CAS No.74-89-5,Methylamine Suppliers,MSDS download

: 107-97-1
sarcosine

A: 50-00-0
formaldehyd

B: 124-38-9
carbon dioxide

C: 74-89-5
methylamine

Conditions

Conditions	Yield
With hydrogenchloride; sodium hydroxide; sodium perchlorate; chlorine at 24.9℃; Mechanism; Rate constant; Equilibrium constant; multistep reaction: 1.) water, 298 deg K, 2.) water, 298 deg K; reactions under var. conditions;	A 100% B n/a C n/a

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: 52316-59-3
N-chloro-sarcosine

A: 50-00-0
formaldehyd

B: 74-89-5
methylamine

Conditions

Conditions	Yield
In water at 24.9℃; Rate constant; Mechanism; Thermodynamic data; Irradiation; I=0.5 mol-1 L-1; various pH; ΔH(excit.), ΔS(excit.);	A 100% B n/a
With water In 1,4-dioxane at 25℃;
With water In 1,4-dioxane at 25℃; Kinetics; Mechanism;

: 60-35-5
acetamide

: 79483-05-9
4,5-diethyl-2,5-dihydro-1,2,2,3-tetramethyl-1H-1,2,5-azasilaborole

A: 111869-87-5
ethylbis(dimethyl(2-penten-2-yl)silyloxy)borane

B: 74-89-5
methylamine

Conditions

Conditions	Yield
In 1,2,5-trimethyl-benzene dropwise addn. of acetamide to boron compd. soln., 160°C, 3.5h; heating (reflux), 10h; evapn.; all under Ar; distn.; elem. anal.;	A 100% B 98%

...Expand

: 75-52-5
nitromethane

: 74-89-5
methylamine

Conditions

Conditions	Yield
With borane-ammonia complex In methanol; water at 20℃; for 0.0833333h;	99%
With ammonia borane; Pd/MIL-101 In methanol; water at 20℃; for 0.025h;	99%
With sodium tetrahydroborate In methanol; water at 20℃; for 0.0666667h; Sealed tube; Green chemistry;	99%

: 110-89-4
piperidine

: 110-68-9
N-n-butyl-N-methylamine

A: 4945-48-6
1-butyl-piperidine

B: 74-89-5
methylamine

Conditions

Conditions	Yield
palladium at 160℃; for 5h;	A 98% B n/a

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: 110-89-4
piperidine

: 103-67-3
benzyl-methyl-amine

A: 2905-56-8
N-Benzylpiperidine

B: 74-89-5
methylamine

Conditions

Conditions	Yield
palladium at 130℃; for 10h;	A 97% B n/a

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: 1-methyl-2-methylamino-4-imino-6-(2,3-dimethylguanidino)-1,4-dihydro-1,3,5-triazine

A: 6726-47-2
1-methyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione

B: 3324-71-8
N,N'-dimethyl-guanidine

C: 74-89-5
methylamine

Conditions

Conditions	Yield
With hydrogenchloride for 10h; Heating;	A 15% B 96% C 4%

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: 96-31-1
N,N'-Dimethylurea

: 18522-92-4
sodium p-toluenesulfonamide

A: 13909-69-8
N-Methyl-N'-toluene-p-sulfonylurea

B: 74-89-5
methylamine

Conditions

Conditions	Yield
at 160℃; for 3h; Product distribution; Rate constant; Equilibrium constant; Other temperature, other time, other ratio of reactants, activation energy, ΔH, ΔS;;	A 95.5% B n/a
at 160℃; for 3h;	A 95.5% B n/a

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: 107-15-3
ethylenediamine

: 103-67-3
benzyl-methyl-amine

A: 74-89-5
methylamine

B: 4152-09-4
N-benzylethylenediamine

Conditions

Conditions	Yield
palladium at 120℃; for 10h;	A n/a B 95%

...Expand

: 13325-10-5
4-Aminobutanol

: 79483-05-9
4,5-diethyl-2,5-dihydro-1,2,2,3-tetramethyl-1H-1,2,5-azasilaborole

A: 129363-73-1
4,5-diethyl-2,2,3-trimethyl-6-oxa-1-azonia-2-sila-5-boratabicyclo{5.3.0}dec-3-ene

