4-Fluorobenzaldehyde Product name: 4-Fluorobenzaldehyde CAS: 459-57-4 Structural formula: Quality specification: Appearance: Colorless to pale yellow liquid Content: 99.5%(Gc)min Free acid:0.3% max Isomer:0.1%max Flash Point: 56℃ Freezing Point:
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inquiryProduct Description Product website: http://www.finerchem.com/pro01en/id/2161.html Product Name 4-Fluorobenzaldehyde CAS No. 459-57-4
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inquiryhigh quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
4-Fluorobenzaldehyde Product name: 4-Fluorobenzaldehyde CAS: 459-57-4 Structural formula: Quality specification: Appearance: Colorless to pale yellow liquid Content: 99.5%(Gc)min Free acid:0.3% max Isomer:0.1%max Flash Point: 56℃
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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inquiryhebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm
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Cas:459-57-4
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inquiryProduct Name: 4-Fluorobenzaldehyde Synonyms: 4-fluoro-benzaldehyd;Benzaldehyde, p-fluoro-;PFAD;PFBA;P-FLUOROBENZALDEHYDE;PARA FLUOROBENZALDEHYDE;FLUOROBENZALDEHYDE(4-);LABOTEST-BB LT00930357 CAS: 459-57-4 MF: C7H5FO MW: 124.11 EINECS: 207-293-
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inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu
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inquiryProduct Name: 4-Fluorobenzaldehyde Synonyms: 4-fluoro-benzaldehyd;Benzaldehyde, p-fluoro-;PFAD;PFBA;P-FLUOROBENZALDEHYDE;PARA FLUOROBENZALDEHYDE;FLUOROBENZALDEHYDE(4-);LABOTEST-BB LT00930357 C
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inquiryWe have two GMP facilities in Hubei Province and cooperative factories in Zhejiang Province We are concentrating on the R&D and technical service of APIs and pharmaceutical intermediates We strive to provide world-class service for every client
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inquiry4-Fluorobenzaldehyde CAS:459-57-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inter
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inquiryHebei Mojin Biological Technology Co., Ltd. is specialize in the production of chemical raw materials and reagents,located in Shijiazhuang, Hebei Province. In recent decades, under the efforts of all staff, in Shandong, Henan, Guangdong and many othe
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inquiryProduct Detail Minimum Order Qty. 10 Gram
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inquiryName 4-Fluorobenzaldehyde Molecular Structure Molecular Formula C7H5FO Molecular Weight 12
Conditions | Yield |
---|---|
With cerium(IV) triflate; water at 20℃; for 22h; | 100% |
With Xylaria polymorpha laccase; 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonate) diammonium salt In 1,4-dioxane at 20℃; for 1.83333h; pH=4.5; Green chemistry; Enzymatic reaction; | 96% |
With cobalt(II) acetate; acetic acid; potassium bromide at 120℃; under 15001.5 Torr; for 2.5h; Reagent/catalyst; Temperature; Pressure; Autoclave; | 95% |
Conditions | Yield |
---|---|
With oxygen; perruthenate modified mesoporous silicate MCM-41 In toluene at 80℃; for 1h; Oxidation; | 100% |
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; oxygen; copper(I) bromide dimethylsulfide complex In chlorobenzene at 90℃; for 6h; | 100% |
