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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Iodotoluene

Cas:615-37-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hubei Vanz Pharm Co.,Ltd

1 high purity 2 able to provide COA/HNMR/HPLC 3 High quality 4 low price 5 Best service Appearance:white powder Storage:rm Package:bag/bottle/drum Application:pharmaceutical intermediate Transportation:common transportation Port:Shanghai, Wuh

2-Iodotoluene

Cas:615-37-2

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Wuhan Fortuna Chemical Co.,Ltd

High quality 2-Iodotoluene Cas 615-37-2 with steady supply Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed additives,

High quality 2-Iodotoluene Cas 615-37-2 with steady supply

Cas:615-37-2

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Intermediates Transportation:by air or by sea Port:shanghai

2-Iodotoluene

Cas:615-37-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-iodotoluene

Cas:615-37-2

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 615-37-2 Benzene,1-iodo-2-methyl-

Cas:615-37-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Iodotoluene

Cas:615-37-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

1-iodo-2-methylbenzene

Cas:615-37-2

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our advantage:Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scient

TIANFU-CHEM 2-Iodotoluene

Cas:615-37-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

2-Iodotoluene 615-37-2

Cas:615-37-2

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 615-37-2 with best quality

Cas:615-37-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Product Name: 2-Iodotoluene Synonyms: 1-iodo-2-methyl-benzen;Benzene,1-iodo-2-methyl-;o-Methyliodobenzene;o-Tolyl iodide;Toluene, o-iodo-;Toluene,o-iodo-;2-IODOTOLUENE;1-Iodo-2-methylbenzene,

2-Iodotoluene

Cas:615-37-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-iodo-2-methyl- 615-37-2

Cas:615-37-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2-Iodotoluene CAS:615-37-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates

2-Iodotoluene CAS:615-37-2

Cas:615-37-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Iodotoluene

Cas:615-37-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:615-37-2

Cas:615-37-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Factory Supply High Quality CAS 615-37-2 ,2-Iodotoluene

Cas:615-37-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Iodotoluene

Cas:615-37-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Iodotoluene

Cas:615-37-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

2-IODOTOLUENE

Cas:615-37-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Iodotoluene

Cas:615-37-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd

2-Iodotoluene

Cas:615-37-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 2-Iodotoluene

Cas:615-37-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2-Iodotoluene

Cas:615-37-2

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 2-Iodotoluene CAS No.:615-37-2 Molecule Formula:C7H7I Molecule Weight:218.03 Purity: 98.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITEMS

High Quality 2-Iodotoluene on stock

Cas:615-37-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

2-Iodotoluene

Cas:615-37-2

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

2-Iodotoluene Chemical Properties Melting point 11.27°C (estimate) Boiling point 211 °C(lit.) density 1.713 g/mL at 25 °C(lit.) refractive index n20/D 1.608(lit.) Fp 194 °F storage temp. Room temperature. form

2-Iodotoluene

Cas:615-37-2

Min.Order:200 Kilogram

FOB Price: $65.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-Iodotoluene

Cas:615-37-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2-Iodotoluene

Cas:615-37-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-Iodotoluene

Cas:615-37-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
With N-iodo-succinimide; [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) at 90℃; for 0.0833333h; Reagent/catalyst; Microwave irradiation;100%
With potassium fluoride; iodine In 1,4-dioxane at 80℃; for 1h;88%
With copper(I) oxide; ammonium hydroxide; oxygen; potassium iodide In water at 25℃; for 24h;81%
2-methylphenyl diazonium tetrafluoroborate
2093-46-1

2-methylphenyl diazonium tetrafluoroborate

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
With potassium iodide In water at 25℃; for 0.0833333h; Sandmeyer Reaction;96%
With iodine; potassium iodide In dimethyl sulfoxide at 15℃;
With diiodomethane; tetrabutylammonium perchlorate In methanol; N,N-dimethyl-formamide at 20℃; for 3h; Sandmeyer Reaction; Electrochemical reaction;53 %Chromat.
With trimethylsilyl iodide at 60 - 70℃; Inert atmosphere; Ionic liquid;
2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
With copper(l) iodide; trans-N,N'-dimethylcyclohexane-1,2-diamine; sodium iodide In acetonitrile at 150℃; for 1h; Buchwald's halogen exchange reaction; Inert atmosphere; Microwave irradiation;89%
With copper(l) iodide; pyrographite In neat (no solvent) at 150℃; for 23h;86%
With copper(I) oxide; L-proline; potassium iodide In ethanol at 110℃; for 30h; Schlenk technique; Inert atmosphere; Sealed tube;28%
potassium o-tolyltrifluoroborate

potassium o-tolyltrifluoroborate

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
With chloroamine-T; sodium iodide In tetrahydrofuran; water at 20℃; for 0.166667h;86%
2-iodobenzyliodide
4622-38-2

