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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

High Quality 1-Fluoro-2-nitrobenzene 1493-27-2 Manufacturer

Cas:1493-27-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

1-Fluoro-2-nitrobenzene Manufacturer/High quality/Best price/In stock

Cas:1493-27-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality o-Nitrofluorobenzene supplier in China

Cas:1493-27-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

1-Fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply O-Fluoronitrobenzene

Cas:1493-27-2

Min.Order:1

Negotiable

Type:Other

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Jinan Finer Chemical Co., Ltd

Product description: Product name 1-Fluoro-2-nitrobenzene CAS number 1493-27-2 Assay ≥99% Appearance Yellowish liquid Capacity 500mt/year Application Pharmaceutical/pesticide

1-Fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 1493-27-2 1-Fluoro-2-nitrobenzene Manufacturer

Cas:1493-27-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Name 1-Fluoro-2-nitrobenzene Synonyms o-Fluoronitrobenzene Molecular Structure Molecular Formula

1-Fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

1-Fluoro-2-Nitrobenzene

Cas:1493-27-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Fluoronitrobenzene

Cas:1493-27-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

1-fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Competitive Price High Quality Fast Delivery custom-made Welcome to Henan Tianfu Chemical Co., Ltd. website. Our company engages in Sodium Tripolyphosphate (STPP) and Sodium Hexametabphosphate (SHMP) production; development of noble me

1-Fluoro-2-nitrobenzene 1493-27-2

Cas:1493-27-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

1-Fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 1493-27-2 with fast shipping

Cas:1493-27-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:Liquid Storage:Store in sealed containers at cool & dry plac

intermediates,1-Fluoro-2-nitrobenzene CAS 1493-27-2

Cas:1493-27-2

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1-Fluoro-2-nitrobenzene 1493-27-2

Cas:1493-27-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

1-Fluoro-2-nitrobenzene CAS NO.: 1493-27-2

Cas:1493-27-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1-Fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1-Fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

cas 1493-27-2 1-Fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1-Fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

1-FLUORO-2-NITROBENZENE

Cas:1493-27-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1-Fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

2-Fluoronitrobenzene

Cas:1493-27-2

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

1-Fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

1-Fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 1-Fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

1-Fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 1-Fluoro-2-Nitrobenzene CAS No.: 1493-27-2 Molecule Formula:C7H8BFO3 Molecule Weight:169.95 Purity: 99.0% Package: 200kg/drum Description:Light yellow liquid Manufacture Standards:Enterprise Standard TESTING ITEMS

Lower Price 1-Fluoro-2-Nitrobenzene on stock

Cas:1493-27-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

1-Fluoro-2-nitrobenzene

Cas:1493-27-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With Cu(Ph3P)3F In N,N-dimethyl-formamide at 170℃; for 5h;100%
1,2-Dinitrobenzene
528-29-0

1,2-Dinitrobenzene

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In tetrahydrofuran for 1.5h; Ambient temperature;100%
With tetrabutyl ammonium fluoride In tetrahydrofuran; water; N,N-dimethyl-formamide at 20℃; for 1h;72%
With tetrabutyl ammonium fluoride In tetrahydrofuran Ambient temperature; Yield given;
With tetraphenylphosphonium hydrogendifluoride In sulfolane at 100℃; for 2h;70 % Chromat.
With tetrabutyl ammonium fluoride In tetrahydrofuran at 20℃; for 1.5h; Inert atmosphere; chemoselective reaction;97.4 %Chromat.
o-fluorophenylboronic acid
1993-03-9

o-fluorophenylboronic acid

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With nitric acid In 1,2-dichloro-ethane at 70℃; for 16h; Inert atmosphere;96%
With N-Bromosuccinimide; [bis(trifluoroacetoxy)iodo]benzene; sodium nitrite In acetonitrile at 20℃; for 3h; regioselective reaction;80%
With N–nitrosuccinimide; tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate In acetonitrile at 20℃; for 19h; Inert atmosphere; Irradiation;68%
Multi-step reaction with 2 steps
1.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.5 h / 20 °C / Sealed tube
1.2: 0.25 h / 20 °C / Sealed tube
2.1: sodium triflate; sodium nitrite / ethyl acetate / 16 h / 70 °C / Sealed tube
View Scheme
3-nitro-4-fluorobenzoic acid
453-71-4

