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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Magnesium,bromo(4-methylphenyl)- Manufacturer/High quality/Best price/In stock

Cas:4294-57-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality p-Tolylmagnesium Bromide supplier in China

Cas:4294-57-9

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

(p-Tolyl)-magnesium bromide

Cas:4294-57-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

p-Tolylmagnesium bromide

Cas:4294-57-9

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

P-TOLYLMAGNESIUM BROMIDE Basic information Product Name: P-TOLYLMAGNESIUM BROMIDE Synonyms: 4-METHYLPHENYLMAGNESIUM BROMIDE;P-TOLYLMAGNESIUM BROMIDE;bromo(4-methylphenyl)-magnesiu;p-tolylmagnesiumbromides

P-TOLYLMAGNESIUM BROMIDE 4294-57-9

Cas:4294-57-9

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Discount price CAS 4294-57-9 with best quality

Cas:4294-57-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Magnesium,bromo(4-methylphenyl)-

Cas:4294-57-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:4294-57-9

Cas:4294-57-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in lead acetate, diphenyl ethylamine and other chemical raw materials and chemical reagents research and development production enterprises. Our business covers more than 30 countrie

high quality best price P-Tolylmagnesium Bromide CAS 4294-57-9

Cas:4294-57-9

Min.Order:1 Kilogram

FOB Price: $100.0

Type:Trading Company

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

P-TOLYLMAGNESIUM BROMIDE

Cas:4294-57-9

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Magnesium,bromo(4-methylphenyl)-

Cas:4294-57-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

P-TOLYLMAGNESIUM BROMIDE Chemical Properties Melting point >300℃ (acetonitrile ethyl ether ) Boiling point 65-67 °C density 1.002 g/mL at 25 °C Fp −1 °F storage temp. 2-8°C BRN 636491 EPA Substance Reg

p-Tolylmagnesium bromide

Cas:4294-57-9

Min.Order:1 Gram

FOB Price: $65.0

Type:Lab/Research institutions

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healthtide biotech co.,ltd

Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can be

P-TOLYLMAGNESIUM BROMIDE CAS 4294-57-9

Cas:4294-57-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Trading Company

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

n-Amylcyclohexane

Cas:4294-57-9

Min.Order:0

Negotiable

Type:Other

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GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

p-Tolylmagnesium bromide

Cas:4294-57-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

p-TolylMagnesiuM BroMide (19% in Tetrahydrofuran, ca. 1Mol/L)

Cas:4294-57-9

Min.Order:0

Negotiable

Type:Manufacturers

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

p-Tolylmagnesium Bromide

Cas:4294-57-9

Min.Order:0

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

p-TolylMagnesiuM broMide, 0.5 M solution in diethyl ether, J&KSeal

Cas:4294-57-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Fandachem Co.,Ltd

Magnesium,bromo(4-methylphenyl)- cas 4294-57-9Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Magnesium,bromo(4-methylphenyl)- cas 4294-57-9

Cas:4294-57-9

Min.Order:0

Negotiable

Type:Other

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Shanghai Yuanye Bio-Technology Co., Ltd.

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Appearance:White powder Storage:keep sealed and keep from direct light Package:According client's requirements Application:pharmaceutica

p-Tolylmagnesium bromide manufacturer

Cas:4294-57-9

Min.Order:0

Negotiable

Type:Trading Company

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

P-TOLYLMAGNESIUM BROMIDE

Cas:4294-57-9

Min.Order:0

Negotiable

Type:Trading Company

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#4294-57-9;CAT#A872788

Cas:4294-57-9

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

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Hebei youze Biotechnology Co.,Ltd

What's our company advantages 1.Government support guarantees good company credibility and finance safe. 2.Place of Origin China with Super quality by reasonable price. 3.Fast delivery by safe express way to all the country. 4.We

P-Tolylmagnesium Bromide CAS.4294-57-9 high purity spot goods best price

Cas:4294-57-9

Min.Order:1 Kilogram

FOB Price: $11.0

Type:Trading Company

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suzhou BetterBioChem Co., Ltd.

