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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiryhebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm
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inquiryProduct Description Product website: http://www.finerchem.com/pro01en/id/33.html Product Name 1-Bromo-4-tert-butylbenzene CAS No.
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inquiryIdentification Product name: Bromo-4-tert-butylbenzene Product name: Bromo-4-tert-butylbenzene Molecular formula: C10H13Br Molecular weight:
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inquiry1-Bromo-4-tert-butylbenzene CAS:3972-65-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organi
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inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
1-Bromo-4-tert-butylbenzene CAS: 3972-65-4 Specification Item Standard Identification A.H-NMR:Comply with the structure B.LC-MS:Comply with the structure C.Th
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inquiryProduct name: 1-Bromo-4-Butylbenzene CAS No.: 3972-65-4 Molecule Formula:C10H13Br Molecule Weight:213.11 Purity: 99.0% Package: 200kg/drum Description:Colorless liquid Manufacture Standards:Enterprise Standard TESTING ITEMS
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inquiry1-Bromo-4-tert-butylbenzene Chemical Properties Melting point 13-16 °C(lit.) Boiling point 80-81 °C2 mm Hg(lit.) density 1.229 g/mL at 25 °C(lit.) refractive index n20/D 1.533(lit.) Fp 97 °C form Liquid Specifi
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inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
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inquirytert-butylbenzene
1-bromo-4-tert-butylbenzene
Conditions | Yield |
---|---|
With bromine; iodine at 0℃; | 100% |
With carbon dioxide; bromine at 40℃; under 187519 Torr; for 2h; Supercritical conditions; Green chemistry; | 100% |
With benzyltrimethylazanium tribroman-2-uide; zinc(II) chloride In acetic acid at 70℃; for 2h; | 95% |
Conditions | Yield |
---|---|
97% |
2-(4-tert-butylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1-bromo-4-tert-butylbenzene
Conditions | Yield |
---|---|
With copper(ll) bromide In methanol Heating; | 96% |
bromobenzene
3,6-di-tert-butylbenzene-1,2-diol
1-bromo-4-tert-butylbenzene
Conditions | Yield |
---|---|
With sulfuric acid | 90% |
p-trifluoromethylphenyl bromide
trimethylaluminum
1-bromo-4-tert-butylbenzene
Conditions | Yield |
---|---|
In hexane; 1,2-dichloro-ethane at 25 - 50℃; Inert atmosphere; | 89% |
bromobenzene
pivaloyl chloride
A
1-bromo-4-tert-butylbenzene
B
1-(4-bromophenyl)-2,2-dimethylpropan-1-one
Conditions | Yield |
---|---|
With iodine for 0.166667h; Ambient temperature; Irradiation; | A 8% B 87% |
With iron(III) sulfate In hexane at 20℃; for 0.75h; Friedel-Crafts acylation; Sonication; | A 8% B 72% |
With aluminium trichloride In hexane for 0.166667h; Ambient temperature; Irradiation; | A 25% B 50% |
4-tert-butylphenyl triflate
1-bromo-4-tert-butylbenzene
Conditions | Yield |
---|---|
With [Cp*Ru(CH3CN)3]OTf; lithium bromide at 120℃; for 48h; Inert atmosphere; | 87% |
Multi-step reaction with 2 steps 1: 86 percent / Et3N / PdCl2(dppf) / dioxane / Heating 2: 96 percent / aq. CuBr2 / methanol / Heating View Scheme |