3-nitro-4-fluorobenzoic acid

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With sulfolane; sodium hydrogencarbonate at 190℃; for 2h;92%
cetyltributylphosphonium bromide
14937-45-2

cetyltributylphosphonium bromide

2-Chloronitrobenzene
88-73-3

2-Chloronitrobenzene

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With potassium fluoride91.2%
2-Chloronitrobenzene
88-73-3

2-Chloronitrobenzene

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With potassium fluoride; polydiallyldimethylammonium chloride In dimethyl sulfoxide at 200℃; for 3h;90.1%
With potassium fluoride; bis(tricyclohexylphosphine)nickel(II) dichloride; tetrabutyl ammonium fluoride In N,N-dimethyl-formamide at 150℃; for 8h; Inert atmosphere;79.8%
With potassium fluoride; bis(triphenylphosphine)iminium chloride In dimethyl sulfoxide at 150℃; for 8h; Inert atmosphere;76%
undecyltributylammonium bromide

undecyltributylammonium bromide

2-Chloronitrobenzene
88-73-3

2-Chloronitrobenzene

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With potassium fluoride84.6%
fluorobenzene
462-06-6

fluorobenzene

A

4-Fluoronitrobenzene
350-46-9

4-Fluoronitrobenzene

B

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With nitric acid at 50℃; for 3h;A 84.4%
B 13.9%
With 2-nitrobenzo[d]isothiazol-3(2H)-one 1,1-dioxide at 55 - 60℃; for 3h; Inert atmosphere; Sealed tube; Overall yield = 96 percent;A 76.8%
B 19.2%
With aluminium trichloride; dinitrogen tetraoxide; Petroleum ether
bis(2-fluorophenyl)iodonium tetrafluoroborate
1034926-54-9

bis(2-fluorophenyl)iodonium tetrafluoroborate

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With sodium triflate; sodium nitrite In ethyl acetate at 70℃; for 16h; Sealed tube;84%
o-nitroiodobenzene
609-73-4

o-nitroiodobenzene

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
Stage #1: o-nitroiodobenzene With phenyllithium In tetrahydrofuran; diethyl ether; cyclohexane at -28℃; Flow reactor;
Stage #2: With N-fluorobis(benzenesulfon)imide In tetrahydrofuran; diethyl ether; cyclohexane at -28℃; Flow reactor;
83%
cetyltrimethylammonium bromide
1119-97-7

cetyltrimethylammonium bromide

2-Chloronitrobenzene
88-73-3

2-Chloronitrobenzene

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With potassium fluoride In water; toluene78%
thiophene
110-01-0

thiophene

2-Chloronitrobenzene
88-73-3

2-Chloronitrobenzene

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
70%
nitrobenzene
98-95-3

nitrobenzene

A

3-fluoro-1-nitrobenzene
402-67-5

3-fluoro-1-nitrobenzene

B

2,6-difluoro-1-nitrobenzene
19064-24-5

2,6-difluoro-1-nitrobenzene

C

4-Fluoronitrobenzene
350-46-9

4-Fluoronitrobenzene

D

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With tetrafluoroammonium tetrafluoroborate In hydrogen fluoride at 0℃; Further byproducts given. Title compound not separated from byproducts;A 62%
B n/a
C 6%
D 15%
With tetrafluoroammonium tetrafluoroborate In hydrogen fluoride at 0℃; Yield given. Further byproducts given. Title compound not separated from byproducts;A 62%
B n/a
C 6%
D 15%
With tetrafluoroammonium tetrafluoroborate In hydrogen fluoride at 0℃; Further byproducts given. Title compound not separated from byproducts;A 62 % Spectr.
B n/a
C 6 % Spectr.
D 15 % Spectr.
dimethyl-(2-nitro-phenyl)-sulfonium ; methyl sulfate
13118-30-4

