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Nanyang Junhao Chemical Co.,Ltd

4-Fluorobenzaldehyde Product name: 4-Fluorobenzaldehyde CAS: 459-57-4 Structural formula: Quality specification: Appearance: Colorless to pale yellow liquid Content: 99.5%(Gc)min Free acid:0.3% max Isomer:0.1%max Flash Point: 56℃ Freezing Point:

4-Fluorobenzaldehyde Spot goods

Cas:459-57-4

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/2161.html Product Name 4-Fluorobenzaldehyde CAS No. 459-57-4

4-Fluorobenzaldehyde

Cas:459-57-4

Min.Order:1 Metric Ton

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

High Quality 4-Fluorobenzaldehyde 459-57-4 Manufacturer

Cas:459-57-4

Min.Order:1 Kilogram

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

4-Fluorobenzaldehyde Manufacturer/High quality/Best price/In stock

Cas:459-57-4

Min.Order:1 Kilogram

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Fluorobenzaldehyde supplier in China

Cas:459-57-4

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

4-Fluorobenzaldehyde

Cas:459-57-4

Min.Order:1 Kilogram

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EAST CHEMSOURCES LIMITED

4-Fluorobenzaldehyde Product name: 4-Fluorobenzaldehyde CAS: 459-57-4 Structural formula: Quality specification: Appearance: Colorless to pale yellow liquid Content: 99.5%(Gc)min Free acid:0.3% max Isomer:0.1%max Flash Point: 56℃

4-Fluorobenzaldehyde

Cas:459-57-4

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-fluorobenzaldehyde

Cas:459-57-4

Min.Order:1

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% 4-Fluorobenzaldehyde 459-57-4 ISO Producer

Cas:459-57-4

Min.Order:1 Gram

FOB Price: $0.1

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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

4-Fluorobenzaldehyde Manufacturer/High quality/Best price/In stock

Cas:459-57-4

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

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Chemwill Asia Co., Ltd.

4-Fluorobenzaldehyde -- CHemwill

Cas:459-57-4

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Product Name: 4-Fluorobenzaldehyde Synonyms: 4-fluoro-benzaldehyd;Benzaldehyde, p-fluoro-;PFAD;PFBA;P-FLUOROBENZALDEHYDE;PARA FLUOROBENZALDEHYDE;FLUOROBENZALDEHYDE(4-);LABOTEST-BB LT00930357 CAS: 459-57-4 MF: C7H5FO MW: 124.11 EINECS: 207-293-

4-Fluorobenzaldehyde 459-57-4

Cas:459-57-4

Min.Order:1 Kilogram

FOB Price: $500.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

4-Fluorobenzaldehyde CAS: 459-57-4

Cas:459-57-4

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 459-57-4 with best quality

Cas:459-57-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

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Henan Sinotech Import&Export Corporation

Product Name: 4-Fluorobenzaldehyde Synonyms: 4-fluoro-benzaldehyd;Benzaldehyde, p-fluoro-;PFAD;PFBA;P-FLUOROBENZALDEHYDE;PARA FLUOROBENZALDEHYDE;FLUOROBENZALDEHYDE(4-);LABOTEST-BB LT00930357 C

4-Fluorobenzaldehyde CAS: 459-57-4

Cas:459-57-4

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

4-Fluorobenzaldehyde 459-57-4

Cas:459-57-4

Min.Order:1 Kilogram

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HANWAYS CHEMPHARM CO.,LIMITED

We have two GMP facilities in Hubei Province and cooperative factories in Zhejiang Province We are concentrating on the R&D and technical service of APIs and pharmaceutical intermediates We strive to provide world-class service for every client

4-Fluorobenzaldehyde CAS#459-57-4

Cas:459-57-4

Min.Order:1 Kilogram

FOB Price: $1.0

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

459-57-44-Fluorobenzaldehyde

Cas:459-57-4

Min.Order:1 Kilogram

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Qingdao Beluga Import and Export Co., LTD

4-Fluorobenzaldehyde CAS:459-57-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inter

