High quality good supplier 4-Acetylbenzonitrile 1443-80-7 manufacturer Product Details Overview Quick Details Pro Name;4-Acetylbenzonitrile CAS NO:1443-80-7 Purity:99% Application: API Appearance:normal MF: C
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inquiryTIANFUCHEM-- 1443-80-7--High purity 4-ACETYLBENZONITRILE in stock Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable busin
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Cas:1443-80-7
Min.Order:1 Gram
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inquiry4-Acetylbenzonitrile CAS:1443-80-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inter
Cas:1443-80-7
Min.Order:1 Gram
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Min.Order:1 Kilogram
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Min.Order:1 Gram
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Product name: P-Cyanoacetophenone CAS No.:1443-80-7 Molecule Formula:C9H7NO Molecule Weight:145.15 Purity: 99% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard TESTING ITEMS
Cas:1443-80-7
Min.Order:1 Kilogram
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inquiryProduct Name 4-Acetylbenzonitrile CAS Number 1443-80-7 Density 1.1±0.1 g/cm3 Boiling Point 294.8±13.0 °C at 760 mmHg
Product Name: 4-Acetylbenzonitrile MF: C9H7NO MW: 145.16 EINECS: 215-885-0 Mol File: 1443-80-7.mol 4-Acetylbenzonitrile Structure 4-Acetylbenzonitrile Chemical Properties Melting point 56-59 °C(lit.) Boiling point 95-96&d
Cas:1443-80-7
Min.Order:1 Gram
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Type:Lab/Research institutions
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Min.Order:1 Kilogram
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Cas:1443-80-7
Min.Order:1 Gram
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Type:Lab/Research institutions
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Min.Order:1 Metric Ton
FOB Price: $7.0 / 8.0
Type:Trading Company
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Cas:1443-80-7
Min.Order:25 Kilogram
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Type:Trading Company
inquiryGOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation
Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai
Cas:1443-80-7
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inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier
high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp
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Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as
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4-Cyanophenacyl bromide
4-cyanophenyl methyl ketone
Conditions | Yield |
---|---|
With AcrH2; perchloric acid; tris(2,2’-bipyridine)ruthenium(II) In acetonitrile at 298℃; for 8h; Irradiation; | 100% |
With AcrH2; perchloric acid; tris(2,2’-bipyridine)ruthenium(II) In acetonitrile at 298℃; for 8h; Quantum yield; Mechanism; Irradiation; Electron-Transfer Rate Constants ;; | 100% |
With ammonium chloride; zinc In ethanol at 80℃; for 0.00833333h; microwave irradiation; | 99% |
Conditions | Yield |
---|---|
With copper(l) iodide; tetrabutylammomium bromide In water at 170℃; under 10343.2 Torr; for 0.05h; microwave irradiation; | 99% |
With sodium tetrahydroborate; zinc(II) chloride; Na2{PdCl2(Ph2P(m-C6H4SO3))2} In n-heptane; water for 1h; Heating; | 91% |
Conditions | Yield |
---|---|
In 1-methyl-pyrrolidin-2-one; water at 200℃; under 10343 Torr; for 0.166667h; microwave irradiation; | 99% |
Conditions | Yield |
---|---|
