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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

3-Fluorotoluene Manufacturer/High quality/Best price/In stock

Cas:352-70-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 3-Fluorotoluene? supplier in China

Cas:352-70-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hefei TNJ chemical industry co.,ltd

Technology: Technology innovation is our eternal pursuit,or we will be left behind.Our technology experts,all from famous universities and institutes,has rich experience and high achievements in chemical research.This makes sure that our technology

m-Fluorotoluene 352-70-5

Cas:352-70-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

3-Fluorotoluene

Cas:352-70-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Fluorotoluene

Cas:352-70-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

3-fluorotoluene

Cas:352-70-5

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

352-70-5 3-Fluorotoluene

Cas:352-70-5

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

Product Name 3-Fluorotoluene Synonyms 3-Fluorotoluene;1-fluoro-3-methyl-benzen CAS 352-70-5 CAS: 352-70-5 MF: - MW: - EINECS:

3-Fluorotoluene CAS: 352-70-5

Cas:352-70-5

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:352-70-5

Cas:352-70-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

3-Fluorotoluene CAS NO.352-70-5

Cas:352-70-5

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-Fluorotoluene

Cas:352-70-5

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Fluorotoluene

Cas:352-70-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality m-Fluorotoluene

Cas:352-70-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:clear colorless to light yellow liquid Storage:In Room Temperature Package:200kg/drum, or as per your request. Application:For medicine , pesticide intermediates Transportation:a

3-Fluorotoluene

Cas:352-70-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

3-Fluorotoluene

Cas:352-70-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/3-Fluorotoluene

Cas:352-70-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti

3-Fluorotoluene

Cas:352-70-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

m-Fluorotoluene

Cas:352-70-5

Min.Order:0

Negotiable

Type:Other

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

3-Fluorotoluene

Cas:352-70-5

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

3-Fluorotoluene

Cas:352-70-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat

3-Fluorotoluene

Cas:352-70-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 352-70-5 with competitive price

Cas:352-70-5

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

3-Fluorotoluene

Cas:352-70-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

3-Fluorotoluene 352-70-5

Cas:352-70-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Bide Pharmatech Ltd

Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical

1-Fluoro-3-methylbenzene

Cas:352-70-5

Min.Order:0

Negotiable

Type:Other

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#352-70-5;CAT#A822704

Cas:352-70-5

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Zouping Mingxing Chemical Co.,Ltd.

m-Fluorotoluene CASNo.:352-70-5 Molecularformula:C7H7F Structuralformula: …

3-Fluorotoluene

Cas:352-70-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

3-Fluorotoluene

Cas:352-70-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

3-Fluorotoluene

Cas:352-70-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Run-Biotech Co., Ltd.

Shanghai, Run-Biotech Co., Ltd is a leading domestic pharmaceutical, biopharmaceutical, and health care products R & D outsourcing services company. As an innovation-driven and customer-focused company, Run Biotech provides a broad and integrat

3-Fluorotoluene

Cas:352-70-5

Min.Order:100 Gram

Negotiable

Type:Trading Company

inquiry

Synthetic route

1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
With pyridine hydrogenfluoride; sodium nitrite 1.) O deg C, 20 min, 2.) 70 deg C, 1 h;98%
Stage #1: 1-amino-3-methylbenzene With hydrogen fluoride at -5 - 0.5℃; Flow reactor; Large scale;
Stage #2: With nitrosylsulfuric acid at 0.5 - 2℃; Flow reactor; Large scale;
98.3%
Stage #1: 1-amino-3-methylbenzene With hydrogen fluoride at 0℃; for 3h;
Stage #2: With sodium nitrite at -5 - 35℃; for 4h;
90.1%
3-fluoro-1-methyl-2,5-cyclohexadiene-1-carboxylic acid
1202873-16-2

3-fluoro-1-methyl-2,5-cyclohexadiene-1-carboxylic acid

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
With chlorosulfonic acid In dichloromethane at 0℃; for 0.166667h;82%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

