Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
Cas:624-31-7
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryAnalysis tests Standard Results Appearance Yellowish Crystallization Hangzhou Dingyan Chem is a leading manufacturer and supplie
Cas:624-31-7
Min.Order:1 Kilogram
FOB Price: $250.0 / 350.0
Type:Manufacturers
inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:624-31-7
Min.Order:0 Metric Ton
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inquiryFactory supply 4-Iodotoluene Cas 624-31-7 with low price Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed additives, F
Cas:624-31-7
Min.Order:10 Kilogram
FOB Price: $10.0
Type:Trading Company
inquiryhigh quality Appearance:Liquid Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
Cas:624-31-7
Min.Order:1 Gram
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inquiry
Cas:624-31-7
Min.Order:1 Metric Ton
FOB Price: $1.0
Type:Manufacturers
inquiryHebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car
Cas:624-31-7
Min.Order:1 Metric Ton
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Type:Trading Company
inquiry4-Iodotoluene Basic information Product Name: 4-Iodotoluene Synonyms: P-IODOTOLUENE;1-iodo-4-methyl-benzen;1-Methyl-4-iodobenzene;4-Methyl-1-iodobenzene;4-Methyliodobenzene;4-Methylpheny
Cas:624-31-7
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryHebei Nengqian Chemical Import and Export Co., LTD.. is located in xingtai City, Hebei Province, China. It is a biotechnology enterprise engaged in the research, development, production and sales of animal and plant extracts, cosmetics, pharmaceutica
Cas:624-31-7
Min.Order:1 Gram
FOB Price: $12.0 / 15.0
Type:Trading Company
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:624-31-7
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryProduct Name: 4-Iodotoluene Synonyms: P-IODOTOLUENE;1-iodo-4-methyl-benzen;1-Methyl-4-iodobenzene;4-Methyl-1-iodobenzene;4-Methyliodobenzene;4-Methylphenyliodide;benzene,1-iodo-4-methyl-;p-Iodomethylben
1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:colorless or light yellow Storage:Store in sealed containers
Cas:624-31-7
Min.Order:100 Gram
Negotiable
Type:Other
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:624-31-7
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryOur company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese
Cas:624-31-7
Min.Order:1 Kilogram
FOB Price: $30.0 / 40.0
Type:Trading Company
inquiry4-Iodotoluene CAS:624-31-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediate
Cas:624-31-7
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:624-31-7
Min.Order:10 Kilogram
Negotiable
Type:Trading Company
inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:624-31-7
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryWe are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov
Cas:624-31-7
Min.Order:100 Gram
FOB Price: $100.0 / 2000.0
Type:Lab/Research institutions
inquiryProduct name: 4-Iodotoluene CAS No.: 624-31-7 Molecule Formula:C7H7I Molecule Weight:218.03 Purity: 99.0% Package: 25kg/drum Description:Yellow crystalline powder Manufacture Standards:Enterprise Standard TESTING I
Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:624-31-7