4-Fluorobenzaldehyde CAS:459-57-4

Cas:459-57-4

Min.Order:1 Gram

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

4-Fluorobenzaldehyde

Cas:459-57-4

Min.Order:1 Kilogram

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS 459-57-4 4-Fluorobenzaldehyde

Cas:459-57-4

Min.Order:1 Kilogram

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Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biological Technology Co., Ltd. is specialize in the production of chemical raw materials and reagents,located in Shijiazhuang, Hebei Province. In recent decades, under the efforts of all staff, in Shandong, Henan, Guangdong and many othe

4-Fluorobenzaldehyde CAS 459-57-4

Cas:459-57-4

Min.Order:1 Kilogram

FOB Price: $20.0 / 40.0

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

4-Fluorobenzaldehyde

Cas:459-57-4

Min.Order:1 Kilogram

FOB Price: $6.0 / 10.0

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

4-Fluorobenzaldehyde

Cas:459-57-4

Min.Order:0

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

4-Fluorobenzaldehyde CAS.459-57-4

Cas:459-57-4

Min.Order:10 Kilogram

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Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

4-Fluorobenzaldehyde CAS NO.459-57-4

Cas:459-57-4

Min.Order:10 Gram

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and quality c

4-Fluorobenzaldehyde

Cas:459-57-4

Min.Order:100 Metric Ton

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Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

4-Fluorobenzaldehyde

Cas:459-57-4

Min.Order:1 Gram

FOB Price: $1.0 / 100000.0

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Fluorobenzaldehyde

Cas:459-57-4

Min.Order:0 Metric Ton

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Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

Name 4-Fluorobenzaldehyde Molecular Structure Molecular Formula C7H5FO Molecular Weight 12

4-Fluorobenzaldehyde

Cas:459-57-4

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Synthetic route

p-fluorotoluene
352-32-9

p-fluorotoluene

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With cerium(IV) triflate; water at 20℃; for 22h;100%
With Xylaria polymorpha laccase; 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonate) diammonium salt In 1,4-dioxane at 20℃; for 1.83333h; pH=4.5; Green chemistry; Enzymatic reaction;96%
With cobalt(II) acetate; acetic acid; potassium bromide at 120℃; under 15001.5 Torr; for 2.5h; Reagent/catalyst; Temperature; Pressure; Autoclave;95%
4-fluorobenzylic alcohol
459-56-3

4-fluorobenzylic alcohol

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With oxygen; perruthenate modified mesoporous silicate MCM-41 In toluene at 80℃; for 1h; Oxidation;100%
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; oxygen; copper(I) bromide dimethylsulfide complex In chlorobenzene at 90℃; for 6h;100%
With iron(III) chloride; 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; oxygen; sodium nitrite In 1,2-dichloro-ethane at 50℃; under 3000.3 Torr; for 5h; Autoclave;99%
4-fluorobenzaldoxime
459-23-4

4-fluorobenzaldoxime

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With phosphoric acid In ethanol at 25℃; for 0.25h; Sonication; Green chemistry;99%
With N,N'-dichlorophenobarbital In acetonitrile at 20℃; for 0.233333h;96%
With water; Dess-Martin periodane In dichloromethane at 5℃; for 0.0333333h;95%
para-fluorostyrene
405-99-2

para-fluorostyrene

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With sodium periodate; C53H44As2N2O3Ru In water; ethyl acetate; acetonitrile at 25℃; for 0.5h;99%
With dihydrogen peroxide In water at 100℃; for 4h;92%
With sodium periodate; C31H29Br2N3Ru*CH2Cl2 In water; ethyl acetate; acetonitrile at 25℃; for 0.5h; Inert atmosphere; Schlenk technique;92%
p-fluorobenzyl acetate
502-00-1

p-fluorobenzyl acetate

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With methanol; potassium permanganate In ethyl acetate at 25℃; for 20h;99%
para-fluorobenzylamine
140-75-0

para-fluorobenzylamine

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; laccasefrom Trametes versicolor; oxygen In water at 30℃; for 24h; pH=4.5; Enzymatic reaction;97%
With sodium periodate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; acetic acid; trifluoroacetic acid In water; acetonitrile for 20h;93%
With cercosporin; oxygen In methanol at 20℃; Schlenk technique; Irradiation; Green chemistry; chemoselective reaction;87%
(4-fluorophenyl)methylene diacetate
64002-52-4