2-iodobenzyliodide

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
With indium; water for 11h; ultrasound;85%
potassium 4-methyl-1-(o-tolyl)-2,6,7-trioxa-1-borabicyclo-[2.2.2]octan-1-uide

potassium 4-methyl-1-(o-tolyl)-2,6,7-trioxa-1-borabicyclo-[2.2.2]octan-1-uide

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
With chloroamine-T; sodium iodide In tetrahydrofuran; water at 20℃; for 0.333333h;80%
tri-tert-butyl phosphine
13716-12-6

tri-tert-butyl phosphine

[(t-Bu)3P](o-tolyl)PdI

[(t-Bu)3P](o-tolyl)PdI

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
In benzene-d6 at 70℃; Equilibrium constant;79%
o-toluidine
95-53-4

o-toluidine

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
Stage #1: o-toluidine With sulfuric acid; silica gel; sodium nitrite at 20℃; grinding; Neat (no solvent);
Stage #2: With water at 20℃; grinding; Neat (no solvent);
Stage #3: With potassium iodide at 20℃; for 0.166667h; Sandmeyer reaction; grinding; Neat (no solvent);
78%
Diazotization.Behandlung der Diazoniumsulfatloesung mit Jodwasserstoffsaeure;
Multi-step reaction with 2 steps
1: 1) HCl, NaNO2, 2) K2CO3 / 1) H2O, 0 degC, 30 min
2: 72 percent / NaI, sulfonic acid resin (H+ form, Bio-Rad AG 50W-12) / acetonitrile / 0.13 h / 75 °C
View Scheme
C6H4S2O4N(1-)*N2C6H5CH2(1+)

C6H4S2O4N(1-)*N2C6H5CH2(1+)

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide In acetonitrile at 20℃; for 0.75h; Substitution;75%
carbon monoxide
201230-82-2

carbon monoxide

1-iodyl-2-methylbenzene
16825-70-0

1-iodyl-2-methylbenzene

A

ortho-methylbenzoic acid
118-90-1

ortho-methylbenzoic acid

B

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
With sodium tetrachloropalladate; sodium carbonate In water at 40℃; for 10h; Yields of byproduct given;A 74%
B n/a
3,3-diethyl-1-(o-tolyl)triaz-1-ene
36719-44-5

3,3-diethyl-1-(o-tolyl)triaz-1-ene

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
With sulfonic acid resin (H+ form, Bio-Rad AG 50W-12); sodium iodide In acetonitrile at 75℃; for 0.133333h;72%
toluene
108-88-3

toluene

A

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

B

4-tolyl iodide
624-31-7

4-tolyl iodide

Conditions
ConditionsYield
With iodine; lithium perchlorate In various solvent(s) Ambient temperature; anodic oxidation;A 30%
B 70%
With dinitrogen tetraoxide; pyrographite; ferric nitrate; sodium iodide at 20℃; for 20h;A 40%
B 60%
With iodine In nitromethane at 120℃; for 1h; Sealed tube; Overall yield = 88 %; regioselective reaction;A 41%
B 47%
toluene
108-88-3

toluene

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
With potassium hydrogensulfate; isoquinolinium dichromate; potassium iodide In water at 20℃; Reagent/catalyst; Temperature; Sonication;69%
With isoquinolinium dichromate; tetra-(n-butyl)ammonium iodide In water at 25 - 30℃; for 4h; Reagent/catalyst;66%
With iodine; silver perchlorate; calcium carbonate Ausschluss von Licht;
With sulfuric acid; iodine; nitric acid; acetic acid
4-Phenyl-1-butene
768-56-9

4-Phenyl-1-butene

4-Iodobenzotrifluoride
455-13-0

4-Iodobenzotrifluoride

(4-4′-di-tert-butyl-2,2′-bipyridine)NiII(2-tolyl)(I)
1474011-55-6

(4-4′-di-tert-butyl-2,2′-bipyridine)NiII(2-tolyl)(I)