3-methylbenzenediazonium tetrafluoroborate
1422-76-0

3-methylbenzenediazonium tetrafluoroborate

A

m-Fluorotoluene
352-70-5

m-Fluorotoluene

B

3-tolyl triflate
32578-31-7

3-tolyl triflate

Conditions
ConditionsYield
at 90℃; for 1h;A n/a
B 75%
para-chlorotoluene
106-43-4

para-chlorotoluene

A

p-fluorotoluene
352-32-9

p-fluorotoluene

B

2-Fluorotoluene
95-52-3

2-Fluorotoluene

C

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
With Al2CuF8 Gas phase; Inert atmosphere;A 71%
B 5%
C 10%
With silver fluoride at 350℃; Product distribution / selectivity; Gas phase;A 20.8%
B 0.6%
C 35.8%
1-(Bromomethyl)-3-fluorobenzene
456-41-7

1-(Bromomethyl)-3-fluorobenzene

A

m-Fluorotoluene
352-70-5

m-Fluorotoluene

B

1,2-bis(3-fluorophenyl)ethane
351-22-4

1,2-bis(3-fluorophenyl)ethane

Conditions
ConditionsYield
With magnesium at 600℃;A 12%
B 67%
potassium trifluoro(3-methylphenyl)borate

potassium trifluoro(3-methylphenyl)borate

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
With lithium hydroxide monohydrate; silver trifluoromethanesulfonate; Selectfluor In ethyl acetate at 55℃; Sealed tube;66%
With copper(I) trifluoromethanesulfonate bis(trimethylacetonitrile) complex; 1-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate In ethyl acetate at 40℃; for 12h; Inert atmosphere; Glovebox;67 %Spectr.
C7H7N2(1+)*F6P(1-)

C7H7N2(1+)*F6P(1-)

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
With boron trifluoride diethyl etherate at 120 - 125℃; for 1h;65%
1-chloro-3-methylbenzene
108-41-8

1-chloro-3-methylbenzene

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
With Al2CuF8 Gas phase; Inert atmosphere;61%
2-methylchlorobenzene
95-49-8

2-methylchlorobenzene

A

2-Fluorotoluene
95-52-3

2-Fluorotoluene

B

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
With Al2CuF8 Gas phase; Inert atmosphere;A 60%
B 7%
m-Toluic acid
99-04-7

m-Toluic acid

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
Stage #1: m-Toluic acid With tetrakis(acetonitrile)copper(I)tetrafluoroborate; tetrabutylammonium tetra(tert-butyl alcohol) coordinate fluoride; copper(II) bis(trifluoromethanesulfonate) In acetonitrile at 23℃; for 0.5h; Sealed tube; Inert atmosphere;
Stage #2: In acetonitrile at 35℃; Irradiation; Sealed tube; Inert atmosphere;
57%
lead(IV) tetraacetate
546-67-8

lead(IV) tetraacetate

trifluoroborane diethyl ether
109-63-7

trifluoroborane diethyl ether

toluene
108-88-3

toluene

A

p-fluorotoluene
352-32-9

p-fluorotoluene

B

2-Fluorotoluene
95-52-3

2-Fluorotoluene

C

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
mercury(II) diacetate Stirring of toluene in BF3*Et2O contg. Pb(OAc)4 and overnight at room temp.; GC anal. 13% recovery of toluene.;A 43%
B 12%
C 4%
1-chloro-3-methylbenzene
108-41-8

1-chloro-3-methylbenzene

A

p-fluorotoluene
352-32-9

p-fluorotoluene

B

2-Fluorotoluene
95-52-3

2-Fluorotoluene

C

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
With silver fluoride at 350℃; Product distribution / selectivity; Gas phase;A 15%
B 6.7%
C 25.7%
1,1,1,3',3',3'-hexafluoro-propanol
920-66-1

1,1,1,3',3',3'-hexafluoro-propanol

3-methylbenzenediazonium tetrafluoroborate
1422-76-0

3-methylbenzenediazonium tetrafluoroborate

A

m-Fluorotoluene
352-70-5

m-Fluorotoluene

B

1,1,1,3,3,3-hexafluoro-2-propyl 3-methylphenyl ether

1,1,1,3,3,3-hexafluoro-2-propyl 3-methylphenyl ether

Conditions
ConditionsYield
at 20℃; Irradiation;A 15%
B 85 % Chromat.
2-methylchlorobenzene
95-49-8

