Dayang Chem (Hangzhou) Co.,Ltd.
DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe
Cas:108-86-1
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquirySimagchem Corporation
Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:108-86-1
Min.Order:1 Kilogram
Negotiable
Type:Manufacturers
inquiryJinan Finer Chemical Co., Ltd
Product Description Product Name Bromobenzene CAS No. 108-86-1 Appearance Colorless transparent liquid Assay ≥99.5% Capacity 500mt/year Min.packing 100gram
Cas:108-86-1
Min.Order:1 Metric Ton
FOB Price: $12.0
Type:Lab/Research institutions
inquiryHenan Allgreen Chemical Co.,Ltd
high quality Appearance:Colorless liquid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
EAST CHEMSOURCES LIMITED
Bromobenzene Product Name: Bromobenzene Molecular Weight: 157.00 CAS NO: 108-86-1 EC NO: 203-623-8 Molecular Formula: C6H5Br
Ality Chemical Corporation
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Chemwill Asia Co., Ltd.
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Hebei yanxi chemical co.,LTD.
Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable
Henan Tianfu Chemical Co., Ltd.
Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O
Cas:108-86-1
Min.Order:1 Kilogram
FOB Price: $1000.0
Type:Lab/Research institutions
inquiryHenan Sinotech Import&Export Corporation
Chemical Name: Bromobenzene CAS No.: 108-86-1 Molecular Fomula: C6H5Br Chemical Structure: Molecular weight: 157.01 Appearance: colorless and transparent to light yellow liquid Assay:≥99.5% Appearance: Colorless Transparent Liquid Stor
Hefei TNJ chemical industry co.,ltd
We are one of the domestic largest manufacturers of API; We are always supplier of products with higher quality and at more competitive price; We are supplier of safe and ecofriendly products ; We provide stable supply and efficient servic
Cas:108-86-1
Min.Order:200 Kilogram
Negotiable
Type:Trading Company
inquiryShanghai Minstar Chemical Co., Ltd
Product Name: Bromobenzene Synonyms: 1-Bromobenzene;Benzene,bromo-;Brombenzol;bromo-benzen;Bromobenzol;NCI-C55492;PHENYL BROMIDE;MONOBROMOBENZENE CAS: 108-86-1 MF: C6H5Br MW: 157.01 EINECS: 203-623-8 Product Categories: Pharmaceutical Interme
Cas:108-86-1
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryTriumph International Development Limilted
Appearance:Colorless liquid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Organic synthesis Transportation:Common products:Sea/Air/Courier Dangerous Chem:Sea/Ai
Cas:108-86-1
Min.Order:100 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryWuhan Zenuo Biological Medicine Technology Co Ltd
Product Name: Bromobenzene Synonyms: Bromobenzene (1mg/ml in Methanol) [for Water Analysis];BROMOBENZENE extrapure;BROMOBENZENE extrapure AR;Bromobenzene, Reagent Grade;Bromobenzene solution;Bromobenzene, 99%, pure;3-Bromobenzene;4-Bromobenzene
Cas:108-86-1
Min.Order:100 Gram
Negotiable
Type:Lab/Research institutions
inquiryHangzhou Keyingchem Co.,Ltd
Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Hangzhou J&H Chemical Co., Ltd.
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Shanghai Massive Chemical Technology Co., Ltd.
Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
Zibo Hangyu Biotechnology Development Co., Ltd
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:108-86-1
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryZibo Dorne chemical technology co. LTD
Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:108-86-1
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co., Ltd.
1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea
Cas:108-86-1
Min.Order:1 Gram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryHangzhou Huarong Pharm Co., Ltd.
Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu
Hangzhou Zhongqi chem Co.,Ltd.
Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an
SAGECHEM LIMITED
SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe
HANGZHOU YUNUO CHEMICAL CO.,LTD
Superior quality, moderate price & quick delivery. Appearance:colorless transparent liquid Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application:Used for Pesticide
Greenutra Resource Inc
BromobenzeneAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air
Kono Chem Co.,Ltd
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
Hangzhou Dingyan Chem Co., Ltd
R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou
JINHUA HUAYI CHEMICAL CO., LTD.
Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands
Wuhan Fortuna Chemical Co.,Ltd
Best service,high quality and cheap price. Storage:Keep away from heat,sparks and flames. Package:25kg/50kg/200kg drum or Customer demand Application:Used as pharmaceutical intermediates Transportation:BY sea/air or by courier
Aecochem Corp.
Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
Synthetic route
| Conditions | Yield |
|---|---|
| With potassium carbonate; iron pentacarbonyl In methanol at 60℃; under 760 Torr; for 48h; | 98% |
| With butyl magnesium bromide; zirconocene dichloride In tetrahydrofuran for 1h; Ambient temperature; | 98% |
| With tris-(trimethylsilyl)silane In acetonitrile for 24h; Schlenk technique; Inert atmosphere; Irradiation; | 93% |
| Conditions | Yield |
|---|---|
| With carbon dioxide; bromine at 40℃; under 187519 Torr; for 2h; Supercritical conditions; Green chemistry; | 100% |
| With lead(II,IV) oxide; trifluoroacetic acid; potassium bromide at 20℃; Product distribution; reagents ratio; | 96% |
| With gold(III) chloride; N-Bromosuccinimide In 1,2-dichloro-ethane at 80℃; for 24h; Inert atmosphere; regioselective reaction; | 94% |
-
-
201230-82-2
carbon monoxide
-
-
589-87-7
1,4-bromoiodobenzene
-
A
-
108-86-1
bromobenzene
-
B
-
1122-91-4
4-bromo-benzaldehyde
-
C
-
71-43-2
benzene
| Conditions | Yield |
|---|---|
| With tri-n-butyl-tin hydride; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 50℃; under 2280 Torr; | A 9 % Chromat. B 70% C 4 % Chromat. |
| With tri-n-butyl-tin hydride; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 50℃; under 2280 Torr; | A 4% B 70% C 10% |
-
-
201230-82-2
carbon monoxide
-
-
589-87-7
1,4-bromoiodobenzene
-
A
-
108-86-1
bromobenzene
-
B
-
1122-91-4
4-bromo-benzaldehyde
| Conditions | Yield |
|---|---|
| With hydrogen; potassium carbonate In 1,4-dioxane at 120 - 140℃; under 30003 Torr; for 20h; Autoclave; | A 17% B 39% |
-
-
66003-76-7
Diphenyliodonium triflate
-
-
108-86-1
bromobenzene
| Conditions | Yield |
|---|---|
| With copper(I) bromide In acetonitrile at 80℃; for 2h; Reagent/catalyst; Solvent; Temperature; | 91% |
| Conditions | Yield |
|---|---|
| With trichloroisocyanuric acid; bromine In tetrachloromethane at -10 - 100℃; for 4h; Photolysis; | A 7% B 87% |
| Conditions | Yield |
|---|---|
| With copper(I) bromide In acetonitrile at 80℃; for 2h; | 71% |
-
-
58109-40-3
diphenyliodonium hexafluorophosphate
-
-
108-86-1
bromobenzene
| Conditions | Yield |
|---|---|
| With copper(I) bromide In acetonitrile at 80℃; for 2h; | 65% |
-
-
108-86-1
bromobenzene
| Conditions | Yield |
|---|---|
| With copper(I) bromide In acetonitrile at 80℃; for 2h; | 63% |
| Conditions | Yield |
|---|---|
| With copper(I) bromide In acetonitrile at 80℃; for 2h; | 45% |
| Conditions | Yield |
|---|---|
| With copper(I) bromide In acetonitrile at 80℃; for 2h; | 40% |
| Conditions | Yield |
|---|---|
| Stage #1: 4-bromo-aniline With tetrafluoroboric acid; acetic acid; isopentyl nitrite In water at 18℃; for 0.0833333h; Stage #2: With eosin Y disodium salt In N,N-dimethyl-formamide at 18℃; for 6h; Concentration; Reagent/catalyst; Solvent; Inert atmosphere; UV-irradiation; Schlenk technique; | 81% |
