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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Fluorobenzene Manufacturer/High quality/Best price/In stock

Cas:462-06-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Fluorobenzene with high purity

Cas:462-06-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hefei TNJ chemical industry co.,ltd

Technology: Technology innovation is our eternal pursuit,or we will be left behind.Our technology experts,all from famous universities and institutes,has rich experience and high achievements in chemical research.This makes sure that our technology

Fluorobenzene 462-06-6

Cas:462-06-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:Colorless liquid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

Fluorobenzene

Cas:462-06-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Fluorobenzene

Cas:462-06-6

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Fluorobenzene

Cas:462-06-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

Fluorobenzene

Cas:462-06-6

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

462-06-6 Fluorobenzene

Cas:462-06-6

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

Chemical Name Fluorobenzene CAS Number Molecular Formula Molecular Weight 462-06-6 C6H5F 96.1 Molecular Structure Packing 200kg/drum

Fluorobenzene CAS: 462-06-6

Cas:462-06-6

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

Advantages: Hubei XinRunde Chemical Co., Ltd is a renowned pharmaceutical manufacturer. We can offer high quality products at competitive price in quick delivery with 100% custom pass guaranteed. Never stop striving to offer our best serv

Fluorobenzene

Cas:462-06-6

Min.Order:10 Gram

Negotiable

Type:Other

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the

Benzene,fluoro-/ LIDE PHARMA- Factory supply / Best price

Cas:462-06-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Mojin Biotechnology Co.,Ltd

Company information: Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in carbomer,carbopol,lead acetate,meglumine diphenyl ethylamine and other chemical raw materials and chemical reagents research and development production ente

China manufacturer 99.5% Fluorobenzene CAS 462-06-6

Cas:462-06-6

Min.Order:1 Kilogram

FOB Price: $20.0 / 30.0

Type:Trading Company

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Hangzhou Fandachem Co.,Ltd

Hangzhou Fanda Chemical Co.,Ltd (FandaChem) , a China-based chemical company, specialize in exporting Fluorobenzene 99.9% CAS:462-06-6, Please contact us by email freely. We are leading exporter in China. If you really need this cargo

Fluorobenzene 99.9%CAS:462-06-6 from FandaChem

Cas:462-06-6

Min.Order:1 Metric Ton

Negotiable

Type:Other

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Fluorobenzene

Cas:462-06-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzene,fluoro-

Cas:462-06-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Fluorobenzene

Cas:462-06-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediat

Benzene,fluoro-

Cas:462-06-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Fluorobenzene High quality/Best price/In stock

Cas:462-06-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

FluorobenzeneCAS NO.: 462-06-6

Cas:462-06-6

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

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Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

Fluorobenzene

Cas:462-06-6

Min.Order:0

Negotiable

Type:Trading Company

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SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/Fluorobenzene

Cas:462-06-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti

Fluorobenzene

Cas:462-06-6

Min.Order:0

Negotiable

Type:Manufacturers

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Fluorobenzene

Cas:462-06-6

Min.Order:0

Negotiable

Type:Other

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Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

Fluorobenzene

Cas:462-06-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Fluorobenzene

Cas:462-06-6

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

stable stock,Competitive priceAppearance:Powder Storage:Avaliable Package:25KG/drum 200KG/drum Application:Agrochemicals Raw material Transportation:BY sea or by air

Fluorobenzene

Cas:462-06-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Fluorobenzene

Cas:462-06-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat

Fluorobenzene

Cas:462-06-6

Min.Order:0

Negotiable

Type:Manufacturers

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Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

Fluorobenzene

Cas:462-06-6

Min.Order:0

Negotiable

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 462-06-6 with competitive price