2-methylchlorobenzene

A

p-fluorotoluene
352-32-9

p-fluorotoluene

B

2-Fluorotoluene
95-52-3

2-Fluorotoluene

C

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
With silver fluoride at 350℃; Product distribution / selectivity; Gas phase;A 0.5%
B 13.9%
C 14.4%
fluorobenzene
462-06-6

fluorobenzene

Methyl fluoride
593-53-3

Methyl fluoride

A

p-fluorotoluene
352-32-9

p-fluorotoluene

B

2-Fluorotoluene
95-52-3

2-Fluorotoluene

C

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
at 37.5℃; Product distribution; Irradiation; various fluorobenzenes, other conditions;
Chlorodifluoromethane
75-45-6

Chlorodifluoromethane

A

fluorobenzene
462-06-6

fluorobenzene

B

p-fluorotoluene
352-32-9

p-fluorotoluene

C

2-Fluorotoluene
95-52-3

2-Fluorotoluene

D

m-Fluorotoluene
352-70-5

m-Fluorotoluene

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
With methylcyclopentadiene at 650.9℃; Product distribution; Mechanism; conditions of pulse gas compression, other temperatures;
4-tolyl iodide
624-31-7

4-tolyl iodide

A

m-Fluorotoluene
352-70-5

m-Fluorotoluene

B

1-chloro-3-methylbenzene
108-41-8

1-chloro-3-methylbenzene

C

meta-bromotoluene
591-17-3

meta-bromotoluene

D

para-chlorotoluene
106-43-4

para-chlorotoluene

E

para-bromotoluene
106-38-7

para-bromotoluene

F

3-methyl-phenol
108-39-4

3-methyl-phenol

Conditions
ConditionsYield
With potassium hydroxide; potassium chloride; sodium fluoride; potassium bromide In water at 308℃; Mechanism; Product distribution;A 1.37 % Chromat.
B 1.67 % Chromat.
C 2.66 % Chromat.
D 1.44 % Chromat.
E 2.22 % Chromat.
F 2.88 % Chromat.
4-tolyl iodide
624-31-7

4-tolyl iodide

A

p-cresol
106-44-5

p-cresol

B

p-fluorotoluene
352-32-9

p-fluorotoluene

C

m-Fluorotoluene
352-70-5

m-Fluorotoluene

D

1-chloro-3-methylbenzene
108-41-8

1-chloro-3-methylbenzene

E

3-methyl-phenol
108-39-4

3-methyl-phenol

F

phenol
108-95-2

phenol

Conditions
ConditionsYield
With potassium hydroxide; potassium chloride; sodium fluoride In water at 312℃; Mechanism; Product distribution;A 13.0 % Chromat.
B 5.01 % Chromat.
C 5.97 % Chromat.
D 3.0 % Chromat.
E 18.6 % Chromat.
F 2.6 % Chromat.
1-fluoro-3-(iodomethyl)benzene
28490-56-4

1-fluoro-3-(iodomethyl)benzene

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
With Perbenzoic acid; tri-n-butyl-tin hydride In benzene at 90℃; for 12h; Mechanism; in the presence of α-iodotoluene (competitor), relative reactivity;
C7H8F(1+)

C7H8F(1+)

toluene
108-88-3

toluene

A

m-Fluorotoluene
352-70-5

m-Fluorotoluene

B

C7H8*H(1+)
52809-63-9

C7H8*H(1+)

Conditions
ConditionsYield
Thermodynamic data;
1-Fluoro-3-methyl-benzene; compound with GENERIC INORGANIC NEUTRAL COMPONENT

1-Fluoro-3-methyl-benzene; compound with GENERIC INORGANIC NEUTRAL COMPONENT

toluene
108-88-3

toluene

A

m-Fluorotoluene
352-70-5

m-Fluorotoluene

B

Toluene; compound with GENERIC INORGANIC NEUTRAL COMPONENT
77406-15-6

Toluene; compound with GENERIC INORGANIC NEUTRAL COMPONENT

Conditions
ConditionsYield
Thermodynamic data;
toluene
108-88-3

toluene

A

p-fluorotoluene
352-32-9

p-fluorotoluene

B

2-Fluorotoluene
95-52-3

2-Fluorotoluene

C

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
With fluorine In trichlorofluoromethane at -78℃; for 1h; Rate constant; Product distribution; competitive reaction with benzene, other solvent;A 29 % Chromat.
B 60 % Chromat.
C 11 % Chromat.
With lead(IV) acetate; boron trifluoride diethyl etherate; mercury(II) diacetate Ambient temperature;A 43 % Chromat.
B 12 % Chromat.
C 4 % Chromat.
With caesium fluoroxysulphate; trifluorormethanesulfonic acid In acetonitrile Ambient temperature; Yield given;
toluene
108-88-3