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryGMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,
Product Name: 4-Iodotoluene Synonyms: 1-IODO-4-METHYLBENZENE;AURORA KA-7367;IODOTOLUENE(4-);4-Iodotouene;4-Iodotoluene,>98%;4-IODOTOLUENE;4-Iodotoluene 98%;4-IODOTOLUENE 99.5% CAS: 624-31-7 MF: C7H7I MW: 218.04 Mol File: 624-31-7
Cas:624-31-7
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiry3,3-diethyl-1-(4-methylphenyl)-1-triazene
4-tolyl iodide
Conditions | Yield |
---|---|
With cation exchange resin BioRad AG 50W-X12 (H+); sodium iodide In acetonitrile at 75℃; Product distribution; further solvent: THF, DMSO; | 99% |
With sulfonic acid resin (H+ form, Bio-Rad AG 50W-12); sodium iodide In acetonitrile at 75℃; for 0.133333h; | 90% |
With chloro-trimethyl-silane; sodium iodide In acetonitrile at 60℃; for 0.0833333h; | 75% |
Conditions | Yield |
---|---|
With potassium iodide In water at 25℃; for 0.0833333h; Solvent; Sandmeyer Reaction; | 99% |
With iodine; potassium iodide In dimethyl sulfoxide at 15℃; | |
With trimethylsilyl iodide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 65℃; for 2h; | 98 % Chromat. |
With diiodomethane; tetrabutylammonium perchlorate In methanol; N,N-dimethyl-formamide at 20℃; for 3h; Sandmeyer Reaction; Electrochemical reaction; | 71 %Chromat. |
With trimethylsilyl iodide at 60 - 70℃; Inert atmosphere; Ionic liquid; |
Conditions | Yield |
---|---|
With potassium ferrate(VI); iodine In hexane for 2.33333h; Reflux; regioselective reaction; | 95% |
With N-iodosaccharine at 20℃; Ionic liquid; Darkness; regioselective reaction; | 92% |
With sodium dodecyl-sulfate; sodium iodide; Ce(OH)3OOH at 20℃; for 2h; | 87% |
Conditions | Yield |
---|---|
Stage #1: p-toluidine With potassium sulfite; phosphoric acid In water at 6 - 18℃; for 0.25h; Stage #2: With sodium iodate In water at 35℃; Temperature; | 93% |
Stage #1: p-toluidine With sodium nitrite Stage #2: With potassium iodide | 91% |
Stage #1: p-toluidine With toluene-4-sulfonic acid In water at 20℃; Stage #2: With potassium iodide In water at 20℃; for 1.25h; | 91% |
Conditions | Yield |
---|---|
With copper(I) oxide; L-proline; potassium iodide In ethanol at 110℃; for 30h; Catalytic behavior; Reagent/catalyst; Time; Schlenk technique; Inert atmosphere; Sealed tube; | 93% |
With copper(l) iodide; pyrographite In neat (no solvent) at 150℃; for 36h; | 90% |
With copper(l) iodide; trans-N,N'-dimethylcyclohexane-1,2-diamine; sodium iodide In acetonitrile at 100℃; for 1h; Buchwald's halogen exchange reaction; Inert atmosphere; Microwave irradiation; | 90% |
4-tolyl iodide
Conditions | Yield |
---|---|
With chloroamine-T; sodium iodide In tetrahydrofuran; water at 20℃; for 0.166667h; | 91% |
4-tolyl iodide
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide In acetonitrile at 20℃; for 0.75h; Product distribution; Further Variations:; various reagent ratios; Substitution; | 90% |
With tetra-(n-butyl)ammonium iodide In acetonitrile at 20℃; for 0.75h; Substitution; | 82% |
Conditions | Yield |
---|---|
With sodium nitrite In acetonitrile at 80℃; for 0.5h; Reagent/catalyst; Temperature; Sealed tube; | 87% |
With copper(I) oxide; ammonium hydroxide; oxygen; potassium iodide In water at 25℃; for 24h; | 83% |