With iron(III) chloride; 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; oxygen; sodium nitrite In 1,2-dichloro-ethane at 50℃; under 3000.3 Torr; for 5h; Autoclave; | 99% |
Conditions | Yield |
---|---|
With phosphoric acid In ethanol at 25℃; for 0.25h; Sonication; Green chemistry; | 99% |
With N,N'-dichlorophenobarbital In acetonitrile at 20℃; for 0.233333h; | 96% |
With water; Dess-Martin periodane In dichloromethane at 5℃; for 0.0333333h; | 95% |
Conditions | Yield |
---|---|
With sodium periodate; C53H44As2N2O3Ru In water; ethyl acetate; acetonitrile at 25℃; for 0.5h; | 99% |
With dihydrogen peroxide In water at 100℃; for 4h; | 92% |
With sodium periodate; C31H29Br2N3Ru*CH2Cl2 In water; ethyl acetate; acetonitrile at 25℃; for 0.5h; Inert atmosphere; Schlenk technique; | 92% |
Conditions | Yield |
---|---|
With methanol; potassium permanganate In ethyl acetate at 25℃; for 20h; | 99% |
Conditions | Yield |
---|---|
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; laccasefrom Trametes versicolor; oxygen In water at 30℃; for 24h; pH=4.5; Enzymatic reaction; | 97% |
With sodium periodate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; acetic acid; trifluoroacetic acid In water; acetonitrile for 20h; | 93% |
With cercosporin; oxygen In methanol at 20℃; Schlenk technique; Irradiation; Green chemistry; chemoselective reaction; | 87% |
(4-fluorophenyl)methylene diacetate
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With indium(III) bromide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 20℃; for 0.416667h; | 97% |
With bovine liver acetone powder In aq. phosphate buffer; acetone at 20℃; for 0.333333h; pH=7.4; Enzymatic reaction; chemoselective reaction; | 97% |
With sodium hydrogen sulfate; PEG-2000 at 70℃; for 0.416667h; | 95% |
4-fluorobenzylic alcohol
di(p-tolyl) sulfoxide
A
di-(p-tolyl)sulfane
B
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With per-rhenic acid In toluene for 17h; Reflux; | A 97% B 90% |
Conditions | Yield |
---|---|
With tetrabutyl ammonium fluoride In tetrahydrofuran for 0.166667h; Inert atmosphere; Microwave irradiation; | 95% |
With tetrabutyl ammonium fluoride In tetrahydrofuran for 10h; Inert atmosphere; Reflux; chemoselective reaction; | 82.1 %Chromat. |
Multi-step reaction with 2 steps 1: benzene-d6 / 23 °C / Inert atmosphere 2: benzene-d6 / 2 h / 60 °C View Scheme |
Conditions | Yield |
---|---|
With 1,3-bis(2,6-diisopropylphenyl)-2,2-difluoro-2,3-dihydro-1h-imidazole; cesium fluoride In toluene at 80℃; for 3h; Product distribution / selectivity; Sealed vial; | 95% |
With 1,3-bis(2,6-diisopropylphenyl)-2,2-difluoro-2,3-dihydro-1h-imidazole; cesium fluoride In toluene at 23 - 80℃; for 3.5h; Inert atmosphere; | 95 %Spectr. |
4,4'-difluorodeoxybenzoin
aniline
A
4-fluoro-N-phenylbenzamide
B
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With 1,10-Phenanthroline; copper(II) chloride dihydrate; oxygen In acetonitrile under 760.051 Torr; for 24h; Reflux; | A 95% B 96 %Chromat. |
Conditions | Yield |
---|---|
With (CH3)2NCH2NpSiH2Ph at 110 - 140℃; | 94% |
With dipotassium hydrogenphosphate; fac-tris(2-phenylpyridinato-N,C2')iridium(III); tris-(trimethylsilyl)silane; dimethyl dicarbonate In acetonitrile at 20℃; for 6h; Schlenk technique; Inert atmosphere; Sealed tube; Irradiation; | 89% |
