CAS No.67-66-3,Chloroform Suppliers,MSDS download

: 75-62-7
Bromotrichloromethane

: 110838-39-6
N,N,N',N'-Tetraisopropyl-P-methylphosphonous diamide

A: 67-66-3
chloroform

B: 124862-13-1
P-(bromomethyl)-N,N,N',N'-tetraisopropylphosphonous diamide

Conditions

Conditions	Yield
In diethyl ether for 0.25h; Ambient temperature;	A 100% B 45%
In diethyl ether for 0.25h; Ambient temperature; or P-ethyl-N,N,N',N'-tetraisopropylphosphonous diamide;	A n/a B 45%

...Expand

: 75-62-7
Bromotrichloromethane

: 122691-44-5
P-ethyl-N,N,N',N'-tetraisopropylphosphonous diamide

A: 67-66-3
chloroform

B: 124862-16-4
P-(1-bromoethyl)-N,N,N',N'-tetraisopropylphosphonous diamide

Conditions

Conditions	Yield
In diethyl ether for 0.25h; Ambient temperature;	A 100% B 45%

...Expand

: 116-16-5
1,1,1,3,3,3-hexachloro-propan-2-one

: 75-31-0
isopropylamine

A: 67-66-3
chloroform

B: 23144-67-4
N-Isopropyl-2,2,2-trichloroacetamide

Conditions

Conditions	Yield
In hexane	A n/a B 100%

...Expand

: 1768-31-6
pentachloroacetone

: 75-31-0
isopropylamine

A: 67-66-3
chloroform

B: 39063-24-6
N-Isopropyl-2,2-dichloroacetamide

Conditions

Conditions	Yield
In hexane for 0.5h;	A n/a B 100%

...Expand

: 116-16-5
1,1,1,3,3,3-hexachloro-propan-2-one

: 109-73-9
N-butylamine

A: 67-66-3
chloroform

B: 31464-96-7
trichloro-acetic acid butylamide

Conditions

Conditions	Yield
In hexane	A n/a B 100%

...Expand

: 1768-31-6
pentachloroacetone

: 74-89-5
methylamine

A: 67-66-3
chloroform

B: 5345-73-3
2,2-dichloro-N-methylacetamide

Conditions

Conditions	Yield
In hexane Heating;	A n/a B 100%

...Expand

: 64697-39-8
1,1,1,3,3-pentachlorobutanone

: 74-89-5
methylamine

A: 67-66-3
chloroform

B: 83703-95-1
2,2-Dichloro-N-methyl-propionamide

Conditions

Conditions	Yield
In hexane Heating;	A n/a B 100%

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: tris(cyclopentadienyl)zirconiumhydride

A: (π-C5H5)3ZrCl

B: 67-66-3
chloroform

Conditions

Conditions	Yield
With tetrachloromethane In toluene under Ar; excess of CCl4 added to suspension of Cp3ZrH in PhMe; stirredat about 20°C for 5 h; stored overnight at 0-5°C; sepd. by pressure; dried in an Ar stream; elem. anal.;	A 99% B 89%

: 116-16-5
1,1,1,3,3,3-hexachloro-propan-2-one

: 76-37-9
2,2,3,3-tetrafluoropropanol

A: 67-66-3
chloroform

B: 1422-70-4
bis(2,2,3,3-tetrafluoropropyl) carbonate

Conditions

Conditions	Yield
With potassium fluoride; zirconium(IV) oxide at 140℃; for 10h; Product distribution / selectivity; pressure tight reactor;	A 99% B 99%

...Expand

: 116-16-5
1,1,1,3,3,3-hexachloro-propan-2-one

: 75-89-8
2,2,2-trifluoroethanol

A: 67-66-3
chloroform

B: 1513-87-7
bis(2,2,2-trifluoroethyl) carbonate

Conditions

Conditions	Yield
With potassium fluoride; zirconium(IV) oxide at 140℃; for 10h; pressure tight reactor;	A 99% B 99%