With iodine; potassium carbonate In acetonitrile at 80℃; for 10h; Solvent; Reagent/catalyst; Temperature; Inert atmosphere; Schlenk technique; Sealed tube; | 81% |
N-(4-methylphenyl)cyanamide
A
phenyl(p-tolyl)cyanamide
B
4-tolyl iodide
Conditions | Yield |
---|---|
With sodium carbonate In water at 80℃; for 2h; | A 86% B 196 mg |
bis(4-methylphenyl)iodonium trifluoromethanesulfonate
isopropylamine
N-(4-methylphenyl)cyanamide
A
4-tolyl iodide
Conditions | Yield |
---|---|
With [2,2]bipyridinyl; potassium carbonate; copper(l) chloride In toluene at 80℃; for 2h; Inert atmosphere; | A 76% B 24% C 85% |
(4-methylphenyl)azo 4-methylphenyl sulfone
4-tolyl iodide
Conditions | Yield |
---|---|
With 18-crown-6 ether; potassium iodide In diethyl ether; acetonitrile for 4h; Ambient temperature; | 84% |
Conditions | Yield |
---|---|
palladium diacetate In tetrahydrofuran at 40℃; for 0.75h; | 83% |
Conditions | Yield |
---|---|
palladium diacetate In water; acetonitrile at 20℃; for 2h; | 82% |
With palladium diacetate In water; acetonitrile at 20℃; for 2h; | 74% |
4-tolyl iodide
Conditions | Yield |
---|---|
With chloroamine-T; sodium iodide In tetrahydrofuran; water at 20℃; for 0.333333h; | 80% |
5,5-dimethyl-2-(4-methylphenyl)-1,3,2-dioxaborinane
4-tolyl iodide
Conditions | Yield |
---|---|
With chloroamine-T; sodium iodide In tetrahydrofuran for 0.166667h; | 78% |
Conditions | Yield |
---|---|
Stage #1: bis(trifluoromethanesulfonyl)amide With tert.-butylnitrite; acetic acid In ethanol Cooling with ice; Stage #2: p-toluidine With tetraethylammonium iodide In water at 20℃; | 78% |
A
4-tolyl iodide
B
diethyl dithiocarbamic acid p-tolyl ester
Conditions | Yield |
---|---|
Ambient temperature; | A n/a B 75% |
Conditions | Yield |
---|---|
With iodine; mercury(II) oxide In nitrobenzene at 180 - 185℃; for 2h; | 75% |
With N-iodo-succinimide; [4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis{3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC}iridium(III) hexafluorophosphate; iodine; caesium carbonate In 1,2-dichloro-ethane at 50℃; for 24h; Inert atmosphere; Irradiation; Sealed tube; | 67% |
Multi-step reaction with 2 steps 1: thionyl chloride 2: N-hydroxypyridine-2-thione sodium salt, AIBN, CH2I2 / toluene / 0.58 h / Heating View Scheme | |
With tris-(dibenzylideneacetone)dipalladium(0); 1-iodo-butane; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; chloro-N,N,N',N'-bis(tetramethylene)formamidinium hexafluorophosphate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 120℃; for 16h; Sealed tube; Inert atmosphere; | 31 %Chromat. |
benzaldehyde
A
4-tolyl iodide
B
4-methylphenyl(phenyl)methanol
C
toluene
Conditions | Yield |
---|---|
With chromium dichloride; nickel dichloride In N,N-dimethyl-formamide at 25℃; for 5h; Arylation; | A 73 % Spectr. B 73% C 41 % Spectr. |
With chromium dichloride; nickel dichloride In N,N-dimethyl-formamide for 5h; Ambient temperature; | A 73 % Chromat. B 72% C 41 % Chromat. |
4-iodo-benzyl alcohol
4-tolyl iodide
Conditions | Yield |
---|---|
With chlorocarbonylbis(triphenylphosphine)iridium(I); hydrazine hydrate; potassium hydroxide In methanol at 160℃; for 3h; Wolff-Kishner Reduction; Sealed tube; | 73% |
With chlorocarbonylbis(triphenylphosphine)iridium(I); hydrazine hydrate; potassium hydroxide In methanol at 160℃; for 3h; Sealed tube; | 73% |