B: 129363-50-4
4,5-diethyl-2,2,3-trimethyl-1-oxa-6-aza-2-sila-5-bora-3-cyclodecene

C: 74-89-5
methylamine

Conditions

Conditions	Yield
In neat (no solvent) addn. of boron compd. to equimolar amt. of aminoalkanol, room temp.; driving out CH3NH2 in a stream of Ar, 20-80°C, 4h;; distn. (vac.); elem. anal.; monocyclic : bicyclic isomer = 95:5;	A n/a B n/a C 95%

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: 79878-19-6
6-methyl-8-nitro-1,6-naphthyridin-5(6H)-one

A: 90004-07-2
8-methylpyrido<2,3-d>pyridazin-5-one

B: 74-89-5
methylamine

C NH3: NH3

Conditions

Conditions	Yield
With hydrazine hydrate at 130 - 140℃; for 5h;	A 94% B n/a C n/a

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: 79483-05-9
4,5-diethyl-2,5-dihydro-1,2,2,3-tetramethyl-1H-1,2,5-azasilaborole

: 141-43-5
ethanolamine

A: 129363-47-9
4,5-diethyl-2,2,3-trimethyl-1-oxa-6-aza-2-sila-5-bora-3-cyclooctene

B: 74-89-5
methylamine

Conditions

Conditions	Yield
In 1,2,5-trimethyl-benzene heating under Ar, 40-70°C, 4h;	A 93% B 93%
In neat (no solvent) addn. of boron compd. to equimolar amt. of aminoalkanol, room temp.; driving out CH3NH2 in a stream of Ar, 20°C, 24h;; distn. (vac.); elem. anal.;	A 82% B 87%

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: 5856-63-3
(2R)-2-aminobutan-1-ol

: 79483-05-9
4,5-diethyl-2,5-dihydro-1,2,2,3-tetramethyl-1H-1,2,5-azasilaborole

A: 129444-01-5
(R)-4,5,7-triethyl-2,2,3-trimethyl-6-oxa-1-azonia-2-sila-5-boratabicyclo{3.3.0}oct-3-ene

B: 129444-00-4
(R)-4,5,7-triethyl-2,2,3-trimethyl-1-oxa-6-aza-2-sila-5-bora-3-cyclooctene

C: 74-89-5
methylamine

Conditions

Conditions	Yield
In neat (no solvent) addn. of boron compd. to equimolar amt. of aminoalkanol, room temp.; driving out CH3NH2 in a stream of Ar, 20-25°C, 18h; distn. (vac.); elem. anal.; monocyclic : bicyclic isomer = 95:5;	A n/a B n/a C 91%

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: 123-75-1
pyrrolidine

: 103-67-3
benzyl-methyl-amine

A: 4383-25-9
N-benzylcyclohexylamine

B: 2211-66-7
N-phenyl(methylidene)cyclohexanamine

C: 74-89-5
methylamine

Conditions

Conditions	Yield
palladium at 120℃; for 10h;	A 10% B 90% C n/a

...Expand

: 96-20-8, 13054-87-0
2-aminobutanol

: 79483-05-9
4,5-diethyl-2,5-dihydro-1,2,2,3-tetramethyl-1H-1,2,5-azasilaborole

A: 129363-71-9
4,5,7-triethyl-2,2,3-trimethyl-6-oxa-1-azonia-2-sila-5-boratabicyclo{3.3.0}oct-3-ene

B: 129363-48-0
4,5,7-triethyl-2,2,3-trimethyl-1-oxa-6-aza-2-sila-5-bora-3-cyclooctene