1-bromo-4-tert-butylbenzene
Conditions | Yield |
---|---|
With tetra-N-butylammonium tribromide In tetrahydrofuran; water at 20℃; for 0.333333h; chemoselective reaction; | 86% |
With tetra-N-butylammonium tribromide In tetrahydrofuran; water at 20℃; for 0.333333h; chemoselective reaction; | 86% |
(P(o-tol)3)2Pd2(C6H4tBu-4)2Br2
tri-tert-butyl phosphine
A
bis(tri-t-butylphosphine)palladium(0)
B
1-bromo-4-tert-butylbenzene
Conditions | Yield |
---|---|
In benzene-d6 byproducts: P(o-tol)3, biaryl, arene; in C6D6 soln. at 70°C; K(eq) = 3.3(6)E-4; | A n/a B 75% |
bromobenzene
pivaloyl chloride
A
1-bromo-4-tert-butylbenzene
B
1-(2-bromophenyl)-2,2-dimethyl-propan-1-one
C
1-(4-bromophenyl)-2,2-dimethylpropan-1-one
Conditions | Yield |
---|---|
With iodine for 6h; Ambient temperature; | A 64% B 6% C 17% |
With aluminium trichloride In hexane for 5h; Ambient temperature; | A 42% B 5% C 12% |
Conditions | Yield |
---|---|
With o-tetrachloroquinone; C16H21IMoO3 In 1,2-dichloro-ethane at 80℃; for 12h; Friedel-Crafts Alkylation; Inert atmosphere; Schlenk technique; Green chemistry; regioselective reaction; | 21.3% |
4-tert-Butylaniline
allyl bromide
A
1-bromo-4-tert-butylbenzene
B
1-allyl-4-(tert-butyl)benzene
Conditions | Yield |
---|---|
With tert.-butylnitrite In acetonitrile at 45 - 50℃; for 1.33h; | A n/a B 19% |
Conditions | Yield |
---|---|
With o-tetrachloroquinone; C16H21IMoO3 In 1,2-dichloro-ethane at 80℃; for 12h; Friedel-Crafts Alkylation; Inert atmosphere; Schlenk technique; Green chemistry; regioselective reaction; | 17.2% |
(i) AlCl3, MeNO2, (ii) /BRN= 1730872/; Multistep reaction; |
Conditions | Yield |
---|---|
With phosphoric acid at 160 - 170℃; |
tert-butylbenzene
A
1-bromo-4-tert-butylbenzene
B
2-tert-butylbromobenzene
Conditions | Yield |
---|---|
With thallium (III) oxide; trifluoroacetic acid; potassium bromide at 20℃; for 6h; | |
With bromine In hexane at 25℃; for 0.0333333h; Darkness; | |
With bromine; iodine |
Conditions | Yield |
---|---|
With tetrachloromethane; bromine; iron |
Conditions | Yield |
---|---|
With aluminium trichloride |
Conditions | Yield |
---|---|
With chlorosulfonic acid |
tert-butylbenzene
bromine
acetic acid
A
1-bromo-4-tert-butylbenzene
B
1-bromo-3-(tertbutyl)benzene
C
2-tert-butylbromobenzene
Conditions | Yield |
---|---|
at 25℃; Kinetics; |
perchloric acid
tert-butylbenzene
A
1-bromo-4-tert-butylbenzene
B
1-bromo-3-(tertbutyl)benzene
C
2-tert-butylbromobenzene
Conditions | Yield |
---|---|
at 25℃; Kinetics; |
tert-butylbenzene
A
1-bromo-4-tert-butylbenzene
B
1,3-di-tert-butylbenzene
C
1-bromo-3-(tertbutyl)benzene
D
2-tert-butylbromobenzene
Conditions | Yield |
---|---|
With bromine at 25℃; for 20h; Irradiation; Yield given; |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 98 percent / pyridine / CH2Cl2 / 0.25 h / 0 °C 2: 86 percent / Et3N / PdCl2(dppf) / dioxane / Heating 3: 96 percent / aq. CuBr2 / methanol / Heating View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: H2SO4 2: AlCl3 / 45 °C 3: iron-turnings; tetrachloromethane; bromine View Scheme | |
Multi-step reaction with 3 steps 1: aqueous H2SO4 2: AlCl3 / 45 °C 3: iron-turnings; tetrachloromethane; bromine View Scheme | |