| With formamide; triethylamine; trifluoroacetic acid; sodium nitrite 1.) formamide/water, r.t.; 2.) water, r.t.; Yield given. Multistep reaction; | |
| Stage #1: 4-bromo-aniline With Nitrogen dioxide In acetonitrile at -20℃; Diazotization; Stage #2: With calcium bis(hypophosphite); Fe2SO4*7H2O In methanol; acetonitrile at 20℃; Dediazonation; | 16 % Chromat. |
-
-
108-86-1
bromobenzene
| Conditions | Yield |
|---|---|
| In water; isopropyl alcohol for 14h; Irradiation; | 97% |
-
-
56075-37-7
1-(4-bromophenyl)-2-(methylsulfonyl)diazene
-
-
108-86-1
bromobenzene
| Conditions | Yield |
|---|---|
| In water; isopropyl alcohol for 14h; Irradiation; | 97% |
| Conditions | Yield |
|---|---|
| With Triethoxysilane; C20H24N4Ni; sodium t-butanolate In toluene at 80℃; for 8h; Kumada Cross-Coupling; Inert atmosphere; Schlenk technique; | 93% |
| With hydrogen cation; copper 1) THF, -78 deg C, 10 min; Yield given. Multistep reaction; | |
| With hydrogenchloride; CuI*P(Et)3; naphthalen-1-yl-lithium 1.) THF, -78 deg C, 10 min; Yield given. Multistep reaction; | |
| With tetrabutylammomium bromide; palladium diacetate; potassium hydroxide; 2′-(diphenylphosphino)-N,N′-dimethyl-(1,1′-biphenyl)-2-amine In methanol; water at 120℃; Microwave irradiation; | 43 %Chromat. |
| Conditions | Yield |
|---|---|
| dicobalt octacarbonyl In water; benzene at 185 - 190℃; under 46543.3 Torr; | 77% |
| Conditions | Yield |
|---|---|
| With dibenzo-18-crown-6; potassium bromide; copper(ll) bromide; 1,10-Phenanthroline; copper(I) bromide In acetonitrile at 20℃; for 0.333333h; Sandmeyer bromination; | A 6% B 91% |
-
-
583-55-1
1-Bromo-2-iodobenzene
-
-
107-11-9
1-amino-2-propene
-
A
-
108-86-1
bromobenzene
-
B
-
73396-91-5
2-bromo-N-(prop-2-enyl)aniline
| Conditions | Yield |
|---|---|
| With dodecane; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0) In toluene at 100℃; for 15h; | A 6.6% B 17.5% |
| Conditions | Yield |
|---|---|
| With N-Bromosuccinimide In acetonitrile at 81℃; for 14h; | 57% |
| With water; copper(ll) bromide | |
| With gold(III) chloride; N-Bromosuccinimide In 1,2-dichloro-ethane at 60℃; for 24h; | |
| With potassium bromide In water at 80℃; |
-
-
998-30-1
Triethoxysilane
-
-
589-87-7
1,4-bromoiodobenzene
-
A
-
108-86-1
bromobenzene
-
B
-
18954-74-0
(4-bromophenyl)triethoxysilane
| Conditions | Yield |
|---|---|
| With N-ethyl-N,N-diisopropylamine; johnphos; bis(dibenzylideneacetone)-palladium(0) In 1-methyl-pyrrolidin-2-one at 20℃; for 2h; | A n/a B 68% |
| Conditions | Yield |
|---|---|
| With boron tribromide; dimethyl sulfoxide at 80℃; for 1h; | 42% |
-
-
583-55-1
1-Bromo-2-iodobenzene
-
-
107-11-9
1-amino-2-propene
-
A
-
589-09-3
N-allyl-N-phenylamine
-
B
-
83-34-1
3-Methylindole
-
C
-
108-86-1
bromobenzene
-
D
-
73396-91-5
2-bromo-N-(prop-2-enyl)aniline
| Conditions | Yield |
|---|---|
| With dodecane; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0) In toluene at 100℃; for 15h; | A 4.3% B 3.7% C 11.4% D 20.3% |
-
-
583-55-1
1-Bromo-2-iodobenzene
-
-
107-11-9
1-amino-2-propene
-
A
-
589-09-3
N-allyl-N-phenylamine
-
B
-
108-86-1
bromobenzene
| Conditions | Yield |
|---|---|
| With dodecane; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0) In toluene at 100℃; for 15h; | A 3.5% B 20.9% |