Betterbiochem is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in

P-Tolylmagnesium Bromide

Cas:4294-57-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen BaiFuchem Co.,Ltd

BaiFuChem is a Professional chemical raw material supplier in China, our main products include Biochemical , Pharma Intermediate and Organic chemical etc. BaiFuChem have wealth of products,experience , expertise and state-of-the-art

High quality p-Tolylmagnesium Bromide

Cas:4294-57-9

Min.Order:1 Kilogram

Negotiable

Type:Other

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AOPHARM

Aopharm is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in modes of

p-Tolylmagnesium Bromide

Cas:4294-57-9

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

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Hangzhou Yierdechem Co. Ltd

With about ten years experiences in the field of pharmaceutical chemicals, Yierdechem has established solid business cooperation relationships with many large companys worldwide.As a leading supplier of API and pharmaceutical intermediates, holds its

p-Tolylmagnesium bromide

Cas:4294-57-9

Min.Order:0

Negotiable

Type:Other

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Xiamen Ikg Chemical Co., Ltd.

IKGCHEM is a leading manufacturer and supplier of chemical in China.As a Professional chemical raw material supplier,our products are produced in accordance with ISO 9001:2015 Quality Management System and ISO14001:2015 Environmental Management Syste

P-Tolylmagnesium Bromide

Cas:4294-57-9

Min.Order:0

Negotiable

Type:Trading Company

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Sigma-Aldrich Chemie GmbH

Package:1 L in Sure/Seal(TM) Application:p-Tolylmagnesium bromide is a common Grignard reagent. It can also be used in a variety of cross-coupling reactions.

p-Tolylmagnesium bromide solution

Cas:4294-57-9

Min.Order:0

Negotiable

Type:Trading Company

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NovaChemistry

high purity Application:Drug intermediates Materials intermediates and active molecules

P-Tolylmagnesium Bromide

Cas:4294-57-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

diethyl ether
60-29-7

diethyl ether

bis(p-tolyl)mercury
537-64-4

bis(p-tolyl)mercury

phenylmagnesium bromide

phenylmagnesium bromide

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

para-bromotoluene
106-38-7

para-bromotoluene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

Conditions
ConditionsYield
With magnesium In diethyl ether
With iodine; magnesium In tetrahydrofuran for 2h; Irradiation;
With magnesium In tetrahydrofuran
para-bromotoluene
106-38-7

para-bromotoluene

magnesium
7439-95-4

magnesium

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

Conditions
ConditionsYield
With ethylene dibromide In tetrahydrofuran for 3h; Heating / reflux;
In tetrahydrofuran
In tetrahydrofuran Inert atmosphere;
With iodine In tetrahydrofuran at 20℃;
para-bromotoluene
106-38-7

para-bromotoluene

bis(chloromethyl)phosphinic chloride
13482-64-9

bis(chloromethyl)phosphinic chloride

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

Conditions
ConditionsYield
With sodium iodide; sodium hydrogensulfite; magnesium In tetrahydrofuran; diethyl ether; water; butanone
5-(2-chlorophenyl)-2-(4-methoxybenzyl)tetrazole
179088-99-4

5-(2-chlorophenyl)-2-(4-methoxybenzyl)tetrazole

para-bromotoluene
106-38-7

para-bromotoluene

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

Conditions
ConditionsYield
With hydrogenchloride; diisobutylaluminium hydride; magnesium; triphenylphosphine In tetrahydrofuran; toluene
para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

(4,4'-dimethyl-1,1'-biphenyl)
613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

Conditions
ConditionsYield
With iron(III) chloride; 1,2-dichloro-ethane In diethyl ether for 1h; Heating;100%
With cobalt(II) chloride hexahydrate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In tetrahydrofuran at 0℃; for 1h; Inert atmosphere;99%
With iron(III) chloride; 1,2-dichloro-ethane In tetrahydrofuran at 0℃; for 0.0833333h; Ionic liquid; Inert atmosphere;99%
((Z)-3-Dimethylamino-2-phenyl-allylidene)-dimethyl-ammonium; perchlorate
7089-34-1

((Z)-3-Dimethylamino-2-phenyl-allylidene)-dimethyl-ammonium; perchlorate

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

(E)-2-phenyl-3-(p-tolyl)acrylaldehyde
79542-20-4

(E)-2-phenyl-3-(p-tolyl)acrylaldehyde

Conditions
ConditionsYield
In tetrahydrofuran 1.) reflux, 3 h, 2.) room temperature, overnight;100%
para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