With tetrabutylammomium bromide In water at 170℃; under 10343.2 Torr; for 0.05h; microwave irradiation; | 99% |
Conditions | Yield |
---|---|
With [(2-di-tert-butylphosphino-2′,4′,6′-triisopropyl-1, 1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)] palladium(II) methanesulfonate In tetrahydrofuran; water at 20℃; for 18h; Inert atmosphere; | 99% |
With 1,1'-bis-(diphenylphosphino)ferrocene; palladium 10% on activated carbon; zinc(II) formate dihydrate In N,N-dimethyl acetamide at 100℃; for 12h; Inert atmosphere; | 89% |
Conditions | Yield |
---|---|
With tri-tert-butyl phosphine; [Pd2(dba)5]; zinc In tetrahydrofuran; acetonitrile at 70℃; for 2h; | 99% |
4-oxiran-2-ylbenzonitrile
4-cyanophenyl methyl ketone
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane; copper(II) choride dihydrate In toluene at 80℃; for 24h; Meinwald Rearrangement; Inert atmosphere; | 99% |
para-chloroacetophenone
2-hydroxy-2-methylpropanenitrile
4-cyanophenyl methyl ketone
Conditions | Yield |
---|---|
With [Pd(cinnamyl)Cl]2; N-ethyl-N,N-diisopropylamine; XPhos In isopropyl alcohol at 80℃; for 2h; Inert atmosphere; | 98% |
With N,N,N,N,-tetramethylethylenediamine; 1,5-bis-(diphenylphosphino)pentane; sodium carbonate; palladium diacetate In N,N-dimethyl acetamide at 140℃; for 21h; | 89 % Chromat. |
Conditions | Yield |
---|---|
With palladium diacetate; PS-triphenylphosphine In tetrahydrofuran at 120℃; for 1.5h; | 98% |
Conditions | Yield |
---|---|
With potassium phosphate tribasic trihydrate; C38H28O4P2Pd In N,N-dimethyl-formamide at 130℃; for 12h; | 98% |
With sodium carbonate In water; N,N-dimethyl-formamide at 120℃; for 10h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; | 96% |
With tris-(dibenzylideneacetone)dipalladium(0); tris(2-morpholinophenyl)phosphine; potassium carbonate In water; tert-butyl alcohol at 85℃; for 5h; Schlenk technique; Inert atmosphere; | 95% |
4-ethylbenzonitrile
4-cyanophenyl methyl ketone
Conditions | Yield |
---|---|
With Oxone; potassium bromide In dichloromethane; water at 20℃; for 24h; visible light irradiation; | 98% |
Stage #1: 4-ethylbenzonitrile With cis-RuCl2(4,4'-di-tert-butyl-2,2'-bipyridine)2; acetic acid In water for 0.0333333h; Darkness; Stage #2: With periodic acid In water for 4h; Darkness; chemoselective reaction; | 72% |
Stage #1: 4-ethylbenzonitrile With dichlorobis(4,4'-di-tert-butyl-2,2'-bipyridine)ruthenium(II); acetic acid In water for 0.0333333h; Darkness; Stage #2: With periodic acid In water for 4h; Darkness; | 72% |
Conditions | Yield |
---|---|
With sodium azide; trifluorormethanesulfonic acid In acetonitrile at 20℃; for 0.0333333h; Schmidt reaction; chemoselective reaction; | 98% |
Stage #1: p-formylacetophenone With hydroxylamine hydrochloride; triethylamine In dichloromethane at 20℃; for 0.0833333h; Stage #2: With potassium hydrogen difluoride; 3-(imidazole-1-sulfonyl)-1-methyl-3H-imidazol-1-ium triflate In water at 20℃; for 3h; | 95% |
With hydroxylamine hydrochloride In methanol; water at 20℃; for 18h; Irradiation; | 88% |
With ferric(III) bromide; trimethylsilylazide In acetonitrile at 60℃; for 4h; | 67% |
With ammonia; oxygen In tert-Amyl alcohol at 40℃; under 750.075 Torr; for 24h; Green chemistry; | 94 %Chromat. |
4-(1-hydroxyethyl)benzonitrile
3,3-dimethyldioxirane
A
4-cyanophenyl methyl ketone
B
2-hydroxy-1-(4-cyanophenyl)ethan-1-one
Conditions | Yield |
---|---|
In acetone at 25℃; for 3h; | A 97% B 2% |
In acetone at 25℃; for 3h; Rate constant; | A 97% B 2% |
Conditions | Yield |
---|---|
With 10% Pd/C; sodium fluoride In water at 130℃; for 2h; Microwave irradiation; | 97% |