...Expand

: 55596-11-7
N-(2,2,2-trichloroethylidene)benzenesulfonamide

: 21326-49-8
complex of sulfur dioxide with dimethylamine

A: 127-18-4
1,1,2,2-tetrachloroethylene

B: 67-66-3
chloroform

C: 13707-43-2
N,N-dimethyl-N′-(phenylsulfonyl)formimidamide

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 24h;	A n/a B n/a C 98%

...Expand

: 55596-11-7
N-(2,2,2-trichloroethylidene)benzenesulfonamide

: 109-89-7
diethylamine

A: 127-18-4
1,1,2,2-tetrachloroethylene

B: 67-66-3
chloroform

C: 29665-24-5
N1,N1-diethyl-N2-phenylsulfonylformamidine

Conditions

Conditions	Yield
In dichloromethane at 0℃; for 24h;	A n/a B n/a C 98%

...Expand

: Schwartz's reagent

A: 1291-32-3
zirconocene dichloride

B: 67-66-3
chloroform

Conditions

Conditions	Yield
With tetrachloromethane In toluene under Ar; elem. anal.;	A 98% B 62%

: 42521-52-8
Trichlormethansulfinsaeureanilid

A: 67-66-3
chloroform

B: 222851-56-1
N-phenylsulfinylamine

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile Ambient temperature;	A n/a B 97.2%

: 116-16-5
1,1,1,3,3,3-hexachloro-propan-2-one

: 107-11-9
1-amino-2-propene

A: 67-66-3
chloroform

B: 39089-56-0
2,2,2-trichloro-N-(2-propenyl)acetamide

Conditions

Conditions	Yield
In hexane for 0.5h;	A n/a B 97%

...Expand

: 116-16-5
1,1,1,3,3,3-hexachloro-propan-2-one

: 141-43-5
ethanolamine

A: 67-66-3
chloroform

B: 35234-31-2
2,2,2-trichloro-N-(2-hydroxyethyl)acetamide

Conditions

Conditions	Yield
In hexane for 0.5h;	A n/a B 96%

...Expand

: 56-23-5
tetrachloromethane

: 628-85-3
di-n-propylmercury

A: mercury(I) chloride

B: 540-54-5
1-Chloropropane

C: 67-66-3
chloroform

D: 2440-40-6
n-propylmercury(II) chloride

E: mercury

Conditions

Conditions	Yield
In neat (no solvent) 150°C, 60 h; further products;	A <1 B 96% C >99 D 5% E 95%

...Expand

: 1768-31-6
pentachloroacetone

: 141-43-5
ethanolamine

A: 67-66-3
chloroform

B: 6419-44-9
2,2-dichloro-N-(2-hydroxyethyl)acetamide

Conditions

Conditions	Yield
In hexane for 0.5h;	A n/a B 95.4%

...Expand

: 116-16-5
1,1,1,3,3,3-hexachloro-propan-2-one

: 74-89-5
methylamine

A: 67-66-3
chloroform

B: 23170-77-6
N-methyltrichloroacetamide

Conditions

Conditions	Yield
In hexane Heating;	A n/a B 95.2%

...Expand

: 56-23-5
tetrachloromethane

: 80937-33-3
oxygen

: 1071-39-2
diisopropylmercury

A: 74-98-6
propane

B: 75-29-6
isopropyl chloride

C: 67-66-3
chloroform

D: 30615-19-1
isopropylmercury(II) chloride

E: mercury

Conditions

Conditions	Yield
In neat (no solvent) 20°C, 96 h; further products;	A 4% B 48% C 30% D 95% E 5%

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: 1768-31-6
pentachloroacetone

: 109-73-9
N-butylamine

A: 67-66-3
chloroform

B: 5345-74-4
2,2-dichloro-N-butylacetamide

Conditions

Conditions	Yield
In hexane	A n/a B 93.9%

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: 64697-39-8
1,1,1,3,3-pentachlorobutanone

