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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

4-chlorobenzoic Acid CAS NO.74-11-3

Cas:74-11-3

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Trading Company

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

4-Chlorobenzoic acid

Cas:74-11-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Chlorobenzoic Acid supplier in China

Cas:74-11-3

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product description: Product name 4-Chlorobenzoic acid CAS number 74-11-3 Assay ≥99% Appearance White powder Capacity 200mt/year Application Pharmaceutical/pesticide intermed

4-Chlorobenzoic acid

Cas:74-11-3

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-chlorobenzoic acid

Cas:74-11-3

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 74-11-3 Benzoic acid, 4-chloro-

Cas:74-11-3

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

4-Chlorobenzoic Acid

Cas:74-11-3

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Chlorobenzoic acid

Cas:74-11-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--74-11-3-- 4-Chlorobenzoic acid factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business re

TIANFUCHEM--74-11-3-- 4-Chlorobenzoic acid factory price

Cas:74-11-3

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

4-Chlorobenzoic acid

Cas:74-11-3

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Fair price CAS 74-11-3 with high-quality service

Cas:74-11-3

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Leader Biochemical Group

About Product Details

China Biggest factory Supply High Quality 4-Chlorobenzoic acid CAS 74-11-3

Cas:74-11-3

Min.Order:1 Kilogram

FOB Price: $3.0 / 5.0

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

4-Chlorobenzoic acid CAS NO.: 74-11-3 Appearance: White powder Content: ≥99.0% Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application: Pharmaceut

4-Chlorobenzoic acid CAS:74-11-3

Cas:74-11-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzoic acid, 4-chloro- 74-11-3

Cas:74-11-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

HANWAYS CHEMPHARM CO.,LIMITED

Wuhan hanweishi Pharmchem Co., Ltd(Hanways chempharm) is a specialized company concentrating on the R&D, production, marketing and technical service of APIs and pharmaceutical intermediates. The leading products range are APIs, Hormones, Peptides

P-Chlorobenzoic Acid CAS 74-11-3

Cas:74-11-3

Min.Order:100 Kilogram

FOB Price: $1.0 / 5.0

Type:Trading Company

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

4-Chlorobenzoic acid Aromatic acid

Cas:74-11-3

Min.Order:1 Kilogram

FOB Price: $60.0 / 100.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

4-Chlorobenzoic acid CAS:74-11-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interme

4-Chlorobenzoic acid CAS:74-11-3

Cas:74-11-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzoic acid, 4-chloro-

Cas:74-11-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanxi Ankesi Biotechnology Co., Ltd

Our Advantage 1. Rich experience We specialize in this filed for many years, our APIs exported to all over the world and and we established long friendly relations of cooperation with our clients. 2. Great quality,purity and favorable Good qual

Good quality and price CAS 74-11-3 4-Chlorobenzoic acid

Cas:74-11-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzoic acid, 4-chloro-

Cas:74-11-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Chlorobenzoic Acid

Cas:74-11-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

74-11-3 4-Chlorobenzoic acid

Cas:74-11-3

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

4-CHLOROBENZOIC ACID

Cas:74-11-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

4-Chlorobenzoic acid

Cas:74-11-3

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Chlorobenzoic acid

Cas:74-11-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

4-Chlorobenzoic acid/High quality/Best price

Cas:74-11-3

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 4-Chlorobenzoic Acid

Cas:74-11-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

4-Chlorobenzoic acidAppearance:White powder Storage:In Shade Package:according to customers' requirements Application:chemical research Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FOB or CIF or CNF ect...)or according to your d

4-Chlorobenzoic acid

Cas:74-11-3

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

74-11-3 4-Chlorobenzoic acid

Cas:74-11-3

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:Colorless or light yellow transparent liquid Storage:Store in a cool, dry and well-ventilated warehouse Package:250kg/barrel Application:Organic microanalysis Determination of carbon