toluene

A

p-fluorotoluene
352-32-9

p-fluorotoluene

B

2-Fluorotoluene
95-52-3

2-Fluorotoluene

C

m-Fluorotoluene
352-70-5

m-Fluorotoluene

D

benzyl fluoride
350-50-5

benzyl fluoride

Conditions
ConditionsYield
With acetyl hypofluorite In acetic acid for 0.0833333h; Ambient temperature; Yield given. Yields of byproduct given;
With fluorine In acetonitrile at 0℃; Flow reactor;
toluene
108-88-3

toluene

A

p-fluorotoluene
352-32-9

p-fluorotoluene

B

2-Fluorotoluene
95-52-3

2-Fluorotoluene

C

m-Fluorotoluene
352-70-5

m-Fluorotoluene

D

2,4-difluorotoluene
452-76-6

2,4-difluorotoluene

Conditions
ConditionsYield
With tetrafluoroammonium tetrafluoroborate In hydrogen fluoride at 0℃; Further byproducts given. Title compound not separated from byproducts;A 15 % Spectr.
B 15 % Spectr.
C 8 % Spectr.
D 30 % Spectr.
toluene
108-88-3

toluene

A

p-fluorotoluene
352-32-9

p-fluorotoluene

B

2-Fluorotoluene
95-52-3

2-Fluorotoluene

C

m-Fluorotoluene
352-70-5

m-Fluorotoluene

D

2,4-difluorotoluene
452-76-6

2,4-difluorotoluene

E

2,3,4,6-tetrafluorotoluene

2,3,4,6-tetrafluorotoluene

Conditions
ConditionsYield
With tetrafluoroammonium tetrafluoroborate In hydrogen fluoride at 0℃; Product distribution;A 15 % Spectr.
B 15 % Spectr.
C 8 % Spectr.
D 30 % Spectr.
E 7 % Spectr.
toluene
108-88-3

toluene

A

p-fluorotoluene
352-32-9

p-fluorotoluene

B

2-Fluorotoluene
95-52-3

2-Fluorotoluene

C

m-Fluorotoluene
352-70-5

m-Fluorotoluene

D

2,3,4,6-tetrafluorotoluene

2,3,4,6-tetrafluorotoluene

Conditions
ConditionsYield
With tetrafluoroammonium tetrafluoroborate In hydrogen fluoride at 0℃; Further byproducts given. Title compound not separated from byproducts;A 15 % Spectr.
B 15 % Spectr.
C 8 % Spectr.
D 7 % Spectr.
1-(Bromomethyl)-3-fluorobenzene
456-41-7

1-(Bromomethyl)-3-fluorobenzene

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
With Perbenzoic acid; tri-n-butyl-tin hydride In benzene at 90℃; for 12h; Mechanism; in the presence of α-bromotoluene, α-iodotoluene, or α,3-dichlorotoluene (20 h) (competitors), relative reactivities;
m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

m-Fluorotoluene
352-70-5

m-Fluorotoluene

Conditions
ConditionsYield
With Perbenzoic acid; tri-n-butyl-tin hydride In benzene at 90℃; for 12h; Mechanism; in the presence of α-chlorotoluene (competitor), relative reactivity;
1-Fluoro-3-methyl-benzene; compound with GENERIC INORGANIC NEUTRAL COMPONENT