A

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

B

1-(4-phenylbutan-2-yl)-4-(trifluoromethyl)benzene

1-(4-phenylbutan-2-yl)-4-(trifluoromethyl)benzene

C

1-methyl-2-(4-phenylbutan-2-yl)benzene

1-methyl-2-(4-phenylbutan-2-yl)benzene

Conditions
ConditionsYield
With monoisopropoxy(phenyl)silane; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; (±)N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II); 1-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate at 22℃; Reagent/catalyst; Inert atmosphere; Glovebox;A 5%
B 68%
C 1.7%
2-iodobenzyl alcohol
5159-41-1

2-iodobenzyl alcohol

A

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

B

bis(2-iodobenzyl) sulfide

bis(2-iodobenzyl) sulfide

Conditions
ConditionsYield
With hydrogen sulfide In Hexadecane; toluene at 180℃; under 3000.3 Torr; for 18h; Autoclave;A 9 %Chromat.
B 54%
ortho-methylbenzoic acid
118-90-1

ortho-methylbenzoic acid

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
With N-iodo-succinimide; [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; iodine; caesium carbonate In 1,2-dichloro-ethane at 50℃; for 24h; Inert atmosphere; Irradiation; Sealed tube;52%
With potassium phosphate; iodine In acetonitrile at 140℃; for 16h; Temperature; Solvent; Glovebox; Inert atmosphere; chemoselective reaction;40%
2-methylchlorobenzene
95-49-8

2-methylchlorobenzene

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
Stage #1: 2-methylchlorobenzene With potassium fluoride; 1,1,1,2,2,2-hexamethyldisilane; water; tris-(dibenzylideneacetone)dipalladium(0); CyJohnPhos In 1,4-dioxane at 100℃; for 24h;
Stage #2: With Iodine monochloride In 1,4-dioxane; dichloromethane at 20℃; for 4h; Further stages.;
51%
With copper(l) iodide; trans-N,N'-dimethylcyclohexane-1,2-diamine; sodium iodide In acetonitrile at 200℃; for 1h; Buchwald's halogen exchange reaction; Inert atmosphere; Microwave irradiation;
2-(chloromethyl)iodobenzene
59473-45-9

2-(chloromethyl)iodobenzene

A

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

B

phenanthrene
85-01-8

phenanthrene

C

9,10-dihydrophenanthrene
776-35-2

9,10-dihydrophenanthrene

D

1,1'-(1,2-Ethylenediyl)bis(2-iodobenzene)
2582-56-1

1,1'-(1,2-Ethylenediyl)bis(2-iodobenzene)

Conditions
ConditionsYield
With magnesium at 600℃;A 1%
B 12%
C 31%
D 40%
ortho-tolylmagnesium bromide
932-31-0

ortho-tolylmagnesium bromide

diiodoacetylene
624-74-8

diiodoacetylene

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
With diethyl ether unter Kuehlung;
ortho-tolylmagnesium bromide
932-31-0

ortho-tolylmagnesium bromide

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
With diethyl ether; iodine
di-o-tolyl-iodonium ; iodide
55145-92-1

di-o-tolyl-iodonium ; iodide

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

Conditions
ConditionsYield
at 155℃;
2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

A

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

B

2,2'-dimethyl-1,1'-biphenyl
605-39-0

2,2'-dimethyl-1,1'-biphenyl

Conditions
ConditionsYield
With tributylphosphine; potassium iodide; nickel dibromide In N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide at 50℃; for 3h;A 66 % Chromat.
B 23 % Chromat.
toluene
108-88-3

toluene

trifluoroacetic acid
76-05-1

trifluoroacetic acid

A

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

B

4-tolyl iodide
624-31-7

4-tolyl iodide

C

benzyl trifluoroacetate
351-70-2

benzyl trifluoroacetate

D

benzaldehyde
100-52-7

benzaldehyde

Conditions
ConditionsYield
With cobalt(III) acetate; potassium iodide In water at 25℃; for 0.166667h; Product distribution; Mn(OAc)3 or (NH4)2Ce(SO4)3 instead Co(OAc)3; object of study: oxidative iodination promoted by Co(III), Ni(III) or Ce(IV);
With cobalt(III) acetate In water at 25℃; for 0.166667h; Yield given. Yields of byproduct given;
toluene
108-88-3