With palladium(II) acetylacetonate; hydrogen; 2,2-dimethylpropanoic anhydride; dicyclohexylphenylphosphine In tetrahydrofuran at 80℃; under 3750.38 Torr; for 20h; Inert atmosphere; | 80% |
2-(4-fluorophenyl)-1,3-dithiolane
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With 1,3,5-trichloro-2,4,6-triazine; dimethyl sulfoxide In dichloromethane at 20℃; for 3.5h; | 93% |
Conditions | Yield |
---|---|
With dimethyl sulfoxide at 120℃; for 12h; | 93% |
With dimethyl amine at 60℃; for 0.166667h; | 86% |
1-(dibromomethyl)-4-fluorobenzene
dimethyl sulfoxide
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
at 120℃; for 12h; | 93% |
4-fluoro-1-iodobenzene
carbon monoxide
A
fluorobenzene
B
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With hydrogen; potassium carbonate In 1,4-dioxane at 120 - 140℃; under 30003 Torr; for 20h; Autoclave; | A 7% B 91% |
Conditions | Yield |
---|---|
With (NH4)4[ZnMo6O18(OH)6]; oxygen In water; acetonitrile at 60℃; under 760.051 Torr; for 12h; | 90% |
With water; sodium hydroxide at 20℃; for 0.0833333h; Microwave irradiation; | 88% |
With bismuth(III) nitrate; tetrabutyl ammonium fluoride at 100℃; for 4h; | 87% |
Conditions | Yield |
---|---|
With 1H-imidazole; C17H16ClMnN2O2; tetrabutylammonium periodite In chloroform at 20℃; for 0.416667h; | 90% |
With potassium 12-tungstocobaltate(III) In water; acetonitrile for 0.3h; Microwave irradiation; | 90% |
With 1H-imidazole; [bis(acetoxy)iodo]benzene; Co(AAOPD) In acetonitrile at 20℃; for 5h; | 89% |
α,α-dimethoxy-4-fluorotoluene
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
perchloric acid In methanol; water at 25 - 30℃; for 0.166667h; | 90% |
With water In methanol at 25 - 30℃; for 0.166667h; | 90% |
Conditions | Yield |
---|---|
With dimethyl amine at 60℃; for 0.166667h; | 89% |
With sodium perchlorate; water In acetonitrile at 25℃; Kinetics; | |
Multi-step reaction with 2 steps 1: 94 percent / 14 h / 70 °C 2: H2O / Acid hydrolysis View Scheme |
(±)-2-[(4-fluorobenzyl)oxy]tetrahydropyran
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With 1-n-butylpyridinium tetrachloroferrate; pyridinium chlorochromate at 50℃; for 0.166667h; | 89% |
With trichloroisocyanuric acid In acetonitrile Reflux; |
Conditions | Yield |
---|---|
With N,N,N,N,-tetramethylethylenediamine; hydrogen; palladium diacetate; propyl di-tert-butylphosphinite In toluene at 100℃; under 3750.38 Torr; for 20h; Inert atmosphere; | 88% |
With 4-methoxy-N'-tetramethylethylenediamine; hydrogen; catacxium A; palladium diacetate In toluene at 100℃; under 3750.3 Torr; for 16h; | 89 % Chromat. |
With N,N,N,N,-tetramethylethylenediamine; hydrogen; catacxium A; palladium diacetate In toluene at 100℃; under 3750.38 Torr; for 16h; | 89 % Chromat. |
With N,N,N,N,-tetramethylethylenediamine; C6H6*C48H78O2P2Pd; hydrogen In toluene at 20 - 100℃; under 3750.38 Torr; Inert atmosphere; Autoclave; | 95 %Chromat. |
With N,N,N,N,-tetramethylethylenediamine; hydrogen; palladium diacetate; catacxium A In toluene at 120℃; under 9000.9 Torr; Flow reactor; Green chemistry; | 86 %Chromat. |
Conditions | Yield |
---|---|
With dichloro [1,1'-bis(diphenylphosphino)propane]palladium(II); 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide at 80℃; under 7500.75 Torr; for 20h; Autoclave; Green chemistry; | 88% |
With rhodium(III) iodide; hydrogen; acetic anhydride; triethylamine; triphenylphosphine In N,N-dimethyl acetamide at 100℃; for 24h; Autoclave; | 84% |