(4-fluorophenyl)methylene diacetate

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With indium(III) bromide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 20℃; for 0.416667h;97%
With bovine liver acetone powder In aq. phosphate buffer; acetone at 20℃; for 0.333333h; pH=7.4; Enzymatic reaction; chemoselective reaction;97%
With sodium hydrogen sulfate; PEG-2000 at 70℃; for 0.416667h;95%
4-fluorobenzylic alcohol
459-56-3

4-fluorobenzylic alcohol

di(p-tolyl) sulfoxide
1774-35-2

di(p-tolyl) sulfoxide

A

di-(p-tolyl)sulfane
620-94-0

di-(p-tolyl)sulfane

B

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With per-rhenic acid In toluene for 17h; Reflux;A 97%
B 90%
4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In tetrahydrofuran for 0.166667h; Inert atmosphere; Microwave irradiation;95%
With tetrabutyl ammonium fluoride In tetrahydrofuran for 10h; Inert atmosphere; Reflux; chemoselective reaction;82.1 %Chromat.
Multi-step reaction with 2 steps
1: benzene-d6 / 23 °C / Inert atmosphere
2: benzene-d6 / 2 h / 60 °C
View Scheme
4-hydroxy-benzaldehyde
123-08-0

4-hydroxy-benzaldehyde

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With 1,3-bis(2,6-diisopropylphenyl)-2,2-difluoro-2,3-dihydro-1h-imidazole; cesium fluoride In toluene at 80℃; for 3h; Product distribution / selectivity; Sealed vial;95%
With 1,3-bis(2,6-diisopropylphenyl)-2,2-difluoro-2,3-dihydro-1h-imidazole; cesium fluoride In toluene at 23 - 80℃; for 3.5h; Inert atmosphere;95 %Spectr.
4,4'-difluorodeoxybenzoin
366-68-7

4,4'-difluorodeoxybenzoin

aniline
62-53-3

aniline

A

4-fluoro-N-phenylbenzamide
366-63-2

4-fluoro-N-phenylbenzamide

B

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With 1,10-Phenanthroline; copper(II) chloride dihydrate; oxygen In acetonitrile under 760.051 Torr; for 24h; Reflux;A 95%
B 96 %Chromat.
4-Fluorobenzoic acid
456-22-4

4-Fluorobenzoic acid

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With (CH3)2NCH2NpSiH2Ph at 110 - 140℃;94%
With dipotassium hydrogenphosphate; fac-tris(2-phenylpyridinato-N,C2')iridium(III); tris-(trimethylsilyl)silane; dimethyl dicarbonate In acetonitrile at 20℃; for 6h; Schlenk technique; Inert atmosphere; Sealed tube; Irradiation;89%
With palladium(II) acetylacetonate; hydrogen; 2,2-dimethylpropanoic anhydride; dicyclohexylphenylphosphine In tetrahydrofuran at 80℃; under 3750.38 Torr; for 20h; Inert atmosphere;80%
2-(4-fluorophenyl)-1,3-dithiolane
83521-64-6

2-(4-fluorophenyl)-1,3-dithiolane

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With 1,3,5-trichloro-2,4,6-triazine; dimethyl sulfoxide In dichloromethane at 20℃; for 3.5h;93%
1-(dibromomethyl)-4-fluorobenzene
6425-24-7

1-(dibromomethyl)-4-fluorobenzene

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With dimethyl sulfoxide at 120℃; for 12h;93%
With dimethyl amine at 60℃; for 0.166667h;86%
1-(dibromomethyl)-4-fluorobenzene
6425-24-7