toluene

A

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

B

3-Iodotoluene
625-95-6

3-Iodotoluene

C

4-tolyl iodide
624-31-7

4-tolyl iodide

Conditions
ConditionsYield
With iodine In acetonitrile Mechanism; Product distribution; electrochemical iodination in presence of benzene; anode: platinum beaker, cathode: nickel spiral, electrolyte: sodium perchlorate; further reagent (CH3-C=N-I)(1+)*ClO4(1-);
With aluminum oxide; iodine for 20h; Ambient temperature; Yield given. Yields of byproduct given;
toluene
108-88-3

toluene

A

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

B

4-tolyl iodide
624-31-7

4-tolyl iodide

C

benzyl trifluoroacetate
351-70-2

benzyl trifluoroacetate

D

benzaldehyde
100-52-7

benzaldehyde

Conditions
ConditionsYield
With cobalt(III) acetate; trifluoroacetic acid In water at 25℃; for 0.166667h; Yield given. Yields of byproduct given;
toluene
108-88-3

toluene

A

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

B

3-Iodotoluene
625-95-6

3-Iodotoluene

C

4-tolyl iodide
624-31-7

4-tolyl iodide

D

Dibromo-iodo-p-tolyl-silane

Dibromo-iodo-p-tolyl-silane

E

Dibromo-iodo-m-tolyl-silane

Dibromo-iodo-m-tolyl-silane

F

Dibromo-iodo-o-tolyl-silane

Dibromo-iodo-o-tolyl-silane

Conditions
ConditionsYield
With Silicon dibromide; Iodine monochloride at -90℃; Product distribution;
toluene
108-88-3

toluene

A

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

B

3-Iodotoluene
625-95-6

3-Iodotoluene

Conditions
ConditionsYield
With iodine; silver trifluoroacetate In dichloromethane
(2-Methylphenyl)(4'-methoxyphenyl)iodonium trifluoroacetate

(2-Methylphenyl)(4'-methoxyphenyl)iodonium trifluoroacetate

A

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

B

2-Fluorotoluene
95-52-3

2-Fluorotoluene

C

para-iodoanisole
696-62-8

para-iodoanisole

D

methoxybenzene
100-66-3

methoxybenzene

Conditions
ConditionsYield
With cesium fluoride In acetonitrile at 85℃; for 0.666667h; GC-MS estimated relative yields;
o-tolyl(p-tolyl)iodonium trifluoromethanesulfonate

o-tolyl(p-tolyl)iodonium trifluoromethanesulfonate

A

p-fluorotoluene
352-32-9

p-fluorotoluene

B

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

C

2-Fluorotoluene
95-52-3

2-Fluorotoluene

D

4-tolyl iodide
624-31-7

4-tolyl iodide

E

toluene
108-88-3

toluene

Conditions
ConditionsYield
With cesium fluoride In acetonitrile at 85℃; for 0.666667h; GC-MS estimated relative yields;
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

toluene
108-88-3

toluene

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride In 2-pentanol at 100℃; for 12h; Inert atmosphere;100%
With lithium aluminium tetrahydride In 1,2-dimethoxyethane at 35℃; for 5h; ultrasonic acceleration of reduction;95%
With 2,2'-azobis(isobutyronitrile); poly(n-hexylsilane) In benzene-d6 at 82 - 85℃; for 3h; sealed;99 % Spectr.
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

benzene-1,4-diboronic acid bispinacol ester
99770-93-1

benzene-1,4-diboronic acid bispinacol ester

2,2”-dimethyl-1,1‘:4’,1“-terphenyl
53092-64-1

2,2”-dimethyl-1,1‘:4’,1“-terphenyl

Conditions
ConditionsYield
With silver carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran for 16h; Suzuki cross-coupling reaction; Heating;100%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

trimethyl[(2-methylphenyl)ethynyl]silane
3989-15-9

trimethyl[(2-methylphenyl)ethynyl]silane

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In N,N-dimethyl-formamide at 50℃; for 6h; Inert atmosphere;100%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In N,N-dimethyl-formamide at 50℃; for 4h; Sonogashira Cross-Coupling; Inert atmosphere;98%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran Sonogashira Cross-Coupling; Inert atmosphere;97%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

dimethyl(hept-1-yn-1-yl)aluminum

dimethyl(hept-1-yn-1-yl)aluminum

1-(1-heptynyl)-2-methylbenzene
64146-63-0

1-(1-heptynyl)-2-methylbenzene

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene In 1,2-dimethoxyethane; n-heptane at 85℃; for 3h;100%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

