CAS No.95-52-3,2-Fluorotoluene Suppliers,MSDS download

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Fluorotoluene Manufacturer/High quality/Best price/In stock

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Fluorotoluene supplier in China

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Hefei TNJ chemical industry co.,ltd

Technology: Technology innovation is our eternal pursuit,or we will be left behind.Our technology experts,all from famous universities and institutes,has rich experience and high achievements in chemical research.This makes sure that our technology

o-Fluorotoluene 95-52-3

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:white powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

2-Fluorotoluene

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-fluorotoluene

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Fluorotoluene

Cas:95-52-3

Min.Order:5 Kiloliter

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

2-fluorotoluen

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

95-52-3 2-Fluorotoluene

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Min.Order:1 Kilogram

FOB Price: $1000.0

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Henan Sinotech Import&Export Corporation

Product Name 2-Fluorotoluene Synonyms 2-Fluorotoluene;1-Fluor-2-methylbenzol CAS 95-52-3 CAS: 95-52-3 MF: - MW: - EINECS:

2-Fluorotoluene CAS: 95-52-3

Cas:95-52-3

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the

2-Fluorotoluene/ LIDE PHARMA- Factory supply / Best price

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Min.Order:1 Kilogram

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:95-52-3

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

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Hangzhou Lingrui Chemical Co.,Ltd.

o-FluorotoluenAppearance:Colorless transparent liquid Storage:Keep away of light, cool place Package:according to customers' requirements Application:pharmaceutical intermediates Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FOB

o-Fluorotoluen

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Min.Order:1 Gram

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:Colorless clear liquid Storage:Store in dry、dark、ventilated place.For medicine , pesticide intermediates Package:25kg/drum, or as per your request. Application:For medicine , pes

2-Fluorotoluene

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Hunan chemfish Pharmaceutical co.,Ltd

95-52-3 Appearance:95%+ Package:R&D,Pilot run Application:95-52-3 Transportation:per client require Port:Express ,Air, Sea

o-Fluorotoluene

Cas:95-52-3

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SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/2-Fluorotoluene

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Shanghai Massive Chemical Technology Co., Ltd.

Shanghai Massive Chemical Technology Co., Ltd. is engaged in development, production and marketing Specialty Chemicals to satisfy the changing needs of the chemical industry. We specialize in manufacturing high quality of Advanced Intermediates, Sp

2-Fluorotoluene

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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti

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Greenutra Resource Inc

o-FluorotolueneAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air

o-Fluorotoluene

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

o-Fluorotoluene

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Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

1-Fluoro-2-Methylbenzene

Cas:95-52-3

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JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

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Min.Order:100 Gram

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Wuhan Fortuna Chemical Co.,Ltd

good quality and cheap price Package:25kg/200kg Application:as intermediates Transportation:by courier/sea/air

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

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Enke Pharma-tech Co.,Ltd. （Cangzhou, China ）

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 95-52-3 with competitive price

Cas:95-52-3

Min.Order:1 Kilogram

FOB Price: $112.0

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

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Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

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Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

95-52-3

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Synthetic route

: 95-53-4
o-toluidine

: 95-52-3
2-Fluorotoluene

Conditions

Conditions	Yield
With pyridine hydrogenfluoride; sodium nitrite 1.) O deg C, 20 min, 2.) 55 deg C, 1 h;	99%
With hydrogen fluoride; sodium nitrite at -1 - 3℃; for 1h;	99.5%
Stage #1: o-toluidine With hydrogen fluoride at -15 - 0.5℃; Flow reactor; Large scale; Stage #2: With nitrosylsulfuric acid at -5 - 0.5℃; Flow reactor; Large scale;	98.1%

: 615-37-2
ortho-methylphenyl iodide

: 95-52-3
2-Fluorotoluene

Conditions

Conditions	Yield
With copper(I) trifluoromethanesulfonate bis(trimethylacetonitrile) complex; silver fluoride In N,N-dimethyl-formamide at 140℃; for 22h; Inert atmosphere;	96%