1-(dibromomethyl)-4-fluorobenzene

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
at 120℃; for 12h;93%
4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

carbon monoxide
201230-82-2

carbon monoxide

A

fluorobenzene
462-06-6

fluorobenzene

B

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With hydrogen; potassium carbonate In 1,4-dioxane at 120 - 140℃; under 30003 Torr; for 20h; Autoclave;A 7%
B 91%
1-chloromethyl-4-fluorobenzene
352-11-4

1-chloromethyl-4-fluorobenzene

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With (NH4)4[ZnMo6O18(OH)6]; oxygen In water; acetonitrile at 60℃; under 760.051 Torr; for 12h;90%
With water; sodium hydroxide at 20℃; for 0.0833333h; Microwave irradiation;88%
With bismuth(III) nitrate; tetrabutyl ammonium fluoride at 100℃; for 4h;87%
p-Fluorophenylacetic acid
405-50-5

p-Fluorophenylacetic acid

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With 1H-imidazole; C17H16ClMnN2O2; tetrabutylammonium periodite In chloroform at 20℃; for 0.416667h;90%
With potassium 12-tungstocobaltate(III) In water; acetonitrile for 0.3h; Microwave irradiation;90%
With 1H-imidazole; [bis(acetoxy)iodo]benzene; Co(AAOPD) In acetonitrile at 20℃; for 5h;89%
α,α-dimethoxy-4-fluorotoluene
32691-93-3

α,α-dimethoxy-4-fluorotoluene

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
perchloric acid In methanol; water at 25 - 30℃; for 0.166667h;90%
With water In methanol at 25 - 30℃; for 0.166667h;90%
4-fluorobenzal chloride
456-19-9

4-fluorobenzal chloride

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With dimethyl amine at 60℃; for 0.166667h;89%
With sodium perchlorate; water In acetonitrile at 25℃; Kinetics;
Multi-step reaction with 2 steps
1: 94 percent / 14 h / 70 °C
2: H2O / Acid hydrolysis
View Scheme
(±)-2-[(4-fluorobenzyl)oxy]tetrahydropyran
18539-44-1

(±)-2-[(4-fluorobenzyl)oxy]tetrahydropyran

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With 1-n-butylpyridinium tetrachloroferrate; pyridinium chlorochromate at 50℃; for 0.166667h;89%
With trichloroisocyanuric acid In acetonitrile Reflux;
carbon monoxide
201230-82-2

carbon monoxide

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; hydrogen; palladium diacetate; propyl di-tert-butylphosphinite In toluene at 100℃; under 3750.38 Torr; for 20h; Inert atmosphere;88%
With 4-methoxy-N'-tetramethylethylenediamine; hydrogen; catacxium A; palladium diacetate In toluene at 100℃; under 3750.3 Torr; for 16h;89 % Chromat.
With N,N,N,N,-tetramethylethylenediamine; hydrogen; catacxium A; palladium diacetate In toluene at 100℃; under 3750.38 Torr; for 16h;89 % Chromat.
With N,N,N,N,-tetramethylethylenediamine; C6H6*C48H78O2P2Pd; hydrogen In toluene at 20 - 100℃; under 3750.38 Torr; Inert atmosphere; Autoclave;95 %Chromat.
With N,N,N,N,-tetramethylethylenediamine; hydrogen; palladium diacetate; catacxium A In toluene at 120℃; under 9000.9 Torr; Flow reactor; Green chemistry;86 %Chromat.
4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

carbon dioxide
124-38-9

carbon dioxide

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With dichloro [1,1'-bis(diphenylphosphino)propane]palladium(II); 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide at 80℃; under 7500.75 Torr; for 20h; Autoclave; Green chemistry;88%
With rhodium(III) iodide; hydrogen; acetic anhydride; triethylamine; triphenylphosphine In N,N-dimethyl acetamide at 100℃; for 24h; Autoclave;84%
With carbon supported Pd nanoparticles; 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 80℃; under 7500.75 Torr; for 12h; Sealed tube; Green chemistry;76%
4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

carbon monoxide
201230-82-2

carbon monoxide

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With rhodium(III) chloride trihydrate; hydrogen; triethylamine; triphenylphosphine In N,N-dimethyl acetamide at 90℃; under 7500.75 Torr; for 12h; Autoclave;88%
carbon monoxide
201230-82-2

carbon monoxide

4-fluorophenyl fluorosulfate

4-fluorophenyl fluorosulfate

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With pyridine; 1,3-bis-(diphenylphosphino)propane; hydrogen; palladium diacetate In dimethyl sulfoxide at 120℃; under 15001.5 Torr; for 0.716667h; Flow reactor;87%
(E)-2-(3-(4-fluorophenyl)allyl)benzaldehyde