dimethyl-(2-nitro-phenyl)-sulfonium ; methyl sulfate

A

methyl 2-nitrophenyl sulfide
3058-47-7

methyl 2-nitrophenyl sulfide

B

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With cesium fluoride In N,N-dimethyl-formamide at 100℃; for 0.166667h;A 25%
B 56%
o-nitroiodobenzene
609-73-4

o-nitroiodobenzene

A

nitrobenzene
98-95-3

nitrobenzene

B

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
Stage #1: o-nitroiodobenzene With phenyllithium In tetrahydrofuran; diethyl ether; cyclohexane at -28℃; Flow reactor;
Stage #2: With 2-fluoro-3,3-dimethyl-2,3-dihydro-1,2-benzisothiazole-1,1-dioxide In tetrahydrofuran; diethyl ether; cyclohexane at -28℃; Flow reactor;
A 24%
B 56%
ortho-nitrobenzoic acid
552-16-9

ortho-nitrobenzoic acid

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
Stage #1: ortho-nitrobenzoic acid With tetrakis(acetonitrile)copper(I)tetrafluoroborate; tetrabutylammonium tetra(tert-butyl alcohol) coordinate fluoride; copper(II) bis(trifluoromethanesulfonate) In acetonitrile at 23℃; for 0.5h; Sealed tube; Inert atmosphere;
Stage #2: In acetonitrile at 35℃; Irradiation; Sealed tube; Inert atmosphere;
54%
2-Fluoroaniline
348-54-9

2-Fluoroaniline

trifluoroacetic acid
76-05-1

trifluoroacetic acid

A

2,2,2-trifluoro-N-(2-fluoro-6-hydroxyphenyl)acetamide

2,2,2-trifluoro-N-(2-fluoro-6-hydroxyphenyl)acetamide

B

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

C

2,2'-difluoroazobenzene
401-44-5

2,2'-difluoroazobenzene

Conditions
ConditionsYield
With Oxone In dimethyl sulfoxide at 90℃; Schlenk technique; Inert atmosphere; chemoselective reaction;A 25%
B 15%
C 40%
2-Fluoroaniline
348-54-9

2-Fluoroaniline

trifluoroacetic acid
76-05-1

trifluoroacetic acid

A

2,2,2-trifluoro-N-(2-hydroxyphenyl)acetamide
10595-66-1

2,2,2-trifluoro-N-(2-hydroxyphenyl)acetamide

B

2,2,2-trifluoro-N-(2-fluoro-6-hydroxyphenyl)acetamide

2,2,2-trifluoro-N-(2-fluoro-6-hydroxyphenyl)acetamide

C

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With Oxone In acetonitrile at 90℃; Schlenk technique; Inert atmosphere; chemoselective reaction;A 10%
B 25%
C 8%
2-Fluoroaniline
348-54-9

2-Fluoroaniline

trifluoroacetic acid
76-05-1

trifluoroacetic acid

A

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

B

2,2'-difluoroazobenzene
401-44-5

2,2'-difluoroazobenzene

Conditions
ConditionsYield
With Oxone In N,N-dimethyl-formamide at 90℃; Schlenk technique; Inert atmosphere; chemoselective reaction;A 10%
B 20%
4-cyanophenol
767-00-0

4-cyanophenol

1,2-Dinitrobenzene
528-29-0

1,2-Dinitrobenzene

A

4-(2-nitrophenoxy)benzonitrile
113344-23-3

4-(2-nitrophenoxy)benzonitrile

B

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With potassium fluoride In dimethyl sulfoxide at 110℃; for 2h;A n/a
B 10%
With potassium fluoride In dimethyl sulfoxide at 110℃; for 2h;A n/a
B 10 % Chromat.
2-Fluoroaniline
348-54-9

2-Fluoroaniline

trifluoroacetic acid
76-05-1

trifluoroacetic acid

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With Oxone In dichloromethane at 90℃; Schlenk technique; Inert atmosphere; chemoselective reaction;10%
fluorobenzene
462-06-6

fluorobenzene

nitro acetate
591-09-3

nitro acetate

A

4-Fluoronitrobenzene
350-46-9

4-Fluoronitrobenzene

B

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

fluorobenzene
462-06-6

fluorobenzene

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With nitric acid; phosphorus pentoxide beim Nitrieren; Trennung vom p-Isomeren durch fraktionierte Destillation und Krystallisation;
4-Fluoro-3-nitroaniline
364-76-1