: 446-48-0
o-fluorobenzyl bromide

A: 95-52-3
2-Fluorotoluene

B: 776-35-2
9,10-dihydrophenanthrene

C: 349-38-2
1,2-bis(2-fluorophenyl)ethane

Conditions

Conditions	Yield
With magnesium at 600℃;	A 11% B 3% C 80%

...Expand

: 1493-13-6
trifluorormethanesulfonic acid

: 2093-46-1
2-methylphenyl diazonium tetrafluoroborate

A: 95-52-3
2-Fluorotoluene

B: 66107-34-4
2-methylphenyl triflate

Conditions

Conditions	Yield
at 90℃; for 1h;	A n/a B 75%

...Expand

: 345-35-7
2-fluorobenzyl chloride

A: 95-52-3
2-Fluorotoluene

B: 776-35-2
9,10-dihydrophenanthrene

C: 349-38-2
1,2-bis(2-fluorophenyl)ethane

Conditions

Conditions	Yield
With magnesium at 600℃;	A 7% B 5% C 73%

...Expand

: 19296-22-1
toluene-2-diazonium ; hexafluoro phosphate

: 95-52-3
2-Fluorotoluene

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate at 120 - 125℃; for 1h;	72%

: 95-48-7
ortho-cresol

: 95-52-3
2-Fluorotoluene

Conditions

Conditions	Yield
With 1,3-bis(2,6-diisopropylphenyl)-2,2-difluoro-2,3-dihydro-1h-imidazole; cesium fluoride; diphenylzinc In 1,4-dioxane at 110℃; for 20h; Product distribution / selectivity; Sealed vial;	72%
With 1,3-bis(2,6-diisopropylphenyl)-2,2-difluoro-2,3-dihydro-1h-imidazole; diphenylzinc; cesium fluoride In 1,4-dioxane at 23 - 110℃; for 20.5h; Inert atmosphere;	87 %Spectr.

: 106-43-4
para-chlorotoluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With Al2CuF8 Gas phase; Inert atmosphere;	A 71% B 5% C 10%
With silver fluoride at 350℃; Product distribution / selectivity; Gas phase;	A 20.8% B 0.6% C 35.8%

...Expand

: potassium o-tolyltrifluoroborate

A: 95-52-3
2-Fluorotoluene

B: 108-88-3
toluene

Conditions

Conditions	Yield
With lithium hydroxide monohydrate; silver trifluoromethanesulfonate; Selectfluor In ethyl acetate at 55℃; Sealed tube;	A 71% B n/a

: 95-49-8
2-methylchlorobenzene

A: 95-52-3
2-Fluorotoluene

B: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With Al2CuF8 Gas phase; Inert atmosphere;	A 60% B 7%

: 68971-87-9
(2-tolyl)tributyltin

: 95-52-3
2-Fluorotoluene

Conditions

Conditions	Yield
With copper(II) bis(trifluoromethanesulfonate); tetrabutylammonium triphenyldifluorosilicate In acetonitrile at 60℃; for 3h; Sealed tube; regiospecific reaction;	50%
With copper(I) trifluoromethanesulfonate bis(trimethylacetonitrile) complex; 1-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate In ethyl acetate at 25℃; for 12h; Inert atmosphere; Glovebox;	76 %Spectr.

: 546-67-8
lead(IV) tetraacetate

: 109-63-7
trifluoroborane diethyl ether

: 108-88-3
toluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
mercury(II) diacetate Stirring of toluene in BF3*Et2O contg. Pb(OAc)4 and overnight at room temp.; GC anal. 13% recovery of toluene.;	A 43% B 12% C 4%

...Expand

: 66107-34-4
2-methylphenyl triflate

: 95-52-3
2-Fluorotoluene

Conditions

Conditions	Yield
With bis[(trimethylsilyl)methyl](1,5-cyclooctadiene)palladium(II); t-BuBrettPhos; cesium fluoride In toluene at 130℃; for 12h;	42%
With bis[(trimethylsilyl)methyl](1,5-cyclooctadiene)palladium(II); t-BuBrettPhos; cesium fluoride In toluene at 130℃; for 12h;	42 %Chromat.