With copper(l) iodide; sodium carbonate In N,N-dimethyl acetamide for 2h; Reflux; | 95% |
With [Pd{C6H3(CH2CH2NH2)-4-OMe-5-κ2-C,N}(μ-Br)]2; potassium carbonate In N,N-dimethyl-formamide at 130℃; for 0.1h; Microwave irradiation; | 93% |
Conditions | Yield |
---|---|
With dichlorobis(dibenzyl diisopropylphosphoramidite)palladium(II); sodium fluoride In N,N-dimethyl-formamide at 130℃; for 16h; Reagent/catalyst; | 97% |
With dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium; sodium carbonate In 1-methyl-pyrrolidin-2-one at 140℃; for 6h; Inert atmosphere; | 94% |
With caesium carbonate In N,N-dimethyl-formamide at 130℃; for 8h; Inert atmosphere; Sealed tube; | 94% |
Conditions | Yield |
---|---|
With Palladium Nanoparticles with two shape-persistent covalent cages CC1' In N,N-dimethyl-formamide at 140℃; for 15h; Reagent/catalyst; Inert atmosphere; | 97% |
With tetrabutylammomium bromide; copper(II) acetate monohydrate; potassium iodide In water at 20 - 140℃; Microwave irradiation; | 32% |
With sodium carbonate In N,N-dimethyl-formamide at 110℃; for 20h; Catalytic behavior; Sealed tube; | 97 %Chromat. |
tert-butylisonitrile
4-Iodoacetophenone
4-cyanophenyl methyl ketone
Conditions | Yield |
---|---|
With copper (II) trifluoroacetate hydrate; palladium diacetate In dimethyl sulfoxide at 130℃; for 6h; Sealed tube; Inert atmosphere; | 97% |
para-bromoacetophenone
2-hydroxy-2-methylpropanenitrile
4-cyanophenyl methyl ketone
Conditions | Yield |
---|---|
Stage #1: para-bromoacetophenone With copper(l) iodide; 1,10-Phenanthroline; potassium iodide In N,N-dimethyl-formamide at 110℃; for 6h; Stage #2: 2-hydroxy-2-methylpropanenitrile With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 110℃; for 60h; | 96% |
With 1,1'-bis-(diphenylphosphino)ferrocene; [(N,N,N',N'-tetramethylethylendiamine)NiCl(o-tolyl)]; N-ethyl-N,N-diisopropylamine In isopropyl alcohol at 80℃; for 2h; Inert atmosphere; | 86% |
With N,N,N,N,-tetramethylethylenediamine; 1,5-bis-(diphenylphosphino)pentane; sodium carbonate; palladium diacetate In N,N-dimethyl acetamide at 100℃; for 21h; | 100 % Chromat. |
Conditions | Yield |
---|---|
Stage #1: zinc(II) cyanide With aluminum oxide; Ni(xantphos)(o-tolyl)Cl for 1h; Schlenk technique; Inert atmosphere; Sealed tube; Stage #2: para-chloroacetophenone In 1-methyl-pyrrolidin-2-one at 20℃; for 24h; Schlenk technique; Inert atmosphere; | 96% |
With dmap; 1,1'-bis-(diphenylphosphino)ferrocene; nickel(II) chloride hexahydrate; zinc In acetonitrile at 80℃; for 8h; Schlenk technique; Inert atmosphere; Sealed tube; | 81% |
With dmap; 1,1'-bis-(diphenylphosphino)ferrocene; nickel(II) chloride hexahydrate; zinc In acetonitrile at 80℃; for 8h; Inert atmosphere; Sealed tube; | 81% |
With 1,1'-bis-(diphenylphosphino)ferrocene; palladium 10% on activated carbon; zinc(II) formate dihydrate In N,N-dimethyl acetamide at 120℃; for 12h; Inert atmosphere; | 70% |
4-Cyanophenacyl bromide
A
4-cyanophenyl methyl ketone
B
(±)-4-(2-bromo-1-hydroxyethyl)benzonitrile
Conditions | Yield |
---|---|
With 9,10-dihydro-10-methylacridine; perchloric acid In acetonitrile at 61.9℃; Product distribution; Mechanism; | A 95% B n/a |
Conditions | Yield |
---|---|
With C46H62NO3PPdS(2-); potassium acetate; XPhos In 1,4-dioxane; water at 100℃; for 1h; Inert atmosphere; Sealed tube; | 95% |
With potassium phosphate tribasic trihydrate; C38H28O4P2Pd In N,N-dimethyl-formamide at 130℃; for 16h; Catalytic behavior; Solvent; Reagent/catalyst; | 93% |
With palladium diacetate; sodium carbonate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In N,N-dimethyl acetamide at 120℃; for 10h; | 63% |