1-{2-[(SS)-(p-tolylsulfinyl)]}pyrrolyl cinnamate
188608-74-4

1-{2-[(SS)-(p-tolylsulfinyl)]}pyrrolyl cinnamate

C27H24(2)HNO2S

C27H24(2)HNO2S

Conditions
ConditionsYield
Stage #1: para-methylphenylmagnesium bromide With copper(l) iodide In tetrahydrofuran at -30℃; for 0.5h;
Stage #2: 1-{2-[(SS)-(p-tolylsulfinyl)]}pyrrolyl cinnamate In tetrahydrofuran at -30℃; for 1h;
Stage #3: With water-d2 In tetrahydrofuran at 20℃; for 12h;
100%
N-methoxy-N-methylcyclohexanecarboxamide
80783-98-8

N-methoxy-N-methylcyclohexanecarboxamide

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

cyclohexyl(p-tolyl)methanone
2789-44-8

cyclohexyl(p-tolyl)methanone

Conditions
ConditionsYield
In diethyl ether at -78 - 25℃;100%
para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

tert-butyl 2-phenyldiazene-1-carboxylate
92491-22-0

tert-butyl 2-phenyldiazene-1-carboxylate

N'-phenyl-N'-p-tolyl-hydrazinecarboxylic acid tert-butyl ester

N'-phenyl-N'-p-tolyl-hydrazinecarboxylic acid tert-butyl ester

Conditions
ConditionsYield
In tetrahydrofuran at -100℃;100%
2-chloropyridine
109-09-1

2-chloropyridine

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With C32H41N12Ni2O(3+)*3F6P(1-) In tetrahydrofuran at 25℃; for 5h; Inert atmosphere; Schlenk technique;100%
With N-heterocyclic carbene-based nickel(II) complex In tetrahydrofuran at 20℃; for 12h; Kumada reaction;99%
With chloro(1,3-bis(pyridin-2-ylmethyl)imidazolylidene)nickel(II) hexafluorophosphate In tetrahydrofuran at 20℃; for 12h; Kumada-Corriu coupling reaction; Inert atmosphere;99%
triphenyltin chloride
639-58-7

triphenyltin chloride

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

triphenyl(p-tolyl)tin
15807-28-0

triphenyl(p-tolyl)tin

Conditions
ConditionsYield
In diethyl ether100%
In tetrahydrofuran byproducts: MgBrCl; dropwise addn. of Mg-compd. to Sn-compd, refluxed for 5 h, hydrolysed with HCl; evapd., filtered, dried, extd. (toluene), recrystd. (EtOH/toluene); elem. anal.;55%
10-chlorophenothiabismine 5,5-dioxide
143674-29-7

10-chlorophenothiabismine 5,5-dioxide

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

10-(4'-methylphenyl)phenothiabismine 5,5-dioxide
143674-28-6

10-(4'-methylphenyl)phenothiabismine 5,5-dioxide

Conditions
ConditionsYield
With ethylacetat In tetrahydrofuran (under Ar); addn. of 4-methylphenylmagnesium bromide in THF to 10-chlorophenothiabismine in THF, stirring for 10 min at room temp.; extn., sepn. of organic layer, drying, concg. under reduced pressure, recrystn. from MeOH-C6H6 (5:1), elem.anal.;100%
3α-hydroxy-4α,4aα,7α,7aα-dihydronepetalactone
77714-57-9

3α-hydroxy-4α,4aα,7α,7aα-dihydronepetalactone

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

(3R,4R,4aR,7S,7aR)-4,7-dimethyl-3-(4-methylphenyl)hexahydrocyclopenta[c]pyran-1(3H)-one

(3R,4R,4aR,7S,7aR)-4,7-dimethyl-3-(4-methylphenyl)hexahydrocyclopenta[c]pyran-1(3H)-one

Conditions
ConditionsYield
Stage #1: 3α-hydroxy-4α,4aα,7α,7aα-dihydronepetalactone With potassium hydride In tetrahydrofuran; hexane at 0℃; for 0.333333h;
Stage #2: para-methylphenylmagnesium bromide In tetrahydrofuran; hexane at 0 - 20℃; for 1h;
100%
P,P-diphenyl-N-(phenyl(o-tolyl)methylene)phosphinic amide

