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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

4-Phenyltoluene Manufacturer/High quality/Best price/In stock

Cas:644-08-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-methyl-1,1'-biphenyl supplier in China

Cas:644-08-6

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------

High purity 644-08-6? 4-Phenyltoluene

Cas:644-08-6

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:OLED Intermediate Transportation:by air or by sea Port:Shanghai, Qingdao

4-Phenyltoluene

Cas:644-08-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Methyl-1,1'-biphenyl

Cas:644-08-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

4-Phenyltoluene Basic information Product Name: 4-Phenyltoluene Synonyms: 1’-Biphenyl,4-methyl-1;4-methyl-1’-biphenyl;4-methyl-bipheny;Biphenyl, 4-methy

best offer 4-Phenyltoluene

Cas:644-08-6

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 644-08-6 with best quality

Cas:644-08-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name: 4-Phenyltoluene Synonyms: 1’-Biphenyl,4-methyl-1;4-methyl-1’-biphenyl;4-methyl-bipheny;Biphenyl, 4-methyl-;p-Methylbiphenyl;p-Methyldiphenyl;p-Phenyltoluene;4-METHYLBIPHENYL

4-Phenyltoluene

Cas:644-08-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

4-Phenyltoluene 644-08-6

Cas:644-08-6

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,1'-Biphenyl,4-methyl- 644-08-6

Cas:644-08-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

4-Phenyltoluene CAS:644-08-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia

4-Phenyltoluene CAS:644-08-6

Cas:644-08-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,1'-Biphenyl,4-methyl-

Cas:644-08-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:644-08-6

Cas:644-08-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Organic raw materials 4-Phenyltoluene 644-08-6

Cas:644-08-6

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Methylbiphenyl

Cas:644-08-6

Min.Order:0

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Lorcaserin(856681-05-5)is an orally administered agent and a selective 5-HT2C receptor agonist for the treatment of obesity. It had been approved for marketing in US by FDA on 27 June in 2012. In clinical studies, lorcaserin h

4-Phenyltoluene

Cas:644-08-6

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS 644-08-6 4-Phenyltoluene

Cas:644-08-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Phenyltoluene

Cas:644-08-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

4-METHYLBIPHENYL

Cas:644-08-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Phenyltoluene

Cas:644-08-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-Phenyltoluene

Cas:644-08-6

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 4-PHENYLTOLUENE

Cas:644-08-6

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 4-methyl-1,1'-biphenyl

Cas:644-08-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

4-Phenyltoluene

Cas:644-08-6

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Hangzhou Think Chemical Co. Ltd

HANGZHOU THINK CHEMICAL CO., LTD. (THINKCHEM) is an integrative corporation of trade, research and contract manufacture. With about ten years of business experiences on the marketing & distribution, thinkchem specializes in exp

4-Phenyltoluene

Cas:644-08-6

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 4-Phenyltoluene Synonyms: 1’-Biphenyl,4-methyl-1;4-methyl-1’-biphenyl;4-methyl-bipheny;Biphenyl, 4-methyl-;p-Methylbiphenyl;p-Methyldiphenyl;p-Phenyltoluene;4-METHYLBIPHENYL CAS: 644-08-6 MF: C13H12 MW: 168.23

4-Phenyltoluene

Cas:644-08-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

4-Phenyltoluene

Cas:644-08-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4-Phenyltoluene

Cas:644-08-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

4-Phenyltoluene

Cas:644-08-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

4-Methylbiphenyl

Cas:644-08-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

para-bromotoluene
106-38-7

para-bromotoluene

phenylboronic acid
98-80-6

phenylboronic acid

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With potassium phosphate; (η5-C5H5)Re(NO)(P(C6H5)3)(C(CH3)3)2; palladium diacetate In toluene at 100℃; for 1h; Suzuki cross-couplings reaction;100%
With N,N-dicyclohexyl-2-(dicyclohexylphosphanyl)benzenesulfonamide; tris(dibenzylideneacetone)dipalladium (0); caesium carbonate In 1,4-dioxane at 80℃; for 3h; Suzuki-Miyaura cross coupling;100%
With potassium phosphate; 3-(2,6-diisopropylphenyl)-1-(2-diphenylphosphanylbenzyl)-3H-imidazol-1-ium chloride; bis(η3-allyl-μ-chloropalladium(II)) In 1,4-dioxane at 80℃; for 12h; Product distribution; Further Variations:; Catalysts; Reagents; Solvents; Suzuki cross-coupling;100%
para-chlorotoluene
106-43-4