1-Fluoro-3-methyl-benzene; compound with GENERIC INORGANIC NEUTRAL COMPONENT

benzene
71-43-2

benzene

A

m-Fluorotoluene
352-70-5

m-Fluorotoluene

B

Benzene; compound with GENERIC INORGANIC NEUTRAL COMPONENT

Benzene; compound with GENERIC INORGANIC NEUTRAL COMPONENT

Conditions
ConditionsYield
Thermodynamic data;
m-Fluorotoluene
352-70-5

m-Fluorotoluene

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With oxygen; pyridinium chlorochromate In water at 120℃; under 45004.5 Torr; for 2h;95%
With copper(l) iodide; oxygen; nitric acid at 160℃; under 11251.1 - 18751.9 Torr; for 4.7h; Autoclave;84.7%
With cerium(III) chloride; 1,1,1-trichloroethanol; oxygen In acetonitrile at 60℃; Irradiation;83%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

chromium(0) hexacarbonyl
199620-14-9, 13007-92-6

chromium(0) hexacarbonyl

(η6-1-fluoro-3-methylbenzene)tricarbonylchromium(0)
33411-10-8

(η6-1-fluoro-3-methylbenzene)tricarbonylchromium(0)

Conditions
ConditionsYield
In tetrahydrofuran; dibutyl ether heating, 8d; filtration; evapn.; chromy. (silica, ether/petroleum ether); recrystn. (petroleum ether/ether); elem. anal.;95%
In tetrahydrofuran; dibutyl ether at 160℃;80%
In tetrahydrofuran; dibutyl ether Cr(CO)6 and arene were heated under reflux in a mixt. of n-Bu2O and THFfor 42 h under N2 atmosphere; soln. was cooled, filtered, evapd. under reduced pressure, residue was dissolved in ether, refiltered, light petroleum was added to the filtrate, ppt. collected, recrystd. from ether-light petroleum; elem. anal.;49%
In tetrahydrofuran; dibutyl ether reflux for 48 h; filtration through Celite, evapn. under reduced pressure, recrystn. from ether/petroleum ether;42%
benzoimidazole
51-17-2

benzoimidazole

m-Fluorotoluene
352-70-5

m-Fluorotoluene

N-(3-methyl-1-phenyl)-1H-benzimidazole
93716-66-6

N-(3-methyl-1-phenyl)-1H-benzimidazole

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl acetamide at 210℃; for 12h; Microwave irradiation;92%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

C15H15F
1453806-84-2

C15H15F

Conditions
ConditionsYield
With dichloro bis(acetonitrile) palladium(II); potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 120℃; for 3h; regioselective reaction;92%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

thiophenol
108-98-5

thiophenol

1-fluoro-3-(phenylsulfinylmethyl)benzene
1312161-82-2

1-fluoro-3-(phenylsulfinylmethyl)benzene

Conditions
ConditionsYield
With copper diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene In 1,4-dioxane at 80℃; for 10h;91%
carbon dioxide
124-38-9

carbon dioxide

m-Fluorotoluene
352-70-5

m-Fluorotoluene

m-Toluic acid
99-04-7

m-Toluic acid

Conditions
ConditionsYield
Stage #1: m-Fluorotoluene With C78H70Al2Cl4N6P4Rh2; magnesium; ethylene dibromide In tetrahydrofuran at -30℃; for 22h; Inert atmosphere; Glovebox;
Stage #2: carbon dioxide In tetrahydrofuran at 20℃; under 760.051 Torr; for 0.5h;
90%
4-nitro-phenol
100-02-7

4-nitro-phenol

m-Fluorotoluene
352-70-5

m-Fluorotoluene

C13H10FNO2

C13H10FNO2

Conditions
ConditionsYield
With di-tert-butyl peroxide; 1,3-di-tert-butylimidazolium at 130℃; for 24h; Green chemistry;90%
4-nitro-phenol
100-02-7

4-nitro-phenol

m-Fluorotoluene
352-70-5

m-Fluorotoluene

1-fluoro-3-((4-nitrophenoxy)methyl)benzene
630412-56-5

1-fluoro-3-((4-nitrophenoxy)methyl)benzene

Conditions
ConditionsYield
With di-tert-butyl peroxide; 1,3-di-tert-butylimidazolium at 130℃; for 24h;90%
morpholine
110-91-8

morpholine

m-Fluorotoluene
352-70-5

m-Fluorotoluene

4-m-tolylmorpholine
7025-91-4

4-m-tolylmorpholine

Conditions
ConditionsYield
With silver(I) hexafluorophosphate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; C17H21O3P In tetrahydrofuran at 120℃; for 20h; Inert atmosphere; Molecular sieve;89%
With dichloro(benzene)ruthenium(II) dimer; silver trifluoromethanesulfonate; P(p-C6H4F)3 In 1,4-dioxane for 24h; Inert atmosphere; Molecular sieve; Reflux;83%
With triethylsilane; [bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); trifluorormethanesulfonic acid; 1,5-bis-(diphenylphosphino)pentane; triethylamine In 1,4-dioxane for 24h; Inert atmosphere; Reflux;79%
9-(2-pyridyl)carbazole
23866-67-3