P,P-diphenyl-N-(phenyl(o-tolyl)methylene)phosphinic amide

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

P,P-diphenyl-N-(phenyl(o-tolyl)(p-tolyl)methyl)phosphinic amide

P,P-diphenyl-N-(phenyl(o-tolyl)(p-tolyl)methyl)phosphinic amide

Conditions
ConditionsYield
In diethyl ether; n-heptane; toluene at 20℃; Inert atmosphere; Schlenk technique;100%
trans geranyl acetone
3796-70-1

trans geranyl acetone

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

E-6,10-dimethyl-2-hydroxy-2-(p-tolyl)-5,9-undecadiene
70026-33-4

E-6,10-dimethyl-2-hydroxy-2-(p-tolyl)-5,9-undecadiene

Conditions
ConditionsYield
In diethyl ether at 20℃;100%
2,4,6-tris(phenyltelluro)-1,3,5-triazine
142312-17-2

2,4,6-tris(phenyltelluro)-1,3,5-triazine

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

2,4,6-tris(p-tolyl)-1,3,5-triazine
6726-45-0

2,4,6-tris(p-tolyl)-1,3,5-triazine

Conditions
ConditionsYield
With bis(triphenylphosphine)nickel(II) chloride In tetrahydrofuran for 8h; Heating;99%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-(4-tolyl)anisole
53040-92-9

4-(4-tolyl)anisole

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene hydrochloride In tetrahydrofuran; 1,4-dioxane at 80℃; for 3h; Arylation;99%
With N-heterocyclic carbene-based nickel(II) complex In tetrahydrofuran at 20℃; for 12h; Kumada reaction;99%
With iron(II) triflate; 1,3-bis(2,4,6-trimethylphenyl)-4,5,6,7-tetrahydro-1H-1,3-diazepinium bromide; sodium t-butanolate In tetrahydrofuran at 60℃; for 16h; Kumada Cross-Coupling; Sealed tube; Inert atmosphere;99%
δ-chlorovaleronitrile
6280-87-1

δ-chlorovaleronitrile

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

5-(p-tolyl)pentanenitrile
79593-79-6

5-(p-tolyl)pentanenitrile

Conditions
ConditionsYield
With 1-methyl-pyrrolidin-2-one; palladium diacetate; tricyclohexylphosphine In tetrahydrofuran at 20℃; for 20h; Kumada coupling;99%
With 1,3-bis(mesityl)imidazolium chloride; palladium diacetate In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 20℃; for 1h; Kumada reaction;93%
isobutyryl chloride
513-36-0

isobutyryl chloride

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

1-methyl-4-(2-methylpropyl)-benzene
5161-04-6

1-methyl-4-(2-methylpropyl)-benzene

Conditions
ConditionsYield
With 1,3-bis(mesityl)imidazolium chloride; palladium diacetate In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 20℃; for 1h; Kumada reaction;99%
1-bromocyclohexane
108-85-0

1-bromocyclohexane

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

1-cyclohexyl-4-methylbenzene
4501-36-4

1-cyclohexyl-4-methylbenzene

Conditions
ConditionsYield
With C34H51N2O2(1+)*Cl4Fe(1-) In diethyl ether Concentration; Reagent/catalyst; Grignard Reaction;99%
With N,N,N,N,-tetramethylethylenediamine; iron(III) chloride In tetrahydrofuran at 25℃; for 0.5h;96%
With N,N,N,N,-tetramethylethylenediamine; iron(III) chloride In tetrahydrofuran at 25℃;96%
fluorobenzene
462-06-6

fluorobenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With C35H31BrN4NiP In tetrahydrofuran at 25℃; for 24h; Schlenk technique; Inert atmosphere;99%
With supramolecular ensemble of HP-T with Au-Fe3O4 nanoparticles; air In tetrahydrofuran; water at 20℃; for 3h; Kumada Cross-Coupling; Irradiation;60%
1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In tetrahydrofuran at 20℃; for 24h;92 % Chromat.
N,N-diethyl phenyl O-sulfamate
1015-49-2

N,N-diethyl phenyl O-sulfamate

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
NiClCpIMes In diethyl ether at 40℃; for 24h; Grignard cross-coupling reaction;99%
1-fluoro-4-methoxybenzene
459-60-9