With carbon supported Pd nanoparticles; 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 80℃; under 7500.75 Torr; for 12h; Sealed tube; Green chemistry; | 76% |
Conditions | Yield |
---|---|
With rhodium(III) chloride trihydrate; hydrogen; triethylamine; triphenylphosphine In N,N-dimethyl acetamide at 90℃; under 7500.75 Torr; for 12h; Autoclave; | 88% |
Conditions | Yield |
---|---|
With pyridine; 1,3-bis-(diphenylphosphino)propane; hydrogen; palladium diacetate In dimethyl sulfoxide at 120℃; under 15001.5 Torr; for 0.716667h; Flow reactor; | 87% |
Conditions | Yield |
---|---|
With C25H19(1+)*BF4(1-) In dichloromethane at 20℃; for 1.5h; Reagent/catalyst; Schlenk technique; Inert atmosphere; | A 86% B 22% |
Conditions | Yield |
---|---|
Stage #1: 4-fluorobenzonitrile With diisobutylaluminium hydride In toluene at 0℃; for 0.00555556h; Flow reactor; Stage #2: With water; sodium L-tartrate In toluene at 0℃; chemoselective reaction; | 85% |
With lithium diisobutyl-iso-propoxyaluminium hydride In tetrahydrofuran; hexane at 20℃; for 1h; | 99 %Chromat. |
With lithium diisobutylmorpholinoaluminum hydride In tetrahydrofuran; hexane at 0℃; for 0.5h; | 99 %Chromat. |
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With methanol; sodium tetrahydroborate; nickel(II) chloride hexahydrate at 20℃; for 1.5h; | 85% |
With eosin Y disodium salt In acetonitrile at 20℃; for 3h; Irradiation; | 50% |
4-fluorobenzaldehyde
4-fluoro-3-nitrobenzaldehyde
Conditions | Yield |
---|---|
With sulfuric acid; nitric acid | 100% |
With sulfuric acid; nitric acid at 20℃; for 3h; | 99% |
With sulfuric acid; nitric acid at -5 - 20℃; for 1h; | 98% |
morpholine
4-fluorobenzaldehyde
(4-fluorophenyl)(morpholino)methane thione
Conditions | Yield |
---|---|
With sulfur In N,N-dimethyl-formamide at 110℃; for 2.5h; | 100% |
With sulfur In neat (no solvent) at 100℃; for 2h; Kindler Reaction; Green chemistry; | 96% |
With sulfur In dimethyl sulfoxide at 20℃; for 6h; | 81% |
With sulfur In N,N-dimethyl-formamide for 0.0333333h; Microwave irradiation; | 80% |
With toluene-4-sulfonic acid; sulfur at 60℃; for 4h; |
Conditions | Yield |
---|---|
With 1-(3-silica-supported propyl)-3-[(3-{[1-(3-silica-supported propyl)-4,5-dihydro-1H-imidazol-3-ium-3-yl]methyl}-2,4,6-trimethylphenyl)methyl]-4,5-dihydro-1H-imidazol-3-ium chloride at 100℃; for 4h; Knoevenagel condensation; | 100% |
With 2C9H3O6(3-)*2C27H18N6*3Ni(2+)*15H2O*5C2H6O In dichloromethane at 60℃; for 2h; Knoevenagel Condensation; Inert atmosphere; | 100% |
With N,N-dimethyl-N-hydroxyethylammonium acetate at 20℃; for 0.0333333h; Knoevenagel Condensation; | 99% |
acetic anhydride
4-fluorobenzaldehyde
(4-fluorophenyl)methylene diacetate
Conditions | Yield |
---|---|
With titanium tetrachloride at 20℃; for 16h; screw-capped vial; Inert atmosphere; neat (no solvent); | 100% |
With indium(III) bromide at 20℃; for 0.333333h; | 98% |
With tetrafluoroboric acid at 20℃; for 0.0333333h; | 98% |
trimethylsilyl cyanide
4-fluorobenzaldehyde
2-(4-fluorophenyl)-2-(trimethylsilyloxy)acetonitrile
Conditions | Yield |
---|---|
With triethylamine at 20℃; for 24h; | 100% |
With C42H50Mg2N4 In benzene-d6 at 25℃; Glovebox; Inert atmosphere; | 99% |
at 100℃; for 6h; Glovebox; | 99% |
potassium cyanide
aniline hydrochloride
4-fluorobenzaldehyde
2-(4-fluorophenyl)-2-(phenylamino) acetonitrile
Conditions | Yield |
---|---|
In ethanol; water 1.) 1 h cooling; 2.) 20 h room temperature; | 100% |