: 446-52-6
2-Fluorobenzaldehyde

A: 271-44-3
benzimidazole

B: 95-52-3
2-Fluorotoluene

Conditions

Conditions	Yield
With hydrazine hydrate In 1,2-dimethoxyethane for 15h; Heating;	A 29% B 45 % Chromat.

: 108-41-8
1-chloro-3-methylbenzene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With silver fluoride at 350℃; Product distribution / selectivity; Gas phase;	A 15% B 6.7% C 25.7%

...Expand

: 95-49-8
2-methylchlorobenzene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With silver fluoride at 350℃; Product distribution / selectivity; Gas phase;	A 0.5% B 13.9% C 14.4%

...Expand

: 462-06-6
fluorobenzene

: 593-53-3
Methyl fluoride

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
at 37.5℃; Product distribution; Irradiation; various fluorobenzenes, other conditions;

...Expand

: 75-45-6
Chlorodifluoromethane

A: 462-06-6
fluorobenzene

B: 352-32-9
p-fluorotoluene

C: 95-52-3
2-Fluorotoluene

D: 352-70-5
m-Fluorotoluene

E: 71-43-2
benzene

Conditions

Conditions	Yield
With methylcyclopentadiene at 650.9℃; Product distribution; Mechanism; conditions of pulse gas compression, other temperatures;

...Expand

: 107-31-3
Methyl formate

: 138850-94-9
C7H7F*H(1+)

A: 95-52-3
2-Fluorotoluene

B: 39014-35-2, 380649-05-8, 52067-01-3
C2H4O2*H(1+)

Conditions

Conditions	Yield
Thermodynamic data;

...Expand

: 770-09-2
benzyltrimethylsilane

: 95-52-3
2-Fluorotoluene

Conditions

Conditions	Yield
With fluorine In trichlorofluoromethane at -78℃;

: 138850-94-9
C7H7F*H(1+)

: 108-88-3
toluene

A: 95-52-3
2-Fluorotoluene

B: 52809-63-9
C7H8*H(1+)

Conditions

Conditions	Yield
Thermodynamic data;

...Expand

: 1-Fluoro-2-methyl-benzene; compound with GENERIC INORGANIC NEUTRAL COMPONENT

: 108-88-3
toluene

A: 95-52-3
2-Fluorotoluene

B: 77406-15-6
Toluene; compound with GENERIC INORGANIC NEUTRAL COMPONENT

Conditions

Conditions	Yield
Thermodynamic data;

...Expand

: 108-88-3
toluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

Conditions

Conditions	Yield
With Selectfluor In acetonitrile for 16h; Heating; also fluorination of other aromatic compounds;	A 20 % Spectr. B 60 % Spectr.
With potassium hydroxide; nitrogen; fluorine In methanol at -40℃; Product distribution; different educt and reagent concentration, different temperatures, different fluorine/nitrogen ratio, different solvents, without or with different additives;	A 57.0 % Chromat. B 32.7 % Chromat.
With acetyl hypofluorite for 2h;
With trifluorormethanesulfonic acid; Selectfluor In dichloromethane at 40℃; for 24h; Fluorination; Title compound not separated from byproducts;

: 108-88-3
toluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With fluorine In trichlorofluoromethane at -78℃; for 1h; Rate constant; Product distribution; competitive reaction with benzene, other solvent;	A 29 % Chromat. B 60 % Chromat. C 11 % Chromat.
With lead(IV) acetate; boron trifluoride diethyl etherate; mercury(II) diacetate Ambient temperature;	A 43 % Chromat. B 12 % Chromat. C 4 % Chromat.
With caesium fluoroxysulphate; trifluorormethanesulfonic acid In acetonitrile Ambient temperature; Yield given;

...Expand

: 108-88-3
toluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

D: 350-50-5
benzyl fluoride

Conditions

Conditions	Yield
With acetyl hypofluorite In acetic acid for 0.0833333h; Ambient temperature; Yield given. Yields of byproduct given;
With fluorine In acetonitrile at 0℃; Flow reactor;

...Expand

: 108-88-3
toluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

D: 452-76-6
2,4-difluorotoluene

Conditions

Conditions	Yield
With tetrafluoroammonium tetrafluoroborate In hydrogen fluoride at 0℃; Further byproducts given. Title compound not separated from byproducts;	A 15 % Spectr. B 15 % Spectr. C 8 % Spectr. D 30 % Spectr.