Cas:462-06-6

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

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Synthetic route

4-fluorophenyl(m-carboran-9-yl)iodonium tetrafluoroborate
99506-39-5

4-fluorophenyl(m-carboran-9-yl)iodonium tetrafluoroborate

sodium chloride
7647-14-5

sodium chloride

A

fluorobenzene
462-06-6

fluorobenzene

B

9-iodo-m-carborane
17157-02-7

9-iodo-m-carborane

C

9-chloro-m-carborane
17819-85-1

9-chloro-m-carborane

D

4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

Conditions
ConditionsYield
In chloroform; water mixt. of aryl(m-carboran-9-yl)iodonium tetrafluoroborate, NaCl, water and chloroform was vigorously stirred under reflux at 56°C, 2-2.5 h; internal standard (chlorobenzene) added and org. layer was analysed by GLC;A 0%
B 0%
C 100%
D 100%
2-(trifluoromethyl)phenylacetic acid
3038-48-0

2-(trifluoromethyl)phenylacetic acid

2-(4-fluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
214360-58-4

2-(4-fluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

A

fluorobenzene
462-06-6

fluorobenzene

B

C15H10F4O2

C15H10F4O2

Conditions
ConditionsYield
With t-Boc-L-valine; 2,5-di-tert-butyl-p-benzoquinone; oxygen; potassium hydrogencarbonate In tert-Amyl alcohol at 90℃; under 2280.15 Torr; for 24h; Catalytic behavior;A n/a
B 99%
aniline
62-53-3

aniline

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
Stage #1: aniline With hydrogen fluoride at -10 - 0.5℃; Flow reactor; Large scale;
Stage #2: With nitrosylsulfuric acid at 0 - 10℃; Temperature; Flow reactor; Large scale;
98.9%
With pyridine; hydrogen fluoride; sodium nitrite Product distribution; changed molar ratio HF/Pyr, changed time and temperature, only HF; multistep reaction; 1.) 20 deg C, 30 min., 2.) 55 deg C, 1 h;95%
Stage #1: aniline With hydrogenchloride; fluoroboric acid; sodium nitrite In water at 25℃; for 0.00416667h; Balz-Schiemann Reaction;
Stage #2: at 125℃; for 0.0166667h; Balz-Schiemann Reaction;
92%
2-fluorobenzenediazonium tetrafluoroborate
446-46-8

2-fluorobenzenediazonium tetrafluoroborate

A

fluorobenzene
462-06-6

fluorobenzene

B

ortho-difluorobenzene
367-11-3

ortho-difluorobenzene

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; hydrogen fluoride at 12℃; for 1h; Decomposition; Fluoro-dediazoniation; Irradiation;A 0.2%
B 98.9%
With boron trifluoride diethyl etherate at 12℃; for 3h; Decomposition; Fluoro-dediazoniation; Irradiation;A 10.7%
B 84.6%
1-fluoro-3,5-dichlorobenzene
1435-46-7

1-fluoro-3,5-dichlorobenzene

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
With C60H48BP3Pd; potassium formate; [2.2.2]cryptande In tetrahydrofuran at 60℃; for 72h; Schlenk technique; Inert atmosphere;97%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

A

fluorobenzene
462-06-6

fluorobenzene

B

2,2'-difluorobiphenyl
388-82-9

2,2'-difluorobiphenyl

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride In 2-pentanol at 100℃; for 18h; Inert atmosphere;A 95.5%
B 4.5%
With palladium; hydroquinone; potassium hydroxide In glycerol at 90℃; for 18h; chemoselective reaction;A n/a
B 71 %Chromat.
benzenediazonium tetrafluoroborate
369-57-3

benzenediazonium tetrafluoroborate

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
With pyridine; hydrogen fluoride at 55℃; for 1h; Product distribution; Rate constant; Thermodynamic data; changed molar ratio HF/Pyr, temp. and time; energy/enthalpy of activation;95%
With tetrakis(acetonitrile)copper(I)tetrafluoroborate; [4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis{3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC}iridium(III) hexafluorophosphate; cesium fluoride In acetone at 30℃; Irradiation;37%
With sodium difluorohydrogenate; 1,2,4-Trichlorobenzene
benzene
71-43-2