para-thiocresol
106-45-6

para-thiocresol

(2‑methylphenyl)(4‑methylphenyl) sulfide
4279-70-3

(2‑methylphenyl)(4‑methylphenyl) sulfide

Conditions
ConditionsYield
Stage #1: para-thiocresol With potassium hydroxide In methanol at 70℃; for 0.25h; Inert atmosphere; Schlenk technique; Green chemistry;
Stage #2: ortho-methylphenyl iodide With copper(l) iodide In methanol at 110℃; for 12h; Inert atmosphere; Schlenk technique; Green chemistry;
100%
With sodium hydroxide; copper(l) iodide; tetrabutylammomium bromide In toluene for 22h; Ullmann coupling; Heating;96%
With caesium carbonate In 1,4-dioxane; N,N-dimethyl-formamide at 110℃; for 24h; Inert atmosphere;91%
With copper(ll) sulfate pentahydrate; caesium carbonate; sodium L-ascorbate In dodecane at 100℃; for 16h; Catalytic behavior; Schlenk technique; Green chemistry;90%
With pyridine In acetonitrile at 20℃; for 24h; Inert atmosphere; Sealed tube; Irradiation;92 %Spectr.
norborn-2-ene
498-66-8

norborn-2-ene

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

exo-5-Methyl-1,2,3,4,4a,8b-hexahydro-1,4-methanobiphenylene

exo-5-Methyl-1,2,3,4,4a,8b-hexahydro-1,4-methanobiphenylene

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydroxide; palladium diacetate; triphenylphosphine In water; toluene at 80℃; for 12h; Inert atmosphere; Sealed vial; regioselective reaction;100%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

stilbene
588-59-0

stilbene

1-(2-Methylphenyl)-1,2-diphenylethen
70588-52-2, 70588-53-3, 1985-77-9

1-(2-Methylphenyl)-1,2-diphenylethen

Conditions
ConditionsYield
With silver(I) acetate; palladium diacetate In acetic acid at 110℃; for 6h; Heck Reaction; Inert atmosphere;100%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

phenylboronic acid
98-80-6

phenylboronic acid

2-methylbiphenyl
643-58-3

2-methylbiphenyl

Conditions
ConditionsYield
With 3-(2-(diphenylarsinyl)benzyl)-1-phenyl-1H-imidazol-3-ium chloride; palladium diacetate; caesium carbonate In ISOPROPYLAMIDE at 60℃; for 19h; Suzuki coupling; Inert atmosphere;99%
With sodium carbonate In water at 100℃; Suzuki-Miyaura reaction;99.5%
With potassium carbonate In toluene at 80℃; for 6h; Suzuki coupling; Inert atmosphere;99%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

thiophenol
108-98-5

thiophenol

2-(phenylthio)toluene
13963-35-4

2-(phenylthio)toluene

Conditions
ConditionsYield
With (R)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; palladium diacetate; sodium t-butanolate In 1,2-dimethoxyethane at 70℃; for 24h; Inert atmosphere;99%
With copper(l) iodide; 2.9-dimethyl-1,10-phenanthroline; sodium t-butanolate In toluene at 110℃; for 24h;96%
With sodium t-butanolate; copper(l) iodide; 2.9-dimethyl-1,10-phenanthroline In toluene at 110℃; for 24h; Product distribution / selectivity;96%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

methyl (E)-3-(2-methylphenyl)-2-propenoate
70625-62-6, 75950-75-3, 130451-86-4

methyl (E)-3-(2-methylphenyl)-2-propenoate

Conditions
ConditionsYield
With trihexyl(tetradecyl)phosphonium chloride; sodium acetate; palladium diacetate In water at 50℃; for 2h; Heck reaction;99%
With triethylamine; bis-<(4-Cl-2-PdCl-Ph)-(4-Cl-Ph)-methanone oxime> In N,N-dimethyl-formamide at 110℃; for 3h; Product distribution; Further Variations:; Reaction partners; Reagents; Temperatures; Heck-Mizoroki reaction;99%
With triethylamine In water; N,N-dimethyl-formamide; toluene at 100℃; for 20h; Mizoroki-Heck reaction;99%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

phenylacetylene
536-74-3

phenylacetylene

1-phenylethynyltoluene
14309-60-5

1-phenylethynyltoluene

Conditions
ConditionsYield
With copper(l) iodide; rac-N2,N2'-bis(benzyl)-1,1'-binaphthyl-2,2'-diamine; potassium carbonate In N,N-dimethyl-formamide at 140 - 145℃; for 8h; Sonogashira coupling; Inert atmosphere;99%
With C19H25CuN5(1+)*F6P(1-); potassium carbonate In N,N-dimethyl-formamide at 135 - 140℃; Sonogashira Cross-Coupling; Sealed tube;99%
With palladium diacetate; potassium carbonate In ethanol at 80℃; for 24h;99%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