para-chlorotoluene

phenylboronic acid
98-80-6

phenylboronic acid

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With Cs2O3; PCy3 adduct of cyclopalladated ferrocenylimine In 1,4-dioxane at 100℃; for 15h; Suzuki cross-coupling reaction;100%
With [PdI(2-(2-thiophenyl)-4,4-dimethyloxazoline)(1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene)]; potassium carbonate In tetrahydrofuran; water at 90℃; for 18h; Catalytic behavior; Reagent/catalyst; Suzuki-Miyaura Coupling;100%
With caesium carbonate; palladium diacetate; 1,3-di-([N-(2,4,6-Me3Ph)imidazolium-3-yl]Me)-2,4,6-Me3Ph*2Cl- In 1,4-dioxane at 80℃; for 1.5h; Suzuki reaction;99%
para-bromotoluene
106-38-7

para-bromotoluene

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With [1,3-bis(2,6-diisopropylphenyl)-imidazolium][Ni(PPh3)Cl3] In tetrahydrofuran at 30℃; for 1h; Kumada Cross-Coupling; Schlenk technique; Inert atmosphere;100%
With C70H40Cl2F68N2O6Pd2 In tetrahydrofuran at 100℃; for 0.0166667h; Kumada coupling reaction; Microwave irradiation;96%
With C17H36ClN6NiP2(1+)*Cl(1-) In tetrahydrofuran for 6h; Reagent/catalyst; Kumada Cross-Coupling; Inert atmosphere;96%
bromobenzene
108-86-1

bromobenzene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With potassium carbonate; palladium dichloride In pyridine for 3h; Suzuki cross-coupling; Heating;100%
With potassium carbonate; carbapalladacycle complex*periodic mesoporous organosilica for 24h; Suzuki coupling; Heating;100%
With tetra-butylammonium acetate; Pd EnCat-30TM In ethanol at 120℃; for 0.166667h; Suzuki cross-coupling; microwave irradiation;100%
iodobenzene
591-50-4

iodobenzene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With potassium carbonate In water at 80℃; Catalytic behavior; Suzuki-Miyaura Coupling; Green chemistry;100%
With aluminum oxide; potassium fluoride; palladium at 100℃; for 4h; Suzuki reaction;99%
With sodium hydroxide; tetrabutylammomium bromide; palladium on activated charcoal at 100℃; for 2h; Suzuki-Miyaura cross-coupling;99%
4-tolyl iodide
624-31-7

4-tolyl iodide

phenylboronic acid
98-80-6

phenylboronic acid

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With potassium carbonate; copper-palladium In N,N-dimethyl-formamide at 110℃; for 2h; Suzuki cross-coupling;100%
With sodium hydroxide; Pd-dodecanethiolate nanoparticles In tetrahydrofuran at 20℃; for 24h; Suzuki-Miyaura cross-coupling;100%
With Br4Pd(2-)*C25H30N4O2(2+); potassium carbonate In N,N-dimethyl-formamide at 120℃; for 12h; Suzuki-Miyaura reaction; Inert atmosphere;100%
p-tolyl triflate
29540-83-8

p-tolyl triflate

phenylboronic acid
98-80-6

phenylboronic acid

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 3-butyl-1-methyl-5-[(3-methyl-1H-imidazol-3-ium-1-yl)methyl]-3H-1,2,3-triazol-1-ium ditetrafluoroborate; caesium carbonate In 1,4-dioxane Suzuki-Miyaura reaction; Inert atmosphere; Heating;100%
With potassium fluoride; palladium diacetate; tricyclohexylphosphine In tetrahydrofuran at 20℃; for 18h; Suzuki cross-coupling;95%
With 2H(1+)*Cl4Pd(2-)*2H3N; poly[N-isopropylacrylamide-co-diphenyl(4'-styryl)phosphine]; sodium carbonate In water at 100℃; for 9h; Suzuki-Miyaura reaction;93%
para-bromotoluene
106-38-7