...Expand

: 108-88-3
toluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

D: 452-76-6
2,4-difluorotoluene

E: 2,3,4,6-tetrafluorotoluene

Conditions

Conditions	Yield
With tetrafluoroammonium tetrafluoroborate In hydrogen fluoride at 0℃; Product distribution;	A 15 % Spectr. B 15 % Spectr. C 8 % Spectr. D 30 % Spectr. E 7 % Spectr.

...Expand

: 108-88-3
toluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

D: 2,3,4,6-tetrafluorotoluene

Conditions

Conditions	Yield
With tetrafluoroammonium tetrafluoroborate In hydrogen fluoride at 0℃; Further byproducts given. Title compound not separated from byproducts;	A 15 % Spectr. B 15 % Spectr. C 8 % Spectr. D 7 % Spectr.

...Expand

: 108-88-3
toluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 350-50-5
benzyl fluoride

Conditions

Conditions	Yield
With caesium fluoroxysulphate In acetonitrile at 25℃; Product distribution; Rate constant; reagents ratio, presence of 1,3,5-trinitrobenzene;	A 2 % Chromat. B 4 % Chromat. C 67 % Chromat.
With caesium fluoroxysulphate In acetonitrile Ambient temperature; Yield given. Yields of byproduct given;

...Expand

: 95-52-3
2-Fluorotoluene

: 124-38-9
carbon dioxide

: 315-31-1
2-fluoro-3-methylbenzoic acid

Conditions

Conditions	Yield
Stage #1: 2-Fluorotoluene With sec.-butyllithium In tetrahydrofuran at -78℃; for 0.5h; Stage #2: carbon dioxide In tetrahydrofuran under 760.051 Torr;	100%
Stage #1: 2-Fluorotoluene With n-butyllithium Metallation; Stage #2: carbon dioxide Carboxylation;

: 51-17-2
benzoimidazole

: 95-52-3
2-Fluorotoluene

: 34734-23-1
N-(2-methyl-1-phenyl)-1H-benzimidazole

Conditions

Conditions	Yield
With caesium carbonate In N,N-dimethyl acetamide at 210℃; for 12h; Microwave irradiation;	100%

: 95-52-3
2-Fluorotoluene

: 320-11-6
1-(tert-butyl)-2-fluorobenzene

Conditions

Conditions	Yield
With triethanolamine; 2,2'-azobis(isobutyronitrile); chlorine at 90 - 115℃; for 5h;	99%

: 95-52-3
2-Fluorotoluene

: 65-85-0
benzoic acid

: 478970-84-2
2-fluorobenzyl benzoate

Conditions

Conditions	Yield
With di-tert-butyl peroxide; C11H23N2(1+)*Br4Fe(1-) at 110℃; for 24h;	98%

: 95-52-3
2-Fluorotoluene

: phenylmagnesium bromide

: 643-58-3
2-methylbiphenyl

Conditions

Conditions	Yield
With 1-[2-(diphenylphosphino)phenyl]ethanol; bis(acetylacetonate)nickel(II) In diethyl ether at 20℃; for 5h;	96%
With 1,3-bis(2,6-diisopropylphenyl)-4,5-dihydro-1H-imidazolium tetrafluoroborate; Ni(acac) In tetrahydrofuran at 20℃; for 18h; Kumada-Corriu cross-coupling;	53 % Chromat.

: 95-52-3
2-Fluorotoluene

: 100-58-3
phenylmagnesium bromide

: 643-58-3
2-methylbiphenyl

Conditions

Conditions	Yield
Stage #1: 2-Fluorotoluene; phenylmagnesium bromide; 1-[2-(diphenylphosphino)phenyl]ethanol; bis(acetylacetonate)nickel(II) In diethyl ether for 5h; Stage #2: With methanol In diethyl ether Product distribution / selectivity;	96%
Stage #1: 2-Fluorotoluene; phenylmagnesium bromide; bis(acetylacetonate)nickel(II); ((2-hydroxymethyl)phenyl)diphenylphosphine In diethyl ether for 48h; Stage #2: With methanol In diethyl ether Product distribution / selectivity;	95%
With C28H32ClN2NiP In tetrahydrofuran at 20℃; for 24h; Time; Schlenk technique; Inert atmosphere;	16 %Chromat.

