Customization Our Key Technology: 1. Low Temperature Reactions 2. Coupling Reactions 3. Fluorine Chemistry 4. Asymmetric HydrogenationNot dangerous goods Our Advantages: Rich experience in loading
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inquiryManufacturer supply 3-Carboxyphenylboronic acid CAS 25487-66-5 with attractive price Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermedi
Cas:25487-66-5
Min.Order:10 Gram
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inquiryhigh quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai
Cas:25487-66-5
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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Min.Order:1 Gram
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inquiryCangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap
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Min.Order:1 Kilogram
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inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
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inquiryOur company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so
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inquiryProduct Description Product Name 3-Carboxyphenylboronic acid CAS No. 25487-66-5 Appearance White powder
Cas:25487-66-5
Min.Order:1 Gram
FOB Price: $54.0
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inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
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inquiryName:3-Carboxyphenylboronic Acid Molecular Formula:C7H7BO4 Molecular Weight:165.94 CAS No.:25487-66-5 Appearance:Similar White Powder Appearance:Similar White Powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Ap
We are leading fine chemicals supplier in China and Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediat
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Min.Order:1 Gram
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inquiry1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:powder Storage:Store in sealed containers at cool & dry pla
Cas:25487-66-5
Min.Order:100 Gram
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Min.Order:1 Kilogram
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Min.Order:1 Kilogram
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inquiry3-Carboxyphenylboronic acidCAS:25487-66-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organi
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Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryProduct Detail Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,
Cas:25487-66-5
Min.Order:20 Metric Ton
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Type:Trading Company
inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Appearance:off-white powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Syntheses material Intermediate Transportation:Common products:Sea/Air/Courier Dangero
Cas:25487-66-5
Min.Order:100 Metric Ton
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Type:Lab/Research institutions
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Cas:25487-66-5
Min.Order:10 Kilogram
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Type:Trading Company
inquiry3-Carboxyphenylboronic acid 25487-66-5 ADVANTAGE 1.Professional: More than 10 years chemical exporting experience. We have produced chemical more than fifteen years, 95% products are for export . More than 10 years chemical exporting experience. Go
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Min.Order:1 Kilogram
FOB Price: $1.0
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inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:25487-66-5
Min.Order:0 Metric Ton
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Cas:25487-66-5
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inquiryChemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff
Cas:25487-66-5
Min.Order:100 Gram
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Type:Other
inquiryMassive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
Cas:25487-66-5
Min.Order:1 Gram
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Type:Lab/Research institutions
inquirySuperior quality Appearance:off-white crystalline powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Widely used in Suzuki coupling chemistry.
Cas:25487-66-5
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
inquiry3-carboxyphenylboronic acid pinacol ester
dihydroxy-methyl-borane
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
With trifluoroacetic acid In dichloromethane at 20℃; | 99% |
(3‐cyanophenyl)boronic acid
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
Stage #1: (3‐cyanophenyl)boronic acid With potassium hydroxide In ethylene glycol at 175℃; for 3h; Stage #2: With hydrogenchloride In water; ethylene glycol pH=2 - 3; | 89% |
potassium permanganate
m-tolylboronic acid
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
With sodium hydroxide In water at 30 - 40℃; Temperature; | 61.2% |
tetrahydroxydiboron
meta-aminobenzoic acid
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