-
-
106-37-6
1.4-dibromobenzene
-
-
98-80-6
phenylboronic acid
-
A
-
108-86-1
bromobenzene
-
B
-
92-66-0
4-bromo-1,1'-biphenyl
-
C
-
92-94-4
[1,1';4',1'']terphenyl
| Conditions | Yield |
|---|---|
| With (2,4-dibenzyl-2,4-dihydro-3H-1,2,4-triazol-3-ylidene)(dibromo)(pyridine)palladium; tetrabutylammomium bromide In N,N-dimethyl-formamide; isopropyl alcohol at 80℃; for 2h; Reagent/catalyst; Suzuki-Miyaura Coupling; Inert atmosphere; | A 10% B n/a C n/a |
-
-
70083-69-1
Tetramethylammonium Bis<α,α-bis(trifluoromethyl)-benzenemethanolato(2-)-C2,O>phenylsilicate
-
A
-
108-86-1
bromobenzene
-
B
-
70091-69-9
C18H8F12O2Si
| Conditions | Yield |
|---|---|
| With bromine at 25℃; for 24h; | A n/a B 75% |
-
-
108-36-1
1,3-dibromobenzene
-
-
25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
-
A
-
108-86-1
bromobenzene
-
B
-
594823-67-3
(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)bromobenzene)
| Conditions | Yield |
|---|---|
| With copper(l) iodide; iron(III)-acetylacetonate; N,N,N,N,-tetramethylethylenediamine; sodium hydride In tetrahydrofuran; mineral oil at -10℃; Inert atmosphere; | A n/a B 79% |
| Conditions | Yield |
|---|---|
| With copper(I) bromide at 135℃; for 24h; | 91% |
| With bromobenzene; tetrabutylammomium bromide; o-CH3C6H4NiBr(PEt3)2 In benzene at 80℃; for 20h; sealed tube; Yield given; | |
| With aluminum oxide; copper(I) bromide In various solvent(s) at 150℃; for 9h; | 87 % Chromat. |
| With copper(I) bromide In N,N-dimethyl acetamide at 137℃; Equilibrium constant; Rate constant; equilibrium order; aalso at 53 deg C; also with CuBr2; | |
| With n-hexylzirconocene chloride; [nickel(II) (4,4'-di-tert-butyl-2,2'-bipyridine)(bromide)2]; tetrabutylammonium p-toluenesulfonate In tetrahydrofuran at 20℃; for 24h; Inert atmosphere; Irradiation; Sealed tube; |
-
-
97878-04-1
tetraethylammonium bis<α,α-bis(trifluorometyl)benzenemethanolato(2-)-C2,O>-n-butylsilicate(1-)
-
A
-
108-86-1
bromobenzene
-
B
-
70091-69-9
C18H8F12O2Si
| Conditions | Yield |
|---|---|
| With bromine at 25℃; for 24h; | A n/a B 74.6% |
| Conditions | Yield |
|---|---|
| With hydrogenchloride; CuI*P(Et)3; naphthalen-1-yl-lithium 1.) THF, 25 deg C, 60 min; Yield given. Multistep reaction; | |
| With tetrahydrofuran; 1,10-Phenanthroline; potassium tert-butylate at 70℃; for 24h; Schlenk technique; Inert atmosphere; chemoselective reaction; | 83 %Chromat. |
| Conditions | Yield |
|---|---|
| With hydrogen bromide; bromine; iron(III) chloride at 60 - 62℃; for 2.66667h; Product distribution / selectivity; | |
| With bromine; iron(III) chloride at 75 - 80℃; for 5.2h; Product distribution / selectivity; | |
| With hydrogen bromide; bromine; ferric(III) bromide In water at 52 - 64℃; for 4.66667h; Product distribution / selectivity; | |
| With hydrogen bromide; bromine; iron In water at 62 - 66℃; for 4.28333h; Product distribution / selectivity; |
| Conditions | Yield |
|---|---|
| With sodium t-butanolate; palladium diacetate; [(μ-PPh2CH2PPh2)Co2(CO)4][μ,η-PhCCP(tBu)2] In toluene at 60℃; for 20h; Product distribution; Further Variations:; Catalysts; Reagents; Solvents; Temperatures; | 100% |
| With C20H45N2OP; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 105℃; for 20h; Reagent/catalyst; | 100% |