4-Chlorobenzoic acid

Cas:74-11-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Synthetic route

4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With sodium perborate In acetic acid for 1.5h; steam bath;100%
With hydrogen bromide; oxygen In acetonitrile at 20℃; for 5h; UV-irradiation;100%
With C4H11FeMo6NO24(3-)*3C16H36N(1+); water; oxygen; sodium carbonate at 50℃; under 760.051 Torr; for 8h; Green chemistry;99%
benzyl p-chlorobenzoate
67483-73-2

benzyl p-chlorobenzoate

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With hydrogen In ethyl acetate at 60℃; for 24h; Reagent/catalyst;100%
With methanol; sodium tetrahydroborate; nickel(II) chloride hexahydrate at 20℃; for 0.0833333h; chemoselective reaction;87%
With ammonium cerium(IV) nitrate In water; acetonitrile for 6h; Mechanism; Heating; other esters react in the same way;65%
allyl 4-chlorobenzoate
15784-28-8

allyl 4-chlorobenzoate

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With formic acid; triethylamine In acetonitrile at 80℃; for 1h; Inert atmosphere;100%
With toluene-4-sulfonic acid for 0.0666667h; microwave irradiation;86%
With iodine; dimethyl sulfoxide for 0.2h; Heating;76%
With ammonium cerium(IV) nitrate In water; acetonitrile for 6h; Mechanism; Heating; other esters react in the same way;74%
para-Chlorobenzyl alcohol
873-76-7

para-Chlorobenzyl alcohol

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With bromine; oxygen In acetonitrile for 10h; Irradiation;100%
With periodic acid; tripropylammonium fluorochromate (VI) In acetonitrile at 0℃;99%
With silica-supported Jones reagent In dichloromethane for 0.035h;99.4%
4-chlorobenzoic anhydride
790-41-0

4-chlorobenzoic anhydride

A

para-Chlorobenzyl alcohol
873-76-7

para-Chlorobenzyl alcohol

B

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With methanol; sodium tetrahydroborate In tetrahydrofuran for 1h; Ambient temperature;A 94%
B 100%
4-chloro-N,N-diisopropylbenzamide
79606-45-4

4-chloro-N,N-diisopropylbenzamide

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With hydrogenchloride; zinc(II) chloride at 160℃; for 72h;100%
para-chlorotoluene
106-43-4

para-chlorotoluene

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With Oxone; potassium bromide In dichloromethane; water at 20℃; for 24h; visible light irradiation;99%
With ruthenium trichloride; sodium hypochlorite; tetrabutylammomium bromide In 1,2-dichloro-ethane at 25℃; for 2h;98%
With ruthenium trichloride; sodium hypochlorite; tetrabutylammomium bromide In 1,2-dichloro-ethane at 25℃; for 2h; Rate constant; Mechanism; pH 9: other methylbenzenes; var. concentration of aq. NaOCl, ruthenium and tetrabutylammonium bromide;98%
Methyl 4-chlorobenzoate
1126-46-1

Methyl 4-chlorobenzoate

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With iodine; aluminium In acetonitrile at 80℃; for 18h;99%
With potassium hydroxide In toluene at 150℃; for 0.166667h; microwave irradiation;94%
With sodium hydroxide In N,N-dimethyl-formamide for 0.5h; Ambient temperature;93%
1-Chloro-4-iodobenzene
637-87-6

1-Chloro-4-iodobenzene

carbon monoxide
201230-82-2

carbon monoxide

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With amphiphilic resin-supported phosphine-palladium; water; potassium carbonate at 25℃; under 760 Torr; for 12h; hydroxycarbonylation;99%
With dichloro bis(acetonitrile) palladium(II); potassium hydroxide; sodium dodecyl-sulfate In water; butan-1-ol at 70℃; under 760 Torr; for 4h;94%
With potassium carbonate; palladium diacetate In water; N,N-dimethyl-formamide at 25℃; under 760 Torr; for 2h;92%
cobalt (II) acetate·4 H2O

cobalt (II) acetate·4 H2O

para-chlorotoluene
106-43-4

para-chlorotoluene

1N,3N,5N-trihydroxy-1,3,5-triazin-2,4,6[1H,3H,5H]-trione
143435-52-3

1N,3N,5N-trihydroxy-1,3,5-triazin-2,4,6[1H,3H,5H]-trione

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With acetic acid99%
4-chlorobenzyl azide
27032-10-6