9-(2-pyridyl)carbazole

m-Fluorotoluene
352-70-5

m-Fluorotoluene

(3-fluorophenyl)(9-(pyridin-2-yl)-9H-carbazol-1-yl)methanone

(3-fluorophenyl)(9-(pyridin-2-yl)-9H-carbazol-1-yl)methanone

Conditions
ConditionsYield
With N-hydroxyphthalimide; oxygen; palladium diacetate at 80℃; under 760.051 Torr; for 24h; Schlenk technique; regioselective reaction;89%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

7-chloro-7-(4-nitrophenyl)norbornane
200001-73-6

7-chloro-7-(4-nitrophenyl)norbornane

NO2/Me-FDPN
200001-80-5

NO2/Me-FDPN

Conditions
ConditionsYield
With aluminium trichloride at 25℃; for 2h;88%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

4-fluoro-3-methylbenzotrifluoride
74483-52-6

4-fluoro-3-methylbenzotrifluoride

Conditions
ConditionsYield
87%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

C25H38O3Si2

C25H38O3Si2

C20H16O3

C20H16O3

Conditions
ConditionsYield
Stage #1: C25H38O3Si2 With lithium diisopropyl amide In tetrahydrofuran at 0 - 3℃; for 2h;
Stage #2: m-Fluorotoluene In tetrahydrofuran at 20℃; for 24h;
87%
1,3-Benzothiazole
95-16-9

1,3-Benzothiazole

m-Fluorotoluene
352-70-5

m-Fluorotoluene

benzo[d]thiazol-2-yl(3-fluorophenyl)methanone

benzo[d]thiazol-2-yl(3-fluorophenyl)methanone

Conditions
ConditionsYield
With Selectfluor; trifluoroacetic acid In acetonitrile at 80℃; for 12h;86%
With dipotassium peroxodisulfate at 110℃; for 12h; Schlenk technique;75%
With Selectfluor; trifluoroacetic acid In acetonitrile at 80℃; for 10h;61%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

3-fluoro-6-nitrotoluene
446-33-3

3-fluoro-6-nitrotoluene

Conditions
ConditionsYield
With nitric acid at -15 - 55℃; for 8.5h; Inert atmosphere;85%
With nitric acid In water at 0 - 5℃; for 0.5h;38%
With nitric acid
m-Fluorotoluene
352-70-5

m-Fluorotoluene

sodium methylate
124-41-4

sodium methylate

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

3-(5-methoxy-2,4-dinitro-phenyl)-2-oxo-propionic acid methyl ester

3-(5-methoxy-2,4-dinitro-phenyl)-2-oxo-propionic acid methyl ester

Conditions
ConditionsYield
In methanol at -10 - 20℃; Green chemistry; Industrial scale;85%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

(E)-N-(2-(4-methoxyphenyl)propan-2-yl)-1-phenylmethanimine

(E)-N-(2-(4-methoxyphenyl)propan-2-yl)-1-phenylmethanimine

N-(2-(3-fluorophenyl)-1-phenylethyl)-2-(4-methoxyphenyl)propan-2-amine

N-(2-(3-fluorophenyl)-1-phenylethyl)-2-(4-methoxyphenyl)propan-2-amine

Conditions
ConditionsYield
With potassium tert-butylate; 2,2,6,6-tetramethylpiperidinyl-lithium at -40℃; for 18h; Glovebox; Inert atmosphere;84%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

