Lonwin Industry group limited as a professional manufactor & exporter of chemical materials ,we totally haver more than 270 stuffs, we have been on this line for more than 9 years. Our chemical materials are exported to lot of countries and reg
Cas:121-73-3
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Cas:121-73-3
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Cas:121-73-3
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inquiryOur company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O
Cas:121-73-3
Min.Order:1 Kilogram
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inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
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Cas:121-73-3
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inquirySuperior quality, moderate price & quick delivery. Appearance:light yellow crystal powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical
Product name: 1-Chloro-3-Nitrobenzene CAS No.: 121-73-3 Molecule Formula:C6H4ClNO2 Molecule Weight:157.55 Purity: 99.0% Package: 25kg/drum Description:White or light yellow crystalline powder Manufacture Standards:Enterprise Standard
Cas:121-73-3
Min.Order:1 Kilogram
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inquiryCAS:121-73-3 EINECS:204-496-1 MW:157.55 MF:C6H4ClNO2 Melting point:43-47 °C(lit.) Boiling point:236 °C(lit.) Appearance:light yellow crystal Package:25kg/drum Transportation:by sea/air/courier Port:Shanghai
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Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
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inquiryProduct Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard
Cas:121-73-3
Min.Order:1 Kilogram
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Type:Trading Company
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TIANFUCHEM--High purity 121-73-3 3-Nitrochlorobenzene Application:TIANFUCHEM--High purity 121-73-3 3-Nitrochlorobenzene
Cas:121-73-3
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Cas:121-73-3
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Cas:121-73-3
Min.Order:10 Milligram
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m-nitrobenzene boronic acid
3-Chloronitrobenzene
Conditions | Yield |
---|---|
With 1,3-dichloro-5,5-dimethylhydantoin; copper(l) chloride In acetonitrile at 80℃; for 2h; | 98% |
With N-chloro-succinimide In acetonitrile at 80℃; for 12h; | 97% |
With 1,3-dichloro-5,5-dimethylhydantoin; sodium methylate In methanol; water; acetonitrile at 60℃; | 43 % Chromat. |
Conditions | Yield |
---|---|
With tetrahydrofuran; tert.-butylnitrite; dimethyl sulfoxide at 30℃; for 1h; Green chemistry; | 96% |
Conditions | Yield |
---|---|
With copper(I) oxide; tetramethlyammonium chloride; L-proline In ethanol at 110℃; for 20h; Inert atmosphere; | 93% |
With lithium chloride In water; acetic acid Irradiation; | 90% |
With hydrogenchloride; lithium chloride In water; acetonitrile at 20℃; Product distribution; Mechanism; Irradiation; investigation of nucleophilic aromatic photosubstitution at different H+ and Cl- ion concentration; | 90% |
Conditions | Yield |
---|---|
With 1,9-diperoxynonanedioic acid In acetonitrile at 50℃; for 0.5h; | 92% |