: 95-52-3
2-Fluorotoluene

: 7353-91-5
4-dimethylaminophenylmagnesium bromide

: 2′-methyl-N,N-dimethylbiphenyl-4-amine

Conditions

Conditions	Yield
With C26H24ClN2NiP*0.1C7H8 In toluene at 25℃; for 24h; Kumada Cross-Coupling; Schlenk technique; Inert atmosphere;	95%

: 95-52-3
2-Fluorotoluene

: 104-82-5
4-Methylbenzyl chloride

: 21895-17-0
p-(2-methylbenzyl)toluene

Conditions

Conditions	Yield
With C23H40Br2N2NiO5P; magnesium In tetrahydrofuran at 60℃; for 12h; Inert atmosphere;	95%

: 95-52-3
2-Fluorotoluene

: 446-52-6
2-Fluorobenzaldehyde

Conditions

Conditions	Yield
With Xylaria polymorpha laccase; 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonate) diammonium salt In 1,4-dioxane at 20℃; for 1.91667h; pH=4.5; Green chemistry; Enzymatic reaction;	94%
With laccase of Pleurotus ostreatus MTCC-1801; 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt In 1,4-dioxane at 20℃; pH=4.5; Enzymatic reaction;	90%
With tert.-butylhydroperoxide; C29H25Cl2N4Ru(1+)*F6P(1-) In acetonitrile at 60℃; for 2h; Schlenk technique; Inert atmosphere;	74%

: ammonium hexafluorophosphate

: 102-54-5
ferrocene

: 95-52-3
2-Fluorotoluene

: 165681-07-2
η-pentadienyl-η-1,2-fluoromethylbenzeneiron(II) hexafluorophosphate

Conditions

Conditions	Yield
With aluminium trichloride; aluminium In water other Radiation; 0.02 mol metal addn. to arene, Fe- and Al-salts mixt. in 1,2,4-C6H3Cl3 (ratio arene:Fe:AlCl3:Al=2:1:2:1.1), homogenization (stirring), mixt. irradiation in microwave oven (850 W) for 3 min, ice addn. (AlCl3 decompn.), filtration, filtrate washing (Et2O); filtration, treating with aq. NH4-salt, ppt. filtration off through sinter, washing (i-PrOH, Et2O); elem. anal.;	94%

Yield

With aluminium trichloride; aluminium In water other Radiation; 0.02 mol metal addn. to arene, Fe- and Al-salts mixt. in 1,2,4-C6H3Cl3 (ratio arene:Fe:AlCl3:Al=2:1:2:1.1), homogenization (stirring), mixt. irradiation in microwave oven (850 W) for 3 min, ice addn. (AlCl3 decompn.), filtration, filtrate washing (Et2O); filtration, treating with aq. NH4-salt, ppt. filtration off through sinter, washing (i-PrOH, Et2O); elem. anal.;

94%

...Expand

: 95-52-3
2-Fluorotoluene

: 824-94-2
p-methoxybenzyl chloride

: 53039-52-4
1-methyl-2-(4-methoxybenzyl) benzene

Conditions

Conditions	Yield
With Ni(PPh3)(1,3-di-tert-butylimidazol-2-ylidene)Br2; magnesium In tetrahydrofuran at 0 - 35℃; for 24h; Schlenk technique; Inert atmosphere;	93%

: 42142-52-9
3-methylamino-1-phenylpropan-1-ol

: 95-52-3
2-Fluorotoluene

: 17199-29-0
(S)-Mandelic acid

: R-(-)-atomoxetine-S-(+)-mandelate

Conditions

Conditions	Yield
Stage #1: 3-methylamino-1-phenylpropan-1-ol With potassium hydroxide In Triethylene glycol dimethyl ether; toluene at 20 - 120℃; for 1h; Large scale; Stage #2: 2-Fluorotoluene In Triethylene glycol dimethyl ether; toluene for 3h; Large scale; Stage #3: (S)-Mandelic acid at 20 - 75℃; for 1h; Temperature; Large scale;	93%