A

1-fluoro-5-methyl-2,4-dinitro-benzene
349-01-9

1-fluoro-5-methyl-2,4-dinitro-benzene

B

1-fluoro-3-methyl-2,4-dinitro-benzene
110600-90-3

1-fluoro-3-methyl-2,4-dinitro-benzene

Conditions
ConditionsYield
With sulfuric acid; nitric acid 1.) not over 35 deg C; 2.) 30 min, room temp.;A 81%
B n/a
With sulfuric acid; nitric acid at 0 - 35℃; for 0.5h;A 36%
B n/a
With sulfuric acid; nitric acid at 35℃; for 0.5h; Cooling with ice; Overall yield = 32 g;A 36%
B n/a
m-Fluorotoluene
352-70-5

m-Fluorotoluene

tris(pentafluorophenyl)borate
1109-15-5

tris(pentafluorophenyl)borate

N,N’-di(3-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide
6016-04-2

N,N’-di(3-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide

C24H12N4O4*2C18BF15*2C7H7F

C24H12N4O4*2C18BF15*2C7H7F

Conditions
ConditionsYield
In benzene at 80℃;80%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

N-(2-(methylthio)phenyl)ferrocene-1-carboxamide

N-(2-(methylthio)phenyl)ferrocene-1-carboxamide

2,5-bis(3-fluorobenzyl)-N-(quinolin-8-yl)ferrocenecarboxamide

2,5-bis(3-fluorobenzyl)-N-(quinolin-8-yl)ferrocenecarboxamide

Conditions
ConditionsYield
With di-tert-butyl peroxide; palladium diacetate; iron(II) chloride at 110℃; for 10h; Inert atmosphere; regioselective reaction;80%
1-bromo-4-tert-butylbenzene
3972-65-4

1-bromo-4-tert-butylbenzene

m-Fluorotoluene
352-70-5

m-Fluorotoluene

1-(4-(tert-butyl)benzyl)-3-fluorobenzene

1-(4-(tert-butyl)benzyl)-3-fluorobenzene

Conditions
ConditionsYield
With Xantphos-Pd-G3; potassium hexamethylsilazane at 110℃; for 12h; Inert atmosphere; Sealed tube;78%
maleic anhydride
108-31-6

maleic anhydride

m-Fluorotoluene
352-70-5

m-Fluorotoluene

3-(4-fluoro-2-methylbenzoyl)-2-propenoic acid

3-(4-fluoro-2-methylbenzoyl)-2-propenoic acid

Conditions
ConditionsYield
With aluminium trichloride In carbon disulfide for 3h; Ambient temperature;77%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

benzyl alcohol
100-51-6

benzyl alcohol

3-benzyloxytoluene
834-17-3

3-benzyloxytoluene

Conditions
ConditionsYield
With 1-methyl-pyrrolidin-2-one; sodium hydride at 100℃; for 15h;77%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

4,4,5,5-tetramethyl-2-m-tolyl-1,3,2-dioxaborolane
253342-48-2

4,4,5,5-tetramethyl-2-m-tolyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); lithium hexamethyldisilazane In toluene at 80℃; for 12h; Inert atmosphere; Schlenk technique;77%
1,3-Benzothiazole
95-16-9

1,3-Benzothiazole

m-Fluorotoluene
352-70-5

m-Fluorotoluene

C14H10FNS

C14H10FNS

Conditions
ConditionsYield
With N,N'-difluoro-1,4-diazoniabicyclo<2.2.2>octane bis(tetrafluoroborate); trifluoroacetic acid In acetonitrile at 20℃; for 24h; Irradiation;77%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

acetyl chloride
75-36-5

acetyl chloride

1-(4-fluoro-2-methylphenyl)ethanone
446-29-7

1-(4-fluoro-2-methylphenyl)ethanone

Conditions
ConditionsYield
With aluminium trichloride In carbon disulfide76.4%
With aluminium trichloride
m-Fluorotoluene
352-70-5

m-Fluorotoluene

(R)-tert-butyl tert-butanethiosulfinate
67734-35-4

(R)-tert-butyl tert-butanethiosulfinate

(S)-tert-butyl (3-fluorophenyl)methyl sulfoxide
1361250-93-2

(S)-tert-butyl (3-fluorophenyl)methyl sulfoxide

Conditions
ConditionsYield
Stage #1: m-Fluorotoluene With 2,2,6,6-tetramethyl-piperidine; n-butyllithium; potassium tert-butylate In tetrahydrofuran; hexane at -78℃; for 0.583333h; Inert atmosphere;
Stage #2: (R)-tert-butyl tert-butanethiosulfinate In tetrahydrofuran; hexane Inert atmosphere; optical yield given as %ee; enantioselective reaction;
76%
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