para-bromotoluene

tributylphenylstannane
960-16-7

tributylphenylstannane

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane; potassium hydroxide; poly(ethylene glycol)-400; palladium diacetate In water at 80℃; for 15h; Stille coupling;100%
With 1,1-Dimethylurea; ammonium chloride; LACTOSE; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; triphenyl-arsane at 90℃; for 6h; Stille coupling;100%
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; cesium fluoride; 3-tert-butyl-5-methyl-1-(2-(diphenylphosphino)phenyl)-1H-pyrazole In toluene at 60℃; for 10h; Stille coupling; Inert atmosphere;96%
para-chlorotoluene
106-43-4

para-chlorotoluene

9-phenyl-9H-xanthen-9-ol
596-38-3

9-phenyl-9H-xanthen-9-ol

A

xanth-9-one
90-47-1

xanth-9-one

B

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; tricyclohexylphosphine In o-xylene for 4h; Heating;A n/a
B 100%
para-bromotoluene
106-38-7

para-bromotoluene

9-phenyl-9H-xanthen-9-ol
596-38-3

9-phenyl-9H-xanthen-9-ol

A

xanth-9-one
90-47-1

xanth-9-one

B

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; tricyclohexylphosphine In o-xylene for 4h; Heating;A n/a
B 100%
4-tolyl iodide
624-31-7

4-tolyl iodide

dimethylphenylsilanol
5272-18-4

dimethylphenylsilanol

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); tetrabutylammonium triphenyldifluorosilicate; silver(l) oxide In tetrahydrofuran at 70℃; for 0.5h; Hiyama-type coupling;100%
With palladium; tetrabutyl ammonium fluoride In tetrahydrofuran at 80℃; for 48h;76%
4-tolyl iodide
624-31-7

4-tolyl iodide

tributylphenylstannane
960-16-7

tributylphenylstannane

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With cesium fluoride In dimethyl sulfoxide at 120℃; for 5h; Catalytic behavior; Stille Cross Coupling; Inert atmosphere;99%
With copper(l) iodide; triphenyl-arsane; 1-butyl-3-methylimidazolium Tetrafluoroborate; bis(benzonitrile)palladium(II) dichloride at 80℃; for 18h; Stille coupling;95%
With sodium acetate; nanocristalline MgO-stabilized nanopalladium(0) In 1-methyl-pyrrolidin-2-one at 100℃; for 2.5h; Stille cross-coupling;92%
para-chlorotoluene
106-43-4

para-chlorotoluene

phenylmagnesium bromide

phenylmagnesium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene hydrochloride In tetrahydrofuran; 1,4-dioxane at 80℃; for 3h; Phenylation;99%
With [1,3-bis(2,4,6-trimethylphenyl)imidazol]-2-ylidene; Ni(1,5-bis-cyclooctadiene)2 In various solvent(s) Kumada-Corriu cross-coupling reaction;88%
With N-heterocyclic carbene-based nickel(II) complex In tetrahydrofuran at 20℃; for 12h; Kumada reaction;83%
With 1-[2-(diphenylphosphino)phenyl]ethanol; bis(acetylacetonate)nickel(II) In diethyl ether at 20℃; for 0.333333h;97 % Chromat.
para-bromotoluene
106-38-7

para-bromotoluene

phenylmagnesium bromide

phenylmagnesium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene hydrochloride In tetrahydrofuran; 1,4-dioxane at 80℃; for 1h; Phenylation;99%
With 1-[2-(diphenylphosphino)phenyl]ethanol; bis(acetylacetonate)nickel(II) In diethyl ether at 20℃; for 3h;91 % Chromat.
para-bromotoluene
106-38-7