4-chlorobenzyl azide

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With tert.-butylhydroperoxide; vanadia In water at 100℃; for 6h;99%
1-chloro-4-{[(phenylmethyl)oxy]methyl}benzene
3395-72-0

1-chloro-4-{[(phenylmethyl)oxy]methyl}benzene

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With Oxone; potassium bromide In acetonitrile at 0 - 30℃; for 24.5h; Green chemistry;99%
2-(4-Chlorophenyl)ethanol
1875-88-3

2-(4-Chlorophenyl)ethanol

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With oxygen; sodium t-butanolate In tetrahydrofuran at 20℃; under 750.075 Torr; for 17h; chemoselective reaction;99%
bromochlorobenzene
106-39-8

bromochlorobenzene

carbon monoxide
201230-82-2

carbon monoxide

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With tetrabutylammomium bromide; dicobalt octacarbonyl In sodium hydroxide; benzene at 65℃; for 1h; Irradiation;98%
With sodium hydroxide; tetrabutylammomium bromide; dicobalt octacarbonyl In water; benzene at 65℃; under 760 Torr; for 1h; Irradiation;98%
ethyl 4-chlorobenzoate
7335-27-5

ethyl 4-chlorobenzoate

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
Stage #1: ethyl 4-chlorobenzoate With iron(III) chloride In tetrachloromethane at 85℃; for 24h; Inert atmosphere;
Stage #2: With hydrogenchloride; water In tetrachloromethane Inert atmosphere;
98%
With potassium hydroxide In methanol at 35℃; for 0.333333h;89%
With ammonium cerium(IV) nitrate In water; acetonitrile for 6h; Mechanism; Heating; other esters react in the same way;58%
Stage #1: ethyl 4-chlorobenzoate With sodium hydroxide In water at 20℃;
Stage #2: With hydrogenchloride In water
With water; lithium hydroxide In tetrahydrofuran at 25℃; for 6h; Reagent/catalyst; Solvent;92 %Chromat.
p-chlorobenzoylmethanesulfonic acid
98554-12-2

p-chlorobenzoylmethanesulfonic acid

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With water; sodium hydroxide for 5h; Heating;98%
para-chloroacetophenone
99-91-2

para-chloroacetophenone

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With 1,10-Phenanthroline; oxygen; copper diacetate; potassium hydroxide In dimethyl sulfoxide at 130℃; under 3000.3 Torr; for 12h; Autoclave;97%
Stage #1: para-chloroacetophenone With tert.-butylhydroperoxide; sodium hydroxide; tungsten(VI) oxide In water at 80℃; for 8h;
Stage #2: With hydrogenchloride In water
94%
With copper(II) nitrate trihydrate; oxygen In acetonitrile at 120℃; under 4500.45 Torr; for 10h; Autoclave;93%
4-amino-benzoic acid
150-13-0

4-amino-benzoic acid

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With t-butyl thionitrite; copper dichloride In acetonitrile at 25℃; for 0.0333333h;97%
Stage #1: 4-amino-benzoic acid With tert.-butylnitrite In acetonitrile at 20℃; Sandmeyer Reaction; Flow reactor;
Stage #2: With copper dichloride In ethylene glycol; acetonitrile at 82℃; Sandmeyer Reaction; Flow reactor;
50%
With hydrogenchloride; potassium nitrite; dimethyl sulfoxide; copper(l) chloride In water at 35℃; for 0.5h;77 % Chromat.
4-chloro-benzoic acid 3-methyl-but-2-enyl ester