With 3-chloro-benzenecarboperoxoic acid In 1,2-dichloro-ethane for 10h; Reflux; | 81% |
With tert.-butylhydroperoxide; potassium iodide In water; acetonitrile at 80℃; for 15h; | 70% |
Conditions | Yield |
---|---|
With tetrahydrofuran; tert.-butylnitrite; dimethyl sulfoxide at 30℃; for 1h; Green chemistry; | 92% |
Stage #1: 2-Chloro-4-nitroaniline With Nitrogen dioxide In acetonitrile at -20℃; Diazotization; Stage #2: With calcium bis(hypophosphite); Fe2SO4*7H2O In methanol; acetonitrile at 20℃; Dediazonation; | 87% |
With sulfuric acid; ethyl acetate; sodium nitrite In water at 50 - 55℃; for 0.5h; | 50% |
Multi-step reaction with 3 steps 1: 98 percent / i-pentyl nitrite; HOAc / 0 - 5 °C 2: 91 percent / aq. NaOH / 0.5 h / 0 - 5 °C 3: 9 percent / aq. HBr / acetonitrile / 0.5 h / 60 °C View Scheme | |
Multi-step reaction with 3 steps 1: 98 percent / i-pentyl nitrite; HOAc / 0 - 5 °C 2: 91 percent / aq. NaOH / 0.5 h / 0 - 5 °C 3: 2 percent / aq. HI; HBF4 / acetonitrile / 0.5 h / 60 °C View Scheme |
Conditions | Yield |
---|---|
With N-chloro-succinimide; iron(III) chloride for 3h; | 91% |
With trichloroisocyanuric acid; sulfuric acid at 80℃; for 5h; | 80% |
With N-chloro-succinimide; boron trifluoride at 100 - 105℃; for 24h; | 69% |
3-chlorophenylboronic acid
3-Chloronitrobenzene
Conditions | Yield |
---|---|
With Iron(III) nitrate nonahydrate In toluene at 80℃; for 18h; Inert atmosphere; | 88% |
With zirconium(IV) oxynitrate hydrate; iodine In toluene at 20℃; for 18h; Inert atmosphere; | 87% |
With copper(I) oxide; ammonium hydroxide; oxygen; sodium nitrite In water at 25℃; for 36h; | 60% |
With chloro-trimethyl-silane; silver nitrate In dichloromethane at 20℃; for 72h; | 90 % Spectr. |
3-Chloronitrobenzene
Conditions | Yield |
---|---|
With trichloroisocyanuric acid In water; ethyl acetate at 80℃; for 4h; Open flask; | 85% |
mesityl(3-nitrophenyl)iodonium trifluoromethanesulfonate
3-Chloronitrobenzene
Conditions | Yield |
---|---|
With copper(l) chloride In acetonitrile at 80℃; for 2h; | 85% |
Conditions | Yield |
---|---|
With nitronium tetrafluoborate; silver carbonate In N,N-dimethyl acetamide at 90℃; for 12h; Inert atmosphere; Schlenk technique; regioselective reaction; | 80% |
Conditions | Yield |
---|---|
With copper(l) iodide; triethylamine In dimethyl sulfoxide at 120℃; under 760.051 Torr; for 20h; Inert atmosphere; Schlenk technique; | 79% |
With 2.9-dimethyl-1,10-phenanthroline; oxygen; copper (I) acetate; silver sulfate; sodium bromide In dimethyl sulfoxide at 160℃; for 24h; Schlenk technique; | 64% |
With copper(I) oxide; N,N,N,N,-tetramethylethylenediamine In 1-methyl-pyrrolidin-2-one at 140℃; for 0.333333h; Inert atmosphere; | 83 %Chromat. |
With copper(I) oxide at 120℃; for 24h; Ionic liquid; | |
Multi-step reaction with 3 steps 1: acetonitrile / 2 h / 20 °C / Darkness 2: acetonitrile / Darkness 3: water / d7-N,N-dimethylformamide / 0.67 h / 100 °C / Inert atmosphere; Glovebox; Sealed tube; Darkness View Scheme |
Conditions | Yield |
---|---|
With sulfuric acid; water; Iodine monochloride; silver sulfate at 20℃; for 0.25h; Yields of byproduct given; | A 74% B n/a |