(E)-2-(3-(4-fluorophenyl)allyl)benzaldehyde

A

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

B

1-indene
95-13-6

1-indene

Conditions
ConditionsYield
With C25H19(1+)*BF4(1-) In dichloromethane at 20℃; for 1.5h; Reagent/catalyst; Schlenk technique; Inert atmosphere;A 86%
B 22%
4-fluorobenzonitrile
1194-02-1

4-fluorobenzonitrile

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
Stage #1: 4-fluorobenzonitrile With diisobutylaluminium hydride In toluene at 0℃; for 0.00555556h; Flow reactor;
Stage #2: With water; sodium L-tartrate In toluene at 0℃; chemoselective reaction;
85%
With lithium diisobutyl-iso-propoxyaluminium hydride In tetrahydrofuran; hexane at 20℃; for 1h;99 %Chromat.
With lithium diisobutylmorpholinoaluminum hydride In tetrahydrofuran; hexane at 0℃; for 0.5h;99 %Chromat.
2-(4-fluorophenyl)-1,3-oxathiolane

2-(4-fluorophenyl)-1,3-oxathiolane

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

Conditions
ConditionsYield
With methanol; sodium tetrahydroborate; nickel(II) chloride hexahydrate at 20℃; for 1.5h;85%
With eosin Y disodium salt In acetonitrile at 20℃; for 3h; Irradiation;50%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

4-fluoro-3-nitrobenzaldehyde
42564-51-2

4-fluoro-3-nitrobenzaldehyde

Conditions
ConditionsYield
With sulfuric acid; nitric acid100%
With sulfuric acid; nitric acid at 20℃; for 3h;99%
With sulfuric acid; nitric acid at -5 - 20℃; for 1h;98%
morpholine
110-91-8

morpholine

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

(4-fluorophenyl)(morpholino)methane thione
73239-00-6

(4-fluorophenyl)(morpholino)methane thione

Conditions
ConditionsYield
With sulfur In N,N-dimethyl-formamide at 110℃; for 2.5h;100%
With sulfur In neat (no solvent) at 100℃; for 2h; Kindler Reaction; Green chemistry;96%
With sulfur In dimethyl sulfoxide at 20℃; for 6h;81%
With sulfur In N,N-dimethyl-formamide for 0.0333333h; Microwave irradiation;80%
With toluene-4-sulfonic acid; sulfur at 60℃; for 4h;
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

malononitrile
109-77-3

malononitrile

4-fluorobenzylidenemalononitrile
2826-22-4

4-fluorobenzylidenemalononitrile

Conditions
ConditionsYield
With 1-(3-silica-supported propyl)-3-[(3-{[1-(3-silica-supported propyl)-4,5-dihydro-1H-imidazol-3-ium-3-yl]methyl}-2,4,6-trimethylphenyl)methyl]-4,5-dihydro-1H-imidazol-3-ium chloride at 100℃; for 4h; Knoevenagel condensation;100%
With 2C9H3O6(3-)*2C27H18N6*3Ni(2+)*15H2O*5C2H6O In dichloromethane at 60℃; for 2h; Knoevenagel Condensation; Inert atmosphere;100%
With N,N-dimethyl-N-hydroxyethylammonium acetate at 20℃; for 0.0333333h; Knoevenagel Condensation;99%
acetic anhydride
108-24-7

acetic anhydride

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

(4-fluorophenyl)methylene diacetate
64002-52-4

(4-fluorophenyl)methylene diacetate

Conditions
ConditionsYield
With titanium tetrachloride at 20℃; for 16h; screw-capped vial; Inert atmosphere; neat (no solvent);100%
With indium(III) bromide at 20℃; for 0.333333h;98%
With tetrafluoroboric acid at 20℃; for 0.0333333h;98%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