| With bis(η3-allyl-μ-chloropalladium(II)); [(μ-Ph2PCH2PPh2)Co2(CO)4(μ,η-Me2NCH2CCP(C6H11)2)]; sodium t-butanolate In toluene at 80℃; for 2h; Inert atmosphere; | 99% |
| Conditions | Yield |
|---|---|
| With palladium diacetate; triethylamine; 2-diphenylphosphino-2'-methylbiphenyl In N,N-dimethyl-formamide at 100℃; for 5h; Ullmann reaction; Inert atmosphere; | 100% |
| With potassium carbonate In ethanol; water at 20℃; for 12h; Ullmann Condensation; | 100% |
| dibromobis(triphenylphosphine)nickel(II); tetraethylammonium iodide; zinc In tetrahydrofuran at 50℃; for 1.5h; | 99% |
| Conditions | Yield |
|---|---|
| With bromine fluoride In ethanol; chloroform at -78℃; for 0.5h; | 100% |
| With sulfuric acid; bromine; mercury(II) oxide In tetrachloromethane for 2.5h; Heating; | 76% |
| With bromine; silver perchlorate; magnesium oxide |
| Conditions | Yield |
|---|---|
| With copper(I) oxide; ammonium hydroxide In 1-methyl-pyrrolidin-2-one at 80℃; for 15h; | 100% |
| With ammonia; copper In water at 100℃; for 24h; Ullmann reaction; | 99.1% |
| With copper(l) iodide; 2-carboxyquinoline N-oxide; potassium carbonate; ammonium hydroxide In dimethyl sulfoxide at 80℃; for 23h; Inert atmosphere; | 98% |
| Conditions | Yield |
|---|---|
| With sodium hydroxide; ethanol; hydrogen; PdCl2-poly(N-vinyl-2-pyrrolidone); palladium dichloride at 65℃; under 760 Torr; for 2h; | 100% |
| With 9-borabicyclo[3.3.1]nonane dimer; triphenylstannane In toluene at 0℃; | 100% |
| With TiCpCl2; diisobutylaluminium hydride In 1,4-dioxane at 80℃; for 4h; Product distribution; further reagents(Zr, Hf complexes), solvents, and temperatures; further halobenzenes, alkyl, alkenyl and cyclopropyl halides; | 100% |
| Conditions | Yield |
|---|---|
| With sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate; Pd{dba(OMe)}2 In toluene at 25℃; for 0.166667h; Buchwald-Hartwig cross coupling reaction; | 100% |
| With potassium ethoxide In 1,4-dioxane at 200℃; Catalytic behavior; Buchwald-Hartwig Coupling; | 100% |
| With C31H26N4PPdS(1+)*Cl(1-); sodium t-butanolate In toluene at 95℃; for 14h; Catalytic behavior; | 100% |
| Conditions | Yield |
|---|---|
| With copper at 240℃; for 12h; Product distribution; further reagents, reaction temperature; | 100% |
| With copper at 180℃; for 12h; | 100% |
| With tris(dibenzylideneacetone)dipalladium (0); caesium carbonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; for 16h; Arylation; | 98% |
| Conditions | Yield |
|---|---|
| With cis-(N,N'-bis(2,2-diethoxyethyl)imidazolin-2-ylidene)dichlorotriphenylphosphinepalladium(II); tetrabutylammomium bromide; potassium carbonate In N,N-dimethyl-formamide at 140℃; for 12h; Heck reaction; | 100% |
| With 1-naphthalenomethyl-3-(2,3,4,5,6-pentamethylbenzyl)imidazolidinium chloride; palladium diacetate; potassium carbonate In water; N,N-dimethyl-formamide at 80℃; for 2h; Reagent/catalyst; Green chemistry; | 100% |
| With tris-(dibenzylideneacetone)dipalladium(0); 2,5-di(2,4,6-trimethylphenyl)-1,2,5-thiadiazolidine-1-oxide; sodium acetate In 1-methyl-pyrrolidin-2-one at 200℃; for 0.5h; Heck reaction; Microwave irradiation; | 99% |
| Conditions | Yield |
|---|---|
| With copper at 210℃; for 12h; | 100% |
-
-