1-fluoro-4-methoxybenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-(4-tolyl)anisole
53040-92-9

4-(4-tolyl)anisole

Conditions
ConditionsYield
With C35H31BrN4NiP In tetrahydrofuran at 25℃; for 24h; Concentration; Schlenk technique; Inert atmosphere;99%
With 1-[2-(diphenylphosphino)phenyl]ethanol; bis(acetylacetonate)nickel(II) In diethyl ether at 20℃; for 12h;97%
With C26H24ClN2NiP*0.1C7H8 In toluene at 25℃; for 24h; Reagent/catalyst; Solvent; Kumada Cross-Coupling; Schlenk technique; Inert atmosphere;90%
iodobenzene
591-50-4

iodobenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
amido pincer complex of nickel chloride catalyst In toluene at 20℃; for 12h; Kumada cross-coupling reaction;99%
[Ni-(o-MeC6H4){2-{OC(Ph)2CH2}-6-(3,5-Me2C3HN2)C5H3N}] In tetrahydrofuran; toluene for 12h; Kumada reaction; Heating;99%
With supramolecular ensemble of HP-T with Au-Fe3O4 nanoparticles; air In tetrahydrofuran; water at 20℃; for 0.333333h; Kumada Cross-Coupling; Irradiation;87%
para-iodoanisole
696-62-8

para-iodoanisole

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-(4-tolyl)anisole
53040-92-9

4-(4-tolyl)anisole

Conditions
ConditionsYield
amido pincer complex of nickel chloride catalyst In toluene at 20℃; for 12h; Kumada cross-coupling reaction;99%
With self-assembled multilayer nickel nanoparticle catalyst - sulfur-modified gold-supported Ni NPs (SANi) In tetrahydrofuran at 75℃; for 3h; Kumada Cross-Coupling; Inert atmosphere;95%
[Ni(1-C10H7){2-{OC(Ph)2CH2}-6-(3,5-Me2C3HN2)C5H3N}] In tetrahydrofuran; toluene for 12h; Kumada reaction; Heating;91%
With supramolecular ensemble of HP-T with Au-Fe3O4 nanoparticles; air In tetrahydrofuran; water at 20℃; for 0.333333h; Kumada Cross-Coupling; Irradiation;89%
chlorobenzene
108-90-7

chlorobenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
amido pincer complex of nickel chloride catalyst In tetrahydrofuran at 20℃; for 24h; Kumada cross-coupling reaction;99%
With ((C6H4)(OPPh2)(NCHPhPPh2))NiCl In tetrahydrofuran at 25℃; for 24h; Kumada cross-coupling; Inert atmosphere;99%
With Fe2(OtBu)6; sodium t-butanolate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In tetrahydrofuran at 80℃; for 16h; Catalytic behavior; Reagent/catalyst; Time; Kumada Cross-Coupling; Glovebox; Inert atmosphere;99%
bromobenzene
108-86-1

bromobenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
[Pd(Cl){2-{OC(Ph)=CH}-6-(3,5-Me2C3HN2)C5H3N}] In tetrahydrofuran; toluene for 6h; Kumada reaction; Heating;99%
With C16H16Cl2CoN8(1+)*F6P(1-) In tetrahydrofuran at 20℃; for 2h; Kumada-Corriu cross-coupling;96%
With [1,3-bis(2,6-diisopropylphenyl)-imidazolium][Ni(PPh3)Cl3] In tetrahydrofuran at 30℃; for 1h; Kumada Cross-Coupling; Schlenk technique; Inert atmosphere;96%
para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

N,N-dimethyl-N-[2-(5,6,7,8-tetrahydronaphthalen-2-yloxy)ethyl]amine

N,N-dimethyl-N-[2-(5,6,7,8-tetrahydronaphthalen-2-yloxy)ethyl]amine

6-(4-methylphenyl)-1,2,3,4-tetrahydronaphthalene

6-(4-methylphenyl)-1,2,3,4-tetrahydronaphthalene

Conditions
ConditionsYield
With tricyclohexylphosphine; bis(tricyclohexylphosphine)nickel(II) dichloride In formaldehyde diethyl acetal at 20 - 95℃; for 15h;99%
bromobenzene
108-86-1

bromobenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

A

(4,4'-dimethyl-1,1'-biphenyl)
613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