2,4'-dimethylbiphenyl
611-61-0

2,4'-dimethylbiphenyl

Conditions
ConditionsYield
With potassium carbonate In ethanol at 80℃; for 12h; Suzuki-Miyaura coupling; Inert atmosphere;99%
With Ti0998Pd0002; potassium carbonate In methanol at 120℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere;88%
With potassium hydroxide; PEG-PS resin-supported Pd-monophosphine at 25℃; for 24h;80%
With potassium carbonate In ethanol; water at 80℃; for 3h; Suzuki Coupling;95 %Chromat.
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

2,2'-dimethyl-1,1'-biphenyl
605-39-0

2,2'-dimethyl-1,1'-biphenyl

Conditions
ConditionsYield
With potassium carbonate In ethanol Suzuki-Miyaura Coupling; Schlenk technique; Heating;99%
With potassium phosphate; 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane; tris(dibenzylideneacetone)dipalladium(0) chloroform complex In toluene at 20℃; for 2.5h; Suzuki cross-coupling;98%
With potassium fluoride; tris(dibenzylideneacetone)dipalladium (0); tri-tert-butyl phosphine In tetrahydrofuran at 20℃; for 5h; Suzuki cross-coupling;98%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

4-acetylphenylboronic acid
149104-90-5

4-acetylphenylboronic acid

4-acetyl-2'-methylbiphenyl
56917-39-6

4-acetyl-2'-methylbiphenyl

Conditions
ConditionsYield
With silver tetrafluoroborate; C16H36N(1+)*C32H25Cl2Fe2N2O3PdS(1-); potassium carbonate In water for 0.25h; Suzuki coupling; Microwave irradiation;99%
With potassium fluoride; silver tetrafluoroborate; tris(dibenzylideneacetone)dipalladium (0); tri-tert-butyl phosphine In tetrahydrofuran at 20℃; for 20h; Suzuki cross-coupling;98%
With potassium phosphate; 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane; tris(dibenzylideneacetone)dipalladium(0) chloroform complex In toluene at 20℃; for 1h; Suzuki cross-coupling;96%
With potassium fluoride; potassium carbonate In water at 100℃; for 6h; Suzuki-Miyaura coupling;93%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

4-methoxy-aniline
104-94-9

4-methoxy-aniline

N-(4-methoxyphenyl)-2-methylbenzenamine
85448-89-1

N-(4-methoxyphenyl)-2-methylbenzenamine

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); sodium t-butanolate; DavePhos In 1,4-dioxane at 45℃;99%
With palladium diacetate; P(i-BuNCH2CH2)3N; sodium t-butanolate In toluene at 80℃;95%
With sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane at 45℃; for 15h;92%
With sodium t-butanolate; C42H52O3NP; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 45℃;89%
With potassium phosphate; tris(1,10-phenanthroline)ruthenium(II) complex; [Ni(2,2′:6′,2''-terpyridine)(pyridine)(CH3CN)2](PF6)2 In acetonitrile for 24h; Irradiation;30%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

2-methyl-but-3-yn-2-ol
115-19-5

2-methyl-but-3-yn-2-ol

2-methyl-4-(2-methylphenyl)-3-butyn-2-ol
40888-14-0

2-methyl-4-(2-methylphenyl)-3-butyn-2-ol

Conditions
ConditionsYield
With copper(l) iodide; tetra-(n-butyl)ammonium iodide; diethylamine; bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 70℃; for 2.5h;99%
With potassium carbonate; copper(l) chloride In methanol; acetonitrile at 25 - 30℃; for 12h; Sonogashira Cross-Coupling; Inert atmosphere; Irradiation;90%
With copper(l) iodide; tetra-(n-butyl)ammonium iodide; diethylamine; bis-triphenylphosphine-palladium(II) chloride
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