Multi-step reaction with 2 steps 1: aqueous H2SO4 2: iron-turnings; tetrachloromethane; bromine View Scheme | |
Multi-step reaction with 2 steps 1: AlCl3 / 15 - 22 °C 2: iron-turnings; tetrachloromethane; bromine View Scheme | |
Multi-step reaction with 2 steps 1: HCl; AlCl3 / 60 °C / Einleiten von Isobutylen 2: iron-turnings; tetrachloromethane; bromine View Scheme |
3-Formylphenylboronic acid
1-bromo-4-tert-butylbenzene
(4-tert-butylphenyl)diazonium tetrafluoroborate
A
tert-butylbenzene
B
1-bromo-4-tert-butylbenzene
C
1-tert-butyl-4-fluorobenzene
Conditions | Yield |
---|---|
With trimethylsilyl bromide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 20℃; | A 9 % Chromat. B 31 % Chromat. C 42 % Chromat. |
bromobenzene
t-butyl bromide
A
1-bromo-4-tert-butylbenzene
B
2-tert-butylbromobenzene
Conditions | Yield |
---|---|
With o-tetrachloroquinone; C16H21IMoO3 In 1,2-dichloro-ethane at 80℃; for 12h; Friedel-Crafts Alkylation; Inert atmosphere; Schlenk technique; Green chemistry; Overall yield = 25.1 %; regioselective reaction; |
Conditions | Yield |
---|---|
Stage #1: 4-tert-Butylaniline With hydrogenchloride; tert.-butylnitrite In methanol; diethyl ether; N,N-dimethyl-formamide at 0℃; for 0.5h; Stage #2: With Bromotrichloromethane; tetrabutylammonium perchlorate In methanol; diethyl ether; N,N-dimethyl-formamide at 20℃; for 3h; Sandmeyer Reaction; Electrochemical reaction; | 53 %Chromat. |
1-bromo-4-tert-butylbenzene
Conditions | Yield |
---|---|
With Bromotrichloromethane; [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate In ethyl acetate for 12h; Reagent/catalyst; Schlenk technique; Inert atmosphere; Irradiation; | 74 %Chromat. |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 20 °C / Inert atmosphere; Schlenk technique 2: [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; Bromotrichloromethane / ethyl acetate / 12 h / Schlenk technique; Inert atmosphere; Irradiation View Scheme |
1-bromo-4-tert-butylbenzene
2-Methylphenylboronic acid
Conditions | Yield |
---|---|
With potassium phosphate; palladium-incarcerated polystyrene-based copolymer; tris(o-methoxyphenyl)phosphine In water; toluene for 2h; Suzuki-Miyaura coupling; Heating; | 100% |
With C25H29N3; potassium carbonate; palladium dichloride In water; N,N-dimethyl-formamide at 90℃; for 2h; Suzuki-Miyaura Coupling; | 99% |
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In toluene at 110℃; for 1.5h; Suzuki-Miyaura reaction; | 98% |
Conditions | Yield |
---|---|
With potassium phosphate; phosphinated polymer incarcerated palladium catalyst In water; toluene for 4h; Suzuki-Miyaura coupling; Heating; | 100% |
With potassium carbonate In water; isopropyl alcohol at 100℃; for 10h; Catalytic behavior; Suzuki-Miyaura Coupling; Inert atmosphere; | 100% |
With potassium carbonate In water; isopropyl alcohol at 100℃; for 10h; Suzuki-Miyaura Coupling; Inert atmosphere; | 99% |
1-bromo-4-tert-butylbenzene
diphenylamine
N,N-diphenyl-N-(4-tert-butylphenyl)amine
Conditions | Yield |
---|---|
With bis(tri-t-butylphosphine)palladium(0); potassium tert-butylate In toluene at 20℃; for 4h; | 100% |
With palladium diacetate; P(i-BuNCH2CH2)3N; sodium t-butanolate In toluene at 80℃; | 96% |
for 3h; | 96% |
1-bromo-4-tert-butylbenzene
Conditions | Yield |
---|---|