B

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With CoF2*4H2O; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In tetrahydrofuran at 60℃; for 3h; Inert atmosphere;A 7%
B 99%
phenylnickel N-Bu-6-[1-(2,6-(Me)2PhN)ethyl]picolinamide In tetrahydrofuran; toluene at 20℃; for 24h;
With (N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))NiCl In tetrahydrofuran at 25℃; for 12h; Kumada coupling reaction; Inert atmosphere;A 32 %Chromat.
B 63 %Chromat.
chlorobenzene
108-90-7

chlorobenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

A

(4,4'-dimethyl-1,1'-biphenyl)
613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

B

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With C68H72Cl2N6NiP2 In diethyl ether at 25℃; for 12h; Kumada coupling reaction; Inert atmosphere;A n/a
B 99%
With FeF3*H2O; tricyclohexylphosphine In tetrahydrofuran at 20 - 60℃; for 24h; Inert atmosphere;A 4%
B 5%
(1-naphthyl)Ni N-Bu-6-[1-(2,6-(i-Pr)2PhN)ethyl]picolinamide In tetrahydrofuran; toluene at 20℃; for 24h;
2-chloropyrimidine
1722-12-9

2-chloropyrimidine

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

2-p-tolyl-pyrimidine
77232-13-4

2-p-tolyl-pyrimidine

Conditions
ConditionsYield
With N-heterocyclic carbene-based nickel(II) complex In tetrahydrofuran at 20℃; for 12h; Kumada reaction;99%
With chloro(1,3-bis(pyridin-2-ylmethyl)imidazolylidene)nickel(II) hexafluorophosphate In tetrahydrofuran at 20℃; for 12h; Kumada-Corriu coupling reaction; Inert atmosphere;99%
With C16H16Cl2CoN8(1+)*F6P(1-) In tetrahydrofuran at 20℃; for 2h; Kumada-Corriu cross-coupling;97%
With (IPr)Ni(π-allyl)Cl In tetrahydrofuran at 20℃; for 24h; Kumada Cross-Coupling; Inert atmosphere;74%
With [Ni(1-(1-ethyl-benzimidazol-2-ylmethyl)-3-mesitylimidazolin-2-ylidene)2][Cl]2; sodium acetate In tetrahydrofuran at 20℃; Kumada-Corriu coupling reaction; Inert atmosphere;
4-Cyanochlorobenzene
623-03-0

4-Cyanochlorobenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

p-(p-tolyl)benzonitrile
50670-50-3

p-(p-tolyl)benzonitrile

Conditions
ConditionsYield
With ((C6H4)(OPPh2)(NCHPhPPh2))NiCl In tetrahydrofuran at 25℃; for 12h; Kumada cross-coupling; Inert atmosphere;99%
With C35H31BrN4NiP In tetrahydrofuran at 25℃; for 14.5h; Schlenk technique; Inert atmosphere;97%
With N-heterocyclic carbene-based nickel(II) complex In tetrahydrofuran at 20℃; for 12h; Kumada reaction;84%
2,6-dichloropyridine
2402-78-0

2,6-dichloropyridine

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

2,6-di-p-tolylpyridine
14435-88-2

2,6-di-p-tolylpyridine

Conditions
ConditionsYield
With chloro(1,3-bis(pyridin-2-ylmethyl)imidazolylidene)nickel(II) hexafluorophosphate In tetrahydrofuran at 20℃; for 12h; Kumada-Corriu coupling reaction; Inert atmosphere;99%
With N-heterocyclic carbene-based nickel(II) complex In tetrahydrofuran at 20℃; for 12h; Kumada reaction;95%
para-dichlorobenzene
106-46-7

para-dichlorobenzene

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

1,4-bis(p-tolyl)benzene
97295-31-3

1,4-bis(p-tolyl)benzene

Conditions
ConditionsYield
With C36H32ClN4NiP In tetrahydrofuran at 70℃; for 20h; Reagent/catalyst; Kumada Cross-Coupling; Schlenk technique; Inert atmosphere;99%
With N-heterocyclic carbene-based nickel(II) complex In tetrahydrofuran at 20℃; for 12h; Kumada reaction;89%
With C20H23BrN4Ni In tetrahydrofuran at 25℃; for 24h; Kumada Cross-Coupling; Inert atmosphere;89%

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