With 2,4,6-trimethyl-pyridine; 4,4'-dimethoxyphenyl disulfide; iridium(lll) bis[2-(2,4-difluorophenyl)-5-methylpyridine-N,C20]-4,40-di-tert-butyl-2,20-bipyridine hexafluorophosphate; triphenylphosphine In toluene for 24h; Irradiation; | 30 %Chromat. |
Conditions | Yield |
---|---|
With iodine; lithium perchlorate In various solvent(s) Ambient temperature; anodic oxidation; | A 30% B 70% |
With dinitrogen tetraoxide; pyrographite; ferric nitrate; sodium iodide at 20℃; for 20h; | A 40% B 60% |
With iodine In nitromethane at 120℃; for 1h; Sealed tube; Overall yield = 88 %; regioselective reaction; | A 41% B 47% |
1-(4-methylphenyl)-3-(2-methoxy-4-nitrophenyl)-2-triazene
A
4-tolyl iodide
B
2-iodo-5-nitroanisole
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate; sodium iodide In acetonitrile at 40℃; for 2h; | A 70% B n/a |
Conditions | Yield |
---|---|
With silver tetrafluoroborate; Iodine monochloride In methanol at 0℃; for 0.25h; | 65% |
With iodine; silver trifluoroacetate In methanol at 0℃; for 0.25h; | 64.8% |
With sulfuric acid; potassium iodide In methanol; acetonitrile at 20℃; Electrochemical reaction; | 96 %Chromat. |
chloroform
4,4'-dimethyldiphenyliodonium iodide
A
4-tolyl iodide
B
p-Toluic acid
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; potassium hydroxide at 50℃; for 1h; Carbonylation; | A n/a B 64% |
Conditions | Yield |
---|---|
With 2-Iodobenzoic acid; iodine; 3-chloro-benzenecarboperoxoic acid In acetonitrile at 50℃; for 8h; Darkness; | 61% |
4-tolyl iodide
Conditions | Yield |
---|---|
With zinc(II) iodide In acetonitrile at 20℃; for 2h; | 60% |
Conditions | Yield |
---|---|
With tri-n-propylamine In neat (no solvent) at 140℃; for 18h; Heck Reaction; Green chemistry; | 58% |
1-(p-methylbenzenesulfonyloxy)-1,2-benziodoxol-3(1H)-one
4-tolyl iodide
Conditions | Yield |
---|---|
With iodine In acetonitrile for 16h; Ambient temperature; | 57% |
With iodine In acetonitrile at 20 - 30℃; for 16h; | 57% |
carbon monoxide
4-iodoxy-toluene
A
4-tolyl iodide
B
p-Toluic acid
Conditions | Yield |
---|---|
With sodium tetrachloropalladate; sodium carbonate In water at 50℃; for 10h; Yields of byproduct given; | A n/a B 55% |
lithium 2-nitropropane
(p-methylphenyl)phenyliodonium bromide
A
formaldehyd
B
iodobenzene
C
2,3-dimethyl-2,3-dinitrobutane
D
4-tolyl iodide
Conditions | Yield |
---|---|
In methanol at 30℃; for 48h; Further byproducts given; | A 37% B 44% C 6% D 54% |
4-tolyl iodide
4-dichloroiodanyl-toluene
Conditions | Yield |
---|---|
With hydrogenchloride; sodium hypochlorite at 15℃; for 1h; | 100% |
With chlorine In dichloromethane at 20℃; for 1h; | 96% |
Stage #1: 4-tolyl iodide With urea hydrogen peroxide adduct at 85℃; for 0.25h; Stage #2: With hydrogenchloride for 1h; | 96% |
Conditions | Yield |
---|---|
With palladium diacetate In benzene at 120℃; for 25h; | 100% |
Conditions | Yield |
---|---|
With potassium carbonate; palladium diacetate In water; N,N-dimethyl-formamide at 25℃; under 760 Torr; for 4h; | 100% |
With potassium hydroxide; amphiphilic resin-supported phosphine-palladium; water at 25℃; under 760 Torr; for 12h; Product distribution; Further Variations:; Reagents; hydroxycarbonylation; | 100% |
With dichloro bis(acetonitrile) palladium(II); sodium dodecyl-sulfate; potassium carbonate In water; toluene; butan-1-ol at 50℃; under 760 Torr; for 4h; | 92% |