4-Fluoro-3-nitroaniline

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
Diazotization.nachfolgend Reduktion zu 4-Fluor-3-nitro-phenylhydrazin und Oxydation mit Kupfersulfat;
fluorobenzene
462-06-6

fluorobenzene

methyl nitrate
598-58-3

methyl nitrate

A

3-fluoro-1-nitrobenzene
402-67-5

3-fluoro-1-nitrobenzene

B

4-Fluoronitrobenzene
350-46-9

4-Fluoronitrobenzene

C

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
Product distribution; gas-phase radiolytic nitration;
fluorobenzene
462-06-6

fluorobenzene

A

3-fluoro-1-nitrobenzene
402-67-5

3-fluoro-1-nitrobenzene

B

4-Fluoronitrobenzene
350-46-9

4-Fluoronitrobenzene

C

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With silver nitrate; boron trifluoride In acetonitrile at 25℃; for 10h; Product distribution; competitive nitration benzene, relative rate;A 1 % Chromat.
B 72 % Chromat.
C 27 % Chromat.
With methyl nitrate; methane at 37.6℃; Product distribution; Irradiation; gas-phase nitration by radiolytically formed MeO(1+)(H)NO2;
With nitro acetate; H-ZSM-11 In hexane at 30℃; Product distribution; different catalysts;
fluorobenzene
462-06-6

fluorobenzene

A

3-fluoro-1-nitrobenzene
402-67-5

3-fluoro-1-nitrobenzene

B

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
With K10 montmorillonite-supported cupric nitrate; acetic anhydride In hexane for 48h; Product distribution; Ambient temperature; var. halobenzenes, other solvent, other time;
4-cyanophenyl methyl ketone
1443-80-7

4-cyanophenyl methyl ketone

1-fluoro-2-nitro-benzene radical anion
34467-51-1, 1493-27-2

1-fluoro-2-nitro-benzene radical anion

A

C9H7NO(1-)

C9H7NO(1-)

B

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Conditions
ConditionsYield
at 149.9℃; Thermodynamic data; ΔG0;
cyclohexylamine
108-91-8

cyclohexylamine

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

N-cyclohexyl-2-nitroaniline
6373-71-3

N-cyclohexyl-2-nitroaniline

Conditions
ConditionsYield
In toluene at 25℃; Rate constant; also in DMSO;100%
In toluene at 25℃;100%
97%
ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

methylamine
74-89-5

methylamine

2-nitro-N-methylaniline
612-28-2

2-nitro-N-methylaniline

Conditions
ConditionsYield
In ethanol; water Reflux;100%
In methanol; water Heating;98%
In water at 20℃; for 2h; Inert atmosphere;93%
N,N-dimethylethylenediamine
108-00-9

N,N-dimethylethylenediamine

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

N1,N1-dimethyl-N2-(2-nitrophenyl)ethane-1,2-diamine
25238-55-5

N1,N1-dimethyl-N2-(2-nitrophenyl)ethane-1,2-diamine

Conditions
ConditionsYield
In toluene at 25℃; Rate constant; also in DMSO;100%
In toluene at 25℃;100%
In isopropyl alcohol at 90 - 100℃; for 16h;92%
pyrrolidine
123-75-1

pyrrolidine

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

1-(2-nitrophenyl)pyrrolidine
40832-79-9

1-(2-nitrophenyl)pyrrolidine

Conditions
ConditionsYield
In tetrahydrofuran at 50℃; under 5400430 Torr; for 20h;100%
With potassium carbonate In acetonitrile for 3h; Heating / reflux;100%
With potassium carbonate In acetonitrile at 90℃; for 3h; Inert atmosphere;99%
piperidine
110-89-4

piperidine

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

1-(2-nitrophenyl)piperidine
15822-77-2

1-(2-nitrophenyl)piperidine

Conditions
ConditionsYield
In toluene at 25℃;100%
In toluene at 25℃; Rate constant; Mechanism; also in DMSO;100%
With potassium phosphate; TPGS-750-M In water at 20℃; for 18h; Inert atmosphere;99%
1H-imidazole
288-32-4

