Simagchem Corporation
Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:108-90-7
Min.Order:0 Metric Ton
Negotiable
Type:Manufacturers
inquiryHefei TNJ chemical industry co.,ltd
Technology: Technology innovation is our eternal pursuit,or we will be left behind.Our technology experts,all from famous universities and institutes,has rich experience and high achievements in chemical research.This makes sure that our technology
Ality Chemical Corporation
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Dayang Chem (Hangzhou) Co.,Ltd.
DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe
Cas:108-90-7
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryHenan Tianfu Chemical Co., Ltd.
Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O
Cas:108-90-7
Min.Order:1 Kilogram
FOB Price: $1000.0
Type:Lab/Research institutions
inquiryJinan Finer Chemical Co., Ltd
Product Description Product website: http://www.finerchem.com Product Name Chlorobenzene CAS No. 108-90-7 A
Cas:108-90-7
Min.Order:1 Metric Ton
FOB Price: $12.0
Type:Lab/Research institutions
inquiryHenan Sinotech Import&Export Corporation
CAS 108-90-7 Name chlorobenzene Appearance colorless liquid Application pharmaceutical Appearance:Colorless liquid Storage:Preserve in well-closed
Cas:108-90-7
Min.Order:5 Metric Ton
FOB Price: $1.0 / 2.0
Type:Other
inquiryChangchun Artel lmport and Export trade company
Product Detail Minimum Order Qty. 10 Gram
Cas:108-90-7
Min.Order:10 Gram
Negotiable
Type:Trading Company
inquiryLonwin Chemical Group Limited
Chlorobenzene CAS：108-90-7 Specification Product Name Chlorobenzene CAS No. 108-90-7 Appearance colorless or light yellow transparent liquid Assay ≥99% Capacity 100mt/year
Cas:108-90-7
Min.Order:1 Kilogram
FOB Price: $100.0 / 150.0
Type:Other
inquiryTriumph International Development Limilted
Appearance:white or yellowish white flaky crystal Storage:Keep the sun from direct sunlight ；prevention against high temperature Package:As customer request Application:Used for research and industrial manufacture. Transportatio
Hangzhou Keyingchem Co.,Ltd
Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Hangzhou J&H Chemical Co., Ltd.
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Zibo Hangyu Biotechnology Development Co., Ltd
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:108-90-7
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryHANGZHOU YUNUO CHEMICAL CO.,LTD
Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:200kg drums or as per your request Application:Chlorobenzene is a halogenated be
Zibo Dorne chemical technology co. LTD
Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Henan Wentao Chemical Product Co., Ltd.
We are leading fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...)
Cas:108-90-7
Min.Order:1 Kilogram
FOB Price: $5.0
Type:Lab/Research institutions
inquirySuzhou Sinosun Imp.&Exp. Corporation
We supply good quality Chlorobenzene CAS# 108-90-7 at competitive price. Our Chlorobenzene CAS# 108-90-7 has been exported to many countries and regions. If you are looking for Chlorobenzene CAS# 108-90-7 suppliers in China, Sinosun is your best ch
Hangzhou Huarong Pharm Co., Ltd.
Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu
Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)
Capability on chemical synthesis 1. Beijing High-Tech Enterprises 2. Strong R&D Team 3. 8 years of experiences in R & D of high-tech Catalyst; 4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sal
SAGECHEM LIMITED
SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe
Kono Chem Co.,Ltd
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
Hangzhou Dingyan Chem Co., Ltd
R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates
Wuhan Fortuna Chemical Co.,Ltd
Best service,high quality and cheap price. Storage:Keep away from heat,sparks and flames. Package:25kg/50kg/200kg drum or Customer demand Application:Used as pharmaceutical intermediates Transportation:BY sea/air or by courier
Henan Allgreen Chemical Co.,Ltd
high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
Aecochem Corp.
Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
Enke Pharma-tech Co.,Ltd. （Cangzhou, China ）
Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat
Hunan chemfish Pharmaceutical co.,Ltd
Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as
Zhuozhou Wenxi import and Export Co., Ltd
Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard
Cas:108-90-7
Min.Order:1 Kilogram
FOB Price: $112.0
Type:Trading Company
inquiryAntimex Chemical Limied
Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
Xiamen AmoyChem Co.,Ltd
Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi
Synthetic route
| Conditions | Yield |
|---|---|
| With potassium carbonate; iron pentacarbonyl In methanol at 60℃; under 760 Torr; for 8h; | 100% |
| With hydrogenchloride; CuI*P(Et)3; naphthalen-1-yl-lithium 1.) THF, 25 deg C, 10 min; Yield given. Multistep reaction; | |
| With 2,2'-azobis(isobutyronitrile); sodium methylate In methanol at 70.2℃; Mechanism; var. iodobenzenes; | |
| With tetrahydrofuran; 1,10-Phenanthroline; potassium tert-butylate at 70℃; for 24h; Schlenk technique; Inert atmosphere; chemoselective reaction; | 90 %Chromat. |
| With potassium tert-butylate at 80℃; for 12h; Inert atmosphere; Schlenk technique; | 88 %Chromat. |
| Conditions | Yield |
|---|---|
| With potassium carbonate; iron pentacarbonyl In methanol at 60℃; under 760 Torr; for 2h; | 100% |
| With hydrogen cation; copper 1) THF, 25 deg C, 10 min; Yield given. Multistep reaction; | |
| With hydrogenchloride; CuI*P(Et)3; naphthalen-1-yl-lithium 1.) THF, 25 deg C, 10 min; Yield given. Multistep reaction; | |
| With sodium methylate In methanol; dimethyl sulfoxide at 50.1℃; Rate constant; Mechanism; other iodoarenes; |
-
-
71-41-0
pentan-1-ol
-
-
95-50-1
1,2-dichloro-benzene
-
A
-
30752-18-2
1-bromo-4-pentyloxybenzene
-
B
-
51241-39-5
2-chlorophenyl pentyl ether
-
C
-
108-90-7
chlorobenzene
| Conditions | Yield |
|---|---|
| With potassium hydroxide; PEG-6000 at 150℃; for 6h; Yields of byproduct given; | A n/a B 100% C n/a |
| Conditions | Yield |
|---|---|
| With potassium chloride; potassium nitrate; trifluoroacetic acid at 20℃; for 5.04h; Product distribution; Mechanism; other time, other ratio of reagents, other solvent; | A 100% B n/a |
| Conditions | Yield |
|---|---|
| In not given decomposition at room temp.; | A 100% B 100% |
| Conditions | Yield |
|---|---|
| With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride In 2-pentanol at 100℃; for 20h; Inert atmosphere; | A 0.2% B 99.8% |
| With nickel at 80℃; for 4h; Product distribution; Ni derived from NiBr2 or from NiCl2; var. times; | |
| With nickel at 80℃; for 4h; | A 77 % Chromat. B 25 % Chromat. |
| Conditions | Yield |
|---|---|
| With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride In 2-pentanol at 100℃; for 57h; Inert atmosphere; | A 0.8% B 99.2% |
| In 1,2-dimethoxyethane at 85℃; Product distribution; var. solvents; var. times; Ni from NiI2 or NiBr2; | |
| With nickel In 1,2-dimethoxyethane at 85℃; for 20h; | A 61 % Chromat. B 32 % Chromat. |
| Conditions | Yield |
|---|---|
| With bis(cyclopentadienyl)titanium dichloride; sodium tetrahydroborate; air In N,N-dimethyl-formamide at 70℃; for 24h; | 99% |