2-(4-fluorophenyl)-2-(trimethylsilyloxy)acetonitrile
82128-66-3

2-(4-fluorophenyl)-2-(trimethylsilyloxy)acetonitrile

Conditions
ConditionsYield
With triethylamine at 20℃; for 24h;100%
With C42H50Mg2N4 In benzene-d6 at 25℃; Glovebox; Inert atmosphere;99%
at 100℃; for 6h; Glovebox;99%
potassium cyanide
151-50-8

potassium cyanide

aniline hydrochloride
142-04-1

aniline hydrochloride

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

2-(4-fluorophenyl)-2-(phenylamino) acetonitrile
124573-71-3

2-(4-fluorophenyl)-2-(phenylamino) acetonitrile

Conditions
ConditionsYield
In ethanol; water 1.) 1 h cooling; 2.) 20 h room temperature;100%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

4-methoxy-aniline
104-94-9

4-methoxy-aniline

N-(4-fluorobenzylidene)-4-methoxyaniline
39769-08-9, 130632-07-4

N-(4-fluorobenzylidene)-4-methoxyaniline

Conditions
ConditionsYield
In ethanol for 1h; Sonication;100%
at 90 - 120℃; Irradiation;98%
With magnesium sulfate In dichloromethane for 15h; Ambient temperature;86%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

ethylamine
75-04-7

ethylamine

(E)-N-(4-fluorobenzylidene)ethanamine
82605-86-5

(E)-N-(4-fluorobenzylidene)ethanamine

Conditions
ConditionsYield
With magnesium sulfate In dichloromethane; water at 24.84℃; for 4h;100%
In diethyl ether for 2h;74%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

N-butylamine
109-73-9

N-butylamine

(E)-N-(4-fluorobenzylidene)butan-1-amine

(E)-N-(4-fluorobenzylidene)butan-1-amine

Conditions
ConditionsYield
In benzene at 80℃; for 2h;100%
In neat (no solvent) at 60℃; for 0.0666667h; Microwave irradiation;98%
In diethyl ether Ambient temperature;87%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

ethyl 2-cyanoacetate
105-56-6

ethyl 2-cyanoacetate

ethyl (E)-2-cyano-3-(4-fluorophenyl)-2-propenoate
18861-57-9, 50737-52-5

ethyl (E)-2-cyano-3-(4-fluorophenyl)-2-propenoate

Conditions
ConditionsYield
With 1-(3-silica-supported propyl)-3-[(3-{[1-(3-silica-supported propyl)-4,5-dihydro-1H-imidazol-3-ium-3-yl]methyl}-2,4,6-trimethylphenyl)methyl]-4,5-dihydro-1H-imidazol-3-ium chloride at 130℃; for 2h; Knoevenagel condensation;100%
With polyacrylonitrile fiber functionalized with N,N-dimethyl-1,3-propanediamine In ethanol for 1.5h; Knoevenagel condensation; Reflux;99%
With N-(propylcarbamoyl)sulfamic acid bonded on silica at 100℃; for 0.25h;97%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

acetone
67-64-1

acetone

(E)-4-(4-fluorophenyl)but-3-en-2-one
65300-29-0

(E)-4-(4-fluorophenyl)but-3-en-2-one

Conditions
ConditionsYield
With sodium hydroxide In water at 65℃; for 2h;100%
With sodium hydroxide In ethanol; water at 20℃; Claisen-Schmidt Condensation; Inert atmosphere;98%
With sodium hydroxide In water at 4 - 20℃; for 2h; Claisen-Schmidt condensation; Inert atmosphere;87%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

benzylamine
100-46-9

benzylamine

N-(4-fluorophenylmethylene)-benzylamine
67907-60-2

N-(4-fluorophenylmethylene)-benzylamine

Conditions
ConditionsYield
for 6h; Molecular sieve; Reflux;100%
With sodium sulfate In dichloromethane for 1h; Ambient temperature;88.6%
With magnesium sulfate In dichloromethane Molecular sieve; Inert atmosphere;58%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