C: 74-89-5
methylamine

Conditions

Conditions	Yield
In neat (no solvent) addn. of boron compd. to equimolar amt. of aminoalkanol, room temp.; driving out CH3NH2 in a stream of Ar, 20-25°C, 22h; distn. (vac.); elem. anal.; monocyclic: bicyclic isomer = 95:5;	A n/a B n/a C 89%

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: 160745-23-3
N-methylisoephedrine

A: 52500-61-5
2-hydroxy-1-phenylpropylamine

B: 50-00-0
formaldehyd

C: 100-52-7
benzaldehyde

D: 75-07-0
acetaldehyde

E: 124-40-3
dimethyl amine

F: 74-89-5
methylamine

Conditions

Conditions	Yield
With water at 25℃; Product distribution; Mechanism; anodic oxidation, carbonate buffer, pH 10; effect of substituents investigated with different types of β-alkanolamines;	A 1.3% B 28% C 82% D 88% E 38% F 33%

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: 79483-05-9
4,5-diethyl-2,5-dihydro-1,2,2,3-tetramethyl-1H-1,2,5-azasilaborole

: 591-27-5
m-Hydroxyaniline

A: 129390-09-6
C30H48B2N2O2Si2

B: 74-89-5
methylamine

Conditions

Conditions	Yield
In 1,2,5-trimethyl-benzene at 125-150°C, 26h under Ar; evapn.; elem. anal.;	A n/a B 88%

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: 3913-67-5
N-methylalanine

A: 124-38-9
carbon dioxide

B: 75-07-0
acetaldehyde

C: 74-89-5
methylamine

Conditions

Conditions	Yield
With hydrogenchloride; sodium hydroxide; sodium perchlorate; chlorine at 24.9℃; Mechanism; Rate constant; Equilibrium constant; multistep reaction: 1.) water, 298 deg K, 2.) water, 298 deg K; reactions under var. conditions;	A n/a B 87% C n/a

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: 299-42-3
2-methylamino-1-phenylpropanol

A: 50-00-0
formaldehyd

B: 100-52-7
benzaldehyde

C: 75-07-0
acetaldehyde

D: 65-85-0
benzoic acid

E: 74-89-5
methylamine

Conditions

Conditions	Yield
Mechanism; Product distribution; anodic oxidation;	A 12% B 65% C 68% D 12% E 87%

...Expand

: 81620-70-4
4,5-diethyl-2,5-dihydro-3-isopropenyl-1,2,2-trimethyl-1,2,5-azasilaborole

: 141-43-5
ethanolamine

A: 129363-59-3
4,5-diethyl-3-isopropenyl-2,2-dimethyl-1-oxa-6-aza-2-sila-5-bora-3-cyclooctene

B: 129363-70-8
4,5-diethyl-3-isopropenyl-2,2-dimethyl-6-oxa-1-azonia-2-sila-5-boratabicyclo{3.3.0}oct-3-ene

C: 74-89-5
methylamine

Conditions

Conditions	Yield
In neat (no solvent) addn. of boron compd. to equimolar amt. of aminoalkanol, room temp.; driving out CH3NH2 in a stream of Ar, 20-25°C, 22h;; distn. (vac.); standing at room temp.; crystn. of bicyclic isomer; elem. anal.;	A 57% B n/a C 87%

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: 79483-05-9
4,5-diethyl-2,5-dihydro-1,2,2,3-tetramethyl-1H-1,2,5-azasilaborole

: 156-87-6
propan-1-ol-3-amine

A: 129363-72-0
4,5-diethyl-2,2,3-trimethyl-6-oxa-1-azonia-2-sila-5-boratabicyclo{4.3.0}non-3-ene

B: 129363-49-1
4,5-Diethyl-2,2,3-trimethyl-1-oxa-6-aza-2-sila-5-bora-3-cyclononene