| With butyl magnesium bromide; zirconocene dichloride In tetrahydrofuran for 1h; Ambient temperature; | 98% |
| With lithium aluminium tetrahydride; di-tert-butyl peroxide In tetrahydrofuran for 0.7h; Irradiation; | 96% |
| Conditions | Yield |
|---|---|
| With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride In 2-pentanol at 100℃; for 36h; Inert atmosphere; | A 98.4% B 1.6% |
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In 1,2-dimethoxyethane at 35℃; for 4h; ultrasonic acceleration of reduction; | A 98% B n/a |
| With lithium aluminium tetrahydride; Tridecane In diethyl ether at 0℃; for 0.25h; Irradiation; Title compound not separated from byproducts; | A 77 % Chromat. B 18 % Chromat. |
| With Amberlite IRA-400; borohydride form; nickel diacetate In methanol at 20℃; for 3h; Reduction; | A 56 % Chromat. B 19 % Chromat. |
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In 1,2-dimethoxyethane at 35℃; for 4h; ultrasonic acceleration of reduction; | A 98% B n/a |
| Conditions | Yield |
|---|---|
| With dibutylbis(cyclopentadienyl)zirconium for 1h; Ambient temperature; | 98% |
| With sodium bis(2-methoxyethoxy)aluminium dihydride In toluene at 70℃; Rate constant; | |
| With tetrahydrofuran; 1,10-Phenanthroline; potassium tert-butylate at 110℃; for 24h; Schlenk technique; Inert atmosphere; chemoselective reaction; | 85 %Chromat. |
| With ZnSe/CdS core/shell QDs; N-ethyl-N,N-diisopropylamine In hexane at 25℃; for 48h; Irradiation; Inert atmosphere; | 51 %Chromat. |
| Conditions | Yield |
|---|---|
| With butyl magnesium bromide; zirconocene dichloride In tetrahydrofuran for 6h; Ambient temperature; | 97% |
| With lithium aluminium tetrahydride; di-tert-butyl peroxide In tetrahydrofuran for 1h; Irradiation; | 92% |
| With tetrabutoxytitanium; diisobutylaluminium hydride In diethyl ether for 6h; Heating; | 91% |
-
A
-
696-63-9
4-Methoxybenzenethiol
-
C
-
5335-87-5
4,4'-dimethoxyphenyl disulfide
-
D
-
603-36-1
triphenylantimony
-
E
-
108-90-7
chlorobenzene
| Conditions | Yield |
|---|---|
| In tetrachloromethane byproducts: biphenyl; reflux; not isolated, GLC; | A 36% B 40% C 22% D 96% E 33% |
-
-
36964-86-0
dichloro(o-chlorophenyl)phenylsilane
-
A
-
18030-58-5
9,9-dichloro-9-silafluorene
-
B
-
98-13-5
Phenyltrichlorosilane
-
C
-
108-90-7
chlorobenzene
-
D
-
80-10-4
diphenylsilyl dichloride
| Conditions | Yield |
|---|---|
| With hexachlorodisilane at 500℃; gas phase; Further byproducts given; | A 95% B 0.3 g C 0.8 g D 0.2 g |
| Conditions | Yield |
|---|---|
| In 1,3,5-trimethyl-benzene Solvent; Temperature; UV-irradiation; | A 95% B 95% |
| Conditions | Yield |
|---|---|
| With iron(III) chloride; sodium chloride In acetonitrile for 10h; Kinetics; Catalytic behavior; Quantum yield; Reagent/catalyst; Irradiation; Green chemistry; | 94.3% |
| With sodium chlorite; trichloroacetic acid In dichloromethane for 3h; Substitution; | 92% |
| With trans-bis(glycinato)copper(II) monohydrate; tetramethlyammonium chloride In ethanol at 100℃; for 12h; Finkelstein Reaction; Schlenk technique; Inert atmosphere; | 90% |
-
-
67-56-1
methanol
-
-
100-34-5
benzene diazonium chloride
-
A
-
92-52-4
biphenyl
-
B
-
100-66-3
methoxybenzene
-
C
-
108-90-7
chlorobenzene
-
D
-
71-43-2