2-Methylacetophenone
577-16-2, 122382-54-1

2-Methylacetophenone

(E)-3-(4-fluorophenyl)-1-o-tolylprop-2-en-1-one

(E)-3-(4-fluorophenyl)-1-o-tolylprop-2-en-1-one

Conditions
ConditionsYield
With sodium ethanolate In ethanol100%
With sodium ethanolate In ethanol for 16h; Ambient temperature;
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

4-fluorobenzylic alcohol
459-56-3

4-fluorobenzylic alcohol

Conditions
ConditionsYield
With sodium tetrahydroborate In methanol at 20℃; for 1h;100%
With C24H30Cl2NPRuS2; potassium tert-butylate; hydrogen In dichloromethane; toluene at 80℃; under 15001.5 Torr; for 5h; Autoclave;100%
With C55H44O2P4Ru; hydrogen In toluene at 80℃; under 38002.6 Torr; for 18h; Glovebox; Autoclave;99%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

di[1-hydroxy(4-fluorophenyl)methyl]peroxide
60008-54-0

di[1-hydroxy(4-fluorophenyl)methyl]peroxide

Conditions
ConditionsYield
With dihydrogen peroxide for 1h; Ambient temperature;100%
With dihydrogen peroxide In water at 0 - 20℃;98%
cyclohexanone
108-94-1

cyclohexanone

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

2-(4-fluorobenzylidene)cyclohexanone
117601-22-6

2-(4-fluorobenzylidene)cyclohexanone

Conditions
ConditionsYield
sodium hydroxide In water at 90 - 95℃; for 3h;100%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

thiophenol
108-98-5

thiophenol

4-phenylsulfanyl-benzaldehyde
1208-88-4

4-phenylsulfanyl-benzaldehyde

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 120℃; for 4.5h; Substitution;100%
Stage #1: thiophenol With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 0.25h;
Stage #2: 4-fluorobenzaldehyde In N,N-dimethyl-formamide at 80℃; for 6h;
96%
With potassium carbonate In dimethyl sulfoxide for 1h; Reflux;92%
isovanillin
621-59-0

isovanillin

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

3-(4-formylphenoxy)-4-methoxybenzaldehyde
2748-98-3

3-(4-formylphenoxy)-4-methoxybenzaldehyde

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide for 18h; Reflux;100%
With potassium carbonate In N,N-dimethyl-formamide at 80℃; Inert atmosphere;89%
With potassium carbonate In N,N-dimethyl-formamide for 4h; Heating;80%
diethylzinc
557-20-0

diethylzinc

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

(S)-1-(4-fluorophenyl)propanol

(S)-1-(4-fluorophenyl)propanol

Conditions
ConditionsYield
(1S)-1-(9-piperidylfluoren-9-yl)ethanol In hexane; toluene at 0℃; for 4h; Addition;100%
Stage #1: diethylzinc In toluene at 0℃; for 0.5h; Inert atmosphere;
Stage #2: 4-fluorobenzaldehyde In toluene at 0℃; for 6h; Inert atmosphere;
Stage #3: With ammonium chloride In water; toluene at 0℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction;
92%
Stage #1: diethylzinc With (Sa)-1-[2-diphenylhydroxymethyl-6-(trifluoromethyl)phenyl]-2-(1-pyrrolidinomethyl)-1H-pyrrole In hexane at 20℃; for 1h; Inert atmosphere;
Stage #2: 4-fluorobenzaldehyde In hexane at 0℃; for 16h; Inert atmosphere; enantioselective reaction;
91%
hexamethylene imine
111-49-9

hexamethylene imine

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

4-(hexamethylenimin-1-yl)benzaldehyde
50333-45-4

4-(hexamethylenimin-1-yl)benzaldehyde

Conditions
ConditionsYield
In acetonitrile for 16h; Heating / reflux;100%
With potassium carbonate In dimethyl sulfoxide for 0.25h; ultrasound;95%
With tetrabutylammomium bromide; potassium carbonate In dimethyl sulfoxide at 90℃; for 48h;83%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