4-tolyl iodide
acrylic acid methyl ester
3-p-tolyl-acrylic acid methyl ester
Conditions | Yield |
---|---|
With triethylamine; PdCl2(4,4'-bis(n-C10F21CH2OCH2)-2,2'-bpy) In N,N-dimethyl-formamide at 140℃; for 5h; Heck reaction; | 100% |
With sodium acetate; 1-(2-iodophenyl)-1H-tetrazole; palladium diacetate In N,N-dimethyl-formamide at 80℃; for 6h; Product distribution; Further Variations:; Solvents; Temperatures; Heck reaction; | 99% |
With C18H19Cl2N2PPd; triethylamine In N,N-dimethyl-formamide at 140℃; for 2h; Catalytic behavior; Reagent/catalyst; Time; Temperature; Heck Reaction; Inert atmosphere; Schlenk technique; | 99% |
Conditions | Yield |
---|---|
With copper(l) iodide; potassium carbonate; bis(triphenylphosphine)nickel(II) chloride In 1,4-dioxane; water for 4h; Sonogashira-Hagihara reaction; Heating; | 100% |
With copper(l) iodide; triethylamine; triphenylphosphine; (MeNC3H3N)(MeNC3H3NCOC4H8N)PdI2 In N,N-dimethyl-formamide at 20℃; Sonogashira coupling; | 100% |
With copper(l) iodide; 4-(diphenylphosphino)-benzyltrimethylammonium bromide; triethylamine; palladium dichloride at 70℃; for 3h; Sonogashira reaction; Ionic liquid; Inert atmosphere; | 100% |
4-tolyl iodide
phosphonic acid diethyl ester
diethyl 4-methylphenylphosphonate
Conditions | Yield |
---|---|
With Pd(PPh2)(m-C6H4SO3Na)*(H2O)4; triethylamine In water; acetonitrile for 1.5h; Ambient temperature; | 100% |
With triethylsilane; bis-triphenylphosphine-palladium(II) chloride; triethylamine In toluene for 0.183333h; Irradiation; | 91% |
With water extract of rice straw ash (WERSA) In water at 90℃; for 4h; | 90% |
Conditions | Yield |
---|---|
With palladium diacetate In benzene at 120℃; for 25h; | 100% |
tris(dibenzylideneacetone)dipalladium (0) In o-xylene at 145℃; for 1h; | 92% |
Conditions | Yield |
---|---|
With 2-(2-methyl-1-oxopropane)cyclohexanone; caesium carbonate; copper(l) iodide In N,N-dimethyl-formamide at 25℃; for 1.5h; | 100% |
With caesium carbonate; copper(I) bromide In dimethyl sulfoxide at 55℃; for 24h; Ullmann coupling; | 87% |
With tetra(n-butyl)ammonium hydroxide; copper(l) chloride In water at 80℃; for 24h; Inert atmosphere; | 86% |
Conditions | Yield |
---|---|
With sodium carbonate In ethanol; water at 80℃; for 0.166667h; Catalytic behavior; Suzuki-Miyaura Coupling; | 100% |
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling; | 99% |
With potassium phosphate tribasic trihydrate In ethanol; water at 60℃; for 0.166667h; Suzuki-Miyaura cross-coupling reaction; | 99% |
Conditions | Yield |
---|---|
With potassium carbonate In ethanol; water at 80℃; for 0.166667h; Suzuki Coupling; | 100% |
With sodium carbonate In ethanol; water at 80℃; for 1h; Suzuki-Miyaura Coupling; Green chemistry; | 100% |
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling; | 99% |
Conditions | Yield |
---|---|
With potassium carbonate; copper-palladium In N,N-dimethyl-formamide at 110℃; for 2h; Suzuki cross-coupling; | 100% |
With sodium hydroxide; Pd-dodecanethiolate nanoparticles In tetrahydrofuran at 20℃; for 24h; Suzuki-Miyaura cross-coupling; | 100% |
With Br4Pd(2-)*C25H30N4O2(2+); potassium carbonate In N,N-dimethyl-formamide at 120℃; for 12h; Suzuki-Miyaura reaction; Inert atmosphere; | 100% |