: 141-43-5
ethanolamine

A: 67-66-3
chloroform

B: 83704-00-1
2,2-Dichloro-N-(2-hydroxy-ethyl)-propionamide

Conditions

Conditions	Yield
In hexane for 0.5h;	A n/a B 93.5%

...Expand

: 64697-39-8
1,1,1,3,3-pentachlorobutanone

: 107-11-9
1-amino-2-propene

A: 67-66-3
chloroform

B: 83703-99-5
N-Allyl-2,2-dichloro-propionamide

Conditions

Conditions	Yield
In hexane for 0.5h;	A n/a B 93.5%

...Expand

: 116-16-5
1,1,1,3,3,3-hexachloro-propan-2-one

: 64-17-5
ethanol

: 76-37-9
2,2,3,3-tetrafluoropropanol

A: 67-66-3
chloroform

B: 2062-06-8
2,2,3,3-Tetrafluor-propyl-propionat

Conditions

Conditions	Yield
Stage #1: 1,1,1,3,3,3-hexachloro-propan-2-one; ethanol With potassium fluoride at 30℃; for 1h; pressure tight reactor; Stage #2: 2,2,3,3-tetrafluoropropanol at 100℃;	A 93% B 74%

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: 1768-31-6
pentachloroacetone

: 110-58-7
1-pentanamine

A: 67-66-3
chloroform

B: 83703-97-3
N-Pentyl-2,2-dichloroacetamide

Conditions

Conditions	Yield
In hexane for 0.5h;	A n/a B 92%

...Expand

: 64697-39-8
1,1,1,3,3-pentachlorobutanone

: 110-58-7
1-pentanamine

A: 67-66-3
chloroform

B: 83703-98-4
2,2-Dichloro-N-pentyl-propionamide

Conditions

Conditions	Yield
In hexane for 0.5h;	A n/a B 92%

...Expand

: 55596-11-7
N-(2,2,2-trichloroethylidene)benzenesulfonamide

: 124-40-3
dimethyl amine

A: 127-18-4
1,1,2,2-tetrachloroethylene

B: 67-66-3
chloroform

C: 13707-43-2
N,N-dimethyl-N′-(phenylsulfonyl)formimidamide

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 24h;	A n/a B n/a C 92%

...Expand

: 112-30-1
1-Decanol

: 1768-31-6
pentachloroacetone

A: 67-66-3
chloroform

B: 83005-00-9
decyl 2,2-dichloroacetate

Conditions

Conditions	Yield
With triethylamine Heating;	A n/a B 91.4%

...Expand

: 56-23-5
tetrachloromethane

: 1071-39-2
diisopropylmercury

A: mercury(I) chloride

B: 75-29-6
isopropyl chloride

C: 67-66-3
chloroform

D: 30615-19-1
isopropylmercury(II) chloride

E: mercury

Conditions

Conditions	Yield
In neat (no solvent) 130°C, 10 h; further products;	A 3% B 51% C 50% D 91% E 3%

...Expand

: 292638-84-7
styrene

: 67-66-3
chloroform

: 2415-80-7
1,1-dichloro-2-phenylcyclopropane

Conditions

Conditions	Yield
With potassium hydroxide; tetrabutylammomium bromide; 1,3,5-trimethyl-benzene In dichloromethane at 40℃; for 6h;	100%
With PEG-supported tetrakis ammonium salt In dichloromethane at 25℃; for 0.5h;	98%
With tetrabutylammomium bromide; sodium hydroxide In dichloromethane at 20℃; for 0.0833333h;	96%

: 67-66-3
chloroform

: 110-83-8
cyclohexene

: 823-69-8
7,7-dichloro-bicyclo[4.1.0]heptane

Conditions

Conditions	Yield
With sodium hydroxide; Sucrose-ethyleneoxide adducts In chloroform at 20℃; for 2h; Product distribution; further catalysts: PEG, DB18K6; further objects of study: phase-transfer catalysis;;	100%
With sodium hydroxide; Sucrose-ethyleneoxide adducts In chloroform at 20℃; for 2h; Product distribution; further catalysts: PEG, DB18K6;	100%
With potassium hydroxide; 18-crown-6 ether In dichloromethane at 40℃; for 6h;	98%

: 292638-84-7
styrene

: 67-66-3
chloroform

: 42956-39-8
1,1,3-trichloro-3-phenylpropane

Conditions

Conditions	Yield
With Grubbs catalyst first generation at 65℃; for 2h;	100%
Grubbs catalyst first generation at 65 - 80℃; Kharasch addition;	99%
With N2[(RuCl2)2(1,3,5-iPr3C6H3)(tricyclohexylphosphine]2 In toluene at 40℃; for 48h;	93%