benzene
| Conditions | Yield |
|---|---|
| With trans-bis[1,2-bis(diphenylphosphino)ethane]bis(dinitrogen)tungsten(0) In methanol for 0.25h; Product distribution; Ambient temperature; reagents' ratio and mode of the mixing dependence; also with EtOH, CH3OD, CD3OD; | A 1.7% B 1.6% C 0.4% D 93.1% |
| Conditions | Yield |
|---|---|
| With Dichlorophenylphosphine In various solvent(s) at 170℃; for 5h; | 93% |
| With thionyl chloride at 160 - 200℃; im Rohr; | |
| With chlorine at 22.85℃; under 700 Torr; Kinetics; Further Variations:; Pressures; Substitution; | |
| With tetrachloromethane at 250℃; for 7h; Inert atmosphere; Autoclave; | 90 %Spectr. |
| With thionyl chloride at 160 - 200℃; im Rohr; |
-
-
201230-82-2
carbon monoxide
-
-
673-41-6
p-chlorobenzenediazonium tetrafluoroborate
-
A
-
104-88-1
4-chlorobenzaldehyde
-
B
-
108-90-7
chlorobenzene
| Conditions | Yield |
|---|---|
| With palladium diacetate; polymethylhydrosiloxane In diethyl ether; acetonitrile under 7355.08 Torr; for 12h; | A 93% B n/a |
| Conditions | Yield |
|---|---|
| With trichloroisocyanuric acid; bromine In tetrachloromethane at -10 - 100℃; for 6h; Solvent; Temperature; Concentration; Time; Photolysis; | 93% |
| Conditions | Yield |
|---|---|
| With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride In 2-pentanol at 100℃; for 29h; Inert atmosphere; | A 7.2% B 92.8% |
| Conditions | Yield |
|---|---|
| palladium on activated charcoal In gas at 360℃; | 92% |
| With nickel at 420℃; |
-
-
108-90-7
chlorobenzene
| Conditions | Yield |
|---|---|
| In dimethyl sulfoxide Ambient temperature; | 92% |
-
-
19819-95-5
2-(2-chlorophenyl)-1-ethanol
-
-
108-90-7
chlorobenzene
| Conditions | Yield |
|---|---|
| With 1,10-Phenanthroline; oxygen; copper diacetate; silver nitrate; sodium hydroxide In dimethyl sulfoxide at 140℃; under 3750.38 Torr; for 12h; Autoclave; Green chemistry; | 92% |
-
-
10557-71-8
4-chlorophenyltrimethylsilane
-
-
108-90-7
chlorobenzene
| Conditions | Yield |
|---|---|
| With potassium trimethylsilonate In dimethyl sulfoxide at 60℃; under 760.051 Torr; for 6h; Catalytic behavior; Reagent/catalyst; Solvent; Sealed tube; | 91% |
| In sulfuric acid; acetic acid at 50℃; | |
| In sulfuric acid; acetic acid at 50℃; Rate constant; 1.) other solvetnts, 2.) k (excit.); | |
| With potassium trimethylsilonate In dimethyl sulfoxide at 70℃; for 6h; Sealed tube; Schlenk technique; | 89 %Chromat. |
| Conditions | Yield |
|---|---|
| With tert.-butylhydroperoxide; manganese(II) acetate; trifluoroacetic acid In acetonitrile at 80℃; under 15001.5 Torr; for 21h; Mechanism; chemoselective reaction; | A n/a B 91% |
-
-
64357-12-6
benzoin phenylhydrazone ethyl ether
-
A
-
93-89-0
benzoic acid ethyl ester
-
B
-
574-09-4
2-ethoxy-1,2-diphenyl-ethanone
-
C
-
119-53-9
2-hydroxy-2-phenylacetophenone
-
D
-
100-52-7
benzaldehyde
-
E
-
108-90-7
chlorobenzene
-
F
-
71-43-2
benzene
| Conditions | Yield |
|---|---|
| With copper dichloride for 5h; Product distribution; Heating; variation of time; | A 90% B 10% C 40% D 10% E n/a F n/a |
-
-
86379-23-9
5-(2-Chloro-phenoxy)-1-phenyl-1H-tetrazole
-
A
-
5097-82-5
1-phenyl-5-hydroxytetrazole
-
B
-
108-90-7
chlorobenzene
-
C
-
71-43-2
benzene
| Conditions | Yield |