benzene

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
With fluorine at 60℃; under 3750.38 Torr; Temperature;95%
With trifluorormethanesulfonic acid; Selectfluor In dichloromethane at 40℃; for 20h; Fluorination;83%
With Al2CuF8 at 500℃; Reagent/catalyst; Inert atmosphere;47%
4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
With formaldehyd; palladium diacetate; caesium carbonate In dimethyl sulfoxide at 80℃; for 12h;94%
With sodium tetrahydroborate; di-tert-butyl peroxide In N,N-dimethyl-formamide at 70℃; for 2h; Irradiation;82 % Chromat.
With hydrogenchloride; CuI*P(Et)3; naphthalen-1-yl-lithium 1.) THF, 25 deg C, 10 min; Yield given. Multistep reaction;
phenylthallium(III) bis(tetrafluoroborate)

phenylthallium(III) bis(tetrafluoroborate)

A

fluorobenzene
462-06-6

fluorobenzene

B

thallium(I) tetrafluoroborate
28625-02-7

thallium(I) tetrafluoroborate

Conditions
ConditionsYield
In solid byproducts: BF3; pyrolisis under Ar without solvent at 100-150°; TlBF4 identified by IR spectrum and comparison of m.p. with that of an authentic sample;A 51%
B 94%
o-fluoro-benzoic acid
445-29-4

o-fluoro-benzoic acid

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
With quinoline; copper(I) oxide; 1,10-Phenanthroline; tetradecane In 1-methyl-pyrrolidin-2-one at 170℃; for 6h; Reagent/catalyst; Inert atmosphere;91%
copper(I) oxide; 1,10-Phenanthroline In quinoline at 170℃; for 6h;75%
With [Rh(OH)(cod)]2; 1,3-bis-(diphenylphosphino)propane; water; sodium hydroxide In tetrahydrofuran at 150℃; for 24h; Inert atmosphere;8 %Chromat.
4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

carbon monoxide
201230-82-2

carbon monoxide

A

fluorobenzene
462-06-6

fluorobenzene

B

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With hydrogen; potassium carbonate In 1,4-dioxane at 120 - 140℃; under 30003 Torr; for 20h; Autoclave;A 7%
B 91%
4-fluorophenyl(m-carboran-9-yl)iodonium tetrafluoroborate
99506-39-5

4-fluorophenyl(m-carboran-9-yl)iodonium tetrafluoroborate

A

fluorobenzene
462-06-6

fluorobenzene

B

9-iodo-m-carborane
17157-02-7

9-iodo-m-carborane

C

9-hydroxy-1,7-dicarba-closo-dodecaborane
54360-42-8

9-hydroxy-1,7-dicarba-closo-dodecaborane

D

9-nitro-m-carbaborane
114992-96-0

9-nitro-m-carbaborane

E

4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

Conditions
ConditionsYield
With sodium nitrite In dichloromethane; water mixt. of NaNO2 and the boron contg. salt in a two phase system stirred vigorously at 40°C, 2.5h (accompanied by evolution of nitrogen oxides), further product: 4-F-C6H4NO2 (traces); organic layer sepd. from aq. layer, evapn. of CH2Cl2 in vac., residue sepd. by chromy. (silica gel, hexane (9-iodo-m-carbaborane); benzene-hexane 1:1 (9-nitro-m-carbaborane); ether (9-hydroxy-m-carbaborane);A 5%
B 8%
C 75%
D 8%
E 90%
phenyl(triphenyl-λ5-phosphanyl)gold

phenyl(triphenyl-λ5-phosphanyl)gold

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
With Selectfluor chemoselective reaction;90%
perfluoro-
128812-96-4

perfluoro-

benzene
71-43-2

benzene

A

fluorobenzene
462-06-6

fluorobenzene

B

1,1,1-trifluoro-N-(perfluoropyridin-4-yl)methanesulfonamide
128812-95-3

1,1,1-trifluoro-N-(perfluoropyridin-4-yl)methanesulfonamide

Conditions
ConditionsYield
In chloroform-d1 at 60℃; for 0.166667h; sealed in vacuo;A 88%
B n/a
phenol
108-95-2