With sulfuric acid; water; Iodine monochloride; silver sulfate at 20℃; for 0.25h; Yield given; | A 74% B n/a |
With sulfuric acid; Iodine monochloride; fluorine Ambient temperature; | A 45% B 44% |
C10H13ClN4O2
A
3-Chloronitrobenzene
B
1-bromo-2-chloro-4-nitrobenzene
Conditions | Yield |
---|---|
With hydrogen bromide In acetonitrile at 60℃; for 0.5h; | A 9% B 74% |
Conditions | Yield |
---|---|
With tetrafluoroboric acid; hydrogen iodide In acetonitrile at 60℃; for 0.5h; | A 2% B 74% |
3-Chloronitrobenzene
Conditions | Yield |
---|---|
With N-benzyl-N,N,N-triethylammonium chloride; copper In acetonitrile at 20℃; for 0.75h; Substitution; | 72% |
With N-benzyl-N,N,N-triethylammonium chloride In acetonitrile at 60℃; for 0.75h; Substitution; | 19% |
Conditions | Yield |
---|---|
With tert.-butylnitrite; N-benzyl-N,N,N-triethylammonium chloride; toluene-4-sulfonic acid; copper dichloride In acetonitrile at 60℃; for 1h; | 66% |
With tert.-butylnitrite; N-benzyl-N,N,N-triethylammonium chloride; toluene-4-sulfonic acid; copper dichloride | 65% |
With tert.-butylnitrite; N-benzyl-N,N,N-triethylammonium chloride; copper dichloride; 10-camphorsulfonic acid In neat (no solvent) Time; Solvent; | 65% |
methyl 4-chloro-2-nitrobenzoate
A
3-Chloronitrobenzene
Conditions | Yield |
---|---|
With potassium fluoride; tetraphenylphosphonium bromide In sulfolane at 220℃; for 0.5h; Product distribution; other chloronitroaromatic compounds, other reagents and solvents, var. temp. and time; | A 66% B 27% |
With potassium fluoride; tetraphenylphosphonium bromide In sulfolane at 220℃; for 0.5h; | A 66 % Chromat. B 27 % Chromat. |
(R,S)-1-(4-chloro-2-nitrophenyl)ethanol
3-Chloronitrobenzene
Conditions | Yield |
---|---|
With 1,10-Phenanthroline; oxygen; copper diacetate; silver nitrate; sodium hydroxide In dimethyl sulfoxide at 140℃; under 3750.38 Torr; for 12h; Autoclave; Green chemistry; | 48% |
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; ammonium iodide; water In dimethyl sulfoxide at 90℃; for 4h; Sealed tube; | 38% |
Conditions | Yield |
---|---|
at 120 - 140℃; anschliessendes Erhitzen auf 250-350grad; |
Conditions | Yield |
---|---|
With sulfuric acid; acetic acid Diazotization.Eintragen der Diazoniumsalz-Loesung in eine Loesung von CuCl in wss. HBr; |
Conditions | Yield |
---|---|
With copper dichloride |
perfluoro(methylcyclohexane)
3-Chloronitrobenzene radical anion
A
3-Chloronitrobenzene
B
1,1,2,2,3,3,4,4,5,5,6-Undecafluoro-6-trifluoromethyl-cyclohexane
Conditions | Yield |
---|---|
In gas at 150℃; Rate constant; |
methyl 4-chloro-2-nitrobenzoate
A
3-Chloronitrobenzene
C
methyl 4-fluoro-2-nitrobenzoate
Conditions | Yield |
---|---|
With potassium fluoride; tetraphenylphosphonium bromide In dimethyl sulfoxide at 130℃; for 27h; | A 2.5 % Chromat. B 72 % Chromat. C 0.9 % Chromat. |
With potassium fluoride; tetraphenylphosphonium bromide In N,N-dimethyl acetamide at 130℃; for 25h; | A 2 % Chromat. B 31 % Chromat. C 5 % Chromat. |
nitrobenzene radical anion
3-Chloronitrobenzene radical anion
A
3-Chloronitrobenzene
B
nitrobenzene
Conditions | Yield |
---|---|
at 76.9℃; Rate constant; |
C7H6ClN3O3
3-Chloronitrobenzene
Conditions | Yield |
---|---|
With methanol; sodium methylate at 10℃; Rate constant; |