4-fluorobenzaldehyde
4-methoxy-aniline
N-(4-fluorobenzylidene)-4-methoxyaniline
Conditions | Yield |
---|---|
In ethanol for 1h; Sonication; | 100% |
at 90 - 120℃; Irradiation; | 98% |
With magnesium sulfate In dichloromethane for 15h; Ambient temperature; | 86% |
Conditions | Yield |
---|---|
With magnesium sulfate In dichloromethane; water at 24.84℃; for 4h; | 100% |
In diethyl ether for 2h; | 74% |
Conditions | Yield |
---|---|
In benzene at 80℃; for 2h; | 100% |
In neat (no solvent) at 60℃; for 0.0666667h; Microwave irradiation; | 98% |
In diethyl ether Ambient temperature; | 87% |
4-fluorobenzaldehyde
ethyl 2-cyanoacetate
ethyl (E)-2-cyano-3-(4-fluorophenyl)-2-propenoate
Conditions | Yield |
---|---|
With 1-(3-silica-supported propyl)-3-[(3-{[1-(3-silica-supported propyl)-4,5-dihydro-1H-imidazol-3-ium-3-yl]methyl}-2,4,6-trimethylphenyl)methyl]-4,5-dihydro-1H-imidazol-3-ium chloride at 130℃; for 2h; Knoevenagel condensation; | 100% |
With polyacrylonitrile fiber functionalized with N,N-dimethyl-1,3-propanediamine In ethanol for 1.5h; Knoevenagel condensation; Reflux; | 99% |
With N-(propylcarbamoyl)sulfamic acid bonded on silica at 100℃; for 0.25h; | 97% |
Conditions | Yield |
---|---|
With sodium hydroxide In water at 65℃; for 2h; | 100% |
With sodium hydroxide In ethanol; water at 20℃; Claisen-Schmidt Condensation; Inert atmosphere; | 98% |
With sodium hydroxide In water at 4 - 20℃; for 2h; Claisen-Schmidt condensation; Inert atmosphere; | 87% |
4-fluorobenzaldehyde
benzylamine
N-(4-fluorophenylmethylene)-benzylamine
Conditions | Yield |
---|---|
for 6h; Molecular sieve; Reflux; | 100% |
With sodium sulfate In dichloromethane for 1h; Ambient temperature; | 88.6% |
With magnesium sulfate In dichloromethane Molecular sieve; Inert atmosphere; | 58% |
4-fluorobenzaldehyde
2-Methylacetophenone
Conditions | Yield |
---|---|
With sodium ethanolate In ethanol | 100% |
With sodium ethanolate In ethanol for 16h; Ambient temperature; |
Conditions | Yield |
---|---|
With sodium tetrahydroborate In methanol at 20℃; for 1h; | 100% |
With C24H30Cl2NPRuS2; potassium tert-butylate; hydrogen In dichloromethane; toluene at 80℃; under 15001.5 Torr; for 5h; Autoclave; | 100% |
With C55H44O2P4Ru; hydrogen In toluene at 80℃; under 38002.6 Torr; for 18h; Glovebox; Autoclave; | 99% |
4-fluorobenzaldehyde
di[1-hydroxy(4-fluorophenyl)methyl]peroxide
Conditions | Yield |
---|---|
With dihydrogen peroxide for 1h; Ambient temperature; | 100% |
With dihydrogen peroxide In water at 0 - 20℃; | 98% |
cyclohexanone
4-fluorobenzaldehyde
2-(4-fluorobenzylidene)cyclohexanone
Conditions | Yield |
---|---|
sodium hydroxide In water at 90 - 95℃; for 3h; | 100% |
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 120℃; for 4.5h; Substitution; | 100% |
Stage #1: thiophenol With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 0.25h; Stage #2: 4-fluorobenzaldehyde In N,N-dimethyl-formamide at 80℃; for 6h; | 96% |
With potassium carbonate In dimethyl sulfoxide for 1h; Reflux; | 92% |
isovanillin
4-fluorobenzaldehyde
3-(4-formylphenoxy)-4-methoxybenzaldehyde
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide for 18h; Reflux; | 100% |
With potassium carbonate In N,N-dimethyl-formamide at 80℃; Inert atmosphere; | 89% |
With potassium carbonate In N,N-dimethyl-formamide for 4h; Heating; | 80% |
Conditions | Yield |
---|---|