4746-97-8
cyclohexanedione monoethylene ketal
-
-
108-86-1
bromobenzene
-
-
94112-58-0
4-hydroxy-4-phenyl-cyclohexanone ethylene ketal
| Conditions | Yield |
|---|---|
| Stage #1: bromobenzene With magnesium In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere; Reflux; Stage #2: cyclohexanedione monoethylene ketal In tetrahydrofuran for 0.5h; Inert atmosphere; Reflux; | 100% |
| Stage #1: bromobenzene With iodine; magnesium In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; Stage #2: cyclohexanedione monoethylene ketal In tetrahydrofuran at 0 - 55℃; Inert atmosphere; | 41% |
| With tert.-butyl lithium 1.) THF, -60 deg C, 3 h, 2.) THF, RT, overnight; Yield given. Multistep reaction; | |
| Stage #1: bromobenzene With n-butyllithium In tetrahydrofuran; hexane at -40℃; for 0.5h; Inert atmosphere; Stage #2: cyclohexanedione monoethylene ketal In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; |
| Conditions | Yield |
|---|---|
| With copper at 240℃; for 12h; | 100% |
| With copper at 240℃; for 12h; Product distribution; further reagents, reaction temperature; | 100% |
| With copper(I) oxide In various solvent(s) at 172℃; for 48h; | 80% |
| Conditions | Yield |
|---|---|
| o-phenylene-bis-nickel(II) bromide In ethylene glycol at 200℃; for 24h; | 100% |
| With 1,5-(2,9-dimethyl-1,10-phenanthroyl)-p-tert-butylcalix[8]arene; copper(l) chloride In toluene at 110℃; for 15h; Schlenk technique; Glovebox; Inert atmosphere; | 95% |
| With tetra(n-butyl)ammonium hydroxide In ammonia at -45℃; for 1.5h; Irradiation; further catalyst (Et3N); | 70% |
| With 2C21H11N3O6(4-)*H(1+)*2Ni(2+)*14H2O*Co(3+) In N,N-dimethyl-formamide at 80℃; for 6h; Reagent/catalyst; Inert atmosphere; | 65 %Chromat. |
| Conditions | Yield |
|---|---|
| With copper(l) iodide; potassium iodide at 200℃; for 5h; Finkelstein reaction; Inert atmosphere; | 100% |
| With aluminum oxide; copper(l) iodide In neat (no solvent) at 150℃; for 27h; Product distribution; different substrates, reagents, solvents and reaction times and temperature; | 94% |
| With aluminum oxide; copper(l) iodide In neat (no solvent) at 150℃; for 27h; | 94% |
| Conditions | Yield |
|---|---|
| With potassium carbonate; thiourea In ethanol for 0.583333h; Reflux; | 100% |
| With potassium phosphate; copper(l) iodide; sodiumsulfide nonahydrate at 150℃; for 24h; | 98% |
| With 1,1'-bis-(diphenylphosphino)ferrocene; potassium phosphate; bis(dibenzylideneacetone)-palladium(0); potassium thioacetate In acetone; toluene at 110℃; for 6h; Inert atmosphere; | 97% |
| Conditions | Yield |
|---|---|
| With magnesium In tetrahydrofuran at 40℃; for 0.25h; Inert atmosphere; Flow reactor; | 100% |
| With magnesium In tetrahydrofuran | |
| With magnesium In diethyl ether at 19.9℃; Rate constant; various concentrations of aryl halide; |
| Conditions | Yield |
|---|---|
| Stage #1: thiophenol With potassium carbonate In xylene at 0 - 20℃; Stage #2: bromobenzene With tris(dibenzylideneacetone)dipalladium (0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In xylene at 140℃; for 0.4h; | 100% |
| With potassium tert-butylate; bis(1,3-dibenzylimidazol-2-ylidene)nickel In N,N-dimethyl-formamide at 110℃; for 16h; | 99% |