bicyclopropylidene
27567-82-4

bicyclopropylidene

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

methyl syn/anti-8-(2-methylphenyl)spiro[2.5]oct-7-ene-5-carboxylate

methyl syn/anti-8-(2-methylphenyl)spiro[2.5]oct-7-ene-5-carboxylate

Conditions
ConditionsYield
With tetraethylammonium chloride; potassium carbonate; triphenylphosphine; palladium diacetate In acetonitrile at 80℃; for 48h; domino Heck-Diels-Alder reaction;99%
acetamide
60-35-5

acetamide

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

N-(2-methylphenyl)acetamide
120-66-1

N-(2-methylphenyl)acetamide

Conditions
ConditionsYield
With aluminum oxide; potassium fluoride; copper(l) iodide; 1,10-Phenanthroline In toluene at 110℃; for 8h;99%
With potassium phosphate; copper(l) iodide; N,N`-dimethylethylenediamine In N,N-dimethyl-formamide at 80℃; for 23h;95%
With aluminum oxide; potassium fluoride; copper(l) iodide; N,N'-Dibenzylethylenediamine In toluene at 110℃; for 3h; Ullmann reaction; Inert atmosphere;90%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

acrylic acid
79-10-7

acrylic acid

(E)-3-(2-methylphenyl)acrylic acid
939-57-1, 2373-76-4, 41397-71-1

(E)-3-(2-methylphenyl)acrylic acid

Conditions
ConditionsYield
With potassium hydroxide; PS-PEG-NH-C(O)C6H4PPh2-PdCl(η3-C3H5) at 50℃; Heck reaction;99%
With tri-n-propylamine; triphenylphosphine; 3-methyl-1-[2-(perfluorodecyl)ethyl]imidazolium iodide; palladium diacetate In various solvent(s) at 120℃; for 2h; Mizoroki-Heck arylation;91%
With sodium carbonate In water at 120℃; for 12h; Green chemistry;62.3%
With potassium carbonate In water at 80℃; for 20h; Heck reaction;47 %Spectr.
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

diphenyl diselenide
1666-13-3

diphenyl diselenide

phenyl o-tolyl selenide
94800-50-7

phenyl o-tolyl selenide

Conditions
ConditionsYield
With copper(II) sulfide; iron; potassium carbonate In dimethyl sulfoxide at 110℃; for 6h; Inert atmosphere; chemoselective reaction;99%
With copper(I) oxide; [2,2]bipyridinyl; magnesium In N,N-dimethyl-formamide at 110℃; for 30h;92%
With magnesium In N,N-dimethyl-formamide at 110℃; for 30h; Inert atmosphere; Schlenk technique; Green chemistry;90%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

butyl 3-o-tolylacrylate

butyl 3-o-tolylacrylate

Conditions
ConditionsYield
With potassium carbonate at 120℃; for 0.5h; Catalytic behavior; Heck Reaction;99%
With triethylamine at 100℃; for 1.66667h; Reagent/catalyst; Heck Reaction; Sealed tube;98%
With triethylamine In N,N-dimethyl-formamide at 85℃; for 0.333333h; Catalytic behavior; Solvent; Heck Reaction;97%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

butyl (2E)-3-(2-methylphenyl)acrylate
163977-61-5

butyl (2E)-3-(2-methylphenyl)acrylate

Conditions
ConditionsYield
With C68H96Br2N2O8P2Pd2; triethylamine; 3,3'-di-tert-butyl-5,5'-dimethoxybiphenyl-2,2'-diyl diisopropylphosphoramidite In 1-methyl-pyrrolidin-2-one at 80℃; for 16h; Mizoroki-Heck reaction; Inert atmosphere; regioselective reaction;99%
With tributyl-amine; chloro-[2-(9-phenyl-1,10-phenanthrolin-2-yl)phenyl]palladium In 1-methyl-pyrrolidin-2-one at 140℃; for 15h; Heck Reaction; Inert atmosphere;99%
With 4,4’‐bis(trimethylammoniummethyl)‐2,2’‐bipyridine; diamminedichloropalladium(II); tributyl-amine In water at 140℃; for 48h; Mizoroki-Heck cross-coupling; Sealed tube;95%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