phenol

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
With 1,3-bis(2,6-diisopropylphenyl)-2,2-difluoro-2,3-dihydro-1h-imidazole; cesium fluoride In toluene at 80℃; for 18h; Product distribution / selectivity; Sealed vial;88%
With 1,3-bis(2,6-diisopropylphenyl)-2,2-difluoro-2,3-dihydro-1h-imidazole; cesium fluoride In toluene at 23 - 80℃; for 18.5h; Inert atmosphere;82 %Spectr.
Multi-step reaction with 2 steps
1: fluorosulfonyl fluoride; triethylamine / 1,4-dioxane / 24 h / 20 °C
2: tetramethylammonium fluoride / N,N-dimethyl-formamide / 24 h / 100 °C / Inert atmosphere; Glovebox; Sealed tube
View Scheme
(p-fluorophenyl)trimethylsilane
455-17-4

(p-fluorophenyl)trimethylsilane

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
With potassium trimethylsilonate In dimethyl sulfoxide at 60℃; under 760.051 Torr; for 5.5h; Catalytic behavior; Reagent/catalyst; Solvent; Sealed tube;88%
With potassium trimethylsilonate In dimethyl sulfoxide at 70℃; for 6h; Sealed tube; Schlenk technique;85 %Chromat.
benzenediazonium tetrafluoroborate
369-57-3

benzenediazonium tetrafluoroborate

A

fluorobenzene
462-06-6

fluorobenzene

B

benzene
71-43-2

benzene

Conditions
ConditionsYield
With pyridine; hydrogen fluoride for 2h; Decomposition; Fluoro-dediazoniation; Irradiation;A 87.9%
B 0.4%
diphenyliodonium tetrafluoroborate

diphenyliodonium tetrafluoroborate

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
With potassium fluoride at 160 - 170℃; for 20h;85%
(2,4,6-trimethylphenyl)(phenyl)iodonium tetrafluoroborate

(2,4,6-trimethylphenyl)(phenyl)iodonium tetrafluoroborate

A

fluorobenzene
462-06-6

fluorobenzene

B

1-fluoro-2,4,6-trimethylbenzene
392-69-8

1-fluoro-2,4,6-trimethylbenzene

Conditions
ConditionsYield
With potassium fluoride; 18-crown-6 ether; copper(II) methanesulfonate In N,N-dimethyl-formamide at 60℃; for 18h; Reagent/catalyst; Time; Solvent;A 85%
B n/a
With potassium fluoride; 18-crown-6 ether; copper(II) bis(trifluoromethanesulfonate) In ethyl acetate at 60℃; for 18h; Reagent/catalyst; Solvent; Glovebox; Overall yield = 39 %Spectr.;
With tetrabutyl ammonium fluoride; copper(II) bis(trifluoromethanesulfonate) In N,N-dimethyl-formamide at 60℃; for 18h; Glovebox;
(2,4,6-trimethylphenyl)(phenyl)iodonium tetrafluoroborate

(2,4,6-trimethylphenyl)(phenyl)iodonium tetrafluoroborate

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
With potassium fluoride; 18-crown-6 ether; copper(II) bis(trifluoromethanesulfonate) In N,N-dimethyl-formamide at 60℃; for 18h; Mechanism; Reagent/catalyst; Solvent; Time; Glovebox;85%
With tetrabutyl ammonium fluoride; copper(II) bis(trifluoromethanesulfonate) In N,N-dimethyl-formamide at 60℃; for 18h; Glovebox;29%
tris(4-fluorophenyl)cyanurate
54416-55-6

tris(4-fluorophenyl)cyanurate

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); sodium isopropylate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In 2-methyltetrahydrofuran at 80℃; for 12h; Green chemistry;85%
triethylsilane
617-86-7