C: 74-89-5
methylamine

Conditions

Conditions	Yield
In neat (no solvent) addn. of boron compd. to equimolar amt. of aminoalkanol, room temp.; driving out CH3NH2 in a stream of Ar, 20-80°C, 24h;; distn. (vac.); elem. anal.; monocyclic : bicyclic isomer = 95:5;	A n/a B n/a C 87%

...Expand

: 90-82-4
pseudoephedrine

: 79483-05-9
4,5-diethyl-2,5-dihydro-1,2,2,3-tetramethyl-1H-1,2,5-azasilaborole

A: 129363-65-1
(4S,5S)-2-Ethyl-4-methyl-5-phenyl-1,3,2-oxazaborolan

B: 129363-66-2
{(1S,2S)-2-[Dimethyl-((E)-1-methyl-but-1-enyl)-silanyloxy]-1-methyl-2-phenyl-ethyl}-methyl-amine

C: 129443-99-8
(7S,8S)-4,5-Diethyl-2,2,3,6,7-pentamethyl-8-phenyl-1-oxa-6-aza-2-sila-5-bora-3-cycloocten

D: 74-89-5
methylamine

Conditions

Conditions	Yield
In 1,2,5-trimethyl-benzene dropwise addn. of boron compd. to aminoalkanol soln. under Ar, 0.5h; heating to 140-150°C, 12h; evapn.; distn. (vac.); elem. anal.;	A n/a B n/a C 75% D 86%

...Expand

: 60-35-5
acetamide

: 74-89-5
methylamine

Conditions

Conditions	Yield
With sodium hydroxide; benzyltrimethylazanium tribroman-2-uide In water at 70℃; for 2h;	85%
With potassium hydroxide; bromine ueber mehrere Stufen;
With potassium hydroxide; bromine
With water; bromine; calcium carbonate ueber mehrere Stufen;
With sodium hydroxide; sodium bromite In water at 70℃; for 0.5h; Yield given;

: 103-67-3
benzyl-methyl-amine

A: 102-05-6
N-methyldibenzylamine

B: 74-89-5
methylamine

Conditions

Conditions	Yield
palladium at 120℃; for 20h;	A 85% B n/a

: 108-01-0
2-(N,N-dimethylamino)ethanol

: 79483-05-9
4,5-diethyl-2,5-dihydro-1,2,2,3-tetramethyl-1H-1,2,5-azasilaborole

A: 129363-54-8
(E)-3-<<2-(Dimethylamino)ethoxy>ethylboryl>-2-<<2-(dimethylamino)ethoxy>dimethylsilyl>-2-penten

B: 74-89-5
methylamine

Conditions

Conditions	Yield
In neat (no solvent) stirring under Ar, 0-20°C, 1-2h; heating to a maximum of 140°C, 10h; distn. (vac.); elem. anal.;	A 82% B 76%

...Expand

: 109-83-1
(2-hydroxyethyl)(methyl)amine

: 79483-05-9
4,5-diethyl-2,5-dihydro-1,2,2,3-tetramethyl-1H-1,2,5-azasilaborole

A: 129363-52-6
4,5-diethyl-2,2,3,6-tetramethyl-1-oxa-6-aza-2-sila-5-bora-3-cyclooctene

B: 74-89-5
methylamine

Conditions

Conditions	Yield
In neat (no solvent) dropwise addn. of boron compd. to aminoalkanol, 10 min; stirring in a stream of Ar, 20°C, 24h;; distn. (vac.); elem. anal.;	A 81% B 82%

...Expand

: 854457-30-0
trimethyl-borane; compound with methylamine

A: 593-90-8
trimethylborane

B: 74-89-5
methylamine

Conditions

Conditions	Yield
at 130.0°C, 77.4 Torr equilibrium;	A 81.95% B 81.95%
at 130.0°C, 77.4 Torr equilibrium;	A 81.95% B 81.95%
at 85.4°C, 52.5 Torr equilibrium;	A 38.86% B 38.86%
at 85.4°C, 52.5 Torr equilibrium;	A 38.86% B 38.86%

