(2,6-diisopropylphenyl)-6-isopropyl-3,3,9-trimethyl-2-azaspiro[4.5]decan-1-ylidene
869085-78-9

(5R,6S,9R)-2-(2,6-diisopropylphenyl)-6-isopropyl-3,3,9-trimethyl-2-azaspiro[4.5]decan-1-ylidene

diphenylamine
122-39-4

diphenylamine

C39H54N2

C39H54N2

Conditions
ConditionsYield
In pentane at 20℃; for 0.5h; Inert atmosphere; Glovebox;100%
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