(1S)-1-(9-piperidylfluoren-9-yl)ethanol In hexane; toluene at 0℃; for 4h; Addition; | 100% |
Stage #1: diethylzinc In toluene at 0℃; for 0.5h; Inert atmosphere; Stage #2: 4-fluorobenzaldehyde In toluene at 0℃; for 6h; Inert atmosphere; Stage #3: With ammonium chloride In water; toluene at 0℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction; | 92% |
Stage #1: diethylzinc With (Sa)-1-[2-diphenylhydroxymethyl-6-(trifluoromethyl)phenyl]-2-(1-pyrrolidinomethyl)-1H-pyrrole In hexane at 20℃; for 1h; Inert atmosphere; Stage #2: 4-fluorobenzaldehyde In hexane at 0℃; for 16h; Inert atmosphere; enantioselective reaction; | 91% |
hexamethylene imine
4-fluorobenzaldehyde
4-(hexamethylenimin-1-yl)benzaldehyde
Conditions | Yield |
---|---|
In acetonitrile for 16h; Heating / reflux; | 100% |
With potassium carbonate In dimethyl sulfoxide for 0.25h; ultrasound; | 95% |
With tetrabutylammomium bromide; potassium carbonate In dimethyl sulfoxide at 90℃; for 48h; | 83% |
4-fluorobenzaldehyde
1,2-bis(4-fluorophenyl)-1,2-ethanediol
Conditions | Yield |
---|---|
With (t-BuOK)3FeK; magnesium In tetrahydrofuran at 20℃; for 12h; | 100% |
With aluminium; potassium hydroxide In methanol at 0℃; for 1h; Inert atmosphere; | 100% |
With ZnIn2S4; triethylamine In water; acetonitrile for 0.5h; Sealed tube; Sonication; Irradiation; Inert atmosphere; | 99% |
4-fluorobenzaldehyde
acrylic acid methyl ester
methyl 3-(4-fluorophenyl)-3-hydroxy-2-methylenepropanoate
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane at 20℃; for 3.5h; Baylis-Hillman reaction; neat (no solvent); | 100% |
With 1,4-diaza-bicyclo[2.2.2]octane; 1-n-butyl-2,3-dimethylimidazolium hexafluorophosphate at 20℃; for 24h; Baylis-Hillman; | 99% |
With 1,4-diaza-bicyclo[2.2.2]octane In methanol at 0℃; for 48h; Baylis-Hillman reaction; | 99% |
Conditions | Yield |
---|---|
With sodium hydroxide; hydroxylamine hydrochloride In ethanol for 3h; | 100% |
With hydroxylamine hydrochloride In tetrahydrofuran; etanol; water at 20℃; for 0.416667h; | 100% |
With hydroxylamine hydrochloride; sodium carbonate In ethanol at 20℃; | 100% |
4-fluorobenzaldehyde
[(4-fluorophenyl)methylidene]hydrazine
Conditions | Yield |
---|---|
With hydrazine hydrate In ethanol for 1h; Reflux; Inert atmosphere; | 100% |
With hydrazine hydrate In methanol at 20℃; for 1h; | 99% |
With hydrazine hydrate In ethanol |
4-fluorobenzaldehyde
allyl alcohol
1-(4-fluorophenyl)-3-buten-1-ol
Conditions | Yield |
---|---|
With indium(III) chloride; indium; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; water at 20℃; for 20h; | 100% |
4-fluorobenzaldehyde
ethyl (triphenylphosphoranylidene)acetate
ethyl 4-fluorocinnamate
Conditions | Yield |
---|---|
In dichloromethane at 20 - 25℃; for 16h; Inert atmosphere; | 100% |
In dichloromethane at 20℃; for 16h; | 98% |
In dichloromethane at 20℃; | 93% |
4-fluorobenzaldehyde
2-(4-(3,4-dichlorophenyl)piperazino)-4-hydroxy-1,6-dihydro-6-oxopyridine-3-carboxylic acid ethyl ester
Conditions | Yield |
---|---|
With piperidine In ethanol for 3h; Heating; | 100% |
4-fluorobenzaldehyde
thiophenol
1-((4-fluorophenyl)(phenylthio)methylthio)benzene
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In toluene at 120℃; for 15h; Inert atmosphere; Schlenk technique; | 100% |
In chloroform at 20℃; | 77% |
With boron trifluoride diethyl etherate In chloroform at 25℃; for 1h; | 75% |
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