1H-imidazole

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

1-(2-nitrophenyl)-1H-imidazole
23309-16-2

1-(2-nitrophenyl)-1H-imidazole

Conditions
ConditionsYield
With 1,2,3-Benzotriazole; potassium tert-butylate; copper(l) iodide In dimethyl sulfoxide at 110℃; for 0.5h;100%
With pyridine; potassium carbonate; copper(II) oxide at 115℃; Ullmann Condensation;96%
With potassium carbonate In acetonitrile for 24h; Heating;95%
1,2,3,4-tetrahydroisoquinoline
91-21-4

1,2,3,4-tetrahydroisoquinoline

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

1,2,3,4-tetrahydro-2-(2-nitrophenyl)isoquinoline
140381-66-4

1,2,3,4-tetrahydro-2-(2-nitrophenyl)isoquinoline

Conditions
ConditionsYield
In neat (no solvent) at 100℃; for 1h;100%
With potassium carbonate In dimethyl sulfoxide at 100℃;81%
With potassium carbonate In N,N-dimethyl-formamide Inert atmosphere; Reflux;60%
2-hydroxybromobenzene
95-56-7

2-hydroxybromobenzene

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

1-(2-bromophenoxy)-2-nitrobenzene
60671-89-8

1-(2-bromophenoxy)-2-nitrobenzene

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 95℃; for 23h;100%
With potassium carbonate In dimethyl sulfoxide at 95℃;95%
With caesium carbonate In N,N-dimethyl-formamide at 0 - 80℃; for 3h;90%
ethyl 2-cyanoacetate
105-56-6

ethyl 2-cyanoacetate

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

(+/-)-ethyl cyano(2-nitrophenyl)acetate
65548-02-9

(+/-)-ethyl cyano(2-nitrophenyl)acetate

Conditions
ConditionsYield
With sodium hydride In dimethyl sulfoxide 1.) 10 min, 2.) 90 deg C, 0.5 h;100%
With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate In dimethyl sulfoxide at 20 - 90℃; Inert atmosphere;99%
Stage #1: ethyl 2-cyanoacetate With potassium tert-butylate In tetrahydrofuran for 0.25h; Cooling with ice;
Stage #2: ortho-nitrofluorobenzene In tetrahydrofuran for 3h; Reflux;
96.4%
6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline
1745-07-9

6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

6,7-dimethoxy-(N-2-nitrophenyl)-1,2,3,4-tetrahydroisoquinoline
93649-88-8

6,7-dimethoxy-(N-2-nitrophenyl)-1,2,3,4-tetrahydroisoquinoline

Conditions
ConditionsYield
In neat (no solvent) at 100℃; for 1h;100%
With potassium carbonate In dimethyl sulfoxide at 100℃; for 4h;40%
With potassium carbonate In N,N-dimethyl-formamide at 120℃; for 12h;
With potassium carbonate In N,N-dimethyl-formamide at 120℃;
methyl 2-(2-acetyl-4,5-dimethoxyphenyl)acetate
17173-27-2

methyl 2-(2-acetyl-4,5-dimethoxyphenyl)acetate

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

methyl 2-[2-(2-nitrophenyl)acetyl]-4,5-dimethoxyphenylacetate
278801-02-8

methyl 2-[2-(2-nitrophenyl)acetyl]-4,5-dimethoxyphenylacetate

Conditions
ConditionsYield
With sulfuric acid In 1,4-dioxane for 2h; Heating;100%
ortho-cresol
95-48-7

ortho-cresol

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

1-methyl-2-(2-nitrophenoxy)benzene
54106-40-0

1-methyl-2-(2-nitrophenoxy)benzene

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 95℃; for 20h;100%
Stage #1: ortho-cresol With sodium hydride In N,N-dimethyl-formamide at 20℃; for 1h; Inert atmosphere;
Stage #2: ortho-nitrofluorobenzene In N,N-dimethyl-formamide at 20 - 50℃; for 13h; Inert atmosphere;
93%
Stage #1: ortho-cresol With potassium tert-butylate In tetrahydrofuran for 1h;
Stage #2: ortho-nitrofluorobenzene In tetrahydrofuran
4-tert-Butylaniline
769-92-6