Conditions | Yield |
---|---|
With tetrakis(p-sulfonatophenyl)porphyrin cobalt(III) trisodium salt hexahydrate; water; bis(trifluoromethanesulfonyl)amide In methanol at 80℃; for 36h; Sealed tube; | 95% |
With chloro(1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene)gold(I) In methanol; water at 120℃; for 6h; Schlenk technique; regioselective reaction; | 92% |
With chloro(1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene)gold(I); water In methanol at 110℃; for 6h; | 92% |
zinc(II) cyanide
4-acetylphenyl p-toluenesulfonate
4-cyanophenyl methyl ketone
Conditions | Yield |
---|---|
With dmap; 1,1'-bis-(diphenylphosphino)ferrocene; nickel(II) chloride hexahydrate; zinc In acetonitrile at 80℃; for 12h; Sealed tube; | 95% |
With dmap; nickel(II) bromide dimethoxyethane; 1,4-di(diphenylphosphino)-butane; zinc In acetonitrile at 80℃; for 12h; Inert atmosphere; | 94% |
para-bromoacetophenone
formamide
4-cyanophenyl methyl ketone
Conditions | Yield |
---|---|
With 1,3,5-trichloro-2,4,6-triazine; palladium on activated charcoal; potassium carbonate; triphenylphosphine at 25 - 130℃; for 12.1667h; | 95% |
-butyl vinyl ether
4-cyanophenyl trifluoromethanesulfonate
A
4-cyanophenyl methyl ketone
B
(Z)-1-Butoxy-2-(4-cyanophenyl)ethylene
C
(E)-1-Butoxy-2-(4-cyanophenyl)ethylene
Conditions | Yield |
---|---|
With triethylamine; Pd(Ac2O)2-DPPP In N,N-dimethyl-formamide at 80℃; for 3h; Yields of byproduct given; | A 94% B n/a C n/a |
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene In various solvent(s) at 60℃; for 2h; | 94% |
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran for 1h; Substitution; Heating; |
Conditions | Yield |
---|---|
With 1,1'-bis-(diphenylphosphino)ferrocene; polymethylhydrosiloxane; palladium diacetate In water at 80℃; for 1.5h; | 94% |
With tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide at 80℃; for 5.5h; | 91% |
With water; tri tert-butylphosphoniumtetrafluoroborate; zinc; tris(dibenzylideneacetone)dipalladium(0) chloroform complex In 1-methyl-pyrrolidin-2-one at 20℃; for 24h; | 89% |
-butyl vinyl ether
4-bromobenzenecarbonitrile
4-cyanophenyl methyl ketone
Conditions | Yield |
---|---|
Stage #1: -butyl vinyl ether; 4-bromobenzenecarbonitrile With palladium diacetate; 1,3-bis-(diphenylphosphino)propane; triethylamine In various solvent(s) at 110℃; for 36h; Heck reaction; Stage #2: With hydrogenchloride Further stages.; | 94% |
With 1,3-bis-(diphenylphosphino)propane; diisopropylamine; 1-butyl-3-methylimidazolium Tetrafluoroborate; palladium diacetate In dimethyl sulfoxide at 115℃; for 36h; Heck arylation; | 88% |
Stage #1: -butyl vinyl ether; 4-bromobenzenecarbonitrile With meso-2,4-bis(diphenylphosphino)pentane; triethylamine; palladium diacetate In dimethyl sulfoxide at 115℃; for 36h; Heck arylation; Stage #2: With hydrogenchloride In dimethyl sulfoxide at 20℃; | 86% |
4-(1-hydroxyethyl)benzonitrile
4-cyanophenyl methyl ketone
Conditions | Yield |
---|---|
With oxygen; C26H21BrO In dichloromethane for 12h; Irradiation; | 94% |
With sodium hypochlorite; sodium hydrogencarbonate; potassium bromide In dichloromethane; water at 0℃; for 0.166667h; Schlenk technique; | 93% |
With iodine; potassium carbonate; [bis(pyridine)iodine]+ tetrafluoroborate In acetonitrile at 60℃; for 21h; | 85% |
4-Iodoacetophenone
4-cyanophenyl methyl ketone
Conditions | Yield |
---|---|
With potassium phosphate In N,N-dimethyl-formamide at 120℃; for 1.5h; | 94% |
4-cyanophenyl methyl ketone
4-Cyanophenacyl bromide
Conditions | Yield |