4-chloro-benzoic acid 3-methyl-but-2-enyl ester

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With Montmorillonite K-10 clay; toluene for 0.333333h; Dealkylation; Microwave irradiation;97%
With toluene-4-sulfonic acid for 0.0666667h; microwave irradiation;84%
benzyl p-chlorobenzoate
67483-73-2

benzyl p-chlorobenzoate

toluene
108-88-3

toluene

A

1-methyl-3-(phenylmethyl)-benzene
620-47-3

1-methyl-3-(phenylmethyl)-benzene

B

1-methyl-4-(phenylmethyl)benzene
620-83-7

1-methyl-4-(phenylmethyl)benzene

C

2-benzyltoluene
713-36-0

2-benzyltoluene

D

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; water at 80℃; for 2h; regioselective reaction;A n/a
B n/a
C n/a
D 97%
1-Chloro-4-(chloromethyl)benzene
104-83-6

1-Chloro-4-(chloromethyl)benzene

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With sodium hydroxide In water; tert-butyl alcohol at 70℃; Ni-anode, 16 mA/cm2;96%
4-chlorobenzyl bromide
622-95-7

4-chlorobenzyl bromide

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With Oxone In water; acetonitrile for 9h; Reflux;96%
With sodium periodate; sulfuric acid In water at 95℃; for 12h;79%
With tert.-butylhydroperoxide In water at 80℃; for 12h; Green chemistry;
Multi-step reaction with 2 steps
1: silver(I) nitrite / diethyl ether / 5 h / 0 °C / Reflux
2: tetra-(n-butyl)ammonium iodide; zinc diacetate; water / 24 h / 80 °C
View Scheme
para-chlorotoluene
106-43-4

para-chlorotoluene

A

N-acetoxy-1,8-naphthalenedicarboximide

N-acetoxy-1,8-naphthalenedicarboximide

B

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With acetic acid In titaniumA n/a
B 96%
1-(p-chlorophenyl)ethyl alcohol
3391-10-4

1-(p-chlorophenyl)ethyl alcohol

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With sodium nitrate; water; oxygen In dimethyl sulfoxide at 130℃; for 24h;96%
With 1,10-Phenanthroline; oxygen; copper diacetate; potassium hydroxide In dimethyl sulfoxide at 130℃; under 3000.3 Torr; for 12h; Autoclave;93%
With iron(III) chloride; cerium(III) chloride; tetrabutyl-ammonium chloride; oxygen In acetonitrile at 20℃; under 760.051 Torr; for 24h; Schlenk technique; Irradiation;90%
para-chlorotoluene
106-43-4

para-chlorotoluene

A

4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

B

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With hydrogenchloride; oxygen; 9-(2-mesityl)-10-methylacridinium perchlorate In acetonitrile at 4.84℃; for 12h; Irradiation;A 5%
B 95%
With N-hydroxyphthalimide; oxygen; cobalt(II) acetate In acetic acid at 25℃; under 760 Torr; for 20h;A 3%
B 67%
With sulfuric acid bei der elektrolytischen Oxydation;
para-dichlorobenzene
106-46-7

para-dichlorobenzene

carbon dioxide
124-38-9

carbon dioxide

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With magnesium In tetrahydrofuran for 0.5h; Heating;95%
With Al-anode In N,N-dimethyl-formamide at 20℃; electrocarboxylation;78%
With tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide at 20℃; under 760.051 Torr; for 4h; Electrolysis;66%
Stage #1: para-dichlorobenzene With bis(cyclopentadienyl)titanium dichloride; butyl magnesium bromide In tetrahydrofuran at 40℃; for 6h; Inert atmosphere; Schlenk technique;
Stage #2: carbon dioxide In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; Schlenk technique;
44%
4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