4-tert-Butylaniline

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

(4-tert-butyl-phenyl)-(2-nitro-phenyl)-amine
188844-98-6

(4-tert-butyl-phenyl)-(2-nitro-phenyl)-amine

Conditions
ConditionsYield
In dimethyl sulfoxide at 100℃;100%
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide at 65℃; for 18h;54%
With triethylamine In N,N-dimethyl-formamide at 80℃; for 12h;
2-(3,4-dimethoxyphenyl)-ethylamine
120-20-7

2-(3,4-dimethoxyphenyl)-ethylamine

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

N-[2-(3,4-dimethoxyphenyl)ethyl]-2-nitroaniline
5761-36-4

N-[2-(3,4-dimethoxyphenyl)ethyl]-2-nitroaniline

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In dimethyl sulfoxide at 70℃; for 16h;100%
With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide for 0.0966667h; microwave irradiation;
With diisopropylamine In N,N-dimethyl-formamide microwave irradiation;
With potassium carbonate In N,N-dimethyl-formamide at 60℃;
With potassium carbonate In N,N-dimethyl-formamide at 60℃; Microwave irradiation;
ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

4-bromo-aniline
106-40-1

4-bromo-aniline

4-bromo-N-(2-nitrophenyl)benzenamine
58476-59-8

4-bromo-N-(2-nitrophenyl)benzenamine

Conditions
ConditionsYield
In dimethyl sulfoxide at 100℃; for 48h; Inert atmosphere; Schlenk technique;100%
With potassium fluoride at 170 - 180℃; for 30h;92%
With potassium fluoride at 150℃; for 18h; Inert atmosphere;90%
ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

L-proline
147-85-3

L-proline

(S)-N-(2-nitrophenyl)proline
31981-54-1

(S)-N-(2-nitrophenyl)proline

Conditions
ConditionsYield
With sodium hydrogencarbonate In ethanol; water for 5h; Heating;100%
With sodium hydrogencarbonate In ethanol; water Heating;94%
With triethylamine In dimethyl sulfoxide80.3%
With sodium hydrogencarbonate In ethanol; water at 100℃;
phenyltrimethylsilyl ether
1529-17-5

phenyltrimethylsilyl ether

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

1-nitro-2-phenoxy-benzene
2216-12-8

1-nitro-2-phenoxy-benzene

Conditions
ConditionsYield
t-Bu-P4 base In hexane; N,N-dimethyl-formamide at 20℃; for 6h;100%
3-amino-2,2-dimethylpropan-1-ol
26734-09-8

3-amino-2,2-dimethylpropan-1-ol

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

2,2-dimethyl-3-(2-nitrophenylamino)propan-1-ol
336106-21-9

2,2-dimethyl-3-(2-nitrophenylamino)propan-1-ol

Conditions
ConditionsYield
In dimethyl sulfoxide at 20℃; for 3h;100%
ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

hexan-1-ol
111-27-3

hexan-1-ol

1-(hexyloxy)-2-nitrobenzene
67285-54-5

1-(hexyloxy)-2-nitrobenzene

Conditions
ConditionsYield
With triethylsilane; t-Bu-P4 In hexane; dimethyl sulfoxide at 100℃; for 2h;100%
ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

(R)-3-aminopyrrolidine-1-carboxylic acid tert-butyl ester
147081-49-0

(R)-3-aminopyrrolidine-1-carboxylic acid tert-butyl ester

tert-butyl (R)-3-((2-nitrophenyl)amino)pyrrolidine-1-carboxylate

tert-butyl (R)-3-((2-nitrophenyl)amino)pyrrolidine-1-carboxylate

Conditions
ConditionsYield
Stage #1: (R)-3-aminopyrrolidine-1-carboxylic acid tert-butyl ester With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 0.333333h;
Stage #2: ortho-nitrofluorobenzene In N,N-dimethyl-formamide at 80℃; for 16h;
100%
With potassium carbonate In N,N-dimethyl-formamide at 60℃;
3-(1-pyrrolidinyl)propylamine
23159-07-1