para-bromotoluene

phenyl trimethylsiloxane
2996-92-1

phenyl trimethylsiloxane

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride; palladium(II) acetylacetonate; 3,9-bis(2,4-tBu-PhO)tetraoxa-3,9-diphosphaspiro[5.5]undecane In xylene at 80℃; for 4h; Hiyama coupling;99%
With tetrabutyl ammonium fluoride; tris-(o-tolyl)phosphine; dichloro bis(acetonitrile) palladium(II) at 80℃; for 0.666667h; Hiyama cross-coupling reaction;99%
With tetrabutyl ammonium fluoride In para-xylene at 120℃; Hiyama coupling; Continuous flow system;99%
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

chlorobenzene
108-90-7

chlorobenzene

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With 4-di-tert-butylphosphanyl-1,5-diphenyl-1H-[1,2,3]triazole; potassium phosphate; bis(dibenzylideneacetone)-palladium(0) In toluene at 100℃; for 12h; Suzuki-Miyaura coupling;99%
With 4-di-tert-butylphosphanyl-1,5-diphenyl-1H-[1,2,3]triazole; potassium phosphate; bis(dibenzylideneacetone)-palladium(0) In toluene at 100℃; for 12h; Suzuki-Miyaura coupling;99%
With potassium phosphate; POPd1 In tetrahydrofuran for 2h; Product distribution; Further Variations:; Reagents; Catalysts; Solvents; reaction times; Suzuki coupling; Heating;99%
para-bromotoluene
106-38-7

para-bromotoluene

benzene
71-43-2

benzene

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With C34H52Cl2N2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 120℃; for 16h; Catalytic behavior; Kinetics; Reagent/catalyst; Concentration;99%
With potassium tert-butylate; vasicine at 20 - 110℃; for 48h; Schlenk technique; Inert atmosphere;94%
With 1,10-Phenanthroline; potassium tert-butylate at 100℃; for 18h; Inert atmosphere; Sealed tube;89%
fluorobenzene
462-06-6

fluorobenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With C35H31BrN4NiP In tetrahydrofuran at 25℃; for 24h; Schlenk technique; Inert atmosphere;99%
With supramolecular ensemble of HP-T with Au-Fe3O4 nanoparticles; air In tetrahydrofuran; water at 20℃; for 3h; Kumada Cross-Coupling; Irradiation;60%
1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In tetrahydrofuran at 20℃; for 24h;92 % Chromat.
N,N-diethyl phenyl O-sulfamate
1015-49-2

N,N-diethyl phenyl O-sulfamate

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
NiClCpIMes In diethyl ether at 40℃; for 24h; Grignard cross-coupling reaction;99%
iodobenzene
591-50-4

iodobenzene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With potassium carbonate In ethanol at 100℃; for 4h; Suzuki Coupling; High pressure; Green chemistry;99%
With potassium phosphate; nanocristalline MgO-stabilized nanopalladium(0) In water at 20℃; Suzuki cross-coupling;97%
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

bis(4-methylphenyl)iodonium bromide
6293-68-1

bis(4-methylphenyl)iodonium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
palladium dichloride In water for 0.00555556h; Suzuki coupling; microwave irradiation;99%
for 0.05h; Suzuki coupling; microwave irradiation;95%
In water at 100℃; for 0.05h; Suzuki coupling reaction; microwave irradiation;93%
In water at 100℃; for 0.05h; Suzuki coupling; microwave irradiation;93%
iodobenzene
591-50-4

iodobenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
amido pincer complex of nickel chloride catalyst In toluene at 20℃; for 12h; Kumada cross-coupling reaction;99%
[Ni-(o-MeC6H4){2-{OC(Ph)2CH2}-6-(3,5-Me2C3HN2)C5H3N}] In tetrahydrofuran; toluene for 12h; Kumada reaction; Heating;99%
With supramolecular ensemble of HP-T with Au-Fe3O4 nanoparticles; air In tetrahydrofuran; water at 20℃; for 0.333333h; Kumada Cross-Coupling; Irradiation;87%
chlorobenzene
108-90-7

chlorobenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
amido pincer complex of nickel chloride catalyst In tetrahydrofuran at 20℃; for 24h; Kumada cross-coupling reaction;99%
With ((C6H4)(OPPh2)(NCHPhPPh2))NiCl In tetrahydrofuran at 25℃; for 24h; Kumada cross-coupling; Inert atmosphere;99%
With Fe2(OtBu)6; sodium t-butanolate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In tetrahydrofuran at 80℃; for 16h; Catalytic behavior; Reagent/catalyst; Time; Kumada Cross-Coupling; Glovebox; Inert atmosphere;99%
bromobenzene
108-86-1

bromobenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
[Pd(Cl){2-{OC(Ph)=CH}-6-(3,5-Me2C3HN2)C5H3N}] In tetrahydrofuran; toluene for 6h; Kumada reaction; Heating;99%
With C16H16Cl2CoN8(1+)*F6P(1-) In tetrahydrofuran at 20℃; for 2h; Kumada-Corriu cross-coupling;96%
With [1,3-bis(2,6-diisopropylphenyl)-imidazolium][Ni(PPh3)Cl3] In tetrahydrofuran at 30℃; for 1h; Kumada Cross-Coupling; Schlenk technique; Inert atmosphere;96%
para-chlorotoluene
106-43-4

para-chlorotoluene

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
Stage #1: para-chlorotoluene With Ni(PPh3)(1,3-di-tert-butylimidazol-2-ylidene)Br2 In tetrahydrofuran at 0℃; for 0.0333333h; Inert atmosphere; Schlenk technique;
Stage #2: phenylmagnesium bromide In tetrahydrofuran at 0 - 25℃; for 3h; Reagent/catalyst; Inert atmosphere; Schlenk technique;
99%
With C46H55ClFeN3Pd; lithium chloride In tetrahydrofuran at 60℃; for 12h; Kumada coupling reaction; Inert atmosphere;93%
With Pd/Al(OH)3 In toluene at 140℃; for 36h; Kumada Cross-Coupling; Inert atmosphere;93%
bromobenzene
108-86-1

bromobenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

A

(4,4'-dimethyl-1,1'-biphenyl)
613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

B

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With CoF2*4H2O; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In tetrahydrofuran at 60℃; for 3h; Inert atmosphere;A 7%
B 99%
phenylnickel N-Bu-6-[1-(2,6-(Me)2PhN)ethyl]picolinamide In tetrahydrofuran; toluene at 20℃; for 24h;
With (N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))NiCl In tetrahydrofuran at 25℃; for 12h; Kumada coupling reaction; Inert atmosphere;A 32 %Chromat.
B 63 %Chromat.
chlorobenzene
108-90-7

chlorobenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

A

(4,4'-dimethyl-1,1'-biphenyl)
613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

B

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With C68H72Cl2N6NiP2 In diethyl ether at 25℃; for 12h; Kumada coupling reaction; Inert atmosphere;A n/a
B 99%
With FeF3*H2O; tricyclohexylphosphine In tetrahydrofuran at 20 - 60℃; for 24h; Inert atmosphere;A 4%
B 5%
(1-naphthyl)Ni N-Bu-6-[1-(2,6-(i-Pr)2PhN)ethyl]picolinamide In tetrahydrofuran; toluene at 20℃; for 24h;
4-tolyl iodide
624-31-7

4-tolyl iodide

phenyl trimethylsiloxane
2996-92-1

phenyl trimethylsiloxane

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In water; toluene at 100℃; for 20h; Solvent; Reagent/catalyst; Hiyama Coupling;99%
With tetrabutyl ammonium fluoride In para-xylene at 50℃; for 20h; Hiyama coupling;98%
With palladium; tetrabutyl ammonium fluoride at 80℃; for 6h;98%
p-tolylzinc(II) chloride
90252-89-4

p-tolylzinc(II) chloride

chlorobenzene
108-90-7

chlorobenzene

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With Ni(Cl){2-(Ph2P)C6H4NCH(Ph)P(O)Ph2} In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 25℃; for 24h; Negishi coupling reaction; Inert atmosphere;99%
With C21H18N8Ni2O(2+)*2F6P(1-) In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 80℃; for 2h; Negishi coupling reaction;97%
4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

[2H]-4-methylbiphenyl

[2H]-4-methylbiphenyl

Conditions
ConditionsYield
With hydrogen; water-d2; palladium on activated charcoal at 110℃; under 760.051 Torr; for 24h;99%

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