|---|---|
| With sodium hypophosphite; palladium on activated charcoal In ethanol; water; benzene for 4.16667h; Heating; | A n/a B 10% C 90% |
| palladium on activated charcoal In ethanol; benzene Mechanism; Product distribution; various reagents, temperatures and reaction times; |
-
-
28557-00-8
phenylzinc chloride
-
-
108-90-7
chlorobenzene
| Conditions | Yield |
|---|---|
| With N-chloro-succinimide; palladium (II) ion In tetrahydrofuran at 45℃; for 16h; | 90% |
| Conditions | Yield |
|---|---|
| With sulfuric acid; trifluoroacetic acid; trifluoroacetic anhydride; Η-β Zeochem at 10 - 53℃; for 4h; Product distribution / selectivity; | 100% |
| With sulfuric acid at 20℃; for 4h; | 95.02% |
| Stage #1: chlorobenzene With aluminum (III) chloride; thionyl chloride In water at 50 - 90℃; for 3h; Stage #2: With sulfuric acid; dihydrogen peroxide; acetic acid In water at 80℃; for 3h; | 93.8% |
| Conditions | Yield |
|---|---|
| With sodium hydroxide; ethanol; hydrogen; PdCl2-poly(N-vinyl-2-pyrrolidone); palladium dichloride at 65℃; under 760 Torr; for 2h; Product distribution; effect of bases and solvents on the hydrodechlorination; | 100% |
| With potassium hydroxide; hydrogen; palladium on activated charcoal; Aliquat 336 In 2,2,4-trimethylpentane at 50℃; for 4.5h; | 100% |
| With sodium hydroxide; ethanol; hydrogen; PdCl2-poly(N-vinyl-2-pyrrolidone); palladium dichloride at 65℃; under 760 Torr; for 2h; | 100% |
| Conditions | Yield |
|---|---|
| With C50H64Cl2N12Pd2(6+)*6F6P(1-); sodium acetate In N,N-dimethyl-formamide at 140℃; for 24h; Reagent/catalyst; Heck Reaction; | 100% |
| With cesium acetate; PdCl[(C6H3)(OP(i-Pr)2)2-2,6] In 1,4-dioxane at 120℃; for 120h; Arylation; Heck reaction; | 99% |
| With tetrabutylammonium acetate; palladium diacetate; DavePhos In 1,4-dioxane at 80℃; for 24h; Heck reaction; Inert atmosphere; Sealed tube; | 99% |
| Conditions | Yield |
|---|---|
| With potassium hydroxide; PEG-6000 at 150℃; for 6h; | 100% |
| Conditions | Yield |
|---|---|
| nickel(II) In tetrahydrofuran for 18h; Product distribution; other catalyst, other solvents; other Grignard compounds and alkyl or vinyl halides; | 100% |
| With CpNi[1-(ethoxycarbonyl)methyl-3-(3,5-dimethylbenzyl)benzimidazolin-2-ylidene]Br In tetrahydrofuran at 25℃; for 3h; Kumada Cross-Coupling; Inert atmosphere; Schlenk technique; | 97% |
| With Pd/Al(OH)3 In toluene at 140℃; for 36h; Kumada Cross-Coupling; Inert atmosphere; | 94% |
| Conditions | Yield |
|---|---|
| With Cs2O3; PCy3 adduct of cyclopalladated ferrocenylimine In 1,4-dioxane at 100℃; for 15h; Suzuki cross-coupling reaction; | 100% |
| With dichloro(cycloocta-1,5-diene)palladium (II); 2,2-[μ-(N,N'-piperazindiyl)dimethyl]-bis(4,6-di-tert-butyl-phenol); potassium carbonate In methanol for 0.166667h; Suzuki cross-coupling reaction; Microwave irradiation; Inert atmosphere; | 100% |
| With potassium carbonate In methanol at 100℃; for 0.0833333h; Suzuki-Miyaura Coupling; Microwave irradiation; | 100% |
| Conditions | Yield |
|---|---|
| With hydrogen; Leuna-Kontakt 6525 at 150℃; Product distribution; other halogen organic compounds, var. catalysts; | 100% |
| With hydrogen; platinum at 120℃; under 16501.7 Torr; for 1.66667h; Autoclave; Inert atmosphere; | 12.8% |