A

para-Chlorobenzyl alcohol
873-76-7

para-Chlorobenzyl alcohol

B

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
Stage #1: 4-chlorobenzaldehyde With potassium hydroxide for 0.0833333h; Cannizzaro Reaction; Milling; Inert atmosphere; Sealed tube; Green chemistry;
Stage #2: With hydrogenchloride In water Green chemistry;
A 95%
B 95%
With sodium hydroxide In water at 20℃; for 3.5h; Cannizzaro Reaction;A n/a
B 89%
With TEA; magnesium bromide In dichloromethane at 20℃; for 48h; Cannizzaro reaction;A 88%
B n/a
cinnamyl 4-chlorobenzoate

cinnamyl 4-chlorobenzoate

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With Montmorillonite K-10 clay; methoxybenzene for 0.333333h; Dealkylation; Microwave irradiation;95%
With methoxybenzene In toluene for 15h; Heating;5%
4-chlorophenyl trifluoromethanesulfonate
29540-84-9

4-chlorophenyl trifluoromethanesulfonate

molybdenum hexacarbonyl

molybdenum hexacarbonyl

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With pyridine; 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate at 150℃; for 0.333333h; microwave irradiation;95%
C16H25ClO2Si

C16H25ClO2Si

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Conditions
ConditionsYield
With water; N,N-dimethyl-formamide at 70℃; for 1h; Green chemistry; chemoselective reaction;95%
methanol
67-56-1

methanol

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

Methyl 4-chlorobenzoate
1126-46-1

Methyl 4-chlorobenzoate

Conditions
ConditionsYield
With sulfuric acid for 4h; Reflux;100%
With sulfuric acid Fischer-Speier esterification method; Reflux;100%
With di(methoxycarbonyl)methylene tri-n-butylphosphorane In toluene at 70℃; for 24h;98%
para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

4-chloro-benzoyl chloride
122-01-0

4-chloro-benzoyl chloride

Conditions
ConditionsYield
With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 20℃;100%
With thionyl chloride for 2h; Reflux;100%
With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 20℃; for 2h; Reflux;100%
para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

para-Chlorobenzyl alcohol
873-76-7

para-Chlorobenzyl alcohol

Conditions
ConditionsYield
With C25H42N6Rh(1+)*CF3O3S(1-); phenylsilane In tetrahydrofuran at 30℃; for 20h; Inert atmosphere;100%
With samarium diiodide; benzaldehyde; samarium(III) trifluoromethanesulfonate In tetrahydrofuran; methanol; water at 20℃; for 0.0166667h; Reduction;99%
With samarium diiodide; phosphoric acid In tetrahydrofuran for 0.000833333h; Ambient temperature;94%
benzyl alcohol
100-51-6

benzyl alcohol

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

benzyl p-chlorobenzoate
67483-73-2

benzyl p-chlorobenzoate

Conditions
ConditionsYield
With N,N-bis[2-oxo-3-oxazolidinyl]phosphorodiamidic chloride In acetonitrile for 1.5h; Heating;100%
Stage #1: para-chlorobenzoic acid With 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine In neat (no solvent) at 20℃; for 0.0166667h;
Stage #2: benzyl alcohol In neat (no solvent) at 20℃; for 0.216667h;
90%
Stage #1: para-chlorobenzoic acid With N-chlorobenzotriazole; triphenylphosphine In dichloromethane for 0.25h; Cooling;
Stage #2: benzyl alcohol With triethylamine In dichloromethane at 20℃; for 0.583333h;
85%
With 2-butyl-1,3-diphenyl-1,3,2-diazaphospholidine; 1,1'-azodicarbonyl-dipiperidine In 1,2-dichloro-ethane at 40℃; under 760.051 Torr; Mitsunobu Displacement;85%
para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
Stage #1: para-chlorobenzoic acid With palladium/alumina; hydrogen; potassium carbonate In water at 60℃;
Stage #2: With hydrogenchloride In water
100%
With hydrogen; triethylamine; palladium on activated charcoal In methanol at 20℃; for 6h;99%
With ammonium formate In water; isopropyl alcohol at 20℃; for 3h;99%
4-(2-AMINOETHYL)MORPHOLINE
2038-03-1