: 67-66-3
chloroform

: 83466-54-0, 93602-74-5, 79073-99-7
Bis(2,4,6-tri-tert-butylphenyl)diphosphen

: 111888-01-8, 126976-48-5
1,2-bis(2,4,6-tri-tert-butylphenyl)3,3-dichloro diphosphirane

Conditions

Conditions	Yield
With potassium hydroxide In hexane at 15℃; for 2h; sonication;	100%
With potassium tert-butylate

: 67-66-3
chloroform

: 132067-80-2
3,3-Diethyl-6,7-dimethoxy-1-phenyl-3,4-dihydro-isoquinoline

: 132067-87-9
6,7-Dimethoxy-8bphenyl-1,1-dichloro-3,3-diethyl-1,3,4,8b-tetrahydroazirino<2,1-a>isoquinoline

Conditions

Conditions	Yield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In hexane 1) 3 h, 12 deg C 2) 1 h, 20 deg C;	100%

: 67-66-3
chloroform

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: Vilsmeier-Haack reagent

Conditions

Conditions	Yield
With trichlorophosphate at 20℃; for 0.5h;	100%

: 67-66-3
chloroform

: 156-43-4
4-Ethoxyaniline

: 67-64-1
acetone

: 74262-33-2
α-p-phenetidino-isobutyric acid p-phenetidide

Conditions

Conditions	Yield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In dichloromethane at 5℃;	100%

...Expand

: 67-66-3
chloroform

: (3aR,6aR)-4-Dichloromethylene-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxole

: (3'aR)-2,2,3,3-tetrachloro-2',2'-dimethyl-(3'ar,6'ac)-tetrahydrospiro(cyclopropane-1,4'-furo[3,4-d][1,3]dioxolane)

Conditions

Conditions	Yield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride 0 deg C, 30 min; RT, 2.5 h;	100%

: 67-66-3
chloroform

: 10605-02-4
palmatine chloride

: 50932-23-5
8-trichloromethyl-7,8-dihydropalmatine

Conditions

Conditions	Yield
With ammonium hydroxide for 24h;	100%
With ammonium hydroxide at 20℃; for 24h;	74.9%

: 67-66-3
chloroform

: (Z)-2,3-Diphenyl-acrylic acid 2-[(E)-phenyliminomethyl]-phenyl ester

: 2-(1,2-diphenylvinyl)-2,5-epoxy-4-phenyl-2,3,4,5-tetrahydro-1,4-benzoxazepin-3-one

Conditions

Conditions	Yield
With potassium hydroxide; N-benzyl-N,N,N-triethylammonium chloride at 20℃;	100%

: 618103-13-2
C20H29NO3

: 67-66-3
chloroform

: 618103-14-3
C21H29Cl2NO3

Conditions

Conditions	Yield
With sodium hydroxide; tetrabutylammomium bromide In water for 16h;	100%

: 4-(3-acetoxy-4-methylanilino)-7-benzyloxy-6-methoxyquinazoline

: 67-66-3
chloroform

: 4-(3-acetoxy-4-methylanilino)-7-hydroxy-6-methoxyquinazoline

Conditions

Conditions	Yield
palladium In methanol; N,N-dimethyl-formamide	100%
palladium In methanol; N,N-dimethyl-formamide	100%

: 4-(3-acetoxy-4-methylanilino)-7-benzyloxy-6-methoxyquinazoline hydrochloride

: 67-66-3
chloroform

: 4-(3-acetoxy-4-methylanilino)-7-hydroxy-6-methoxyquinazoline hydrochloride

Conditions

Conditions	Yield
palladium In methanol; N,N-dimethyl-formamide	100%

: 1-hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)

: 67-66-3
chloroform

: dicarbonylchloro(η5-1-hydroxy-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium(II)