| With potassium tert-butylate; nickel 1,3-dibenzylimidazolidene In N,N-dimethyl-formamide at 110℃; for 16h; Product distribution / selectivity; | 99% |
| Conditions | Yield |
|---|---|
| With triethylamine; bis(tert-butylaminophosphine)palladium(II) at 80℃; for 0.333333h; Sonogashira cross-coupling reaction; | 100% |
| With triethylamine; [Pd{t-Bu2PCH2N(CH2Ph)CH2Pt-Bu2}(OAc)2] at 80℃; for 0.333333h; Sonogashira coupling; | 100% |
| With tetrabutylammomium bromide; triethylamine In water; N,N-dimethyl-formamide at 70℃; for 12h; Sonogashira coupling; | 100% |
| Conditions | Yield |
|---|---|
| With iodine; magnesium In tetrahydrofuran 1.) reflux; 2.) 20 deg C then 22 deg C; | 100% |
| With lithium In diethyl ether for 0.5h; ultrasonic agitation; | 83% |
| Stage #1: bromobenzene With magnesium; ethylene dibromide In 2-methyltetrahydrofuran at 20℃; Inert atmosphere; Stage #2: acetophenone In 2-methyltetrahydrofuran at 0 - 20℃; for 2.25h; Grignard reaction; Inert atmosphere; chemoselective reaction; | 78% |
| Conditions | Yield |
|---|---|
| With copper(l) iodide; C80H65BrN2O2P4Pd; triethylamine In water for 7h; Reagent/catalyst; Sonogashira Cross-Coupling; Inert atmosphere; Reflux; | 100% |
| With copper(l) iodide; diethylamine; triphenylphosphine; palladium diacetate for 36h; Heating; | 98% |
| With copper(l) iodide; palladium diacetate; triphenylphosphine; 3-aminopentane for 36h; Inert atmosphere; Reflux; | 98% |
| Conditions | Yield |
|---|---|
| With potassium phosphate; tetrabutylammomium bromide; [PdCl{[η5-C5H5)]Fe[(η5-C5H3)C(CH3)=NC12H25]}]2 In N,N-dimethyl-formamide at 140℃; for 12h; Heck coupling; | 100% |
| With {4-[di(2-hydroxyethyl)amino]butyl}tri(n-butyl)ammonium bromide; palladium diacetate at 100℃; for 6h; Heck reaction; Inert atmosphere; stereoselective reaction; | 99% |
| With C37H38BrClFeN3Pd; potassium acetate In N,N-dimethyl acetamide at 150℃; for 12h; Heck reaction; Inert atmosphere; regioselective reaction; | 97% |
-
-
108-86-1
bromobenzene
-
-
1066-54-2
trimethylsilylacetylene
-
-
2170-06-1
1-Phenyl-2-(trimethylsilyl)acetylene
| Conditions | Yield |
|---|---|
| With copper(l) iodide; diisopropylamine; polymer-supp. 11-(2-[Pd(OAc)2]-1-Mes-3-imidazolyl)undecanol In tetrahydrofuran at 20℃; for 2.5h; Sonogashira coupling; | 100% |
| With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine for 24h; Sonogashira coupling; Inert atmosphere; Reflux; | 99% |
| With potassium carbonate In water at 60℃; for 2h; | 95% |
| Conditions | Yield |
|---|---|
| With potassium carbonate; {1,3-di[(R)-1-PhEt]imidazolin-2-ylidene}(PPh3)PdI2 In xylene at 130℃; for 13h; Suzuki-Miyaura cross-coupling reaction; | 100% |
| With potassium phosphate; triphenylphosphine; Ni(II) complexes of bidentate carbene; phosphine ligand In toluene at 80℃; Suzuki cross-coupling; | 100% |
| With [PdCl2(2-ethyl-2-oxazoline)2]; potassium carbonate In toluene at 110℃; for 3h; Suzuki reaction; | 100% |
-
-
108-86-1
bromobenzene
-
-
141-32-2
acrylic acid n-butyl ester
-
-
52392-64-0
(E)-3-(phenyl)acrylic acid butyl ester
| Conditions | Yield |
|---|---|
| With 1-methyl-pyrrolidin-2-one; sodium carbonate; [PdClMe(MeSC6H4CH2PPh2)] at 130℃; for 72h; Heck arylation; | 100% |