tert-Butyl acrylate
4-tolyl iodide
tert-butyl 4-methylcinnamate
Conditions | Yield |
---|---|
With tetrabutyl ammonium fluoride; palladium dichloride at 40℃; for 3h; Heck reaction; Inert atmosphere; neat (no solvent); | 100% |
With triethylamine; palladium In N,N-dimethyl acetamide at 80℃; for 36h; Heck reaction; | 99% |
With poly(N-isopropylacerylamide)-SCS-PdCl; TEA In n-heptane; N,N-dimethyl acetamide; water at 95℃; for 10h; Heck coupling; | 99% |
acrylic acid n-butyl ester
4-tolyl iodide
(E)-n-butyl 3-(p-tolyl)acrylate
Conditions | Yield |
---|---|
With 1-tert-butyl-3-(2-(diphenylarsinyl)benzyl)-1H-imidazol-3-ium chloride; caesium carbonate; bis(dibenzylideneacetone)-palladium(0) In ISOPROPYLAMIDE at 60℃; for 20h; Heck reaction; Inert atmosphere; | 100% |
With triethylamine; bis(N-methylimidazol-2-yl)Pd(Cl)Me In various solvent(s) at 120℃; for 0.5h; Heck coupling; | 99% |
With potassium phosphate; N,N'-(1,2-ethanediylidene)bishexahydro-1H-azepin-1-amine; tetrabutylammomium bromide; dichloro bis(acetonitrile) palladium(II) In N,N-dimethyl-formamide at 130℃; for 24h; Mizoroki-Heck reaction; | 99% |
4-tolyl iodide
acrylic acid methyl ester
methyl 3-(4-methylphenyl)acrylate
Conditions | Yield |
---|---|
With triethylamine at 145℃; for 6h; Catalytic behavior; Heck Reaction; | 100% |
With [2,6-bis(2-methyloxalol-4-yl)phenyl-κ3-NCN]bromopalladium(II); potassium acetate In 1-methyl-pyrrolidin-2-one at 120℃; for 7h; Mizoroki-Heck reaction; | 99% |
With potassium carbonate In water at 20℃; Heck Reaction; Green chemistry; | 99% |
Conditions | Yield |
---|---|
With C20H20N4O6Pd(2+)*2C2H3O2(1-); tetrabutylammomium bromide; sodium acetate In N,N-dimethyl-formamide at 110℃; for 24h; Heck Reaction; Green chemistry; | 100% |
With tris-(dibenzylideneacetone)dipalladium(0); 2,5-di(2,4,6-trimethylphenyl)-1,2,5-thiadiazolidine-1-oxide; triethylamine In N,N-dimethyl-formamide at 200℃; for 0.166667h; Heck reaction; Microwave irradiation; | 99% |
With potassium hydroxide In water at 80℃; for 20h; Heck reaction; | 99% |
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; for 5.5h; Sonogashira coupling; Inert atmosphere; | 100% |
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In dimethyl sulfoxide; triethylamine at 40 - 45℃; for 10.3h; | 91% |
With potassium carbonate In N,N-dimethyl-formamide at 110℃; for 7h; Sonogashira coupling; | 87% |
4-tolyl iodide
toluene-4-sulfonic acid
<(hydroxy)(tosyloxy)iodo>-p-toluene
Conditions | Yield |
---|---|
With 3-chloro-benzenecarboperoxoic acid In chloroform at 20℃; for 2h; | 100% |
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 20℃; for 0.5h; | 98% |
With 3-chloro-benzenecarboperoxoic acid In dichloromethane; 2,2,2-trifluoroethanol at 20℃; for 0.5h; | 95% |
4-tolyl iodide
(3-benzyloxy-prop-1-ynyl)trimethylsilanebenzyl ether
bis(iodozinc)methane
Conditions | Yield |
---|---|
With bis(1,5-cyclooctadiene)nickel (0); trifuran-2-yl-phosphane In tetrahydrofuran at 25℃; for 14h; | 100% |
Conditions | Yield |
---|---|
polymer supported palladium catalyst In N,N-dimethyl-formamide at 70℃; for 8h; Stille coupling reaction; | 100% |
Conditions | Yield |
---|---|
With copper(II) acetate monohydrate; caesium carbonate In N,N-dimethyl-formamide at 110℃; for 24h; Inert atmosphere; | 100% |