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene for 12h; | 99.7% |
1-bromo-4-tert-butylbenzene
Conditions | Yield |
---|---|
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene for 12h; | 99.6% |
1-bromo-4-tert-butylbenzene
Conditions | Yield |
---|---|
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene for 12h; | 99.6% |
Conditions | Yield |
---|---|
Stage #1: poly(methacrylic acid) With sodium carbonate In water Stage #2: With palladium dichloride Stage #3: 1-bromo-4-tert-butylbenzene With 2,6-di-tert-butyl-4-methyl-phenol; sodium carbonate In water at 130 - 135℃; under 9000.9 - 12001.2 Torr; for 2h; Autoclave; Inert atmosphere; | 99.6% |
1-bromo-4-tert-butylbenzene
tert-butylbenzene
Conditions | Yield |
---|---|
With potassium phosphate In N,N-dimethyl-formamide; cyclohexanol at 110℃; for 12h; | 99% |
With n-butyllithium; samarium diiodide; dipyrrolidinomethylaminophosphoric acid triamide; tert-butyl alcohol In tetrahydrofuran; hexane at -66 - 21℃; | 94% |
With triethylamine In acetonitrile at 20℃; for 15h; Irradiation; Inert atmosphere; | 84% |
Conditions | Yield |
---|---|
With tetraethylammonium tosylate; tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide Ambient temperature; electrolysis; | 99% |
With DPEPhos; potassium tert-butylate; palladium diacetate; bis(pinacol)diborane for 12h; Heating; | 99% |
With potassium carbonate In ethanol; water at 80℃; for 4h; Ullmann Condensation; Schlenk technique; Sealed tube; | 88% |
1-bromo-4-tert-butylbenzene
copper(I) cyanide
4-tert-butyl benzonitrile
Conditions | Yield |
---|---|
Stage #1: 1-bromo-4-tert-butylbenzene; copper(I) cyanide In N,N-dimethyl-formamide for 8h; Heating; Stage #2: With hydrogenchloride; iron(III) chloride In water; N,N-dimethyl-formamide at 70℃; for 0.5h; | 99% |
In N,N-dimethyl-formamide for 5h; Heating; | 71% |
Conditions | Yield |
---|---|
With di-tert-butyl{2′-isopropoxy-[1,1′-binaphthalen]-2-yl}phosphane; sodium hydride; bis(dibenzylideneacetone)-palladium(0) In o-xylene at 110℃; for 18h; Inert atmosphere; | 99% |
With caesium carbonate; copper(l) iodide In 1-methyl-pyrrolidin-2-one at 195℃; for 2h; microwave irradiation; | 89% |
With potassium phosphate; copper(l) iodide; N,N′-bis(2-phenylphenyl)oxalamide In N,N-dimethyl-formamide at 90℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube; | 88% |
With copper(I) trifluoromethanesulfonate benzene; 1-naphthalenecarboxylic acid; caesium carbonate; ethyl acetate In toluene at 110℃; | 81% |
morpholine
1-bromo-4-tert-butylbenzene
4-(4-(tert-butyl)phenyl)morpholine
Conditions | Yield |
---|---|
With sodium t-butanolate; 1-(2-di-isopropylphosphinophenyl)-3,5-diphenyl-1H-pyrazole; tris(dibenzylideneacetone)dipalladium (0) In toluene at 85℃; | 99% |
With 5-(di-tert-butylphosphino)-1′, 3′, 5′-triphenyl-1′H-[1,4′]bipyrazole; potassium hydroxide; tris(dibenzylideneacetone)dipalladium (0) In tert-Amyl alcohol; water at 90℃; for 5h; | 99% |
With palladium diacetate; P(i-BuNCH2CH2)3N; sodium t-butanolate In toluene at 80℃; | 99% |
Conditions | Yield |
---|---|
With palladium diacetate; P(i-BuNCH2CH2)3N; sodium t-butanolate In toluene at 80℃; | 99% |
With potassium tert-butylate; (ϖ-allyl)(diphosphinecyclobutene)palladium at 20℃; for 12h; | 97% |