| With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; hydrogen; triethylamine In isopropyl alcohol at 75℃; under 31028.9 Torr; for 4h; other chloroaromatics; var. reaction time; catalytic hydrodechlorination; |
| Conditions | Yield |
|---|---|
| With sodium t-butanolate; (SIPr)Pd(allyl)Cl In tetrahydrofuran at 70℃; for 1h; Product distribution; Further Variations:; Catalysts; | 100% |
| With potassium tert-butylate; C41H50ClN3Pd In tetrahydrofuran at 80℃; for 4h; Reagent/catalyst; Inert atmosphere; | 99% |
| With sodium t-butanolate; N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene-acetylacetonate palladium chloride In toluene at 60℃; for 1h; | 98% |
| Conditions | Yield |
|---|---|
| With (55)Pd068(44)Ni032; potassium carbonate In water at 80℃; for 8h; Catalytic behavior; Buchwald-Hartwig Coupling; | 100% |
| With (R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl di-t-butylphosphine; sodium t-butanolate; palladium diacetate In 1,2-dimethoxyethane at 100℃; for 48h; | 99% |
| With sodium t-butanolate; palladium diacetate; (R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl di-t-butylphosphine In 1,2-dimethoxyethane at 100℃; for 48h; | 99% |
-
-
25603-67-2
9-phenyl-fluoren-9-ol
-
-
108-90-7
chlorobenzene
-
-
377092-23-4
phenyl-[1,1';2',1'']terphenyl-2-yl-methanone
| Conditions | Yield |
|---|---|
| With palladium diacetate; caesium carbonate; tricyclohexylphosphine In o-xylene for 4h; Heating; | 100% |
-
-
108-90-7
chlorobenzene
-
-
25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
-
-
195062-61-4
4-chlorophenylboronic acid pinacol ester
| Conditions | Yield |
|---|---|
| [Ir(COD)(1,3-dicyclohexylimidazolidin-2-ylidene)2]CF3CO2 at 40℃; for 10h; | 100% |
| (η4-1,5-cyclooctadiene)bis(1,3-dimethylimidazolin-2-ylidene)iridium(I) trifluoracetate In chlorobenzene byproducts: H2; (N2); using Schlenk techniques; dissolving of 2 mmol pinacolborane and 1.5 mol% of Ir(COD)(C3H2N2Me2)2(CF3CO2) in chlorobenzene; stirring and heating at 40°C for 12 h; monitoring by GC-MS; removal of solvent under vac. at room temp.; chromy. over silica gel, eluting with CH2Cl2; | 100% |
| (η4-1,5-cyclooctadiene)(1,1'-dimethyl-3,3'-o-xylylene-diimidazolin-2,2'-diylidene)iridium(I) trifluoroacetate In chlorobenzene (N2); using Schlenk techniques; dissolving of 2 mmol pinacolborane and 1.5 mol% of Ir(COD)(1,1'-dimethyl-3,3'-o-xylylene-diimidazolin-2,2'-diylidene)2(CF3CO2) in chlorobenzene; stirring and heating at 40°C for12 h; monitoring by GC-MS; removal of solvent under vac. at room temp.; chromy. over silica gel, eluting with CH2Cl2; | 100% |
| Conditions | Yield |
|---|---|
| With sodium carbonate; palladium diacetate In 1-methyl-pyrrolidin-2-one; Hexadecane at 140℃; for 16h; Product distribution / selectivity; | 100% |
| With [Pd{C6H3(CH2CH2NH2)-4-OMe-5-κ2-C,N}(μ-Br)]2; potassium carbonate In N,N-dimethyl-formamide at 130℃; for 0.166667h; Microwave irradiation; | 94% |
| With sodium carbonate; palladium diacetate; tri-tert-butyl phosphine In 1-methyl-pyrrolidin-2-one; Hexadecane at 140℃; for 16h; Product distribution / selectivity; | 88% |
| Conditions | Yield |
|---|---|