C8H8ClN3O3
3-Chloronitrobenzene
Conditions | Yield |
---|---|
With ethanol; sodium ethanolate at 10℃; Rate constant; var. base concentrations; |
methoxybenzene
A
3-Chloronitrobenzene
B
4-chlorobenzonitrile
C
2-Chloronitrobenzene
Conditions | Yield |
---|---|
With N-nitro-2,4,6-trimethylpyridinium tetrafluoroborate In nitromethane at 25℃; Rate constant; competitive nitration with benzene; |
nitrobenzene
A
3,4-dichloronitrobenzene
B
3-Chloronitrobenzene
C
1,2-Dichloro-3-nitrobenzene
D
4-chlorobenzonitrile
E
2-Chloronitrobenzene
F
2,5-dichloronitrobenzene
Conditions | Yield |
---|---|
With chlorine; iron(III) chloride at 60 - 120℃; Product distribution; Kinetics; relative rates of each steps; |
Conditions | Yield |
---|---|
With 2 weight% platinum on carbon; ethanol at 100℃; under 7500.75 Torr; for 8h; Autoclave; | 100% |
With hydrogen In ethanol at 20℃; under 7500.75 Torr; for 8h; Catalytic behavior; Sealed tube; | 100% |
With hydrazine hydrate In ethanol; water at 80℃; for 1h; chemoselective reaction; | 100% |
3-Chloronitrobenzene
potassium isopropoxide
3,3'-dichloroazoxybenzene
Conditions | Yield |
---|---|
In isopropyl alcohol at 75℃; Mechanism; Product distribution; Rate constant; also with the K+ complexing 18-crown-6 ether under anaerobic and aerobic conditions; | 100% |
3-Chloronitrobenzene
chloromethyl phenyl sulfone
1-Benzenesulfonylmethyl-2-chloro-4-nitro-benzene
Conditions | Yield |
---|---|
Stage #1: chloromethyl phenyl sulfone With potassium hydroxide In dimethyl sulfoxide for 0.166667h; Inert atmosphere; Stage #2: 3-Nitrochlorobenzene In dimethyl sulfoxide at 20℃; for 0.166667h; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With caesium carbonate; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane for 1h; Suzuki-Miyaura coupling; Heating; | 99% |
With [PdCl{[(η5-C5H5)]Fe[(η5-C5H3)CH=NCy]}(PCy3)]; caesium carbonate In 1,4-dioxane at 100℃; for 12h; Suzuki coupling reaction; | 98.5% |
With (bis(tricyclohexyl)phosphine)palladium(II) dichloride; cesium fluoride In various solvent(s) at 100℃; for 10h; | 97% |
Conditions | Yield |
---|---|
With sodium t-butanolate; palladium diacetate; [(μ-PPh2CH2PPh2)Co2(CO)4][μ,η-PhCCP(tBu)2] In toluene at 60℃; for 4h; | 99% |
With sodium methylate; triethylamine; 2-(di-t-butylphosphino)biphenyl palladium In toluene at 60℃; for 5h; | 85% |
With potassium acetate; 1-butyl-3-methylimidazolium Tetrafluoroborate for 0.0333333h; microwave irradiation; | 56% |
In various solvent(s) at 180℃; for 5h; Irradiation; | 14% |
Conditions | Yield |
---|---|
With copper(l) iodide; potassium carbonate In N,N-dimethyl-formamide at 20 - 110℃; | 99% |
3-Chloronitrobenzene
m-tolylboronic acid
3-methyl-3'-nitro-1,1'-biphenyl
Conditions | Yield |
---|---|
With potassium phosphate tribasic trihydrate; C30H39P; palladium diacetate In tetrahydrofuran at 110℃; for 3h; Suzuki-Miyaura Coupling; Inert atmosphere; | 99% |
With potassium phosphate tribasic trihydrate; (2-(anthracen-9-yl)-1H-inden-3-yl)dicyclohexylphosphine; palladium diacetate In water; isopropyl alcohol; toluene at 90℃; for 16h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere; | 94% |
3-Chloronitrobenzene
N-(3-chlorophenyl)hydroxylamine