4-(2-AMINOETHYL)MORPHOLINE

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

moclobemide
71320-77-9

moclobemide

Conditions
ConditionsYield
With tetramethylorthosilicate In toluene at 110℃; for 1h; Inert atmosphere;100%
With zirconocene dichloride In toluene at 110℃; for 24h; Inert atmosphere; sealed tube;86%
With [((CH3)5Cp)2Zr(H2O)2OSO2C8F17]+[OSO2C8F17]-*THF In tetrahydrofuran at 100℃; for 12h; Catalytic behavior; Reagent/catalyst; Temperature;85%
n-heptan1ol
111-70-6

n-heptan1ol

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

heptyl 4-chlorobenzoate
97222-05-4

heptyl 4-chlorobenzoate

Conditions
ConditionsYield
With Candida antarctica lipase B immobilised in a macroporous DVB crosslinked polymer (Novozym 435) In cyclohexane at 80℃; for 24h; Enzymatic reaction;100%
propargyl bromide
106-96-7

propargyl bromide

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

prop-2-yn-1-yl 4-chlorobenzoate
79318-18-6

prop-2-yn-1-yl 4-chlorobenzoate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene for 5h;100%
ethanol
64-17-5

ethanol

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

ethyl 4-chlorobenzoate
7335-27-5

ethyl 4-chlorobenzoate

Conditions
ConditionsYield
With sulfuric acid for 0.666667h; Reflux;99.7%
With sulfuric acid for 5h; Reflux;93.4%
With sulfuric acid for 3h; Heating;87%
4-(diazomethyl)-7-methoxycoumarin
84471-16-9

4-(diazomethyl)-7-methoxycoumarin

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

4-Chloro-benzoic acid 7-methoxy-2-oxo-2H-chromen-4-ylmethyl ester
76196-61-7

4-Chloro-benzoic acid 7-methoxy-2-oxo-2H-chromen-4-ylmethyl ester

Conditions
ConditionsYield
In acetonitrile at 80℃; for 1h;99.7%
aniline
62-53-3

aniline

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

4-chlorobenzanilide
6833-15-4

4-chlorobenzanilide

Conditions
ConditionsYield
With fluorosulfonyl fluoride; N-ethyl-N,N-diisopropylamine In acetonitrile at 20℃; for 5h;99%
With nano sulfated-TiO2 at 115℃; under 760.051 Torr; for 4h; Neat (no solvent);98%
With triethylamine; Phenyl N-phenylphosphoramidochloridate In dichloromethane for 0.333333h; Ambient temperature;93%
para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

4-chlorobenzoic anhydride
790-41-0

4-chlorobenzoic anhydride

Conditions
ConditionsYield
With iodine; triethylamine; triphenylphosphine In dichloromethane at 0 - 20℃;99%
With N,N-bis[2-oxo-3-oxazolidinyl]phosphorodiamidic chloride; tributyl-amine In acetonitrile at 20℃; for 0.5h;97%
With thionyl chloride In dichloromethane at 22 - 25℃; for 1h;96.9%
benzylamine
100-46-9

benzylamine

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

N-benzyl-p-chlorobenzamide
7461-34-9

N-benzyl-p-chlorobenzamide

Conditions
ConditionsYield
With Bromotrichloromethane; 4-(diphenylphosphino)-benzyltrimethylammonium bromide; triethylamine In tetrahydrofuran at 60℃; for 6h; Inert atmosphere;99%
With borane-ammonia complex In 5,5-dimethyl-1,3-cyclohexadiene for 6h; Reflux;99%
With nickel ferrite nanoparticle In neat (no solvent) for 0.166667h; Irradiation; Sealed tube;92%
thiophene
188290-36-0

thiophene

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

2-(4-chlorobenzoyl)thiophene
4153-45-1

2-(4-chlorobenzoyl)thiophene

Conditions
ConditionsYield
With pyridin-2-yl trifluoromethanesulfonate; trifluoroacetic acid for 4h; Heating;99%
With phosphoric acid; trifluoroacetic anhydride In water at 20℃; for 2h;87%
benzyl bromide
100-39-0

benzyl bromide

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

benzyl p-chlorobenzoate
67483-73-2

benzyl p-chlorobenzoate

Conditions
ConditionsYield
With N(Et)4(1+)*(2-pyrrolidone-anion) In N,N-dimethyl-formamide for 1h; Ambient temperature;99%
N,O-dimethylhydroxylamine*hydrochloride
6638-79-5