3-(1-pyrrolidinyl)propylamine

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

2-Nitro-1-(3-pyrrolidino-propylamino)-benzol
88858-51-9

2-Nitro-1-(3-pyrrolidino-propylamino)-benzol

Conditions
ConditionsYield
With potassium carbonate In DMF (N,N-dimethyl-formamide) at 20℃; for 16h;100%
In tetrahydrofuran at 30℃; for 12h; Inert atmosphere;
N,N',N'-trimethylenediamine
142-25-6

N,N',N'-trimethylenediamine

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

N,N,N'-trimethyl-N'-(2-nitrophenyl)-1,2-ethanediamine
371244-16-5

N,N,N'-trimethyl-N'-(2-nitrophenyl)-1,2-ethanediamine

Conditions
ConditionsYield
With sodium hydrogencarbonate In ethanol at 80℃; for 16h;100%
ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

1,1-dimethylethyl (3R)-3-(aminomethyl)-1-piperidinecarboxylate
140645-23-4

1,1-dimethylethyl (3R)-3-(aminomethyl)-1-piperidinecarboxylate

1,1-dimethylethyl (3R)-3-{[(2-nitrophenyl)amino]methyl}-1-piperidinecarboxylate
876590-06-6

1,1-dimethylethyl (3R)-3-{[(2-nitrophenyl)amino]methyl}-1-piperidinecarboxylate

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 5h; Heating / reflux;100%
With potassium carbonate In acetonitrile for 5h; Heating / reflux;100%
With potassium carbonate In acetonitrile Reflux;98%
ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

L-3-(2-thienyl)alanine
22951-96-8

L-3-(2-thienyl)alanine

(S)-2-(2-nitrophenylamino)-3-(thiophen-2-yl)propanoic acid
911359-29-0

(S)-2-(2-nitrophenylamino)-3-(thiophen-2-yl)propanoic acid

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 20 - 100℃; for 16h;100%
With potassium carbonate In ethanol; water at 20 - 100℃; for 16h;100%
With potassium carbonate In ethanol; water at 100℃; for 16h; sealed tube;95%
4-Trifluoromethoxyphenol
828-27-3

4-Trifluoromethoxyphenol

ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

1-nitro-2-[4 (trifluoromethoxy)phenoxy]benzene
23891-48-7

1-nitro-2-[4 (trifluoromethoxy)phenoxy]benzene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide for 5h; Product distribution / selectivity; Heating / reflux;100%
ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

4-fluoro-3-nitro-benzenesulfonic acid
3888-84-4

4-fluoro-3-nitro-benzenesulfonic acid

Conditions
ConditionsYield
With sulfuric acid at 60℃; for 0.5h;100%
With sulfuric acid; sulfur trioxide at 60℃; for 0.5h;
With chlorosulfonic acid at 80℃; for 10h;
ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

(2S)-aminopentanoic acid tert-butyl ester hydrochloride

(2S)-aminopentanoic acid tert-butyl ester hydrochloride

(S)-2-(2-nitro-phenylamino)-pentanoic acid tert-butyl ester
1090903-13-1

(S)-2-(2-nitro-phenylamino)-pentanoic acid tert-butyl ester

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 70℃;100%
ortho-nitrofluorobenzene
1493-27-2

ortho-nitrofluorobenzene

Cyclopropylamine
765-30-0

Cyclopropylamine

cyclopropyl-(2-nitro-phenyl)-amine
55432-23-0

cyclopropyl-(2-nitro-phenyl)-amine

Conditions
ConditionsYield
With triethylamine In acetonitrile at 110℃;100%
In dimethyl sulfoxide at 20 - 80℃;100%
at 20℃; for 12h;90.3%
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