triethylsilane

1-Chloro-4-fluorobenzene
352-33-0

1-Chloro-4-fluorobenzene

A

fluorobenzene
462-06-6

fluorobenzene

B

triethyl(4-fluorophenyl)silane

triethyl(4-fluorophenyl)silane

Conditions
ConditionsYield
With sodium carbonate In N,N-dimethyl acetamide at 100℃; for 7h; Schlenk technique; Inert atmosphere;A 13%
B 85%
diphenyliodonium p-toluenesulfonate
6293-66-9

diphenyliodonium p-toluenesulfonate

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In tetrahydrofuran for 8h; Heating;84%
Multi-step reaction with 3 steps
1: potassium iodide / water; acetonitrile
2: silver(l) oxide / water / 11 h / 0 - 20 °C
3: dimethylsulfoxide-d6 / 0.17 h / 100 °C
View Scheme
diphenylmercury(II)
587-85-9

diphenylmercury(II)

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
With hypofluorous acid trifluoromethyl ester In chloroform for 0.5h; Ambient temperature;83%
With sulfur tetrafluoride at -70 - -60℃; for 8h;58%
trimethylphenylsilane
768-32-1

trimethylphenylsilane

lead(IV) tetraacetate
546-67-8

lead(IV) tetraacetate

trifluoroborane diethyl ether
109-63-7

trifluoroborane diethyl ether

A

fluorobenzene
462-06-6

fluorobenzene

B

benzene
71-43-2

benzene

Conditions
ConditionsYield
Stirring of silane with a slurry of Pb(OAc)4 in excess of BF3*Et2O overnight at room temp.; GC anal.;A 83%
B 6%
4-fluorophenyl(m-carboran-9-yl)iodonium tetrafluoroborate
99506-39-5

4-fluorophenyl(m-carboran-9-yl)iodonium tetrafluoroborate

sodium fluoride

sodium fluoride

A

fluorobenzene
462-06-6

fluorobenzene

B

9-iodo-m-carborane
17157-02-7

9-iodo-m-carborane

C

9-fluoro-m-carborane
73050-37-0

9-fluoro-m-carborane

D

4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

Conditions
ConditionsYield
In chloroform; water mixt. of aryl(m-carboran-9-yl)iodonium tetrafluoroborate, NaF, water and chloroform was vigorously stirred under reflux at 56°C, 1.25 h; internal standard (chlorobenzene) added and org. layer was analysed by GLC;A 9%
B 2%
C 83%
D 82%
phenylboronic acid
98-80-6

phenylboronic acid

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
Stage #1: phenylboronic acid With sodium hydroxide In methanol at 23℃; for 0.25h; Inert atmosphere;
Stage #2: With silver trifluoromethanesulfonate In methanol at 0℃; for 0.5h; Inert atmosphere;
Stage #3: With Selectfluor In acetone at 23℃; for 1h; Inert atmosphere; Molecular sieve; regiospecific reaction;
82%
Stage #1: phenylboronic acid With sodium hydroxide In methanol at 23℃;
Stage #2: With silver trifluoromethanesulfonate In methanol at 0℃; for 0.5h;
Stage #3: With Selectfluor In acetone for 0.5h; Molecular sieve;
Stage #1: phenylboronic acid With sodium hydroxide In methanol at 23℃; for 0.25h;
Stage #2: With silver trifluoromethanesulfonate In methanol at 0℃; for 0.5h;
Stage #3: With Selectfluor In [(2)H6]acetone for 1h; Molecular sieve;
95 %Spectr.
C28H21N5O6PdS

C28H21N5O6PdS

fluorobenzene
462-06-6

fluorobenzene

Conditions
ConditionsYield
With Selectfluor In [(2)H6]acetone at 50℃; for 0.166667h; Product distribution / selectivity;82%
With Selectfluor In [(2)H6]acetone at 50℃; for 0.166667h; Product distribution / selectivity;47%
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