Stage #1: meta-aminobenzoic acid With hydrogenchloride; sodium nitrite In water at 0℃; for 0.25h; Stage #2: tetrahydroxydiboron With sodium acetate In water at 20℃; for 0.333333h; | 52.5% |
Stage #1: meta-aminobenzoic acid With hydrogenchloride; sodium nitrite In water at 0℃; for 0.25h; Stage #2: tetrahydroxydiboron With potassium carbonate In water at 20℃; for 0.333333h; |
Conditions | Yield |
---|---|
Stage #1: 1,3-Diiodobenzene With n-butyllithium In diethyl ether; hexane at -70℃; Inert atmosphere; Stage #2: With Triisopropyl borate In diethyl ether; hexane at -70℃; for 0.25h; Inert atmosphere; Stage #3: carbon dioxide Further stages; | 50% |
tetrahydroxydiboron
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 20℃; for 0.25h; | 39% |
m-tolylboronic acid
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
With alkaline aqueous potassium permanganate | |
With potassium permanganate In sodium hydroxide | |
With permanganate(VII) ion In sodium hydroxide oxidation in alkaline soln.;; | |
With permanganate In sodium hydroxide aq. NaOH; oxidation in alkaline soln.;; |
3-chlorobenzoate
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
With tetrahydroxydiboron; (chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II)); potassium acetate; XPhos In ethanol at 80℃; for 5h; Inert atmosphere; |
meta-aminobenzoic acid
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: ethanol; water / 0.03 h / 20 °C 1.2: 1.25 h / 0 - 20 °C 2.1: N,N-dimethyl-formamide / 0.25 h / 20 °C View Scheme |
carbon dioxide
tris(3-bromo phenyl)boroxine
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
Stage #1: tris(3-bromo phenyl)boroxine With iodine; magnesium In tetrahydrofuran at 40 - 70℃; Inert atmosphere; Stage #2: carbon dioxide In tetrahydrofuran at -20℃; | 110 g |
5-bromo-2-furancarboxaldehyde
3-Carboxyphenylboronic acid
5-(3-carboxyphenyl)furane-2-carbaldehyde
Conditions | Yield |
---|---|
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; toluene at 90℃; for 7h; Suzuki-Miyaura coupling; | 100% |
With C11H8Cl4N2O3Pd; potassium carbonate In methanol; water; N,N-dimethyl-formamide at 100℃; for 0.0833333h; Suzuki Coupling; | 98% |
With ethylenediaminetetraacetic acid; tetrabutylammomium bromide; potassium carbonate; palladium dichloride at 50℃; for 0.166667h; Suzuki-Miyaura reaction; | 92% |
3-Carboxyphenylboronic acid
para-nitrophenyl bromide
4'-nitrobiphenyl-3-carboxylic acid
Conditions | Yield |
---|---|
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene for 48h; Suzuki Coupling; Heating / reflux; | 100% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 48h; Suzuki Coupling; Reflux; Inert atmosphere; | 96.1% |
Stage #1: 3-Carboxyphenylboronic acid; para-nitrophenyl bromide With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 48h; Suzuki coupling; Inert atmosphere; Reflux; Stage #2: With hydrogenchloride In water pH=3; | 89% |
Conditions | Yield |
---|---|
With diisopropyl-carbodiimide In methanol at 0 - 20℃; for 24.5h; | 100% |
With diisopropyl-carbodiimide In methanol at 0 - 20℃; for 24.5h; |
3-Carboxyphenylboronic acid
para-chlorobenzoic acid
Conditions | Yield |
---|---|
With sodium 2'‐(dicyclohexylphosphaneyl)‐2,6‐diisopropyl‐[1,1'‐biphenyl]‐3‐sulfonate; palladium diacetate; potassium carbonate In water at 50℃; for 8h; Suzuki-Miyaura coupling; | 99% |
1,1-dimethylethyl 1-[(5-bromo-2-methylphenyl)methyl]-3-[4-(1,1-dimethylethyl)phenyl]-1H-indole-2-carboxylate
3-Carboxyphenylboronic acid
3'-({2-{[(1,1-dimethylethyl)oxy]carbonyl}-3-[4-(1,1-dimethylethyl)phenyl]-1H-indol-1-yl}methyl)-4'-methyl-3-biphenylcarboxylic acid
Conditions | Yield |
---|---|
Stage #1: 1,1-dimethylethyl 1-[(5-bromo-2-methylphenyl)methyl]-3-[4-(1,1-dimethylethyl)phenyl]-1H-indole-2-carboxylate; 3-Carboxyphenylboronic acid With sodium hydrogencarbonate; palladium 10% on activated carbon In water; N,N-dimethyl-formamide at 90℃; for 36h; Stage #2: With hydrogenchloride In water; N,N-dimethyl-formamide | 99% |
5-chloro-2-nitrotoluene
3-Carboxyphenylboronic acid
3'-methyl-4'-nitrobiphenyl-3-carboxylic acid
Conditions | Yield |
---|---|
With palladium diacetate; sodium carbonate; triphenylphosphine In ethanol; water; toluene at 100℃; for 24h; Suzuki coupling; Inert atmosphere; Sealed vessel; | 99% |
6-bromo-1-methyl-3-trityl-1H-imidazo[4,5-b]pyridin-2(3H)-one
3-Carboxyphenylboronic acid
3-(1-methyl-2-oxo-3-trityl-2,3-dihydro-1H-imidazo[4,5-b]pyridin-6-yl)benzoic acid
Conditions | Yield |
---|---|
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); tricyclohexylphosphine In 1,4-dioxane at 100℃; for 1h; Microwave irradiation; | 99% |
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate In water; acetonitrile at 100℃; Suzuki Coupling; Inert atmosphere; | 98% |
methanol
3-Carboxyphenylboronic acid
[3-(methoxycarbonyl)phenyl]boronic acid
Conditions | Yield |
---|---|
With thionyl chloride at 55 - 65℃; Autoclave; Industrial scale; | 97.1% |
With sulfuric acid at 80℃; for 20h; Temperature; |
Conditions | Yield |
---|---|
With ammonium bicarbonate In water at 20℃; for 2h; Schlenk technique; | 97% |
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,4-dioxane; water at 90℃; for 4h; | 96% |