---|---|
With bromine | 100% |
With N-Bromosuccinimide; trimethylsilyl trifluoromethanesulfonate In acetonitrile at 25℃; Inert atmosphere; | 72% |
With bromine In chloroform at 20℃; for 20h; Inert atmosphere; | 71% |
4-cyanophenyl methyl ketone
4-(1-hydroxyethyl)benzonitrile
Conditions | Yield |
---|---|
With methanol; sodium tetrahydroborate In tetrahydrofuran at 0 - 20℃; for 0.666667h; | 100% |
With methanol; sodium tetrahydroborate at 0 - 25℃; for 5h; Inert atmosphere; | 100% |
With C15H13MnN3O3(1+)*Br(1-); potassium tert-butylate; isopropyl alcohol at 70℃; for 24h; Schlenk technique; Inert atmosphere; chemoselective reaction; | 99% |
4-cyanophenyl methyl ketone
4-(1,1-difluoroethyl)benzonitrile
Conditions | Yield |
---|---|
With diethylamino-sulfur trifluoride In dichloromethane at 50℃; for 20h; | 100% |
With (bis-(2-methoxyethyl)amino)sulfur trufluoride for 24h; | 68.6% |
With F6Mo; boron trifluoride In dichloromethane at -20 - 20℃; |
4-cyanophenyl methyl ketone
4,4′-(2,3-dihydroxybutane-2,3-diyl)dibenzonitrile
Conditions | Yield |
---|---|
With zinc(II) chloride; zinc In tetrahydrofuran; water for 3h; Ambient temperature; | 100% |
With CdS(x)Se(1-x) x:0-1;; para-thiocresol In hexane for 22h; Inert atmosphere; Irradiation; | 99% |
With CeI2 In tetrahydrofuran 1.) 2 h, 0 deg C, 2.) 12 h, room temp.; | 91% |
With tetrachlorosilane; zinc In dichloromethane at 20℃; for 20h; | 62% |
With ytterbium In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide for 3h; Ambient temperature; | 58% |
4-cyanophenyl methyl ketone
ethylene glycol
4-(2-methyl-[1,3]dioxolan-2-yl)benzonitrile
Conditions | Yield |
---|---|
With zeolite HSZ-360 In toluene for 5h; Heating; | 100% |
With ammonium chloride In toluene Reflux; Dean-Stark; | 94% |
With N-Bromosuccinimide; trimethyl orthoformate at 25 - 65℃; for 12h; | 92% |
4-cyanophenyl methyl ketone
potassium cyanide
ammonium carbonate
4-(R,S)-(4-cyanophenyl)-4-methyl-2,5-dioxoimidazolidine
Conditions | Yield |
---|---|
In ethanol at 60℃; for 72h; | 100% |
4-cyanophenyl methyl ketone
4-oxoacetyl-benzonitrile hydrate
Conditions | Yield |
---|---|
With selenium(IV) oxide; water In 1,4-dioxane for 72h; Inert atmosphere; Reflux; | 100% |
With selenium(IV) oxide; water In 1,4-dioxane at 50 - 55℃; Reflux; Inert atmosphere; Schlenk technique; |
4,7-dichloroisatin
4-cyanophenyl methyl ketone
4-(2-(4,7-dichloro-3-hydroxy-2-oxoindolin-3-yl)acetyl)benzonitrile
Conditions | Yield |
---|---|
With diethylamine In methanol at 20℃; | 100% |
With diethylamine In methanol at 20℃; | 100% |
With diethylamine In methanol at 20℃; | 64% |
4-cyanophenyl methyl ketone
methyltrichlorotitanium
4-(2-hydroxypropan-2-yl)benzenecarbonitrile
Conditions | Yield |
---|---|
at -5 - -4℃; for 1h; Solvent; Temperature; Large scale; | 99.7% |
Conditions | Yield |
---|---|
With phosphate buffer at 30℃; for 24h; rhodococcus rhodocrous AJ270, pH 7.0; | 99% |
With potassium phosphate buffer at 30℃; for 24h; Rhodococcus sp. AJ270 cells; | 99.3% |
With sulfuric acid |
4-cyanophenyl methyl ketone
(S)-4-(1-hydroxyethyl)benzonitrile
Conditions | Yield |
---|---|
With (R)-2,2',6,6'-tetramethoxy-4,4'-bis(di-3,5-dimethylphenylphosphine)3,3'-bipyridine; phenylsilane; cobalt(II) diacetate tetrahydrate In toluene at 40℃; for 36h; Molecular sieve; Under air; optical yield given as %ee; enantioselective reaction; | 99% |
With triiron dodecarbonyl; C52H58N4P2; hydrogen; potassium hydroxide In methanol at 45℃; under 37503.8 Torr; for 10h; enantioselective reaction; | 98% |