With tris-(dibenzylideneacetone)dipalladium(0); (S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine); sodium t-butanolate In toluene at 80℃; for 21h; Schlenk technique; Inert atmosphere; | 95% |
1-bromo-4-tert-butylbenzene
1-Bromo-4-tert-butyl-2-nitro-benzene
Conditions | Yield |
---|---|
With sulfuric acid; nitric acid at 20℃; for 12h; | 99% |
With sulfuric acid; nitric acid | 95% |
With sulfuric acid; nitric acid Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium (0); lithium hexamethyldisilazane; CyJohnPhos In tetrahydrofuran at 65℃; for 15h; | 99% |
With copper(l) iodide; 2-carboxyquinoline N-oxide; potassium carbonate; ammonium hydroxide In dimethyl sulfoxide at 80℃; for 23h; Inert atmosphere; | 90% |
With bis(tri-ortho-tolylphosphine)palladium(0); (R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl-di-tert-butylphosphine; ammonia; sodium t-butanolate In 1,4-dioxane at 80℃; for 6h; Inert atmosphere; | 88% |
Conditions | Yield |
---|---|
With monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; palladium compound; sodium t-butanolate In toluene at 100℃; for 4h; | 99% |
With sodium t-butanolate; monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; palladium diacetate In toluene | 99% |
Conditions | Yield |
---|---|
With sodium t-butanolate; 1-(di-2-tert-butylphosphinophenyl)-2,5-diphenyl-1H-pyrrole; tris(dibenzylideneacetone)dipalladium (0) In toluene at 85℃; | 99% |
With 5-(di-t-butylphosphanyl)-1-naphthalen-1-yl-1H-pyrazole; potassium hydroxide; tris(dibenzylideneacetone)dipalladium (0) In tert-Amyl alcohol; water at 90℃; | 90% |
Conditions | Yield |
---|---|
With sodium t-butanolate; 1-(2-di-tert-butylphosphinophenyl)-3,5-diphenyl-1H-pyrazole; tris(dibenzylideneacetone)dipalladium (0) In tert-Amyl alcohol at 85℃; | 99% |
With 5-(di-tert-butylphosphino)-1′, 3′, 5′-triphenyl-1′H-[1,4′]bipyrazole; potassium hydroxide; tris(dibenzylideneacetone)dipalladium (0) In tert-Amyl alcohol; water at 90℃; for 5h; | 99% |
With sodium t-butanolate; dicyclohexyl[2-(1-phenylvinyl)phenyl]phosphane; palladium diacetate In toluene at 100℃; | 72% |
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium (0); 2,8,9-tribenzyl-2,3,8,9-tetraaza-1-phosphabicyclo[3,3,3]undecane; cesium fluoride In tetrahydrofuran at 20℃; for 10h; Stille cross-coupling; | 99% |
With cesium fluoride; palladium diacetate In 1,4-dioxane at 100℃; for 3h; Stille cross-coupling; | 99% |
With bis(tri-t-butylphosphine)palladium(0) In water at 20℃; for 4h; Stille Cross Coupling; Inert atmosphere; | 92% |
Conditions | Yield |
---|---|
With 5-(di-t-butylphosphanyl)-1-naphthalen-1-yl-1H-pyrazole; potassium hydroxide; tris(dibenzylideneacetone)dipalladium (0) In tert-Amyl alcohol; water at 90℃; | 99% |
1-bromo-4-tert-butylbenzene
di-4-methoxyphenylzinc
Conditions | Yield |
---|---|
With catalyst 1 (aliphatic, phosphine based pincer complex of palladium) In 1,4-dioxane; 1-methyl-pyrrolidin-2-one at 100℃; for 0.25h; Negishi cross-coupling reaction; | 99% |
4-benzyl pyridine
1-bromo-4-tert-butylbenzene
(4-tert-butylphenyl)(4-pyridyl)phenylmethane
Conditions | Yield |
---|---|
With KN(SiMe3)2; palladium diacetate; nixantphos In cyclopentyl methyl ether at 24℃; for 12h; Inert atmosphere; | 99% |
With BF4(1-)*C20H25N2O2(1+); palladium diacetate; sodium hexamethyldisilazane In toluene at 60℃; for 12h; Reagent/catalyst; Inert atmosphere; | 96% |