3-Carboxyphenylboronic acid
2,2-Dimethyl-1,3-propanediol
Conditions | Yield |
---|---|
In chloroform at 25℃; for 12h; | 96% |
In diethyl ether at 20℃; Inert atmosphere; Molecular sieve; |
2-bromo-4-chlorophenol
3-Carboxyphenylboronic acid
5'-chloro-2'-hydroxybiphenyl-3-carboxylic acid
Conditions | Yield |
---|---|
With palladium diacetate; sodium carbonate In water at 50℃; for 4h; Inert atmosphere; | 95% |
With palladium diacetate; sodium carbonate In water at 50℃; for 19h; Inert atmosphere; |
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In water; acetonitrile at 160℃; for 1h; Inert atmosphere; Microwave irradiation; | 95% |
3,5-dibromopyridine
3-Carboxyphenylboronic acid
3,3’-(pyridine-3,5-diyl)dibenzoic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In acetonitrile at 90℃; for 36h; Suzuki Coupling; Inert atmosphere; | 93% |
p-bromobenzamide
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; sodium carbonate In water at 100℃; for 4h; Suzuki Coupling; | 93% |
2,3-dimethyl-2,3-butane diol
3-Carboxyphenylboronic acid
3-carboxyphenylboronic acid pinacol ester
Conditions | Yield |
---|---|
In toluene for 12h; Reflux; Inert atmosphere; | 92% |
In ethyl acetate for 4h; | 91% |
With 1H-imidazole; iron(III) chloride In water; acetonitrile at 20℃; for 0.5h; | 21.5% |
In ethyl acetate for 4h; Inert atmosphere; |
3-Carboxyphenylboronic acid
3-Carboxyphenol
Conditions | Yield |
---|---|
With copper(II) ferrite; water; sodium hydroxide at 40℃; for 24h; Green chemistry; | 92% |
With oxygen; triethylamine In water; acetonitrile at 25℃; for 8h; UV-irradiation; | 86% |
With oxygen; N-ethyl-N,N-diisopropylamine; [5,6]fullerene-C70 In chloroform; toluene at 20℃; for 12h; Irradiation; | 66% |
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,4-dioxane; water at 75 - 80℃; for 2h; Suzuki Coupling; Inert atmosphere; | 92% |
2-bromo-6-nitro-phenol
3-Carboxyphenylboronic acid
2'-hydroxy-3'-nitro-biphenyl-3-carboxylic acid
Conditions | Yield |
---|---|
With palladium on activated charcoal; potassium carbonate In methanol; water for 6h; Inert atmosphere; Reflux; | 92% |
3-Carboxyphenylboronic acid
2-bromopyrimidine
3-(pyrimidin-2-yl)benzoic acid
Conditions | Yield |
---|---|
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In acetonitrile at 90℃; for 4h; Substitution; Suzuki reaction; | 91% |
2-bromo-5-nitropyridine
3-Carboxyphenylboronic acid
3-(5-nitropyridin-2-yl)benzoic acid
Conditions | Yield |
---|---|
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene for 48h; Suzuki Coupling; Heating / reflux; | 91% |
2-bromo-4-chlorophenol
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
Stage #1: 2-bromo-4-chlorophenol With potassium hydroxide In 1,2-dimethoxyethane; water Inert atmosphere; Stage #2: 3-Carboxyphenylboronic acid With 5%-palladium/activated carbon; potassium carbonate In 1,2-dimethoxyethane; water at 18 - 40℃; Inert atmosphere; | 90.7% |
(6-chloro-2-methoxy-pyrimidin-4-yl)-[2-(4-methoxy-phenyl)-ethyl]-amine
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
Stage #1: (6-chloro-2-methoxy-pyrimidin-4-yl)-[2-(4-methoxy-phenyl)-ethyl]-amine; 3-Carboxyphenylboronic acid With caesium carbonate In 1,2-dimethoxyethane; water for 0.0833333h; Stage #2: tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water at 90℃; for 17h; | 90.4% |
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water at 90℃; for 17.0833h; | 90.4% |
1-bromo-2-naphthylamine
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; palladium diacetate; sodium carbonate; potassium carbonate; disodium ethylenediamine tetraacetic acid In water for 16h; Reflux; Inert atmosphere; | 90.4% |
3-Carboxyphenylboronic acid
5-bromosalicyclaldehyde
Conditions | Yield |
---|---|
With palladium bis[bis(diphenylphosphino)ferrocene] dichloride; caesium carbonate In water; N,N-dimethyl-formamide at 100℃; for 4h; | 90.2% |
3-Bromopyridine
3-Carboxyphenylboronic acid
3-(pyridine-3-yl)benzoic acid
Conditions | Yield |
---|---|
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In acetonitrile at 90℃; for 16h; Substitution; Suzuki reaction; | 90% |
With potassium carbonate; bis-triphenylphosphine-palladium(II) chloride In water; acetonitrile Reflux; | 83% |
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium carbonate In 1,2-dimethoxyethane; water at 100℃; for 4h; Suzuki Coupling; Inert atmosphere; | 70% |
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In acetonitrile at 90℃; for 36h; Suzuki Coupling; Inert atmosphere; | 22% |
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In acetonitrile at 90℃; for 14h; |
3-Carboxyphenylboronic acid
cyclopentyl N-[3-(dihydroxyboryl)benzoyl]-2-methylalaninate
Conditions | Yield |
---|---|
Stage #1: 3-Carboxyphenylboronic acid With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0℃; for 0.333333h; Stage #2: cyclopentyl 2-amino-2-methylpropanoate hydrochloride In dichloromethane at 20℃; for 4h; | 90% |
3-bromobenzamide
3-Carboxyphenylboronic acid
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; sodium carbonate In water at 100℃; for 4h; Suzuki Coupling; | 90% |
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