| With tetrabutylammonium acetate; resin-PPh2-Pd(OAc)2 In carbon dioxide at 120℃; under 155149 Torr; for 16h; Heck reaction; | 100% |
| With tetrabutylammonium acetate; polyurea-encapsulated Pd(OAc)2 In various solvent(s) at 100℃; Heck reaction; | 99% |
| Conditions | Yield |
|---|---|
| In neat (no solvent) at 150℃; for 0.366667h; Product distribution; Irradiation; varying method of heating; | 100% |
| With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine In neat (no solvent) at 150 - 160℃; for 0.366667h; Irradiation; | 100% |
| With sodium acetate; {1,1'-(3-MeOBn)2-3,3'-CH2-diimidazolin-2,2'-diylidene}PdBr2 In N,N-dimethyl acetamide at 165 - 175℃; for 1h; Product distribution; Further Variations:; Catalysts; Reaction partners; time; Heck coupling reaction; | 100% |
| Conditions | Yield |
|---|---|
| With palladium diacetate; sodium hydroxide; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In 1,4-dioxane at 100℃; for 1h; | 100% |
| With rubidium carbonate; tri-tert-butyl phosphine; palladium diacetate In xylene at 120℃; for 4h; Condensation; | 96% |
| With copper(II) oxide; potassium carbonate In N,N-dimethyl-formamide at 40℃; for 1.5h; Ullmann Condensation; | 96% |
| Conditions | Yield |
|---|---|
| With tetrakis(triphenylphosphine)palladium dichloride In benzene at 80℃; for 7h; | 100% |
-
-
108-86-1
bromobenzene
-
-
4381-25-3
S-methyl-S-phenylsulfoximine
-
-
83706-39-2
(±)-methyl(phenyl)(phenylimino)-λ6-sulfanone
| Conditions | Yield |
|---|---|
| With palladium diacetate; caesium carbonate; ruphos In toluene at 110℃; for 12h; Buchward-Hartwig coupling; Inert atmosphere; | 100% |
| Stage #1: bromobenzene With copper(l) iodide; N,N-dimethylethylenediamine; sodium iodide In 1,4-dioxane at 110℃; for 20h; Inert atmosphere; Schlenk technique; Stage #2: S-methyl-S-phenylsulfoximine With caesium carbonate In 1,4-dioxane at 110℃; for 20h; Temperature; Reagent/catalyst; Inert atmosphere; Schlenk technique; | 93% |
| With caesium carbonate; copper(I) oxide In N,N-dimethyl-formamide at 110℃; for 18h; | 89% |
| Conditions | Yield |
|---|---|
| With tetrakis(triphenylphosphine) palladium(0) In toluene for 24h; Heating; | 100% |
| With 1,4-diaza-bicyclo[2.2.2]octane; tetrabutyl ammonium fluoride; palladium diacetate In 1,4-dioxane at 100℃; for 16h; Stille reaction; | 98% |
| With 1,4-diaza-bicyclo[2.2.2]octane; potassium hydroxide; poly(ethylene glycol)-400; palladium diacetate In water at 80℃; for 15h; Stille coupling; | 87% |
| With potassium fluoride; 1,4-dicyclohexyl-diazabutadiene; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane at 100℃; for 20h; Stille cross-coupling reaction; | 52% |
| With tetrakis(triphenylphosphine) palladium(0) In toluene Inert atmosphere; Reflux; | 45% |
| Conditions | Yield |
|---|---|
| With potassium carbonate; palladium dichloride In pyridine for 3h; Suzuki cross-coupling; Heating; | 100% |
| With potassium carbonate; carbapalladacycle complex*periodic mesoporous organosilica for 24h; Suzuki coupling; Heating; | 100% |
| With tetra-butylammonium acetate; Pd EnCat-30TM In ethanol at 120℃; for 0.166667h; Suzuki cross-coupling; microwave irradiation; | 100% |
Related products
Downstream Products
Hot Products
Xi,
NAbout|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View