N,O-dimethylhydroxylamine*hydrochloride

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

4-chloro-N-methoxy-N-methylbenzamide
122334-37-6

4-chloro-N-methoxy-N-methylbenzamide

Conditions
ConditionsYield
With 4-methyl-morpholine; 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride In methanol at 20℃; for 0.5h;99%
Stage #1: para-chlorobenzoic acid With 1,1'-carbonyldiimidazole In dichloromethane at 0℃; for 0.5h;
Stage #2: N,O-dimethylhydroxylamine*hydrochloride With triethylamine In dichloromethane at 0 - 20℃;
99%
Stage #1: para-chlorobenzoic acid With triethylamine; trichloromethyl chloroformate In dichloromethane at 0℃;
Stage #2: N,O-dimethylhydroxylamine*hydrochloride In dichloromethane at 25℃; for 1h;
96%
N,0-dimethylhydroxylamine
1117-97-1

N,0-dimethylhydroxylamine

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

4-chloro-N-methoxy-N-methylbenzamide
122334-37-6

4-chloro-N-methoxy-N-methylbenzamide

Conditions
ConditionsYield
Stage #1: N,0-dimethylhydroxylamine; para-chlorobenzoic acid In toluene at 0℃; for 0.166667h;
Stage #2: With phosphorus trichloride In toluene at 20 - 60℃; for 0.5h;
99%
With 1,1'-carbonyldiimidazole
With triethylamine; 1,1'-carbonyldiimidazole
Boc-Apns-Dmt-NHtBu
159000-71-2

Boc-Apns-Dmt-NHtBu

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

(1S,2S)-2-[(tert-butoxycarbonyl)amino]-1-({(4R)-4-[(tert-butylamino)carbonyl]-5,5-dimethyl-1,3-thiazolan-3-yl}carbonyl)-3-phenylpropyl 4-chlorobenzoate

(1S,2S)-2-[(tert-butoxycarbonyl)amino]-1-({(4R)-4-[(tert-butylamino)carbonyl]-5,5-dimethyl-1,3-thiazolan-3-yl}carbonyl)-3-phenylpropyl 4-chlorobenzoate

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 0 - 20℃;99%
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃;
sodium cyanide
143-33-9

sodium cyanide

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

4-cyanobenzoic Acid
619-65-8

4-cyanobenzoic Acid

Conditions
ConditionsYield
With nickel dibromide In 1-methyl-pyrrolidin-2-one at 200℃; under 10343 Torr; for 0.166667h; microwave irradiation;99%
para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

phenylboronic acid
98-80-6

phenylboronic acid

biphenyl-4-carboxylic acid
92-92-2

biphenyl-4-carboxylic acid

Conditions
ConditionsYield
With potassium hydroxide In water at 80℃; for 2h; Suzuki Coupling; Green chemistry;99%
With glucosamine-based dicyclohexylarylphosphine; sodium carbonate; palladium diacetate In ethanol; water; toluene at 80℃; Suzuki-Miyaura cross coupling reaction;97%
With sodium hydroxide; polyaniline-supported palladium In water at 80℃; for 4h; Suzuki coupling;97%
3-Carboxyphenylboronic acid
25487-66-5

3-Carboxyphenylboronic acid

para-chlorobenzoic acid
74-11-3

para-chlorobenzoic acid

biphenyl-3,4′-dicarboxylic acid
92152-01-7

biphenyl-3,4′-dicarboxylic acid

Conditions
ConditionsYield
With sodium 2'‐(dicyclohexylphosphaneyl)‐2,6‐diisopropyl‐[1,1'‐biphenyl]‐3‐sulfonate; palladium diacetate; potassium carbonate In water at 50℃; for 8h; Suzuki-Miyaura coupling;99%
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