With BF4(1-)*C20H25N2O2(1+); palladium diacetate; sodium hexamethyldisilazane In toluene at 60℃; for 16h; Reagent/catalyst; Solvent; Temperature; Inert atmosphere; | 95% |
With C25H21N2O(1+)*Cl(1-); palladium diacetate; sodium hexamethyldisilazane In toluene at 60℃; for 12h; Reagent/catalyst; Inert atmosphere; | 89% |
With bis(1,5-cyclooctadiene)nickel (0); sodium hexamethyldisilazane; nixantphos at 110℃; for 16h; | 80% |
2-Benzylpyridine
1-bromo-4-tert-butylbenzene
(4-tert-butylphenyl)(2-pyridyl)phenylmethane
Conditions | Yield |
---|---|
With diethylene glycol dimethyl ether; NiXantphos; palladium diacetate; sodium hexamethyldisilazane at 23℃; for 12h; Catalytic behavior; Reagent/catalyst; Glovebox; Inert atmosphere; Sealed tube; | 99% |
With bis(1,5-cyclooctadiene)nickel (0); sodium hexamethyldisilazane; nixantphos at 20℃; for 16h; Catalytic behavior; Temperature; Concentration; Time; | 99% |
With KN(SiMe3)2; palladium diacetate; nixantphos In cyclopentyl methyl ether at 24℃; for 12h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
With KN(SiMe3)2; palladium diacetate; nixantphos In cyclopentyl methyl ether at 24℃; for 12h; Inert atmosphere; | 99% |
With bis(1,5-cyclooctadiene)nickel (0); sodium hexamethyldisilazane; nixantphos at 110℃; for 16h; | 81% |
Conditions | Yield |
---|---|
With bis(1,5-cyclooctadiene)nickel (0); sodium hexamethyldisilazane; nixantphos at 50℃; for 16h; | 99% |
With KN(SiMe3)2; palladium diacetate; nixantphos In tetrahydrofuran at 85℃; for 12h; Inert atmosphere; | 87% |
1-bromo-4-tert-butylbenzene
Diphenylmethane
((4-(tert-butyl)phenyl)methylene)dibenzene
Conditions | Yield |
---|---|
With 15-crown-5; NiXantphos; palladium diacetate; sodium hexamethyldisilazane at 23℃; for 12h; Catalytic behavior; Reagent/catalyst; Temperature; Solvent; Concentration; Glovebox; Inert atmosphere; Sealed tube; | 99% |
With KN(SiMe3)2; palladium diacetate; nixantphos In cyclopentyl methyl ether at 24℃; for 12h; Inert atmosphere; | 95% |
Stage #1: 1-bromo-4-tert-butylbenzene; Diphenylmethane With palladium diacetate; potassium hexamethylsilazane; nixantphos at 24℃; for 12h; Inert atmosphere; Glovebox; Stage #2: With depe at 24℃; for 0.666667h; | 91% |
1-bromo-4-tert-butylbenzene
1-Benzyl-naphthalene
(4-tert-butylphenyl)(1-naphthyl)phenylmethane
Conditions | Yield |
---|---|
With KN(SiMe3)2; palladium diacetate; nixantphos In cyclopentyl methyl ether at 24℃; for 12h; Inert atmosphere; | 99% |
1-bromo-4-tert-butylbenzene
4-fluorodiphenylmethane
(4-tert-butylphenyl)(4-fluorophenyl)phenylmethane
Conditions | Yield |
---|---|
With 1,1,4,7,10,10-hexamethyltriethylenetetramine; NiXantphos; palladium diacetate; sodium hexamethyldisilazane at 23℃; for 12h; Catalytic behavior; Reagent/catalyst; Glovebox; Inert atmosphere; Sealed tube; | 99% |
With KN(SiMe3)2; palladium diacetate; nixantphos In cyclopentyl methyl ether at 24℃; for 12h; Inert atmosphere; | 96% |
1-bromo-4-tert-butylbenzene
2-benzylthiophene
(4-tert-butylphenyl)(2-thienyl)phenylmethane
Conditions | Yield |
---|---|
With KN(SiMe3)2; palladium diacetate; nixantphos In cyclopentyl methyl ether at 24℃; for 12h; Inert atmosphere; | 99% |
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