: 299-42-3
L(-)-ephedrine hemihydrate

: 79483-05-9
4,5-diethyl-2,5-dihydro-1,2,2,3-tetramethyl-1H-1,2,5-azasilaborole

A: 129363-53-7
(7S,8R)-4,5-diethyl-2,2,3,6,7-pentamethyl-1-oxa-6-aza-2-sila-5-bora-3-cyclooctene

B: 74-89-5
methylamine

Conditions

Conditions	Yield
In neat (no solvent) dropwise addn. of boron compd. to aminoalkanol under Ar, 5 min; heating to 110-150°C, 8.5h;; distn. (vac.); elem. anal.;	A 73% B 80.5%

...Expand

: 110-68-9
N-n-butyl-N-methylamine

: 103-67-3
benzyl-methyl-amine

A: 31844-65-2
N-Butyl-N-methylbenzenemethanamine

B: 74-89-5
methylamine

Conditions

Conditions	Yield
palladium at 120℃; for 10h;	A 80% B n/a

...Expand

: 123-56-8
Succinimide

: 74-89-5
methylamine

: 3025-97-6
N-methyl-succinic diamide

Conditions

Conditions	Yield
at 20℃; under 600.048 - 750.06 Torr; Addition; soid-gas reaction; ring cleavage;	100%
With water
In water for 1h; Ambient temperature;

: 487-89-8
Indole-3-carboxaldehyde

: 74-89-5
methylamine

: 22980-06-9
3-(N-methylformimidoyl)-1H-indole

Conditions

Conditions	Yield
With magnesium sulfate In methanol; dichloromethane for 7h; Heating;	100%
With water
In water 1.) 40 - 45 deg C, 15 min, 2.) room temp., 4 h; Yield given;

: 87-41-2
2-benzofuran-1(3H)-one

: 74-89-5
methylamine

: 5342-91-6
2-methylisoindolin-1-one

Conditions

Conditions	Yield
In water at 220℃; under 114000 Torr; for 4h;	100%
With ethanol at 220℃;
In 5,5-dimethyl-1,3-cyclohexadiene

: 136918-14-4
phthalimide

: 74-89-5
methylamine

: 19532-98-0
N1,N2-dimethylphthalamide

Conditions

Conditions	Yield
at -20℃; under 75.006 Torr; Addition; solid-gas reaction; ring cleavage;	100%
In ethanol	55%

: 81-84-5
1,8-Naphthalic anhydride

: 74-89-5
methylamine

: 2382-08-3
N-methylnaphthalimide

Conditions

Conditions	Yield
In ethanol; water at 20℃; for 72h; Inert atmosphere;	100%
In water for 72h; Reflux;	100%
In water	100%

: 4295-06-1
4-chloro-2-methylquinoline

: 74-89-5
methylamine

: 21875-68-3
N,2-dimethylquinolin-4-amine

Conditions

Conditions	Yield
In ethanol at 120℃; for 7h; Sealed tube; Microwave irradiation;	100%
With ethanol at 120℃;
With phenol at 190℃;

: 104-87-0
4-methyl-benzaldehyde

: 74-89-5
methylamine

: 17972-13-3, 29086-13-3, 53699-34-6
p-methylbenzylidene-methylamine

Conditions

Conditions	Yield
at 20℃; for 12h;	100%
In methanol; dichloromethane for 18h; Molecular sieve;	86%

: 2004-06-0
6-Chloropurine riboside

: 74-89-5
methylamine

: 1867-73-8
N6-methyladenosine

Conditions

Conditions	Yield
With triethylamine In ethanol for 4h; Reflux;	100%
In ethanol; water Sealed tube; Reflux;	94%
In ethanol; water at 100℃; for 72h; Sealed tube;	54%