Conditions

Conditions	Yield
In ethanol; chloroform byproducts: CH2Cl2, CH3CHO; (Ar); using Schlenk techniques; dissolving of ((Ph4C4CO)2H)Ru2(CO)4(H) in degassed CHCl3 and C2H5OH; closing of flask, stirring at 90°C for 7 h; removal of solvent under high vac., elem .anal.;	100%

: 67-66-3
chloroform

: bis[tris-(3,5-dimethyl-2-oxidobenzyl-κO)ammonium]zirconium(IV)

: bis[tris-(3,5-dimethyl-2-oxidobenzyl-κO)ammonium]zirconium(IV) chloroform disolvate

Conditions

Conditions	Yield
In chloroform Zr((CH3)2C6H2(O)CH2)3NH) dissolved in dry CHCl3 in air; recrystd.; elem. anal.; detd. by XRD;	100%

: 67-66-3
chloroform

: 866488-88-2
bis(η2-ethene)[η5-(8-quinolyl)cyclopentadienyl]iridium(I)

: 1184999-49-2
[η5-(8-quinolyl)cyclopentadienyl]dichloridoiridium(III)

Conditions

Conditions	Yield
In chloroform Irradiation (UV/VIS); under Ar atm.soln. Ir complex in CHCl3 was irradiated for 3 days with light 150-W Hg high-pressure lamp; solvent was evapd.;	100%

: 67-66-3
chloroform

: (OC-6-54-C) μ-chlorido, μ-hydroxo, bis(cis-dicarbonyl, [2,2'-phenylene-4,5-(R,R)-pinenopyridine-κC,N]ruthenium(II))

: bis(cis-dicarbonyl, μ-chlorido, [2,2'-phenylene-4,5-(R,R)-pinenopyridine-κC,N]ruthenium(II))*CH2Cl2

Conditions

Conditions	Yield
In chloroform 80°C, 48 h;	100%

: 6573-11-1
1,4,7-trithiacyclononane

: di-μ-chlorobis(azobenzene-2C,N)dipalladium(II)

: 67-66-3
chloroform

: 67-64-1
acetone

: [Pd(C6H4N=NC6H5)(1,4,7-trithiacyclononane)][Pd(C6H4N=NC6H5)(Cl2)]*CHCl3

Conditions

Conditions	Yield
In dichloromethane byproducts: AgCl; under N2 or Ar using Schlenk app.; CH2Cl2 added to solid mixt. of (Pd(C6H4NNC6H5)Cl)2 (0.20 mol) and 1,4,7-trithiacyclononane (0.40 mol); stirred for 18 h; filtered; evapd. to dryness; extd. (MeOH); ext. filtered and evapd. to dryness; crystd. (CHCl3 and hexane) at room temp. for 3 d;	100%

...Expand

: 39929-21-0
(tetrahydrothiophene)gold(I) chloride

: 67-66-3
chloroform

: (C5H5O2(OCH3)2CH2OCH3)5(PC6H5(CH2C5H5O2(OCH3)2)2)

: P-chlorido-[6(A),6(B)-dideoxy-6(A),6(B)-[(R)-phenylphosphinidene]-2(A),2(B),2(C),2(D),2(E),2(F),2(G),3(A),3(B),3(C),3(D),3(E),3(G),6(C),6(D),6(E),6(F),6(G)-nonadeca-O-methyl-β-cyclodextrin]gold(I)*0.5CHCl3

Conditions

Conditions	Yield
In dichloromethane (Schlenk, N2) to stirred soln. of phosphane in CH2Cl2 was added to a soln. of Au-complex in CH2Cl2, 30 min; evapd. to dryness, column chromy. (silica gel, CH2Cl2-CH3OH, 96:4, v/v);elem. anal.;	100%

...Expand

: 67-66-3
chloroform

: 88-05-1
2,4,6-trimethylaniline

: 57116-96-8
2-mesityl isocyanide

Conditions

Conditions	Yield
Stage #1: 2,4,6-trimethylaniline With 15-crown-5; sodium hydride In benzene at 40 - 50℃; for 0.25h; Stage #2: chloroform In benzene at 40℃; for 1h;	100%
With benzyltriethylammonium chloride; sodium hydroxide In dichloromethane; water for 22h;	53%