With Cu6[1,4-bis(imidazol-1-yl)butane]3I6; caesium carbonate In N,N-dimethyl-formamide at 100℃; for 24h; Inert atmosphere; | 97% |
With copper(II) acetate monohydrate; caesium carbonate In N,N-dimethyl-formamide at 110℃; for 24h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
Stage #1: 4-tolyl iodide With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; for 0.166667h; Stage #2: 5-hexyl-1-ol at 20℃; | 100% |
With C24H28Cl2N2PPd; tetrabutyl ammonium fluoride In N,N-dimethyl-formamide at 110℃; for 6h; Sonogashira Cross-Coupling; Inert atmosphere; | 96% |
With potassium phosphate; copper(l) iodide; (E)-1,1-diphenyl-2-(pyridin-2-ylmethylene)hydrazine; dichloro bis(acetonitrile) palladium(II) In N,N-dimethyl-formamide at 70℃; for 5h; Sonogashira cross-coupling; | 73% |
4-(trifluoromethyl)phenylbromonium bis[(trifluoromethyl)sulfonyl]methylide
4-tolyl iodide
p-methylphenyliodonium bis(trifluoromethylsulfonyl)methylide
Conditions | Yield |
---|---|
dirhodium tetraacetate at 40℃; for 0.0833333h; | 100% |
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); tetrabutylammonium triphenyldifluorosilicate; silver(l) oxide In tetrahydrofuran at 70℃; for 0.5h; Hiyama-type coupling; | 100% |
With palladium; tetrabutyl ammonium fluoride In tetrahydrofuran at 80℃; for 48h; | 76% |
n-octyne
trans-[Pt(C6H4Me-p)(SC6H4OCH3-p)(PPh3)2]
4-tolyl iodide
trans-PtI(PPh3)2C6H4Me-p
Conditions | Yield |
---|---|
With triphenylphosphine In (2)H8-toluene byproducts: p-CH3C6H4CHC(n-C6H13)SC6H4OCH3-p, p-CH3C6H4SC6H4OCH3-p; P(C6H5)3, toluene-d8, 110°C, 10 h; detected by NMR spectra; | 100% |
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tetrabutyl ammonium fluoride; sodium t-butanolate In tetrahydrofuran; water at 60℃; for 1h; Inert atmosphere; | 100% |
cyclopentadienyl iron(II) dicarbonyl dimer
4-tolyl iodide
aniline
4-methyl-N-phenylbenzamide
Conditions | Yield |
---|---|
With palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 110℃; for 1h; | 100% |
Conditions | Yield |
---|---|
Stage #1: para-iodoanisole With dichloro [1,1'-bis(diphenylphosphino)propane]palladium(II); diisopropopylaminoborane; triethylamine; potassium iodide In toluene at 110℃; for 1h; Suzuki coupling; Inert atmosphere; Stage #2: 4-tolyl iodide With caesium carbonate In ethanol; water; toluene at 90℃; for 15h; Suzuki coupling; Inert atmosphere; | 100% |
With sodium hydroxide In methanol at 20℃; for 24h; Ullmann Condensation; Irradiation; chemoselective reaction; | 95% |
With palladium diacetate; caesium carbonate; 1-indene In N,N-dimethyl-formamide at 20 - 90℃; for 24h; Inert atmosphere; Sealed tube; | 45% |
4-tolyl iodide
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; XPhos In 1,4-dioxane for 4h; Inert atmosphere; Reflux; | 100% |
Conditions | Yield |
---|---|
With [NiBr(2,4,6-trimethylphenyl)(2,2'-bipyridine)] In tetrahydrofuran at 20℃; for 12h; Reagent/catalyst; Negishi Coupling; | 100% |
4-tolyl iodide
Conditions | Yield |
---|---|
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium tert-butylate; bis(dibenzylideneacetone)-palladium(0) In Dimethyl ether; tert-butyl alcohol at 80℃; for 20h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere; stereoselective reaction; | 100% |
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