Conditions | Yield |
---|---|
With carbon dioxide; zinc In water at 25℃; under 750.075 Torr; for 0.666667h; Sonication; | 98% |
With ammonium formate; zinc In acetonitrile at 25 - 30℃; for 1h; sonification; | 94% |
With hydrazine hydrate at 60℃; for 0.666667h; Green chemistry; chemoselective reaction; | 87% |
3-Chloronitrobenzene
3,3'-dichloroazobenzene
Conditions | Yield |
---|---|
With C24H16CoN4O4; hydrogen; sodium hydroxide In tert-butyl alcohol at 80℃; under 22502.3 Torr; for 1h; chemoselective reaction; | 98% |
With hydrogen In toluene at 50℃; under 15001.5 Torr; for 7h; Autoclave; Green chemistry; chemoselective reaction; | 97% |
Stage #1: 3-Nitrochlorobenzene In ethanol for 0.0333333h; Stage #2: With sodium tetrahydroborate In ethanol for 0.3h; Reflux; | 96% |
styrene
carbon monoxide
3-Chloronitrobenzene
N-(3-chlorophenyl)-2-phenylpropanamide
Conditions | Yield |
---|---|
With 1,1'-bis-(diphenylphosphino)ferrocene; potassium tetrachloropalladate(II); boric acid In tetrahydrofuran at 80℃; under 26252.6 Torr; for 20h; Reagent/catalyst; Autoclave; regioselective reaction; | 98% |
Conditions | Yield |
---|---|
With sulfuric acid; nitric acid at 30℃; for 1h; | 97% |
With sulfuric acid; uronium nitrate at 0 - 20℃; Nitration; | 77% |
With sulfuric acid; potassium nitrate | |
With sulfuric acid; potassium nitrate |
Conditions | Yield |
---|---|
With potassium hydroxide; tetrabutylammomium bromide In various solvent(s) 1) 5 h, room temperature, 2) 3 h, 50 deg C; other nitrobenzene derivatives, other reaction times and temperatures; | 97% |
With potassium hydroxide; tetrabutylammomium bromide In various solvent(s) at 50℃; for 24h; | 97% |
5-Amino-1,3-dimethylpyrazole
3-Chloronitrobenzene
1,3-dimethyl-N-(3-nitrophenyl)-1H-pyrazol-5-amine
Conditions | Yield |
---|---|
With chloro[2-(dicyclohexylphosphino)-3 ,6-dimethoxy-2’,4’, 6’-triisopropyl- 1,1’-biphenyl] [2-(2-aminoethyl)phenyl]palladium(II); caesium carbonate; ruphos In tert-butyl alcohol at 110℃; for 24h; Inert atmosphere; | 97% |
Conditions | Yield |
---|---|
With silver nanoparticles decorated mesoporous 1,3,5-triformylphloroglucinol-DMB covalent organic framework nanomaterial In water at 20℃; for 2h; Catalytic behavior; Irradiation; Green chemistry; | 97% |
With gold nano particles supported on rutile TiO2 In toluene at 70℃; under 750.075 Torr; for 3h; Inert atmosphere; chemoselective reaction; | 96% |
With cobalt nanoparticles anchoring on nitrogen doped carbon, pyrolysis at 700 °C In acetonitrile at 110℃; under 750.075 Torr; for 5h; Inert atmosphere; chemoselective reaction; | 93.8% |
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; triethylamine; potassium iodide In dimethyl sulfoxide at 100℃; for 20h; Inert atmosphere; chemoselective reaction; | 86% |
With palladium(II) trifluoroacetate; triphenylphosphine In water at 80℃; for 2.5h; Sealed tube; Green chemistry; | 77% |
3-Chloronitrobenzene
2-Methyl-4-phenyl-3-butyn-2-ol
1-(3-nitrophenyl)-2-phenylacetylene
Conditions | Yield |
---|---|
With {(Pd{Fe(η5-C5H5)(η5-C5H3C(CH3)=NC6H4CH3-4)}(μ-Cl))2}; potassium carbonate; XPhos In acetonitrile at 110℃; for 16h; Inert atmosphere; | 96% |