...Expand

: 100-02-7
4-nitro-phenol

: 95-52-3
2-Fluorotoluene

: C13H10FNO2

Conditions

Conditions	Yield
With di-tert-butyl peroxide; 1,3-di-tert-butylimidazolium at 130℃; for 24h; Green chemistry;	93%

: 100-02-7
4-nitro-phenol

: 95-52-3
2-Fluorotoluene

: 891-75-8
1-fluoro-2-((4-nitrophenoxy)methyl)benzene

Conditions

Conditions	Yield
With di-tert-butyl peroxide; 1,3-di-tert-butylimidazolium at 130℃; for 24h;	93%

: 95-52-3
2-Fluorotoluene

: 63940-51-2
(+/-)-atomoxetine

Conditions

Conditions	Yield
Stage #1: 3-methylamino-1-phenylpropan-1-ol With potassium hydroxide In dimethyl sulfoxide at 110℃; Stage #2: 2-Fluorotoluene In dimethyl sulfoxide at 145 - 147℃; for 1h; Heating / reflux;	92.7%

: 95-52-3
2-Fluorotoluene

: 13139-86-1
4-methoxyphenyl magnesium bromide

: 92495-54-0
4'-methoxy-2-methylbiphenyl

Conditions

Conditions	Yield
Stage #1: 2-Fluorotoluene With Ni(PPh3)(1,3-di-tert-butylimidazol-2-ylidene)Br2 In tetrahydrofuran at 0℃; for 0.0333333h; Inert atmosphere; Schlenk technique; Stage #2: 4-methoxyphenyl magnesium bromide In tetrahydrofuran at 0 - 25℃; for 10h; Inert atmosphere; Schlenk technique;	92%
With palladium diacetate; DavePhos In 1,2-dimethoxyethane at 80℃; for 12h;	73%

: 95-52-3
2-Fluorotoluene

: 124-38-9
carbon dioxide

: 118-90-1
ortho-methylbenzoic acid

Conditions

Conditions	Yield
Stage #1: 2-Fluorotoluene With C78H70Al2Cl4N6P4Rh2; magnesium; ethylene dibromide In tetrahydrofuran at 20℃; for 22h; Inert atmosphere; Glovebox; Stage #2: carbon dioxide In tetrahydrofuran at 20℃; under 760.051 Torr; for 0.5h;	92%

: 95-52-3
2-Fluorotoluene

: 75-36-5
acetyl chloride

: 369-32-4
1-(4-fluoro-3-methylphenyl)ethanone

Conditions

Conditions	Yield
With aluminum (III) chloride In chloroform at -5 - 20℃; for 2h; Solvent; Reagent/catalyst; Temperature;	91%
With aluminium trichloride In dichloromethane at 20℃; for 24h; Friedel-Krafts reaction;	82%
With aluminium trichloride
Stage #1: 2-Fluorotoluene; acetyl chloride With aluminum (III) chloride In dichloromethane at 20℃; for 26h; Reflux; Stage #2: With water; sodium carbonate In dichloromethane
With aluminum (III) chloride In dichloromethane at 20℃; for 26h; Reflux;

: 95-52-3
2-Fluorotoluene

: 100-47-0
benzonitrile

: 948-65-2
2-phenyl-indole

Conditions

Conditions	Yield
With cesium fluoride; lithium hexamethyldisilazane at 110℃; for 12h; Reagent/catalyst; Temperature; Green chemistry;	90%
With cesium fluoride; lithium hexamethyldisilazane at 110℃; for 12h; Reagent/catalyst; Concentration; Sealed tube; Inert atmosphere;	90%