Stage #1: 4-cyanophenyl methyl ketone With dimethylsulfide borane complex; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole In tetrahydrofuran; toluene at -20 - -12.8℃; for 3.33333h; Industry scale; Stage #2: With methanol In tetrahydrofuran; toluene at -1.5℃; for 0.55h; | 95% |
4-cyanophenyl methyl ketone
1-(4-(1-H-tetrazol-5-yl) phenyl) ethanone
Conditions | Yield |
---|---|
With trimethylsilylazide; dibutyltin diacetate In benzene at 30℃; for 60h; | 99% |
With trimethylsilylazide; di(n-butyl)tin oxide In toluene at 90 - 120℃; | 99% |
With sodium azide; C32H25ClCuN6O9 In dimethyl sulfoxide at 110℃; for 5h; Reagent/catalyst; | 98% |
m-bromobenzoic aldehyde
4-cyanophenyl methyl ketone
4-[3-(3-bromophenyl)-1-oxo-2-propenyl]benzonitrile
Conditions | Yield |
---|---|
With sodium hydroxide In methanol at 0 - 20℃; for 4h; Claisen-Schmidt condensation; | 99% |
4-cyanophenyl methyl ketone
diphenylsilane
4-(1-((diphenylsilyl)oxy)ethyl)benzonitrile
Conditions | Yield |
---|---|
With C84H110N10Zn2 In neat (no solvent) at 20℃; for 12h; Sealed tube; Inert atmosphere; Schlenk technique; Glovebox; | 99% |
With iron(II) bis(trimethylsilyl)amide In benzene-d6 at 23℃; for 17h; Inert atmosphere; |
Conditions | Yield |
---|---|
With C42H50Mg2N4 In benzene-d6 at 60℃; for 5h; Glovebox; Inert atmosphere; | 99% |
With C32H39Br2MgN2(1-)*C16H32LiO4(1+) In chloroform-d1 at 20℃; for 48h; Inert atmosphere; Glovebox; chemoselective reaction; | 73% |
With TBA8H2[(γ-SiYW10O36)2]*7H2O In 1,2-dichloro-ethane at 30℃; under 760.051 Torr; for 1h; Air atmosphere; | 90 %Chromat. |
With zinc(II) iodide In dichloromethane for 2h; |
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 0.0833333h; | 99% |
4-cyanophenyl methyl ketone
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
Conditions | Yield |
---|---|
With C84H110N10Zn2 In neat (no solvent) at 20℃; for 6h; Sealed tube; Inert atmosphere; Schlenk technique; Glovebox; | 99% |
With C14H24N4Si(1+)*I(1-) In benzene-d6 at 90℃; for 1h; Catalytic behavior; Inert atmosphere; Schlenk technique; regioselective reaction; | 90% |
With C24H45MgNO2Si at 20℃; for 4h; Schlenk technique; Glovebox; Inert atmosphere; | 99 %Spectr. |
4-cyanophenyl methyl ketone
ketene t-butyldimethylsilyl methyl acetal
Conditions | Yield |
---|---|
Stage #1: 4-cyanophenyl methyl ketone With bis(trifluoromethanesulfonyl)amide In diethyl ether at -78 - 23℃; Mukaiyama Aldol Addition; Schlenk technique; Inert atmosphere; Stage #2: ketene t-butyldimethylsilyl methyl acetal In diethyl ether at -20℃; for 0.5h; Mukaiyama Aldol Addition; Schlenk technique; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
With C39H50N6O In toluene at -60℃; for 68h; enantioselective reaction; | 99% |
Conditions | Yield |
---|---|
With C56H48ClN3Pd; sodium t-butanolate In 1,4-dioxane at 100℃; for 4h; Reagent/catalyst; | 99% |
4-cyanophenyl methyl ketone
4-acetylbenzamide
Conditions | Yield |
---|---|
With 4-(benzyloxy)-1-hydroxy-2,2,6,6-tetramethylpiperidine In dichloromethane at 50℃; for 65h; | 98% |
With [2,2]bipyridinyl; water; palladium diacetate at 70℃; for 24h; Schlenk technique; Sealed tube; | 98% |
With water at 140℃; for 1h; Inert atmosphere; | 97% |
4-cyanophenyl methyl ketone
benzaldehyde
4-(1-oxo-3-phenyl-2-propen-1-yl)benzonitrile
Conditions | Yield |
---|---|
With Co(II)-VP-St (crosslinked 4-vinylpyridine-styrene copolimer); N,N-dimethyl-formamide at 80℃; for 18h; | 98% |
With sodium hydroxide In ethanol; water at 20℃; | 50% |
With potassium hydroxide In water at 20℃; Claisen-Schmidt Condensation; | 23% |
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