: 100-52-7
benzaldehyde

: 74-89-5
methylamine

: 622-29-7
N-Benzylidenemethylamine

Conditions

Conditions	Yield
at 20℃; for 12h;	100%
In water for 1h; Ambient temperature;	95%
at 20℃; for 15h;	95%

: 123-08-0
4-hydroxy-benzaldehyde

: 74-89-5
methylamine

: 5766-74-5
4-(Methylimino-methyl)-phenol

Conditions

Conditions	Yield
at 0℃; under 187.515 Torr; Solid phase reaction; gas-solid reaction;	100%
at 20℃; for 12h;	100%
With ethanol; water at 40℃;

: 123-11-5
4-methoxy-benzaldehyde

: 74-89-5
methylamine

: 13114-23-3
4-methoxybenzyl-N-methylimine

Conditions

Conditions	Yield
In ethanol; water at 40℃; for 2h;	100%
In ethanol at 0 - 40℃;	90%
In water for 10h; Ambient temperature;	80%

: 90-02-8
salicylaldehyde

: 74-89-5
methylamine

: 3117-65-5
2-(methyliminomethyl)phenol

Conditions

Conditions	Yield
In ethanol at 20℃; for 8h;	100%
In ethanol at 20℃; for 8h;	100%
With molecular sieve In ethanol; water for 0.5h;	96%

: 1605-65-8
N,N,N',N'-Tetramethylphosphorodiamidic chloride

: 74-89-5
methylamine

: 10159-46-3
Pentamethylphosphoramide

Conditions

Conditions	Yield
at 20℃; for 48h;	100%
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In dichloromethane at 0℃; for 1h;	83%
	64%

: 120-14-9
3,4-dimethoxy-benzaldehyde

: 74-89-5
methylamine

: 17972-14-4
N-(3,4-dimethoxybenzylidene)methanamine

Conditions

Conditions	Yield
With 4 A molecular sieve In toluene at 0℃;	100%
With benzene
In methanol at 40℃; for 5h;
In ethanol at 50℃;
In benzene for 2h; Reflux;

: 100-83-4
meta-hydroxybenzaldehyde

: 74-89-5
methylamine

: 7221-33-2
3-(Methylimino-methyl)-phenol

Conditions

Conditions	Yield
In ethanol at 0 - 5℃; for 2h;	100%
at 20℃; for 12h;	100%
With benzene zuletzt unter Abdestillieren des gebildeten Wassers;

: 556-61-6
methyl thioisocyanate

: 74-89-5
methylamine

: 534-13-4
N,N-dimethylthiourea

Conditions

Conditions	Yield
at 0℃; under 375.03 Torr; Addition; solid-gas reaction;	100%

: 292638-85-8
acrylic acid methyl ester

: 74-89-5
methylamine

: 24549-12-0
methyl 3-(methylamino)propanoate

Conditions

Conditions	Yield
In diethyl ether at 4℃; Addition;	100%
With C12H18NO3S(1+)*HO4S(1-) at 25℃; for 0.0833333h; Ionic liquid; Neat (no solvent); chemoselective reaction;	99%
In ethanol at -10℃;	86%

: 98-86-2
acetophenone

: 74-89-5
methylamine

: 6907-71-7
N-(1-phenylethylidene)methanamine

Conditions

Conditions	Yield
In ethanol at 20℃; for 48h; Molecular sieve; Inert atmosphere;	100%
In ethanol at 20℃; for 48h; Molecular sieve; Inert atmosphere;	100%
With triethylamine In ethanol for 1h; Molecular sieve;	97%

: 591-31-1
3-methoxy-benzaldehyde

: 74-89-5
methylamine

: 16928-30-6
N-(3-methoxybenzylidene)methanamine

Conditions

Conditions	Yield
at 20℃; for 12h;	100%
In ethanol at 0 - 40℃;	90%
In water for 10h; Ambient temperature;	86%