| With dichloro[1-(3-methylbenzyl)-3-(n-butyl)benzimidazol-2-ylidene]ruthenium(II); potassium acetate In water at 100℃; for 1h; Reagent/catalyst; | 100% |
| With rhodium(III) chloride hydrate; sodium carbonate; triphenylphosphine In 1-methyl-pyrrolidin-2-one at 140℃; for 22h; Inert atmosphere; | 99% |
| With C36H35Cl2PRu; potassium carbonate In 1-methyl-pyrrolidin-2-one at 120℃; for 24h; regioselective reaction; | 87% |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 20℃; for 21h; | A 100% B n/a C n/a |
| Conditions | Yield |
|---|---|
| at 140℃; for 1h; Microwave irradiation; | 100% |
| Conditions | Yield |
|---|---|
| Stage #1: filgotinib hydrochloride; chlorobenzene at 20℃; for 0.166667h; Stage #2: With sodium hydroxide In water at 5℃; for 32h; | 100% |
-
-
108-90-7
chlorobenzene
| Conditions | Yield |
|---|---|
| In benzene-d6 for 2h; Irradiation; | 100% |
-
-
75-79-6
Methyltrichlorosilane
-
-
1185-55-3
Methyltrimethoxysilan
-
-
108-90-7
chlorobenzene
-
-
3027-21-2
dimethoxy(methyl)phenylsilane
| Conditions | Yield |
|---|---|
| Stage #1: Methyltrimethoxysilan; chlorobenzene With magnesium In tetrahydrofuran for 1h; Reflux; Stage #2: Methyltrichlorosilane; Methyltrimethoxysilan; chlorobenzene In tetrahydrofuran for 6.5h; Concentration; Reflux; | 99.6% |
| Conditions | Yield |
|---|---|
| With C33H37N4P; potassium carbonate; bis(dibenzylideneacetone)-palladium(0) In tert-butyl alcohol at 95℃; for 18h; Catalytic behavior; Solvent; Temperature; Reagent/catalyst; Time; Inert atmosphere; Sonication; | 99.1% |
| With 5-(di-tert-butylphosphino)-1′, 3′, 5′-triphenyl-1′H-[1,4′]bipyrazole; bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; potassium carbonate In 1,4-dioxane at 90℃; for 18h; Buchwald-Hartwig Coupling; Inert atmosphere; Glovebox; | 80% |
| With potassium phosphate; copper(l) iodide In N,N-dimethyl-formamide at 120℃; for 48h; Ullmann condensation; | 33% |
| With copper(l) iodide; potassium carbonate; pipecolic Acid In N,N-dimethyl-formamide at 110℃; for 30h; Goldberg coupling reaction; | 24% |
| With C33H37N4P; potassium carbonate; bis(dibenzylideneacetone)-palladium(0) In tert-butyl alcohol at 95℃; for 18h; Catalytic behavior; Reagent/catalyst; Solvent; Inert atmosphere; Sonication; |
| Conditions | Yield |
|---|---|
| With zinc at 65 - 68℃; for 0.00833333h; Friedel-Crafts acylation; microwave irradiation; | 99% |
| With iron(III) oxide at 20℃; for 0.0833333h; Friedel Crafts acylation; regioselective reaction; | 95% |
| With zinc(II) oxide at 20℃; for 0.166667h; Friedel-Crafts acylation; | 87% |
| Conditions | Yield |
|---|---|
| With sodium t-butanolate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride; Ni(PPh3)2(1-(p-acetylnaphthyl))Cl In 1,4-dioxane at 100℃; | 99% |
| With bis(η3-allyl-μ-chloropalladium(II)); potassium tert-butylate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In 1,4-dioxane at 100℃; for 1.5h; Inert atmosphere; | 99% |
| With sodium t-butanolate In toluene at 110℃; Inert atmosphere; Glovebox; chemoselective reaction; | 99% |
| Conditions | Yield |
|---|---|
| With potassium carbonate In N,N-dimethyl-formamide at 110℃; for 12h; | 99% |
| With potassium hydroxide; copper at 375 - 400℃; |
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