(3E)-4-[isopropoxy(dimethyl)silyl]-1-phenylbut-3-an-1-ol
119093-12-8

(3E)-4-[isopropoxy(dimethyl)silyl]-1-phenylbut-3-an-1-ol

(3E)-4-(2-methylphenyl)-1-phenylbut-3-en-1-ol

(3E)-4-(2-methylphenyl)-1-phenylbut-3-en-1-ol

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride; bis(η3-allyl-μ-chloropalladium(II)) In tetrahydrofuran at 20℃; for 3h;99%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

N-o-tolyl-hydrazinecarboxylic acid tert-butyl ester
380383-85-7

N-o-tolyl-hydrazinecarboxylic acid tert-butyl ester

N,N'-di-o-tolyl-hydrazinecarboxylic acid tert-butyl ester

N,N'-di-o-tolyl-hydrazinecarboxylic acid tert-butyl ester

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate In toluene for 2h; Heating;99%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

(R)-N-methyl-3-phenyl-3-hydroxypropylamine
115290-81-8

(R)-N-methyl-3-phenyl-3-hydroxypropylamine

atomoxetine hydrochloride
82248-59-7

atomoxetine hydrochloride

Conditions
ConditionsYield
Stage #1: ortho-methylphenyl iodide; (R)-N-methyl-3-phenyl-3-hydroxypropylamine With potassium carbonate; copper(l) iodide In toluene at 148℃; for 21h; Ullmann type reaction; Heating / reflux;
Stage #2: With hydrogenchloride In water pH=1 - 2;
Stage #3: With sodium hydroxide In water pH=11 - 12;
99%
Stage #1: ortho-methylphenyl iodide; (R)-N-methyl-3-phenyl-3-hydroxypropylamine With potassium carbonate; copper(l) iodide In toluene at 148℃; for 21h; Ullmann type reaction; Heating / reflux;
Stage #2: With hydrogenchloride In water pH=1 - 2;
Stage #3: With sodium hydroxide In water pH=11 - 12;
94%
Stage #1: ortho-methylphenyl iodide; (R)-N-methyl-3-phenyl-3-hydroxypropylamine With potassium phosphate; copper(l) iodide In toluene for 24h; Ullmann type reaction; Heating / reflux;
Stage #2: With hydrogenchloride In water pH=1 - 2;
Stage #3: With sodium hydroxide In water pH=12 - 14;
82%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

p-toluidine
106-49-0

p-toluidine

N-(4-methylphenyl)-2-methylaniline
34160-14-0

N-(4-methylphenyl)-2-methylaniline

Conditions
ConditionsYield
With sodium t-butanolate; palladium diacetate; (R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl di-t-butylphosphine In 1,2-dimethoxyethane at 100℃; for 48h;99%
With nickel(II) iodide; potassium phosphate; 2-Phenyl-1,3,2-dioxaborinane In 1,4-dioxane at 115℃; for 24h; Buchwald-Hartwig Coupling; Inert atmosphere; chemoselective reaction;86%
triethylsilane
617-86-7

triethylsilane

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

(2-methylphenyl)triethylsilane
18412-78-7

(2-methylphenyl)triethylsilane

Conditions
ConditionsYield
With potassium phosphate; rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate In 1-methyl-pyrrolidin-2-one at 20℃; for 96h;99%
1-octyl-4-phenyl-1H-[1,2,3]triazole
853052-50-3

1-octyl-4-phenyl-1H-[1,2,3]triazole

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

1-N-octyl-4-phenyl-5-(2-tolyl)-1H-1,2,3-triazole
1037412-34-2

1-N-octyl-4-phenyl-5-(2-tolyl)-1H-1,2,3-triazole

Conditions
ConditionsYield
With copper(l) chloride; lithium tert-butoxide In N,N-dimethyl-formamide at 140℃; for 9h; Inert atmosphere;99%
With copper(l) iodide; lithium tert-butoxide In N,N-dimethyl-formamide at 140℃; for 20h; Inert atmosphere; regioselective reaction;98%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

2,4,5-trimethylphenylacetylene

2,4,5-trimethylphenylacetylene

1,2,4-trimethyl-5-[(2-methylphenyl)ethynyl]benzene
1191900-12-5

1,2,4-trimethyl-5-[(2-methylphenyl)ethynyl]benzene

Conditions
ConditionsYield
With potassium phosphate; C28H47ClN4P2Pd In 1,4-dioxane; ethylene glycol at 140℃; for 0.25h; Sonogashira coupling; Inert atmosphere;99%

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