1,2-bis(4-fluorophenyl)-1,2-ethanediol
24133-58-2

1,2-bis(4-fluorophenyl)-1,2-ethanediol

Conditions
ConditionsYield
With (t-BuOK)3FeK; magnesium In tetrahydrofuran at 20℃; for 12h;100%
With aluminium; potassium hydroxide In methanol at 0℃; for 1h; Inert atmosphere;100%
With ZnIn2S4; triethylamine In water; acetonitrile for 0.5h; Sealed tube; Sonication; Irradiation; Inert atmosphere;99%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

methyl 3-(4-fluorophenyl)-3-hydroxy-2-methylenepropanoate
353506-65-7

methyl 3-(4-fluorophenyl)-3-hydroxy-2-methylenepropanoate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane at 20℃; for 3.5h; Baylis-Hillman reaction; neat (no solvent);100%
With 1,4-diaza-bicyclo[2.2.2]octane; 1-n-butyl-2,3-dimethylimidazolium hexafluorophosphate at 20℃; for 24h; Baylis-Hillman;99%
With 1,4-diaza-bicyclo[2.2.2]octane In methanol at 0℃; for 48h; Baylis-Hillman reaction;99%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

4-fluorobenzaldoxime
459-23-4

4-fluorobenzaldoxime

Conditions
ConditionsYield
With sodium hydroxide; hydroxylamine hydrochloride In ethanol for 3h;100%
With hydroxylamine hydrochloride In tetrahydrofuran; etanol; water at 20℃; for 0.416667h;100%
With hydroxylamine hydrochloride; sodium carbonate In ethanol at 20℃;100%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

[(4-fluorophenyl)methylidene]hydrazine
401514-49-6

[(4-fluorophenyl)methylidene]hydrazine

Conditions
ConditionsYield
With hydrazine hydrate In ethanol for 1h; Reflux; Inert atmosphere;100%
With hydrazine hydrate In methanol at 20℃; for 1h;99%
With hydrazine hydrate In ethanol
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

allyl alcohol
107-18-6

allyl alcohol

1-(4-fluorophenyl)-3-buten-1-ol
86718-78-7, 136185-86-9

1-(4-fluorophenyl)-3-buten-1-ol

Conditions
ConditionsYield
With indium(III) chloride; indium; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; water at 20℃; for 20h;100%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

ethyl (triphenylphosphoranylidene)acetate
1099-45-2

ethyl (triphenylphosphoranylidene)acetate

ethyl 4-fluorocinnamate
136265-10-6, 352-03-4, 24393-50-8

ethyl 4-fluorocinnamate

Conditions
ConditionsYield
In dichloromethane at 20 - 25℃; for 16h; Inert atmosphere;100%
In dichloromethane at 20℃; for 16h;98%
In dichloromethane at 20℃;93%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

2-(4-(3,4-dichlorophenyl)piperazino)-4-hydroxy-1,6-dihydro-6-oxopyridine-3-carboxylic acid ethyl ester
556039-75-9

2-(4-(3,4-dichlorophenyl)piperazino)-4-hydroxy-1,6-dihydro-6-oxopyridine-3-carboxylic acid ethyl ester

C43H41Cl4FN6O8

C43H41Cl4FN6O8

Conditions
ConditionsYield
With piperidine In ethanol for 3h; Heating;100%
4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

thiophenol
108-98-5

thiophenol

1-((4-fluorophenyl)(phenylthio)methylthio)benzene
175235-76-4

1-((4-fluorophenyl)(phenylthio)methylthio)benzene

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene at 120℃; for 15h; Inert atmosphere; Schlenk technique;100%
In chloroform at 20℃;77%
With boron trifluoride diethyl etherate In chloroform at 25℃; for 1h;75%
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