: 95-52-3
2-Fluorotoluene

: 115290-81-8
(R)-N-methyl-3-phenyl-3-hydroxypropylamine

: 105314-52-1, 105314-53-2, 63940-51-2, 83015-26-3
(R)-tomoxetine

Conditions

Conditions	Yield
Stage #1: (R)-N-methyl-3-phenyl-3-hydroxypropylamine With potassium hydroxide In dimethyl sulfoxide at 130℃; for 1h; Stage #2: 2-Fluorotoluene In dimethyl sulfoxide at 130℃;	89.51%
Stage #1: (R)-N-methyl-3-phenyl-3-hydroxypropylamine With sodium hydride In dimethyl sulfoxide for 0.25h; Stage #2: With Potassium benzoate In dimethyl sulfoxide at 50 - 55℃; for 1h; Stage #3: 2-Fluorotoluene In dimethyl sulfoxide at 50 - 120℃; for 6.25 - 7.25h;
With potassium tert-butylate In dimethyl sulfoxide at 60℃; for 8h;

: 95-52-3
2-Fluorotoluene

: 4210-32-6
4-tert-butyl benzonitrile

: 521295-49-8
2-(4-(tert-butyl)phenyl)-1H-indole

Conditions

Conditions	Yield
With cesium fluoride; lithium hexamethyldisilazane at 110℃; for 12h; Sealed tube; Inert atmosphere;	89%

: 95-52-3
2-Fluorotoluene

: 455-88-9
5-nitro-2-fluorotoluene

Conditions

Conditions	Yield
With 2C2H3F3O*BF3; potassium nitrate at 20℃; for 5h;	88%
With nitric acid
With nitric acid; Nitrogen dioxide
With nitric acid

: 95-52-3
2-Fluorotoluene

: C15H25AlO

: 92495-54-0
4'-methoxy-2-methylbiphenyl

Conditions

Conditions	Yield
With bis(tricyclohexylphosphine)nickel(II) dichloride In tetrahydrofuran at 50℃; for 24h; Inert atmosphere;	88%

: cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate

: 95-52-3
2-Fluorotoluene

: C12H12FRu(1+)*F6P(1-)

Conditions

Conditions	Yield
In 1,2-dichloro-ethane at 90℃; for 18h; Inert atmosphere;	88%

: 95-52-3
2-Fluorotoluene

: (E)-N-(2-(4-methoxyphenyl)propan-2-yl)-1-phenylmethanimine

: N-(2-(2-fluorophenyl)-1-phenylethyl)-2-(4-methoxyphenyl)propan-2-amine

Conditions

Conditions	Yield
With potassium tert-butylate; 2,2,6,6-tetramethylpiperidinyl-lithium at -40℃; for 18h; Glovebox; Inert atmosphere;	88%

: 613-46-7
2-naphthalenecarbonitrile

: 95-52-3
2-Fluorotoluene

: 23746-81-8
2-(2-naphthyl)indole

Conditions

Conditions	Yield
With cesium fluoride; lithium hexamethyldisilazane In 1,4-dioxane at 110℃; for 12h; Green chemistry;	88%
With cesium fluoride; lithium hexamethyldisilazane In 1,2-dimethoxyethane at 110℃; for 12h; Solvent; Sealed tube; Inert atmosphere;	88%

: 95-52-3
2-Fluorotoluene

: 73183-34-3
bis(pinacol)diborane

: 195062-59-0
2-methylphenylboronic acid pinacol ester

Conditions

Conditions	Yield
With bis(1,5-cyclooctadiene)nickel (0); copper(l) iodide; cesium fluoride; tricyclohexylphosphine In toluene at 80℃; for 24h; Inert atmosphere;	87.6%
With chlorobis(tricyclohexylphosphine)copper(I); cesium fluoride In toluene at 80℃; for 24h;	79%
With tetramethylammonium fluoride; 2-mercaptopyridine sodium salt In acetonitrile at 30 - 35℃; for 24h; Irradiation; Inert atmosphere;	57%

: 95-52-3
2-Fluorotoluene

: C19H13CrO3

: 32913-59-0
(η6-1-fluoro-2-methylbenzene)tricarbonylchromium(0)

Conditions

Conditions	Yield
In 1,4-dioxane at 90℃; for 16h;	86%

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