With tetrabutylammomium bromide; potassium carbonate; palladium dichloride; XPhos In water at 120℃; Inert atmosphere; Schlenk technique; Green chemistry; | 87% |
3-Chloronitrobenzene
sodium 4-methylbenzenesulfinate
N-(3-chloro-phenyl)-4-methylbenzenesulfonamide
Conditions | Yield |
---|---|
With trans-N,N'-dimethyl-1,2-cyclohexyldiamine; sodium hydrogen sulfite; iron(II) chloride In dimethyl sulfoxide at 60℃; for 12h; Sealed tube; Inert atmosphere; | 96% |
Stage #1: 3-Nitrochlorobenzene With tetrahydroxydiboron In methanol; water at 100℃; for 8h; Schlenk technique; Stage #2: sodium 4-methylbenzenesulfinate With iodine In methanol; water at 35℃; for 3h; Schlenk technique; | 80% |
Conditions | Yield |
---|---|
With indium; acetic acid In methanol at 20℃; for 1h; | 95% |
3-Chloronitrobenzene
N-(2-bromophenyl)formamide
molybdenum hexacarbonyl
3-(3-chlorophenyl)-4(3H)-quinazolinone
Conditions | Yield |
---|---|
With palladium diacetate; triethylamine In 1,4-dioxane at 140℃; under 7500.75 Torr; for 16h; Inert atmosphere; | 95% |
1-trifluoromethyl-4-vinyl-benzene
carbon monoxide
3-Chloronitrobenzene
Conditions | Yield |
---|---|
With tetrakis(acetonitrile)palladium bistriflate; boric acid; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 80℃; under 750.075 Torr; for 20h; Autoclave; regioselective reaction; | 95% |
Conditions | Yield |
---|---|
With palladium diacetate; caesium carbonate; 2-N,N-(dimethylamino)-2'-di-tert-butylphosphino-1,1'-binaphthyl In toluene at 70℃; | 94% |
Conditions | Yield |
---|---|
With potassium hydroxide; tris(dibenzylideneacetone)dipalladium (0); XPhos In water at 60℃; for 8h; | 94% |
With potassium acetate; 1-butyl-3-methylimidazolium Tetrafluoroborate for 0.0333333h; microwave irradiation; | 43% |
3-Chloronitrobenzene
4-[4-(4-fluorophenyl)-1-methyl-2-methylsulfanyl-1H-imidazol-5-yl]pyridin-2-ylamine
Conditions | Yield |
---|---|
With BrettPhos precatalyst; caesium carbonate In 1,4-dioxane; tert-butyl alcohol for 4h; Reagent/catalyst; Solvent; Buchwald-Hartwig Coupling; | 94% |
Conditions | Yield |
---|---|
With tetrakis(acetonitrile)palladium bistriflate; boric acid; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 80℃; under 750.075 Torr; for 20h; Reagent/catalyst; Autoclave; regioselective reaction; | 94% |
3-Chloronitrobenzene
3,3'-dichloroazoxybenzene
Conditions | Yield |
---|---|
With potassium hydroxide In water; isopropyl alcohol at 30℃; under 760.051 Torr; for 8h; Inert atmosphere; | 93% |
With bismuth for 1.5h; | 92% |
With cerium(IV) oxide; hydrogen In toluene at 120℃; under 7500.75 Torr; chemoselective reaction; | 92% |
Conditions | Yield |
---|---|
With methanol; indium(III) chloride; indium In chloroform at 20℃; for 19h; | 93% |
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; hydrogen In water; toluene at 160℃; under 30003 Torr; for 36h; Autoclave; | 93% |
3-Chloronitrobenzene
(E)-1,2-bis(3-chlorophenyl)diazene
Conditions | Yield |
---|---|
With isopropyl alcohol; sodium hydroxide at 30℃; for 2h; Catalytic behavior; Inert atmosphere; UV-irradiation; | 92% |
With ammonium acetate; lead In methanol at 20℃; | 87% |
With hydrazine hydrate; potassium hydroxide In toluene at 100℃; for 1h; Sealed tube; | 85% |
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