: 135-02-4
ortho-anisaldehyde

: 74-89-5
methylamine

: 1125-90-2
1-(2-methoxyphenyl)-N-methylmethanimine

Conditions

Conditions	Yield
In ethanol at 0 - 40℃;	100%
In water for 10h; Ambient temperature;	80%
With water

: 100-10-7
4-dimethylamino-benzaldehyde

: 74-89-5
methylamine

: 877-79-2
4-(dimethylamino)-N-methylbenzylimine

Conditions

Conditions	Yield
at 20℃; under 750.06 Torr; Solid phase reaction; gas-solid reaction;	100%
at 20℃; for 12h;	100%
With benzene

: 1493-27-2
ortho-nitrofluorobenzene

: 74-89-5
methylamine

: 612-28-2
2-nitro-N-methylaniline

Conditions

Conditions	Yield
In ethanol; water Reflux;	100%
In methanol; water Heating;	98%
In water at 20℃; for 2h; Inert atmosphere;	93%

: 97-00-7
1-chloro-2,4-dinitro-benzene

: 74-89-5
methylamine

: 2044-88-4
N-methyl-2,4-dinitroaniline

Conditions

Conditions	Yield
In ethanol at 20℃; for 15h;	100%
In ethanol; water at 20℃; for 1h;	100%
In ethanol at 0 - 20℃; for 15h;	95%

: 551-06-4
1-isothiocyanatonaphthalene

: 74-89-5
methylamine

: 2740-98-9
1-methyl-3-naphthalene-1-yl-thiourea

Conditions

Conditions	Yield
at 20℃; under 750.06 Torr; Addition; solid-gas reaction;	100%
With ethanol

: 2131-61-5
p-nitrophenyl isothiocyanate

: 74-89-5
methylamine

: 16361-69-6
1-(4-nitrophenyl)-3-methyl-thiourea

Conditions

Conditions	Yield
at 20℃; under 750.06 Torr; Addition; solid-gas reaction;	100%

: 74-89-5
methylamine

: 135-19-3
β-naphthol

: 2216-67-3
2-N-methylaminonaphthalene

Conditions

Conditions	Yield
With ammonium chloride In ethanol at 200℃; for 20h;	100%
With water at 200 - 220℃; unter Druck;
With sodium hydrogensulfite In water Bucherer reaction; Autoclave;

: 74-89-5
methylamine

: 28188-41-2
3-(bromomethyl)benzonitrile

: 90389-96-1
3-((methylamino)methyl)benzonitrile

Conditions

Conditions	Yield
In THjfF (tetrahydrofuran) at 20℃; for 3h; Inert atmosphere;	100%
In tetrahydrofuran at 20℃; for 24h;	96%
In water at 0 - 20℃; for 3.16h;	82%

: 74-89-5
methylamine

: 1985-12-2
4-Bromophenyl isothiocyanate

: 61449-55-6
1-(4-bromophenyl)-3-methyl-thiourea

Conditions

Conditions	Yield
at 20℃; under 750.06 Torr; Addition; solid-gas reaction;	100%
With ethanol

: 74-89-5
methylamine

: 86-51-1
2,3-dimethyoxybenzaldehyde

: 722495-95-6
(2,3-dimethoxy-benzylidene)-methyl-amine

Conditions

Conditions	Yield
at 20℃; for 12h;	100%
In ethanol at 0 - 40℃;	90%
With benzene zuletzt unter Erwaermen und Entfernen des gebildeten Wassers;
In benzene for 2h; Reflux;
In ethanol; water

: 74-89-5
methylamine

: 49845-33-2
2,4-Dichloro-5-nitropyrimidine

: 89283-49-8
2-chloro-4-(methylamino)-5-nitropyrimidine

Conditions

Conditions	Yield
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran; methanol at -78 - 20℃; for 3h;	100%
With N-ethyl-N,N-diisopropylamine In dichloromethane at -60℃; for 1h;	85%
With N-ethyl-N,N-diisopropylamine In ethanol; dichloromethane at 0℃; for 0.5h;	85.4%

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